This study compares four different methods to measure hydraulic conductivity (K) at two sites on the East Tennessee State University Valleybrook Campus. It compares the K values to each other, to the different K values between the two sites, and to United States Department of Agriculture (USDA) K values. Two field methods, Well Bail Test and Auger Hole Test, and two lab methods, Constant Head Permeameter Test and Grain Size Distribution Test (GSD), were performed on the clay rich Ultisol soils on an East Tennessee hillslope in the Valley and Ridge Physiographic Province. One site was located close to a monitoring well and the other on the floodplain of an existing stream. The Hazen, Alyamani & Sen, and Slichter methods were used to compute K from the GSD Test. The Alyamani & Sen, Slichter, and permeameter methods produced similar K values ranging from 9.52 x 10-6 to 1.25 x 10-3 cm/sec. These are similar to the USDA K values ranging from 9.17 x 10-4 to 2.82 x 10-4 cm/sec. The Hazen method overestimated K and ranged from 8.10 x 10-3 to 1.09 x 10-1 cm/sec. The Well Bail Test yielded a lower K value (ranging from 8.16 x 10-9 to 1.19 x 10-8 cm/sec) than the USDA values as expected for water flow in deeper soil horizons at a depth of 8.50 meters. Comparing these values helped to better understand the difference between various methods to compute the hydraulic conductivity.

Groundwater in the Kentucky Appalachian region is constrained by physiography and lithology. Lithostratigraphy, groundwater flow, and chemistry were delineated in the alluvial aquifer along the Cumberland River at H.L. Disney Training Center. To assess groundwater-river interactions and water quality, 11 monitoring wells were installed and sampled quarterly, plus the river and an existing bedrock well. Analytical results were evaluated for temporal and spatial trends. Collected soil cores were analyzed for bulk chemistry and grain size. Solute speciation and saturation indices were calculated and hydraulic conductivity estimated from grain-size analyses. Pumping and slug tests were performed to estimate hydraulic conductivity and hydraulic head was monitored using logging transducers for river stage comparison. Site lithology consists of loamy soils underlain by silty clay, transitioning downward to clayey-fine sands on friable sandstone/shale. Alluvium becomes finer-grained and has lower hydraulic conductivities with proximity to the river (10-9–10-2 cm/s). Meteoric recharge drives local groundwater flow from ridges toward rivers. Hydraulic head fluctuates with stage and temporary gradient reversals occur. Groundwater does not appear to be impacted by current land use. Wells have elevated iron and manganese concentrations; post-treatment, the alluvial aquifer may provide sufficient quality and rates of water to support onsite military activities.

The influence of bulk density on saturated, unsaturated hydraulic conductivity , diffusivity and water con tent was measured on undisturbed and disturbed soil samples of Vernal sandy loam and Nibley silty clay loam. Bulk density was changed by artificially compacting the samples. There was a very large decrease in hydraulic conductivity and diffusivity as water content decreased as has been noted by many others . For the disturbed and compacted samples of the Vernal sandy loam, the water content was higher at .33 and 1.0 bar suction than for the disturbed- uncompacted samples. The same general effect was noted for the undisturbed samples, but differences due to treatment were small . The reverse was true at .05 bars. In the Nibley silty clay loam samples , water content was higher for the uncompacted than for the compacted samples at all suctions applied. The effect of compaction on unsaturated hydraulic conductivity and diffusivity was not consistent. At the same value of water content , both diffusivity and unsatura ted hydraulic conductivity were sometimes higher in the compacted samples, others lower than in the uncompacted.

Hemiepiphytes are important components of tropical forests and are attractive to scientists due to their unique epiphytic growth habit during some period of their life cycle. Unique characteristics in plant water relations and carbon economy have been found in hemiepiphytic plants; however, to further understand this group of species on an evolutionary basis it is necessary to carry out comparative studies between hemiepiphytes and their close relatives. In this dissertation I conduced a comparative study in a suite of functional traits related to plant water relations and photosynthesis between hemiepiphytic and non-hemiepiphytic tree species from a single genus-Ficus. Great differentiation in functional traits has been found between species of the two growth forms both during juvenile and adult stages. Seedlings of hemiepiphytic Ficus species (H) had significantly lower xylem hydraulic conductivity, stomatal conductance, net light saturated CO2 assimilation, and higher water use efficiency than congeneric non-hemiepiphytic species (NH), which are adaptive to a drought-prone epiphytic growth conditions under natural conditions. The conservative water use adaptation in H species is likely crucial to the drought tolerance and survival in the forest canopy but is related to much lower growth rates than NH species. Species of the two growth forms both showed relatively large plasticity in responding to variation in light level as in typical light-demanding species. Surprisingly, the NH species showed characteristics related to higher light demand than H species, which is opposite from the prediction that H species are more light-demanding than NH species. Thus, although commonly accepted, it is likely that light was not the selective pressure for the evolution of hemiepiphytism in Ficus. Using adult trees grown in a common garden, I found that H species showed characteristics of more conservative water use even after they established connections to the soil. Moreover, H species showed significantly different traits in photochemistry compared to NH species due to hydraulic-photosynthetic coordination. The evolution of an epiphytic growth habit during the juvenile stage of a life cycle in the hemiepiphytic Ficus species thus involved changes in a suite of functional traits that persist during their terrestrial growth stages.

