Outdoor electrical insulator is one of the important components of a power system which directly influences the system reliability. Traditionally ceramic insulators have been used for close to a century in both transmission and distribution lines. In the last few decades, polymer based outdoor insulators are being increasingly used in the above application. Polymeric insulators offer attractive advantages such as light weight, resistance to vandalism and they also outperform conventional ceramic insulators under contaminated wet conditions at least in the initial stages of their usage. However, there are certain disadvantages with polymeric insulators which have made the utilities hesitant to replace readily the ceramic insulators with polymeric insulators. One of the major concerns with the polymeric insulators is the aging w.r.t time due to the presence of multiple environmental stresses (fog, humidity, temperature, rain as well as contamination due to industrial, sea and agricultural pollution) along with electrical stress. The manifestations of the aging of insulators include tracking or/and erosion of the weathersheds. Polymers in pure form (unfilled) can not perform satisfactorily all the required functions (electrical, mechanical, thermal etc.) of an insulator used in such high voltage transmission lines. Polymers have inherently poor thermal stability. Thermal stability directly influences the tracking and erosion resistance of the weathershed. Without adequate tracking and erosion resistance, polymeric insulators can not perform satisfactorily under contaminated wet conditions. Hence the common practice to improve the tracking and erosion resistance (and other properties such as mechanical, thermal) is by filling the base polymer with large loadings (> 30 wt %) of micron sized fillers. This makes the processing of the polymer composite difficult as the viscosity of the material rises substantially at such large loadings. Due to the large filler loadings beyond a certain limit, the flexibility of the end product also suffers. Though tracking and erosion resistance of the polymer has been improved substantially at these large filler loadings, the recent failures in the field suggest the need for an alternate material with higher tracking and erosion resistance than what is achieved at these large loadings of micron sized fillers. Of late nanocomposites are emerging as promising alternatives which can offer the above mentioned functionalities at low filler loadings itself without sacrificing the flexibility in the end product as well as ease of processing. There are even indications suggesting that the tracking and erosion resistance performance is better than what is obtained using micronsized fillers. As the development of nanocomposite dielectrics/insulation is still at its infancy, it is required to investigate their specific properties needed for outdoor applications and to understand the various mechanisms responsible for the interesting behaviour of the nanocomposites. Also, it is known that dc pollution performance of ceramic insulators is much inferior to the performance under ac stress. With the introduction of higher ac/dc transmission voltages in many countries including India, it is required to design insulators with better performing materials so as to get a reliable performance under polluted wet conditions. Due to the hydrophobic nature of the polymers, it is believed that polymers especially silicone rubber insulators can perform better as compared to the ceramic insulators under polluted conditions under ac and dc. As the dc tracking and erosion (T&E) resistance of polymer is poor compared to the ac tracking and erosion resistance, it is required to investigate the T&E resistance characteristics of the nanocomposites under dc stress. In addition, due to the enhanced electric fields at the line end of the insulators in extra and ultra high voltage transmission lines, there is always a possibility of corona generation on the hardware at the metal-sheath junction and at the water droplet tips on the weathersheds of the polymeric insulators especially under foul weather conditions. It is reported that the long-term exposure to such corona has the potential to degrade the polymeric material. The effects include reduction of the hydrophobicity, surface oxidation of the weathersheds and development of microcracks on the surface of the polymeric material. These cracks (corona