Approved for public release; distribution is unlimited / Design requirements for a small satellite (NPSAT-1) Attitude Determination and Control Subsystem (ADCS) is a three-axis stabilized spacecraft which requires a control attitude of +/- 1.0 degrees and knowledge attitude of +/- 0.1 degree. Several design aspects are considered in development of attitude control systems for a small satellite, such as: spacecraft dynamics, space environment, disturbance torques, orbit type, and spacecraft complexity. The ideal spacecraft's attitude sensor is a rate gyroscope, which provides rate information to the attitude control system. In the case of NPSAT-1, due to budget constraints alternative sensors will be utilized, such as: a three-axis magnetometer, earth sensors, and a Global Positioning System (GPS). A small satellite designed to have a three-axis stabilized, biased momentum system, must have a robust control system and requires a momentum wheel to provide stiffness to maintain attitude, and magnetic torque rods on each axis. The current design of NPSAT-1 uses all of these sensors to provide rate information for damping and stability to the control system that requires a complicated attitude control design. The purpose of this attitude control design simulation is to investigate and propose a control law utilizing a single pitch momentum wheel and three magnetic torque rods. A further proposal is to utilize a constant speed momentum wheel to avoid momentum damping and over speed, replace the pitch control with magnetic torquers, and develop a Kalman filter estimator to provide all the required angular rates. / Lieutenant Commander, United States Navy

The olefin metathesis reaction has become one of the most powerful carbon-carbon bond forming reaction in synthetic chemistry. This work has expanded the utility of olefin metathesis in metal coordination spheres in three major directions (1) the synthesis and characterization of trans-spanning bis(pyridine)PtCl2 complexes, (2) the developme-adducts of polyacetylene (PA), and (3) the development of regioregular -adducts of poly(phenylene-vinylene) (PPV). Chapter I gives a brief overview of olefin metathesis and previous applications to organometallic substrates. Chapter II details the synthesis of pyridine ligands containing alkenyl substituents, 2-NC5H4(CH2O(CH2)nCH=CH2) (n = 1, 2), 3-NC5H4(CH2O(CH2)nCH=CH2) (n = 1-5, 8, 9), and 3,5-NC5H3(p-C6H4O(CH2)7CH=CH2)2. Metalation of the new ligands with PtCl2 affords the corresponding trans-bis(pyridine)dichloroplatinum complexes, trans-PtCl2(2-NC5H4(CH2O(CH2)nCH=CH2))2 (n = 1, 2), trans-PtCl2(3-NC5H4(CH2O(CH2)nCH=CH2))2 (n = 1-5, 8, 9), and trans-PtCl2(3,5-NC5H3(p-C6H4O(CH2)7CH=CH2))2. Ring-closing metathesefirst generation catalyst followed by hydrogenations with Pd/C afford the title complexes trans-PtCl2-(NC5H4(CH2O(CH2)2n+2OCH2)H4C5N)] (n = 1, 2), trans-PtCl2-(NC5H4(CH2O(CH2)2n+2OCH2)H4C5N)] (n = 4, 8, 9), and trans-PtCl2-(NC5H3(p-C6H4O(CH2)12O-p-C6H4)2H3C5N)]. Reactions with methylmagnesium bromide afford trans-PtCl(CH3)(3-NC5H4(CH2O(CH2)nCH=CH2))2 (n = 2, 8) and trans-PtCl(CH3-(NC5H4(CH2O(CH2)nOCH2)H4C5N)] (n = 10, 18), which feature dipolar rotators. Low temperature NMR spectra in the latter remained facile on the NMR time scale in CDFCl2 at -120 degrees Celsius. Chapter III focuses on the application of ROMP with organometallic monomers to form metal pi-adducts of polyacetylene. The new complex (n4-benzene)Cp*Ir has been synthesized, crystallographically characterized, and evaluated in the ROMP reaction. Monomers (n4-benzene)CpIr, [(n6-COT)CpRu][PF6], and (n4-COT)Fe(CO)3 were also evaluated in the ROMP reaction. ROMP of (?4-benzene)CpIr with Grubbs' first generation catalyst afforded the conductive regioregular polymer CpIr-PA. Chapter IV focuses on the synthesis of the divinyl benzene complexes [Cp*Ir(C6H4(CH=CH2)2)][BF4]2 and [Cp*Ru(C6H4(CH=CH2)2)][OTf] and their polymerization via ADMET to afford PPV systems. Treatment of divinyl benzene ed the conductive regioregular polymers [Cp*Ir-PPV][BF4]2n and [Cp*Ru-PPV][OTf]n. The photophysical properties of the new -metal adducts of PPV exhibit blue-shifts relative to typical PPVs and retain strong UV absorption.

