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Addition of alkalinity to acid mine drainage (AMD) results in the neutralisation of acidity and precipitation of dissolved metals as insoluble hydroxides. Two aspects of the current AMD treatment practice at the Stockton Mine could be enhanced. Firstly, residual water quality may be poor due to unreacted alkalinity reagents, particularly CaCO3, resulting in poor water clarity and elevated suspended solids (SS). Secondly, neutralisation to circum-neutral pH may not avoid the discharge of residual metals (Ni and Zn) due to incomplete adsorption and hydroxide precipitation. The aim of this project was to enhance the conventional neutralisation of AMD through addition of humic substances (HS) to reduce residual SS and trace metal concentrations. Humic substances are organically derived and have a high molecular weight. Functional groups on the surface of HS are capable of binding dissolved metals, forming HS-metal complexes. Incorporation of HS complexed metals into settling floc could result in increased metal removal from the dissolved phase. Modified jar testing was used to investigate the effects of HS addition before, after and during (pH 4.5) neutralisation of AMD in two treatment scenarios at the Stockton Mine; the Blackwater Treatment Plant (BTP) using NaOH and Ca(OH)2 and the Mangatini Stream-sump System (MSS) using CaCO3. Supernatant samples collected during the sedimentation period were analysed for basic water quality parameters (turbidity and suspended solids) and dissolved (< 0.45 µm) metal concentrations. The addition of HS to the BTP process before (pH 2.8) and during (pH 4.5) neutralisation resulted in HS precipitation. Precipitated HS subsequently acted as a nucleation site, triggering flocculation of precipitating metal hydroxides, resulting in low turbidity and suspended solids (SS) of less than 2 NTU and 5 mg/L, respectively. The addition of HS after neutralisation (pH 7) did not result in HS precipitation. Intermolecular bridging of HS by the divalent Ca resulted in incorporation of HS into floc when neutralised by Ca(OH)2, resulting in low turbidity and SS. However, in NaOH neutralised conditions, the monovalent Na was unable to bridge HS molecules, resulting in HS remaining dissolved and contributing to elevated turbidity and SS of up to 24.4 NTU and 18.4, respectively. The neutralisation efficiency of CaCO3 is relatively low, thus approximately 1000 mg/L CaCO3 remained unreacted in MSS scenarios, resulting in elevated turbidity and SS. When added after neutralisation, dissolved Solid Energy Humic Acid (SEHA) facilitated flocculation of residual CaCO3 SS, resulting in an up to 75% lower suspended solids than CaCO3 neutralisation alone conditions. Although the results are good, the efficiency of SEHA as a polymer compared unfavorably in a cost: benefit analysis to two commercially available polymers for the removal of residual CaCO3. Neutralisation of AMD in control samples resulted in decreased concentrations of the target metal group (Ni, Zn, Cu, Cd, and Pb) by hydroxide precipitation, co-precipitation, and adsorption. Equilibrium speciation modeling showed that the HS-metal binding affinity controlled the effectiveness of HS addition for metal removal. The low HS complexation affinity of Ni and Zn resulted in no additional metal removal by HS dosing. The removal of Cu was enhanced by over 50% for SEHA 20 during-neutralisation conditions neutralised by both NaOH and Ca(OH)2. Up to 80% lower Cd concentrations were observed for all HS dose conditions when neutralised by Ca(OH)2. Data for CaCO3 HS dosed metal removal was statistically indeterminate. The high detection limit for Pb made any HS dosed removal enhancement difficult to identify, which was unfortunate as Pb has a high HS complexation affinity (Čežı́ková, Kozler et al. 2001; Milne, Kinniburgh et al. 2003). A simple cost: benefit analysis showed that the additional removal of metals by HS dosing was less efficient than conventional neutralisation alone, on a cost basis. Overall, incorporation of HS into AMD treatment results in improved water quality for CaCO3 neutralisation and lower concentrations of metals with a high HS binding affinity, for some conditions. However, further investigation is required to improve the feasibility of HS incorporation into the AMD neutralisation process.