cutting) can worsen the wet pollution performance of the insulator. If the cracks grow deeper, then FRP rod would get exposed to the atmospheric conditions leading to brittle fracture of the FRP rod and finally resulting in the line drop. Hence, the corona aging resistance of nanocomposites has also been studied especially at low filler concentrations to see its performance under the above mentioned adverse conditions. Therefore, the research work presented here deals with three aspects of the aging (1) Study the ac and dc tracking and erosion resistance performance of silicone rubber nanocomposites with low concentrations of fillers and their suitability for outdoor applications (2) Study the corona aging performance of silicone rubber nanocomposites with low concentrations of fillers and (3) To develop a model to explain the unusual behaviour of nanocomposites observed in the above studies. The thesis also reports results of the accelerated multistress weathering studies conducted on normal polymeric outdoor insulators under prolonged dry conditions. The major challenge in case of the polymer nanocomposite processing is getting uniform distribution of the fillers. A protocol has been standardised for the processing which comprises high shear mechanical mixing followed by sonication to get good dispersion of the fillers. Room Temperature Vulcanised (RTV) silicone rubber was successfully processed with different micron and nanosized fillers and with different weight (wt.) percentages in the present work. For carrying out the T & E resistance, corona aging and multistress aging studies, facilities (such as Inclined Plane T & E Resistance Test Apparatus in line with IEC/ASTM standards and aging chambers) have been designed and developed in house as a part of the thesis work. The ac tracking and erosion resistance performance of the unfilled, microcomposite (filled with alumina trihydrate filler of 5, 10, 15, 20 and 30 % by wt) and nanocomposite (filled with alumina, silica and magnesium hydroxide fillers of 2.5 and 4 % by wt) have been compared in inclined plane (IP) tracking and erosion resistance test facility specifically developed for the work. It was very interesting to observe that nanocomposites at 4 % performed on par with the microcomposites at 30 % filler loadings. Leakage current was also measured during the IP test and it was found that the form factor (ratio of r.m.s to average leakage current) was in good agreement with the variation in the erosion resistance of the silicone rubber composites and hence it can be used as a diagnostic tool for assessing the aging state of the polymeric materials. It was also observed that the performance under positive dc stress was much inferior to the performance under ac stress. The dissipation of power under dc stress was estimated by measuring the leakage current through the sample and is found to be about four times (towards the end of the test) higher as compared to the power dissipation under ac stress. Intense electrolytic corrosion has been observed (under positive dc) on the grounded electrode and on the sample and chemical studies of the same have been carried out. The poor performance under dc is due to the absence of the voltage zero crossing, more accumulation of the contaminant (scaling) and electrolytic corrosion. It was also observed that to get the same tracking and erosion resistance under dc as in the case of ac during IP test, dc stress levels have to be reduced to about 60 % of the ac stress. This information would be helpful to the design engineer of the outdoor insulators for the HVDC transmission lines. To understand the different mechanisms responsible in improving the tracking and erosion resistance of the micro and nanocomposites, thermal, SEM and FTIR studies have been carried out. Thermal stability of the samples was measured using thermogravimetric analysis (TGA) and differential thermo gravimetric (DTG) studies. It was observed that thermal stability of nanocomposites even at low filler loadings (4 wt %) was comparable with the microcomposites at higher filler loadings (30 wt %). SEM studies indicate that the barrier resistance (against discharges) offered by the fillers in the nanocomposites even at low filler loadings (4 %) could be comparable with the microcomposites at higher filler loadings (30 %). The interaction between the fillers and the host matrix has been studied using various techniques. SEM studies done