Thesis (M. Eng.)--Carleton University, 2001. / Includes bibliographical references p. (115-117). Also available in electronic format on the Internet.

Thesis--Auburn University, 2009. / Abstract. Vita. Includes bibliographic references (p.75-76).

Thesis (M.S. in Applied Science (Physical Oceanography))--Naval Postgraduate School, June 2005. / Thesis Advisor(s): Anthony J. Healey, Edward B. Thornton. Includes bibliographical references (p. 49). Also available online.

Orientador: Elnatan Chagas Ferreira / Dissertação (mestrado) - Universidade Estadual de Campinas, Faculdade de Engenharia Eletrica de de Computação / Made available in DSpace on 2018-08-14T09:49:48Z (GMT). No. of bitstreams: 1 Watanabe_RodrigoHorikawa_M.pdf: 3063258 bytes, checksum: be7be3e3a64afd0f71a2a09a1c4642f4 (MD5) Previous issue date: 2009 / Resumo: Os girômetros a fibra óptica são partes importantes de um sistema de navegação inercial. Para atingir as especificações necessárias para aplicações em sistemas inerciais, é indispensável que o demodulador eletrônico do sinal de Sagnac seja construído com componentes eletrônicos do estado da arte.A proposta deste trabalho é realizar o estudo e o desenvolvimento de uma técnica de compensação da deriva de temperatura no circuito eletrônico do girômetro, afim de melhorar a performance do mesmo. Para emulação do circuito óptico, foi desenvolvido um software em LabVIEW. O software controla um gerador de onda arbitrarias e calcula a saída do fotodiodo através da formulação teórica. Os resultados da emulação quando comparados com os valores teóricos do sinal de Sagnac apresentaram um erro de apenas §0; 02%. Foi desenvolvido também um sistema de calibração que utiliza a técnica look-up-table para compensação da deriva térmica, estabilidade do fator de escala e para linearização do circuito de condicionamento de sinais. Os resultados obtidos com as compensações se mostraram bastante importantes, melhorando a deriva do bias de 0; 15±=h para 0; 065±=h em uma faixa de temperatura de 35±C à 75±C; estabilidade do ganho de §1000ppm para §175ppm em uma faixa de temperatura 35±C à 75±C e a linearidade da resposta do circuito eletrônico de 3% para 0; 03%. / Abstract: Fiber Optic gyroscopes are an important part of inertial navigation systems. To meet the necessary specifications required for application in inertial systems, it is mandatory that the electronic Sagnac demodulator uses state of the art devices. The proposal of this work is to study and develop a technique to correct all together for the nonlinearities, the bias drift and scale factor stability, found in gyroscope electronic circuits, in order to improve the gyroscope performance. An optical circuit emulator, was developed using a software written in LabVIEW. The software controls an arbitrary wave generator and calculate the optical circuit output signal using a theoretical formulation. The results of the emulated signal are compared with theoretical values of a Sagnac interferometer and presents only §0; 02% difference error. It was developed a new calibration system that uses look-up-table technique to compensate for the thermal drift and correct the circuit non-linearities. This correction technique improves bias drift from 0; 15±=h to 0; 065±=h, for the temperature range 35±C to 75±C; scale factor stability from §1000ppm to §175ppm, for the temperature range 35±C to 75±C and linearity from 3% to 0; 03%. / Mestrado / Eletrônica, Microeletrônica e Optoeletrônica / Mestre em Engenharia Elétrica

M.Ing. / Vehicle attitude is the most significant of the navigational parameters in terms of its influence on accumulated dead reckoning errors. To determine the attitude of the host vehicle body, with respect to the earth, it is necessary to keep track of the orientation of the body axes with respect to the local earth navigational frame (north, east and down). The aim of this research is to investigate the feasibility and the enhancement of low cost inertial sensors (such as gyroscopes) by the addition of magnetometer and pitch and roll angle sensors. The focus of this research is on the use of low cost inertial measurement systems to determine the attitude of a vehicle body. Strapdown system principles and the estimation theory are applied to achieve this goal. Both Euler angles and Quatemions as attitude representation are implemented and compared with one another. Work is concentrated around the mathematical models for low cost sensors and the attitude system dynamics. A sensor cluster is constructed using three gyroscopes, a magnetometer and two inclinometers. These inertial sensors were integrated using a Kalman filter. The mathematics, calculations and principles used are universal for all attitude systems. Practical data was recorded after which it was filtered to illustrate the working of the Kalman filter. The addition of a magnetometer and two inclinometers are indeed feasible for enhancing the attitude obtained from the inertial sensors. The benefit associated with the gyroscopes, when the magnetometer readings are disturbed by external magnetic anomalies, where small and of little significance. This thesis fully describes the theory and approach followed to implement the Kalman filter, making this a good example of a Kalman filter implementation, especially with the MATLAB software realisation presented in the appendix.