Rain fall-runoff response in temperate humid headwater catchments is mainly controlled by hydrolo gical processes at the hillslope scale. Applied tracer experiments with fluore scent dye and salt tracers are well known tools in groundwater studies at the large scale and vadose zone studies at the plot scale, where they provide a means to characterise subsurface flow. We extend this approach to the hillslope scale to investigate saturated and unsaturated flow path s concertedly at a forested hill slope in the Austrian Alps. Dye staining experiments at the plot scale revealed that crack s and soil pipe s function as preferential flow path s in the fine-textured soils of the study area, and these preferenti al flow structures were active in fast subsurface transport of tracers at the hillslope scale. Breakthrough curves obtained under steady flow conditions could be fitted well to a one-dimensional convection-dispersion model. Under natural rain fall a positive correlation of tracer concentrations to the transient flows was observed. The results of this study demon strate qualitative and quantitative effects of preferential flow feature s on subsurface stormflow in a temperate humid headwater catchment. It turn s out that / at the hill slope scale, the interaction s of structures and processes are intrinsically complex, which implies that attempts to model such a hillslope satisfactorily require detailed investigation s of effective structures and parameters at the scale of interest.

A patterned, partially-treed, fen in the mid-boreal region of central Saskatchewan was the site of renewed hydrological research from 2002 to 2004. Hydraulic conductivity, transmissivity, and storativity were determined through use of a surface loading test, pumping tests, and an enclosed field drainage test. None of these field tests have been previously described in the literature as having been used in peat environments. The combined results of field and laboratory drainage tests were used to obtain a general storativity with water table depth relationship in the upper peat layer. The hydraulic conductivity, measured with slug tests, the loading test, and pumping tests, is high near the surface, declining greatly with depth. These previously untested field methods have the advantage of representing volumes of peat from tenths of a meter to cubic meters. </p>Characterization of the hydrology of the peatland involved year round observations of water table, piezometric head, peat surface elevations, frost depth and peat temperatures. Fluctuations of the water table, and soil moisture changes produce changes in effective stress that lead to volume change in the highly compressible peat. This is particularly important for sites with thick peat deposits. Independent compressibility estimates were as high as 10-5 N/m2 in the upper peat. At three fen sites, changes in peat thickness were estimated from monthly estimates of effective stress change, using year round hydrological observations, and compared to measured annual peat thickness changes. Water table changes causing soil moisture changes, and freeze-thaw processes, explained the majority of peat surface movements.

This thesis describes a numerical modelling methodology to interpret dynamic fluctuations in pore-pressures to isolate the effects of loading associated with changes in total soil moisture (site water balance) alone. The methodology is required to enhance the data-interpretation and performance-assessment for potential applications of a novel piezometer-based, large-scale, geological weighing lysimeter. This interpretative methodology is based on a method of superimposing computer-based numerical analyses of independent causes of pore-pressure transients to separate the different pore-pressure responses. Finite element coupled load-deformation and seepage numerical models were used to simulate field-observed piezometric responses to water table fluctuations and loading induced by surface water balance (using meteorological data).<p> Transient pore-pressures in a deep clay-till-aquitard arising from variations in the water table within a surface-aquifer were modelled and removed from the measured pore-pressure record (corrected for earth tide and barometric effects) to isolate and identify pore-pressure fluctuations arising from loading associated with site water balance. These estimates were compared to simulated pore-pressure responses to an independently measured water balance using meteorological instrumentation. The simulations and observations of the pore-pressure responses to surface water balance were in good agreement over the dry years of a 9-year period. Some periods of significant differences did occur during wet years in which runoff, which is not accounted for in the current analyses, may have occurred.<p> The identification of pore-pressure response to total soil moisture loading using the developed numerical modelling methodology enhances the potential for the deployment of the piezometer-based geological weighing lysimeter for different applications which include real-time monitoring of site water balance and hydrological events such as precipitation and flooding. Interestingly, the disparity occurring during the wet years even suggests the potential to adapt the method to monitor runoff (net lateral flow).<p> The methodology also demonstrated the capability to accurately estimate in situ elastic and hydraulic parameters. Calibration of the model yielded equivalent properties of the aquitard (hydraulic conductivity, Kv, of 2.1E-5 m/day and specific storage, Ss, of 1.36E-5 /m) for a Skemptons B-bar coefficient of 0.91 for an assumed porosity of 0.26. Sensitivity tests also provided insight into the consolidation and pressure propagation (swelling) behaviour of the aquitard under parametric variations. The parameters obtained are consistent with range of values reported for glacial clay till soil. Therefore, this work also provides a unique case history of a method for determining, large scale, in situ material properties for geo-engineers and scientists to explore by simply using piezometric and meteorological data.