on the eroded regions of the composites revealed that a honey comb type formation had taken place on the nanocomposites during the IP test which was believed to be due to the interaction of the filler and the polymer. This honey comb structure formation at the eroded site in the nanocomposites greatly helps to protect the sample from further damage due to the discharges. The interaction at the interface between the polymer and fillers could also lead to further improvement in the thermal stability of the nanocomposite. A model was proposed which considers barrier resistance and a single-layer interaction around the fillers to explain the improvements offered by the nanocomposites. Corona aging studies have been carried out on unfilled silicone rubber, micro and nanocomposites for 25 h and 50 h of aging using a needle-plane electrode arrangement. Different parameters such as hydrophobicity, surface roughness, microcracks width on the aged surface, FTIR and SEM studies were carried out to study the corona aging resistance of the new and aged samples. The studies indicate that silicone rubber samples containing nanofillers at 3 wt % are able to impart significantly enough corona resistance compared to the unfilled and microcomposite samples. It is known that the discharge resistance offered by the fillers and the interaction/bonding between the fillers and polymers directly influences the corona aging resistance. Hence, the model proposed (discussed above) is valid for understanding the corona aging performance of the nanocomposites which is better than the unfilled and ATH filled silicone rubber. In addition to the tracking and erosion resistance and corona aging studies, multistress aging of commercially available polymeric insulators containing micron sized fillers has been carried out. The aging behaviour of the polymeric insulators under tropical and subtropical conditions (in the absence of discharges under wet conditions) has not been explored. Further, the long-term influence of the UV radiation on silicone rubber in the presence of temperature and electric stress is also not explored. Hence, to understand the aging phenomena (weathering characteristics) under multistress (electric, thermal and UV), distribution class composite polymeric insulators were aged for 30,000 h in a multistress aging chamber developed specifically for the studies. Insulators were continuously subjected to the accelerated electric and thermal stresses as well as UV radiation. Different studies like leakage current, SEM, hydrophobicity, surface roughness and low molecular weight (LMW) molecules content in the samples before and after the aging have been investigated. It is interesting to observe that even in the absence of electrical discharges on the surface of the material, significant monotonous reduction in LMW molecules has been observed w.r.t weathering time. Appreciable increase in the surface roughness (at least 200 % as that of the new material) as well as increased oxygen levels on the surface has also been observed. The results indicate that surface hydrophobicity is dynamic in nature and may not reflect the slow and permanent changes taking place in the bulk of the material. The results obtained for the nanocomposites enable us to design a better material with improved tracking, erosion and corona resistance without sacrificing the flexibility in the end product as well as ease of processing. The silicone rubber nanocomposites also open up the possibility for economically designing a smart material possibly with a higher reliability for outdoor insulator application.

Thesis (MScEng)--Stellenbosch University, 2012. / ENGLISH ABSTRACT: The use of high voltage direct current (HVDC) applications has gained enormous popularity for long distance power transmission. This is due to the lucrative benefits offered by this type of power transmission technology when compared to the traditional high voltage alternative current (HVAC). This new shift in the paradigm of power system design has led to the increased interest in the research that focuses on issues relating to the reliability of power supply associated with HVDC. Amongst such issues, insulation coordination has increasingly become a challenging task that continues to receive renewed research focus. It has been convincingly demonstrated, both from field experience and laboratory research, that insulator contamination constitutes a multifaceted