By allowing to measure the magnetic field distribution inside a material, muon spin rotation experiments have the potential to provide valuable information about microscopic properties of high-temperature superconductors. Nevertheless, information about the intrinsic superconducting properties of the material is masked by random thermal and static fluctuations of the magnetic field which penetrates the material in the form of vortices of quantized magnetic flux. A good understanding of the fluctuations of those vortices is needed for the correct determination of intrinsic properties, notably the coherence length &xi;, and the field penetration depth &lambda;. We develop a simulation based on the Metropolis algorithm in order to understand the effect, on the magnetic field distribution, of disorder- and thermally-induced fluctuations of the vortex lattice inside a layered superconductor. <br /><br /> Our model correctly predicts the melting temperatures of the YBa₂Cu₃O_{6. 95} (YBCO) superconductor but largely underestimates the observed entropy jump. Also we failed to simulate the high field disordered phase, possibly because of a finite size limitation. In addition, we found our model unable to describe the first-order transition observed in the highly anisotropic Bi₂Sr₂CaCu₂O_8+<em>y</em>. <br /><br /> Our model predicts that for YBCO, the effect of thermal fluctuations on the field distribution is indistinguishable from a change in &xi;. It also confirms the usual assumption that the effect of static fluctuations at low temperature can be efficiently modeled by convolution of the field distribution with a Gaussian function. However the extraction of &xi; at low fields requires a very high resolution of the field distribution because of the low vortex density.

Effects of Nb2O5 addition on the formation and properties of the Bi-based superconductors were studied. The superconducting samples were synthesized by two different methods, the solid state reaction (SSR) and ammonium nitrate melt route (ANM) to obtain information about the growth techniques. Ten samples (five with each method) with the chemical compositions of Bi1.6Pb0.4Sr2Ca2Cu3NbxOy, with x= 0.00, 0.05, 0.10, 0.20, and 0.30 were prepared. Phase identification, structural and microstructural analysis were carried out using powder X-ray diffraction method, scanning electron microscopy and energy dispersive X-ray (EDX) analysis. The transition temperature and the critical current measurements were carried out using the electromagnetic measurement system. The critical parameters of the samples were also determined by AC susceptibility and magnetization measurements. Improvements in the formation of the Bi-2223 phase with Nb addition have been observed by both methods. The ANM method leads mixtures of Bi-2223 and Bi-2212 phases, but with the SSR method pure Bi-2223 phase was obtained. With small amounts of Nb addition the critical temperature, Tc, remains the same for ANM samples and it increases for the SSR samples. For both series of samples Tc decreases with further increase of Nb content. With Nb addition the critical currents of the ANM sample almost remain the same and those of the SSR samples increases. Observations based on AC susceptibility measurements showed that Nb addition improve inter-grain coupling. Inductive critical current densities obtained from magnetization measurements agree with the critical currents stated above and show that Jc increase with increase Nb content.

Die vorliegende Arbeit beschäftigt sich mit der Entwicklung und Anwendung der Kernmagnetresonanz (NMR) unter extremen Drücken bis 101 kbar. Es wird gezeigt, dass die Empfindlichkeit von NMR Experimenten unter hohen Drücken in Diamantstempel- und ähnlichen Hochdruckzellen im Vergleich zu früheren experimentellen Versuchsanordnungen durch Verwendung von Mikrospulen um mehrere Größenordnungen verbessert werden kann. Die neue Versuchsanordnung wird dann zum einen bei der Untersuchung der Druckabhängigkeit elektronischer Eigenschaften von metallischem Aluminium bis 101 kbar verwendet. Zum anderen wird damit der Pseudogap des Hochtemperatursupraleiters YBa2Cu4O8 bei Drücken bis zu 63 kbar untersucht.