The effective and efficient remediation of contaminated groundwater sites requires site specific information regarding the physical, chemical and biological properties of the aquifer. Building on the dipole flow test (DFT) and the dipole flow and tracer test (DFTT), the dipole flow and reactive tracer test (DFRTT) has been proposed as an alternative to current aquifer parameter estimation methods. A steady-state dipole flow field is created by circulating groundwater between chambers isolated by the dipole tool. A tracer is released into the injection chamber and the breakthrough curve at the extraction chamber is interpreted with the DFRTT specific model. The overall goal of this thesis was to demonstrate the ability of a prototype dipole system to produce tracer BTCs in conventional wells installed in an unconfined sandy aquifer. The Waterloo dipole probe was constructed and field tested at CFB Borden. DFTs conducted along the length of the screen of non-filter packed monitoring wells provided similar estimates of radial hydraulic conductivity (Kr) to slug tests and literature values. The geometric mean Kr estimated in the filter packed wells was approximately an order of magnitude greater than the mean Kr estimate for the non-filter packed wells due to short-circuiting through the filter pack. A total of 46 DFTTs were completed in the monitoring wells at CFB Borden to investigate the properties of the BTCs. The shape of the BTC for a conservative tracer is affected by test set up parameters, well construction, and aquifer formation properties. The BTCs from the DFTTs completed in the non-filter pack monitoring wells were categorized into four “type curves” based on the BTC properties. The differences between the type curves were largely defined by the ratio of K between the skin zone and the aquifer (Ks/Kr). Now that a series of DFTT BTCs have been generated, the DFRTT model will be used to estimate the aquifer parameters. To continue the work outlined in this thesis, DFRTTs are planned for well-documented contaminated sites.

The purpose of this study was to evaluate the effectiveness of traditional hydrogeologic characterization approaches in a highly heterogeneous glaciofluvial aquifer at the North Campus Research Site (NCRS), situated on the University of Waterloo campus. Continuous soil cores to a depth of approximately 18 m were collected during the installation of the CMT monitoring wells and the multi-screen pumping well. K estimates were obtained for the core by obtaining 471 samples and testing them with a falling head permeameter, as well as by utilizing empirical equations developed to estimate K. A geostatistical analysis performed on the K datasets yielded strongly heterogeneous kriged K fields for the site. K and Ss were also estimated via type curve analysis of slug and pumping test data collected at the site. The various K and Ss estimates were then evaluated by simulating the transient drawdown data using a 3D forward numerical model constructed using Hydrogeosphere (Therrien et al., 2005). Results showed that, while drawdown predictions generally improved as more complexity was introduced into the model, the ability to make accurate drawdown predictions at all of the CMT ports was inconsistent. These results suggest that new techniques may be required to accurately capture subsurface heterogeneity for improved predictions of flow in similar systems.

Excess global elemental sulphur (So) production has resulted in a decrease in its price. As a result, many companies, such as Syncrude Canada Ltd., have resorted to above ground storage alternatives. Geochemical reactions in these above ground blocks produce elevated concentrations of H2SO4 (acid). This acid can have potentially deleterious effects on the environment. As such, these blocks will require long-term (500 years) monitoring and maintenance. Presently the So is removed from the product stream, piped in a molten state, and poured over a low permeability liner in thin lifts. As the So cools and undergoes crystal structure change it fractures, creating preferential flow passages which are potentially highly conductive. An understanding of the liquid conductivity (Kl) of the block and knowledge regarding the spatial and temporal distribution of acid (H2SO4) within these blocks is required. In this thesis, gas pumping tests were conducted on an above ground block to determine the gas flow rates within the block and to indirectly determine the Kl of the block. Measurements of the relative humidity (RH) in the block were used to observe changes in stored acid concentrations with time and location. The results of the gas conductivity (Kg) testing showed that the block is anisotropic and is highly conductive in both the horizontal and vertical directions. Cross hole tests appeared to produce the most representative estimates of Kg due to the negation of turbulence that arises in the vicinity of the borehole. The choice of gas used in the analysis had negligible effect on the resulting Kl in contrast to choice of liquid, which resulted in larger variations in Kl. The Kl was a maximum when the liquid was pure water and decreased with increasing acid strength. The geometric mean of the resulting cross hole Kl values was 2 x 10-3 m s-1 (pure water). RH measurements were observed to fluctuate with depth and increased following precipitation. The resulting minimum pH observed within the block occurred at depths of 3 and 7 meters below the surface of the So block and increased with depth. The arithmetic mean pH value based on the daily averaged RH measurements was -1.7.