phenomenon, especially when transmission voltages ramp up into high operating voltage levels. More so, this is particularly interesting with reference to the increasing applications of high voltage direct current (HVDC). The recently commissioned HVDC power-line in Namibia is one of the major motivations upon which NamPower (Namibia‟s national power utility) has committed financial resources to research on insulator pollution performance. This project was a part of NamPower‟s research initiative – seeking to investigate the phenomena associated with insulator pollution performance under natural pollution environments when energized under both AC and DC excitation voltage types. The significance of this research is especially crucial for HVDC applications given the paucity of research conducted on the DC performance of insulators, under natural pollution environments. This study was conducted at the Koeberg Insulator Pollution Test Station (KIPTS) on the west coast of Cape Town in the Western Cape province of South Africa. KIPTS is an internationally recognized insulator pollution test facility, which is widely used by both insulator manufacturers and academic researchers from many parts of the world. STRI and ABB, both Swedish-based companies, are good examples of international subscribers to the KIPTS research facility. The first objective of this research was to design a suitable DC excitation voltage system for both DC+ and DC- to be used at KIPTS. This apparatus was designed and built at the University of Stellenbosch. The second objective was to conduct a comparative evaluation of the performance of high temperature vulcanized silicone rubber (HTV-SR) power line insulators under AC, DC+ and DC- when subjected to natural pollution conditions at KIPTS. All test insulators were made from the same material and sourced from the same manufacturer – having different creepage lengths. Five different creepage lengths were considered for each excitation voltage – summing up to fifteen HTV-SR test samples. A standard DC glass disc insulator was also installed on each excitation voltage as a control sample. It was therefore envisaged that this study would give rise to new research questions, leading to future explorations on the subject. With reference to weather monitoring and leakage current measurements (using an online leakage current monitoring device - OLCA), a correlation was found to exist between the variations in climatic conditions and the corresponding occurrence of leakage current on the insulator surfaces. High leakage current levels were recorded in summer due to the high pollution levels that were measured in that season (using the equivalent salt deposit density (ESDD) approach). Winter, in contrast, had lower levels of leakage current recorded. This corresponds to a high prevalence of rainfall in winter, which caused occasional natural washing of the insulator surfaces. The leakage current levels for the HTV-SR insulators were of a similar order of magnitude for AC and DC+ and lower for DC-. The harshest pollutants (with high conductivities, as measured with the directional dust deposit gauges (DDDG)) were found to have emanated largely from the south. As a result, most instances of erosion were observed in the southward direction on the test insulators. The electrical discharge activity observations, conducted at night, had revealed that dryband corona (DBC) and dryband discharge (DBD) prominently occurred on the terminating sheaths (both live and ground ends) and bottom side of HTV-SR and glass disc insulators, respectively. This justifies the dominance of erosion that was observed on the terminating sheaths and bottom side of HTV-SR and glass disc insulators, respectively. Flashover events were recorded on the shortest HTV-SR insulator installed on DC+ and the glass disc insulator installed on DC-. All flashover events occurred in summer (the harshest season at KIPTS). Two interesting observations, albeit unexplained, were observed: star-shaped erosion on the shed bottoms of the HTV-SR insulators installed on DC+ and material peel-off at the shed-to-sheath bonding interface of the HTV-SR insulators installed on DC-. These observations therefore require further investigation in order to establish possible explanations. / AFRIKAANSE OPSOMMING: Die gebruik van hoë gelykspanning (HSGS) het baie gewild geword vir kragtransmissie oor lang afstande. Dit is as gevolg van die uitstekende voordele