We report a systematic investigation of the local electronic, magnetic, and superconducting properties of the new iron-based high temperature superconductor Ba(Fe(1-x)Co(x)As(2) (x = 0, 0.02 , 0.04, 0.082) through the measurement of 75As and 59Co NMR (Nuclear Magnetic Resonance) lineshapes, Knight shift (K), and spinlattice relaxation rate ( 1/ T1) . The 75As NMR lineshape of the undoped parent compound splits into two sets due to discrete values of hyperfine magnetic field B(c)(hf)= ±1.32 Tesla below the magnetic ordering temperature to the SDW (Spin Density Wave) state, TSDW. In contrast, for lightly Co doped samples with x=0.02 and 0.04, the 75As and 59Co lineshapes become broad and featureless below Tsnw , indicating that the ground state is no longer the commensurate SDW ordered state. The observed lineshape is consistent with an incommensurate SDW ordered state, or a commensurate state with large distribution of hyperfine field Bhf. In the optimally doped superconductor with x = 0.082 (Tc = 22 K) , we observe two types of As sites and three types of Co sites, respectively, as expected from a binomial distribution of Co dopants. We found no evidence for induced localized moments in the vicinity of Co dopants. This finding is in remarkable contrast with the case of Zn or Ni doped high Tc cuprates, and suggests that the fundamental physics of iron-based superconductors is different from that of cu prates. The temperature dependences of 75,59K and 75,59 (1/T1T) at both 75As and 59Co sites show that Ba(Fe(1-x)Co(x))(2)As(2) exhibits spin pseudo-gap like behavior down to ~100 K for a broad Co concentration range. Below ~100 K , we observe the enhancement of residual antiferromagnetic spin fluctuations associated with inter-band spin excitations between the hole and electron Fermi surfaces even for x= 0.082. This effect is suppressed in the overdoped sample with x= 0.099, and Tc decreases. Therefore, we suggest that antiferromagnetic spin fluctuations play a crucial role in the superconducting mechanism of Ba(Fe(1-x)Co(x))(2)As(2) . We also demonstrate that the superconductivity arises from a novel electronic state with spin susceptibility Xs ~ constant and in-plane resistivity P(ab)~T, which is not consistent with canonical Fermi-liquid behavior. / Thesis / Doctor of Philosophy (PhD)

No description available.

科学研究費補助金 研究種目:試験研究(B) 課題番号:06555177 研究代表者:佐々木 勝寛 研究期間:1994-1995年度

No / A new dual-log spiral geometry is proposed for microstrip resonators, offering substantial advantages in performance and size reduction at subgigahertz frequencies when realized in superconducting materials. The spiral is logarithmic in line spacing and width such that the width of the spiral line increases smoothly with the increase of the current density, reaching its maximum where the current density is maximum (in its center for ¿/2 resonators). Preliminary results of such a logarithmic ten-turn (2 × 5 turns) spiral, realized with double-sided YBCO thin film, showed a Q.-factor seven times higher than that of a single ten-turn uniform spiral made of YBCO thin film and 64 times higher than a copper counterpart. The insertion loss of the YBCO dual log-spiral has a high degree of independence of the input power in comparison with a uniform Archimedian spiral, increasing by only 2.5% for a 30-dBm increase of the input power, compared with nearly 31% for the uniform spiral. A simple approximate method, developed for prediction of the resonant frequency of the new resonators, shows a good agreement with the test results.

Die für technische Anwendungen attraktivsten Eigenschaften der Hochtemperatur-Supraleiter beruhen auf der Wechselwirkung der Materialien mit einem externen Magnetfeld. Für hochleistungsfähige Supraleiteranwendungen werden großvolumige Funktionselemente mit eindomänigem Magnetisierungsverhalten benötigt. Zur Vergrößerung der magnetischen Domäne schmelztexturierter YBa2Cu3O7-δ-Kompaktsupraleiter wurde anhand der Multi-Seeding-Technik, die Rekristallisation unter Verwendung mehrerer SmBa2Cu3O7-δ-Keimpräparate untersucht. Als Schlüsseltechnologie zur Herstellung anwendungsorientierter Supraleitererzeugnisse wurde zu Beginn der Arbeit die Keimkristallherstellung optimiert. Gemäß den Zielvorgaben stehen zukünftig quasi-einkristalline Keimkörper definierter Form und Orientierung in hoher Stückzahl zur Verfügung. Die Supraleiter betreffend ist es gelungen, für den wechselseitigen Abstand und die Ausrichtung der Keimpräparate ein Optimum zu finden sowie tolerierbare Winkel der Verschwenkung angrenzender Kristalle zu ermitteln. Es wurde festgestellt, dass das Auftreten isolierender Korngrenzeneinschlüsse mit den magnetischen Materialeigenschaften korreliert und vom Keimabstand und der Korngrenzenorientierung abhängig ist. Mit Einsatz von bis zu 16 Keimkristallen gelang es, eindomänige Supraleiterhalbzeuge mit Höchstmaßen von (79 x 39 x 20) mm3 und Remanenzflussdichten von bis zu 1,3 T zu erzeugen. Im Chargenprozess konnten abschließend Multi-Seeding-Funktionselemente mit anwendungskonformen geometrischen und magnetischen Materialeigenschaften zum Aufbau eines hochdynamischen Supraleitermotors reproduzierbar gefertigt werden. In Leistungstests wurde für die Dynamik des Motors mit 200.000 rpm/s ein Rekordwert erzielt – nun können die Motoren in der Anwendung erprobt werden.