Thesis (MScEng (Mechanical and Mechatronic Engineering))--University of Stellenbosch, 2008. / This thesis aims to contribute to the modelling and analysis of MEMS gyroscope technologies. Various gyroscope types are studied, and the phase-based vibratory gyroscope is then selected for further investigation. In the literature, vibratory MEMS gyroscopes are mostly used in a single excitation and amplitude detection mode. However, a dual excitation and phase detection mode has recently been proposed, since phase-based detection, as opposed to amplitude-based detection modes, may be expected to increase measurement accuracy (in turn since improved signal-to-noise ratios may be expected). However, the presented analytical model was relatively crude, and the assumptions made appear unrealistic. Accordingly, in this thesis, an improved analyticalmodel is developed. To describe the dual excitation and phase detection problem more comprehensively, principles of classical dynamics are used herein to investigate the dual excitation of a two degree of freedom spring-mass-damper system subjected to an applied rotation rate. In doing so, an analytical formulation including mechanical coupling effects is extended into a generalized form, after which the amplitude and phase responses of the mechanically uncoupled system are interpreted. The differences between the amplitude and phase measurement techniques are illustrated. Finally, the system is modelled numerically, and the scale factor of a hypothetical device based on the phase-based detection method is optimized, subject to constraints on the nonlinearity of the device, using constrained mathematical optimization techniques.

Devices that exploit the properties of quantum mechanics for their operation can offer unique advantages over their classical counterparts. Interference of matter waves can be used to dramatically increase the rotational sensitivity of gyroscopes. Complete control of the quantum evolution of a system could produce a new powerful computational device known as a quantum computer. Research into these technologies offers a deeper understanding of quantum mechanics as well as exciting new insights into many other areas of science. Currently, a limiting factor in many quantum devices using neutral atoms is accurate motional control over the atoms. This thesis describes two recent advancements in neutral atom motional control using both magnetic and electromagnetic confining fields. Part I reports on the demonstration of the first storage ring for neutral atoms. This storage ring may one day provide the basis for the world's most sensitive gyroscope. Part II describes the optical delivery of neutral atoms into the mode of a high-finesse cavity for applications in quantum computing and communication.

Micromachined gyroscopes are attractive replacements to conventional macro-mechanical and optical gyroscopes due to their small size, low power and low cost. The application domain of these devices is quickly expanding from automotive to aerospace and consumer electronics industries. As potential high volume consumer applications for micromachined gyroscopes continue to emerge, design and manufacturing techniques that improve their performance, shock survivability and reliability without driving up the cost and size become important. Today, state-of-the-art micromachined gyroscopes can achieve high performance with low frequency operation (3-30kHz) but at the cost of large form factor, large operating voltages and high vacuum packaging. At the same time, most consumer applications require gyroscopes with fast response time and high shock survivability, which are generally unavailable in low frequency gyroscopes. As a result, innovative designs and fabrication technologies that will offer more practical gyroscopes are desired. In this dissertation, capacitive bulk acoustic wave (BAW) silicon disk gyroscopes are introduced as a new class of micromachined gyroscope to investigate the operation of Coriolis-based vibratory gyroscopes at high frequency and further meet consumer electronics market demands. Capacitive BAW gyroscopes, operating in the frequency range of 1-10MHz are stationary devices with vibration amplitudes less than 20nm, resulting in high device bandwidth and high shock tolerance. They require low operating voltages, which simplifies the interface circuit design and implementation in standard CMOS technologies. They also demonstrate appropriate thermally stable performance in air, which eliminates the need both for vacuum packaging and for temperature control. A revised high aspect ratio poly- and single crystal silicon (HARPSS) process was utilized to implement these devices in thick SOI substrates with very small capacitive gap sizes (~200 nm). The prototype devices show ultra-high quality factors (Q>200,000) and large bandwidth of 15-30Hz. In addition, the design and implementation of BAW disk gyroscopes are optimized for self-matched mode operation. Operating a vibratory gyroscope in matched mode is a straightforward way to improve performance parameters but, is challenging to achieve without applying large voltages. In this work, self-matched mode operation was provided by enhanced design of the perforations of the disk structure. Furthermore, a multi-axis BAW gyroscope, an extension of the z-axis, is developed. This novel approach avoids the issues associated with integrating multiple proof masses, permitting a very small form factor. The multi-axis gyroscopes operate in out-of plane and in-plane modes to measure the rotation rate around the x- and z-axes. These gyroscopes were also optimized to achieve self-matched mode operation in their both modes.