wat hierdie tipe tegnologie teenoor die tradisionele hoë wisselspanning (HSWS) bied. Hierdie paradigmaskuif in die ontwerp van kragstelsels het tot verhoogde belangstelling in navorsing gelei wat betrekking het op aspekte wat verband hou met die betroubaarheid van kragvoorsiening deur HSGS. Van hierdie aspekte word isolasiekoördinasie toenemend ʼn uitdagende taak en navorsing word tans daarop toegespits. Daar bestaan oortuigende bewyse, gebaseer op laboratorium- en veldtoetse dat isolatorbesoedeling ʼn verskynsel met vele fasette is, veral wanneer hoër spannings gebruik word. Dit is in „n meerdere mate van belang met verwysing na toepassings van HSGS. Die onlangs inbedryfgestelde HSGS kraglyn in Namibië is een van die hoofmotiverings vir die verskaffing van geldelike steun deur NamPower (Namibië se nasionale kragvoorsiener) vir navorsing oor die besoedelingsprestasie van isolators. Hierdie projek is deel van NamPower se navorsingsinisiatief om verskynsels betreffende die besoedelingsprestasie van isolators in natuurlik-besoedelde omgewings te ondersoek, onder WS en GS-bekragtiging. Die betekenis van hierdie navorsing is veral belangrik vir die HSGS-toepassings in die lig van die skaarsheid van navorsing oor die GS-prestasie van isolators in natuurlik-besoedelde omgewings. Hierdie studie is gedoen by die Koeberg isolatorbesoedelingstoetsstasie (KIPTS) aan die weskus van die Wes-Kaap. KIPTS is 'n internasionaal-erkende toetsfasiliteit en word algemeen gebruik deur beide isolatorvervaardigers en akademiese navorsers uit baie dele van die wêreld. STRI en ABB, albei Sweeds-gebaseerde maatskappye, is die goeie voorbeelde van die internasionale gebruikers van die KIPTS navorsingsfasiliteit. Die oogmerk van hierdie navorsing was om eerstens 'n geskikte GS-kragbron vir beide die GS+ en die GS- vir gebruik by KIPTS te ontwerp. Hierdie apparaat is ontwerp en gebou deur die Universiteit van Stellenbosch. Tweedens is 'n vergelykende evaluering van die prestasie hoë temperatuur gevulkaniseerde silikoon (HTV-SR) kraglynisolators onder WS, GS+ en GS– onder natuurlike besoedeling by die KIPTS uitgevoer. Alle toetsisolators is van dieselfde materiaal gemaak en is afkomstig van dieselfde vervaardiger, maar het verskillende kruipafstande. Vyf verskillende kruipafstande is gebruik vir elke tipe spanning  'n totaal van vyftien HTV-SR toets monsters. 'n Standaard GS glasisolatorskyf is ook vir elke spanning as' n kontrolemonster geïnstalleer. Dit kan dus verwag word dat hierdie studie aanleiding sal gee tot nuwe navorsingsvrae, wat kan lei tot verdere toekomstige ondersoeke oor die onderwerp. Met verwysing na die monitering van die weer en die lekstroommetings (met behulp van 'n aanlyn-lekstroommoniteringstoestel - OLCA), is 'n korrelasie gevind tussen die variasie in klimaatstoestande en die ooreenstemmende voorkoms van lekstroom op die isolator- oppervlaktes. Hoë lekstroomvlakke is waargeneem in die somer, as gevolg van die hoë besoedelingsvlakke wat in daardie seisoen gemeet is (met behulp van die ekwivalente soutneerslag-digtheid (ESDD) metode). In die winter, in teenstelling, is die laagste vlakke van lekstroom aangeteken. Dit stem ooreen met 'n hoë voorkoms van reënval in die winter, wat die isolatoroppervlaktes van tyd tot tyd natuurlik gewas het. Die lekstroomvlakke op die HTV-SR isolators was van soortgelyke ordegrootte vir WS en GS+ maar laer vir GS-. Dit is bevind dat die ergste besoedelingstowwe, met 'n hoë geleiding, soos gemeet met die rigtingsensitiewe stofneerslagsmeters (DDDG), hoofsaaklik uit ʼn suidelike rigting kom. As gevolg hiervan, is die meeste gevalle van erosie aan die suidekant van die toetsisolators waargeneem. Die waarneming van elektriese ontladingsaktiwiteit in die nag, het aan die lig gebring dat droëbandkorona (DBC) en droëbandontladings (DBD) prominent voorgekom het op die skedes aan die uiteindes (beide lewende en grond kante) en onderste kant van HTV-SR en glasskywe, onderskeidelik. Oorvonkings is waargeneem op die kortste HTV-SR isolator op GS+ en op die glasisolator op GS-. Al die oorvonkings het in die somer (die ergste seisoen by KIPTS) voorgekom. Twee interessante, dog onverklaarbare, verskynsels is waargeneem: stervormige erosie aan die onderkante van die skerms van die HTV-SR isolators op GS+ en material-afskilfering by die skerm-skede tussenvlak van die HTV-SR isolators op GS-. Hierdie verskynsels vereis verdere ondersoek ten einde moontlike verklarings vas te stel.