Cryocoolers are closed cycle devices which produce cooling below 120 K. Usually, one or two linear motors are used to drive one pulse tube cryocooler. Cryocoolers are used for various applications like, cooling of infra red detectors, cryo surgical knife, cryogen recondenser etc. In this thesis the design development and testing of Twin Pulse Tube Cryocooler (TPTC) are discussed. TPTC consists of two pulse tubes driven by dual piston head linear compressor. This dual piston linear compressor is operated using single linear motor. Using this configuration, cooling power is doubled with reduced cost of compressor. The design, fabrication and testing of Linear Moving Magnet Synchronous Motor (LMMSM) based dual piston head linear compressor are carried out indigenously. Finite Element Method (FEM) analysis is used for estimating eddy current loss and flux distribution pattern in various mover configurations of the linear motor. The developed fabrication and assembly procedure of linear motor are discussed in detail. The mover of linear motor is supported by using a pair of cross armed C – type flexures. These flexures are designed using FEM and are fabricated indigenously. The flexure pairs are tested for 108 cycles with ± 3 mm stroke length of linear motor before assembling compressor. Linear motor is usually required to be operated at different frequencies. Thus, a variable frequency and variable voltage Pulse Width Modulated (PWM) based power supply is designed using analog circuits like Op-Amps. This cost effective power supply is capable of delivering 27 A at 100 V with frequency range of 25 Hz to 80 Hz continuously. Sage software was used to carry out 1-D simulation and obtain dimensions of various Pulse Tube Cryocooler (PTC) components. Various pulse tube configurations like Joint Twin PTC, Twin PTC with buffer volume and single PTC with buffer volume were carried out. A Computational Fluid Dynamics (CFD) Fluent 2-D analysis was carried out for single PTC with buffer volume. The fabrication and assembly procedure of PTC is discussed in detail. A novel method of heat exchanger fabrication was developed and analyzed using FEM and its performance is tested experimentally. The twin PTC is operated at 34 bar and 48 Hz. A light weight High Temperature Superconductor (HTS) based level sensor is developed to monitor the cryogen level. The developed sensor was calibrated against discrete diode array and pre-calibrated continuous capacitance type level sensor. The calibrations were carried out in indigenously designed and fabricated 4-wall cryostat using Liquid Nitrogen (LN2) and LOX as cryogen. LabVIEW software based data acquisition was designed for testing, recording and monitoring the performance of twin PTC and level sensors during experiments.

Die für technische Anwendungen attraktivsten Eigenschaften der Hochtemperatur-Supraleiter beruhen auf der Wechselwirkung der Materialien mit einem externen Magnetfeld. Für hochleistungsfähige Supraleiteranwendungen werden großvolumige Funktionselemente mit eindomänigem Magnetisierungsverhalten benötigt. Zur Vergrößerung der magnetischen Domäne schmelztexturierter YBa2Cu3O7-δ-Kompaktsupraleiter wurde anhand der Multi-Seeding-Technik, die Rekristallisation unter Verwendung mehrerer SmBa2Cu3O7-δ-Keimpräparate untersucht. Als Schlüsseltechnologie zur Herstellung anwendungsorientierter Supraleitererzeugnisse wurde zu Beginn der Arbeit die Keimkristallherstellung optimiert. Gemäß den Zielvorgaben stehen zukünftig quasi-einkristalline Keimkörper definierter Form und Orientierung in hoher Stückzahl zur Verfügung. Die Supraleiter betreffend ist es gelungen, für den wechselseitigen Abstand und die Ausrichtung der Keimpräparate ein Optimum zu finden sowie tolerierbare Winkel der Verschwenkung angrenzender Kristalle zu ermitteln. Es wurde festgestellt, dass das Auftreten isolierender Korngrenzeneinschlüsse mit den magnetischen Materialeigenschaften korreliert und vom Keimabstand und der Korngrenzenorientierung abhängig ist. Mit Einsatz von bis zu 16 Keimkristallen gelang es, eindomänige Supraleiterhalbzeuge mit Höchstmaßen von (79 x 39 x 20) mm3 und Remanenzflussdichten von bis zu 1,3 T zu erzeugen. Im Chargenprozess konnten abschließend Multi-Seeding-Funktionselemente mit anwendungskonformen geometrischen und magnetischen Materialeigenschaften zum Aufbau eines hochdynamischen Supraleitermotors reproduzierbar gefertigt werden. In Leistungstests wurde für die Dynamik des Motors mit 200.000 rpm/s ein Rekordwert erzielt – nun können die Motoren in der Anwendung erprobt werden.