This thesis presents a unique design for an infrared spectrometer based on a MEMS Binary Fresnel Zone Plate for the purpose of assessing the health of oil-impregnated high voltage (HV) equipment. It does so by measuring dissolved gases within it. These gases include carbon monoxide, carbon dioxide, methane, ethane, ethylene, and acetylene. These gases are currently measured using numerous technologies such as gas combustion, gas chromatography, photoacoustic spectroscopy, and FTIR spectroscopy. Each of these technologies have their advantages and disadvantages. The design presented in this thesis consists of an analysis of how the various Binary Zone Plate parameters affect its spectral resolution and transmission efficiency. Simulations show that increasing the number of zones and the focal length, as well as decreasing the aperture diameter, increases the spectral resolution of the spectrometer. Simulations also show that transmission efficiency is proportional to the number of zones and the aperture diameter. This thesis presents a theoretical argument for how one zone plate lens can be used to measure all dissolved gases present in HV equipment. Lenses for the visible and infrared ranges were fabricated in the University of Manitoba NSFL Cleanroom. The lenses were then tested in an optical setup. The results show that the visible light experiments were successful in achieving appropriate spectral discrimination by changing the distance between the aperture and the lens. The results from the infrared experiment show that a detector was able to discriminate between full and no incident radiation. / May 2017

This dissertation deals with research on the numerical modelling of electrical discharges in laboratory long air gaps excited with positive switching impulses. It begins with the preliminary work of several scientists during the last decades, making a detailed analysis of different approaches for modelling all the stages in a full discharge. The relations between these models are identified as well as the effect on the outcome when modifying some important input parameters. The general concept describing the discharge phenomenon usually includes three main elements: the streamer inception, the streamer-to-leader transition and the stable leader propagation. These elements are present in many of the analysed models and the main differences between them are the assumptions and simplifications made by each author at a specific point in their methodologies. The models are usually simplified by assigning experimentally determined values to physical constants pertinent to different stages of the full discharge. These constants are the potential gradient in the leader-corona region to sustain the leader propagation, the charge per unit length along the leader channel which depends on the atmospheric conditions and the voltage impulse wave shape; and the leader propagation velocity, which is closely related to the discharge current. The dissertation includes the results of laboratory work related the study of leaders in long gap discharges, electrical parameters and optical records. By reconstructing the three-dimensional leader propagation for the rod-to-plane configuration, it was possible to study the random tortuous path followed by the leader as it propagates. One important element included in the discharge modelling is the representation of the leader-corona region in front of the leader tip as it propagates towards the grounded electrode. For the calculation of the net charge available in the leader-corona region, two new methodologies were pro-posed based on the electrostatic potential distribution obtained from a finite element method solver. This allowed the inclusion of more elements representing different parts of the discharge in the simulation domain. In the final part, all the analysed elements and the new proposed ones were included in a new methodology for the modelling of electrical dis-charges in long air laboratory gaps. The results obtained from this methodology were compared to experimental data. A good agreement was found between the simulation results and the experimental data.

M. Tech. (Power Engineering Department, Faculty of Engineering and Technology) -- Vaal University of Technology / This dissertation is devoted to the study of partial discharge evaluation of a high voltage transformer. The 400 V/300 000 V (300 kV) high voltage transformer in the high voltage laboratory was manufactured in 1967. Given the old age of the transformer and the crucial importance of insulation systems, it is vital to assess the condition of its insulation to ensure the effectiveness and the reliability of the transformer as well as the safety of the personnel using it. In order to achieve that, it is important to evaluate the partial discharge in the insulation system as this is the main cause of destruction of insulation. The phase-resolved partial discharge method was the main method used to perform the partial discharge measurements in this research. Partial discharge measurements were performed on a faulty 11 kV voltage transformer. Defects were also created in samples of solid insulation at predetermined locations with different shapes and sizes. The measurements taken on the 11 kV voltage transformer and samples of solid insulation formed a basis to prove the validity of the assessment methods on the 300 kV transformer. Using the method mentioned above, partial discharges were recorded with respect to the phase of the applied voltage with the aid of a commercial instrument which complies with IEC 60270, (ICM monitor - partial discharge detector from Power Diagnostix Systems GmbH). The observations from this study have furthered the understanding of partial discharge processes. The patterns recorded were analysed in order to conclude about the condition of the transformer. From the partial discharge pattern, the type and location of partial discharges were concluded. The patterns obtained from the transformer reveal that the device is healthy and can be operated up to 200 kV.

This thesis proposes a novel algorithm to optimize multi-modal, nonlinear, black-box objective functions for electric power system design using an electromagnetic transients (EMT) simulator. The algorithm discovers multiple local optimal solutions for a given complex power system, and then generates accurate surrogate models of an objective function around each discovered local optimal solution. These surrogate models represent the local behaviour of the objective function that can be used in the subsequent stages of sensitivity analyses. Using surrogate models instead of intensive transient simulation during sensitivity analysis reduces computational intensity and simulation time. This makes the proposed algorithm particularly suited for optimization of computationally expensive black-box functions. The stages of the algorithm can be implemented independently and hence the computations can be done in parallel. Therefore, the algorithm is implemented in a parallel environment to gain significant speed-up in the design of electric power systems. Comparative studies in terms of objective function evaluation and computation time are provided. Using several multi-modal benchmark objective functions, the superiority of the proposed algorithm compared to other recently developed algorithms is demonstrated. Additionally, the application of the algorithm in the design process of complex electric power system demonstrated through several examples. The case studies show that the parallelized algorithm provides computational savings up to 39 times compared to the conventional sequential approach. / May 2016

Thesis (D. Tech. Electrical engineering) --Vaal University of Technology / A comprehensive study upon "Non-conventional methods for energy extraction from the high voltage transmission lines" was addressed in this thesis. As defined in this study, a non-conventional method to extract energy is one that does not touch the conductors of the line. The theoretical framework which originated in the Maxwell's equations was presented as a base for discussion of all the methods and the conditions for the extraction to be possible. This study presents various methods such as capacitive and inductive to extract energy from high voltage alternating current transmission lines (HVAC). Although in theory, for high voltage direct current transmission lines (HVDC), the conditions for extraction are not matched, there remain some methods that could still attract interest. The centre point of this thesis is the new power application of the Rogowski coil. This method is analysed in full extent starting from theoretical modelling, computer simulations, design of the actual Rogowski coil and power electronics associated with it, and experimental results on a reduced scale model. In doing this, strong mathematical tools and computer software such as Matlab 6, Quick Field and MathCAD were used. At the end of this thesis, some conclusions are presented together with new ideas for further research in the field.

Student Number : 9803381J - MSc Dissertation - Faculty of Engineering and the Built Environment / Although pulsed power has been used in many parts of the world over the last few decades to initiate high-voltage discharges through rock, no systematic test work on South African ore bodies and related rock types has been done so far. As part of CSIR Miningtek’s integrated approach of combining underground comminution with a novel Tore© hydrotransport system, which has been shown to operate well with coarse particles up to 10 mm, various rock types were fragmented in single discharge mode under laboratory conditions. The work was conducted at the University of the Witwatersrand’s high-voltage laboratory with a custom-designed test rig. The rig configuration was based on a critical review and analysis of the literature and on assessments of existing test facilities elsewhere. Core samples with diameters ranging from 16 to 48 mm were cut from test specimens with thicknesses ranging from 8 to 48 mm. Rock types included Ventersdorp Contact Reef, Carbon Leader, Elsburg Formation, UG2 and Merensky, as well as pure quartz, shales, lava and dykes. A six-stage Marx generator provided a voltage rise time of 2 000 kV/μs to create a discharge through the rock, in preference to a discharge through the surrounding water, which acts as an insulator at ramp-up times faster than 0,5 μs. High-speed photography, and an analysis of the voltage and current signals for various rock types and for water alone, were used to quantify the potential benefits of rock breaking by electric discharge. It was found that some Kimberlite specimens and mineralised gold-bearing reefs were much easier to fragment than hanging wall or footwall material. Merensky reef appeared to be more susceptible than the less brittle UG2 material. A correlation was derived between the dynamic resistivity of various rock types, measured at 16 MHz excitation frequency, and the electrical breakdown strength at which discharge took place. The fragments created had a more cubical shape than would be created by conventional impact crushing. However, the high voltage requirements of about 30 to 35 kV per millimetre of rock thickness would necessitate not only efficient mechanical and electrical contact between the electrodes and the rock, but also considerable safety features for underground installations. The clearly identified, preferential fracturing of reef rock types, compared with the hanging or footwall materials, suggests that the greater benefit of electric rock breaking may lie in primary rock breaking as a mining method, rather than in secondary comminution of broken rock to enable hydraulic transportation by pipeline to surface.

Nesta dissertação, é apresentado o projeto de uma interface que permite o controle e monitoramento de cargas de alta tensão alimentadas na faixa de 8,5V a 35V. A interface fornece duas funções básicas: a primeira é permitir que circuitos alimentados no domínio dos 5V controlem o chaveamento de transistores de potência PMOS com uma tensão de porta 5V abaixo da tensão de alimentação; a segunda é realizar o monitoramento de sobrecorrentes na carga de alta tensão, alertando, com um sinal de baixa tensão, estas ocorrências. A interface foi projetada e fabricada no processo CMOS XC06 - 0,6µm da XFAB, com a inclusão de módulos que permitem o uso de transistores de alta tensão. Como parte da solução proposta, foi analisado, implementado e caracterizado um regulador de tensão flutuante que gera uma tensão de saída 5V abaixo da tensão de alimentação. A área de silício do regulador é de 599µm x 330µm, e as medidas da tensão de saída gerada apresentam variações menores que 10%. Também foi projetado e integrado no mesmo circuito integrado um sensor para medir o nível da tensão flutuante do regulador e comunicar seu estado com um sinal de 5V, este bloco ocupa uma área de 599µm x µm. Este sensor apresentou um desvio padrão de 7% nas medidas da sua tensão limiar. A interface foi integrada em um sensor de proximidade indutivo, permitindo o chaveamento de uma carga de 430pF a 1,2kHz em toda a faixa de alimentação. / This work presents the design of an interface that allow to control and monitoring high voltage loads in the range of 8,5V to 35V. The interface provides two main features, the first one is to allow low voltage circuits supplied with 5V to control the switching of power PMOS transistors with a gate voltage 5V bellow the supply voltage. The second one is monitoring overcurrents on the high voltage load alerting with a low voltage signal these occurences. The interface was designed and fabricated on the CMOS XC06 - 0,6µm process from XFAB with the inclusion of modules that allow the use of high voltage transistors. As part of the proposed solution it was analyzed, implemented and measured a floating voltage regulator wich provides an output voltage 5V bellow the supply voltage. The area of the regulator is 599µm x 330µm and the measures of the output voltage presents variations under the 10%. Also it was designed and integrates in the same integrated circuit a sensor to measure the output level of the floating regulator and communicate the state of this output with a 5V signal, this block occupies an area of 599µm x 579µm. This sensor presented a 7% standard desviation on the measured voltage threashold. The interface was integrated on an inductive proximity sensor allowing the switching of a 430pF load at 1,2kHz for the entire all supply range.

"Lithium ion batteries have dominated the portable electronics market and have the potential to dominate large-scale battery applications including hybrid and electric vehicles, as well as grid storage, because of their high energy and power densities1,2. It is well known that conventional electrolytes show poor anodic stabilities above 4.5 V versus Li/Li+.3 As a result, high voltage electrolytes are essential for the development of next generation high energy lithium ion batteries. Both fluorinated electrolytes and additives can be introduced into the electrolyte system.4 In this work, fluorinated electrolytes were used in both graphite-LiNi0.5Co0.2Mn0.3O2 (NCM523) (operated between 3.0 - 4.6 V) and graphite- LiNi0.5Mn1.5O4 (LNMO) (operated between 3.5 - 4.9 V) full cell systems. The baseline electrolyte for all cells (referred to as Gen2) was composed of 1.2M LiPF6 dissolved in a mixture of EC and EMC (3:7 in weight ratio). After a series of electrochemical tests, compared to the baseline electrolyte, the fluorinated electrolytes displayed significantly enhanced performance under both high cut off voltage and high temperature (55 oC). The post test analysis results showed that the cycled electrode can not only reach a much more stable interface but also overcome the crystal structure change after long term cycling when the fluorinated electrolyte system was used. In addition to changing the solvent, a series of additives were designed, synthesized and evaluated for high-voltage Li-ion battery cells using a Ni-rich layered cathode materials LiNi0.5Co0.2Mn0.3O2 (NCM523). The repeated charge/discharge cycling for NCM523/graphite full cells using Gen2 with 1 wt % of these additives as electrolytes was performed. Electrochemical performance testing and post analysis result demonstrated that our as selected or designed cathode additives could passivate the cathode and prevent the cathode from side reactions. The developed methodology could provide fundamental direction in the design and investigation of better electrolytes for the next generation lithium ion batteries."