Virginia Woolf and Sylvia Plath are two well-known women writers of the twentieth century who committed suicide. The narratives created by their deaths have in some instances become as important as the canonical work they produced. In an effort to understand their motivations and struggles, critics and the public alike have sometimes reduced these women to victims of the patriarchy, mental illness, or even themselves. Beginning with my own discovery of this issue in the legacies of Plath and Woolf combined with my personal dealings with suicide in my family, I recount how I lost these two women as exemplary figures because of their choice to commit suicide. I then take a look at what others have said about their deaths and how it has affected their legacies as writers. Finally, I take a look at Woolf’s Mrs. Dalloway and Plath’s The Bell Jar for an alternate perspective on suicide. Through this journey, I recount how I have been able to regain my respect for these two talented women by considering multiple viewpoints and acknowledging the nuance inherent in any account.

abstract: Mineral weathering and industrial activities cause elevated concentration of hexavalent chromium (Cr(VI)) in groundwater, and this poses potential health concern (>10 ppb) to southwestern USA. The conversion of Cr(VI) to Cr(III) – a fairly soluble and non-toxic form at typical pH of groundwater is an effective method to control the mobility and carcinogenic effects of Cr(VI). In-situ chemical reduction using SnCl2 was investigated to initiate this redox process using jar testing with buffered ultrapure water and native Arizona groundwater spiked with varying Cr(VI) concentrations. Cr(VI) transformation by SnCl2 is super rapid (<60 seconds) and depends upon the molar dosage of Sn(II) to Cr(VI). Cr(VI) removal improved significantly at higher pH while was independent on Cr(VI) initial concentration and dissolved oxygen (DO) level. Co-existing oxyanions (As and W) competed with Cr(VI) for SnCl2 oxidation and adsorption sites of formed precipitates, thus resulted in lower Cr(VI) removal in the challenge water. SnCl2 reagent grade and commercial grade behaved similarly when freshly prepared, but the reducing strength of the commercial product decreased by 50% over a week after exposing to atmosphere. Equilibrium modeling with Visual MINTEQ suggested redox potential < 400 mV to reach Cr(VI) treatment goal of 10 ppb. Kinetics of Cr(VI) reduction was simulated via the rate expression: r=-k[H+]-0.25[Sn2+]0.5[Cr2O72-]3 with k = 0.146 uM-2.25s-1, which correlated consistently with experimental data under different pH and SnCl2 doses. These results proved SnCl2 reductive treatment is a simple and highly effective method to treat Cr(VI) in groundwater. / Dissertation/Thesis / Masters Thesis Civil, Environmental and Sustainable Engineering 2019

Lake Waikare is a large, shallow eutrophic lake devoid of submerged macrophytes. I investigated potential methods for re-establishing submerged macrophytes in the lake. Specifically, I subjected charophyte (Chara corallina) plantlets to two treatments of exposure in the lake (in areas exposed and sheltered from wind) to test for survival and growth under these conditions, and inside and outside fish exclosures to test for growth and survival in the presence of fish. While plantlets grew outside the exclosures in winter, their accumulated biomass over 21 days was less than protected plantlets. In winter, the accumulated biomass was lower outside than inside exclosures (by ~40%) at the sheltered site and was lower outside than inside exclosures (by 43%) at the exposed site. Overall, growth rates in winter were higher at the sheltered site (compared to the exposed site) by ~7%. In summer, charophyte accumulated biomass inside the exclosures increased by 85%, while at the sheltered site accumulated biomass increased by 58%. Outside the exclosures in summer the plantlets were completely removed at both sites. Overall, growth rates where higher at the exposed site than the sheltered site by 31%. Fish were responsible for the partial removal of plantlets in winter and total removal of plantlets in summer, and therefore affect the survival and growth of charophytes in Lake Waikare. The embayment at the sheltered site provides the best location in winter for re-establishment of charophytes from oospores because better growth rates were obtained there, and its sheltered location provides protection from severe wave action found at the exposed site. Oospores did not germinate after being submersed in the lake for 90 days due to heavy sedimentation. To induce an improvement in the present light climate, Alum was tested to determine its effectiveness and longevity for settling lake sediments to allow charophytes to establish and grow. Examining the settling rates of Lake Waikare sediments and water treated with Alum over a range of suspended sediment concentrations and time intervals, sediments settled faster with Alum than without for at least 15 days (at 200 g l^1 suspended sediment concentration) and it remained active to 60 days but at reduced effectiveness. At the other concentrations tested (100 g l^1 and 300 g l^1 suspended sediment concentration), Alum responses were insignificant. An improved light climate achieved by fish removal or Alum treatment will likely not be sufficient to permit the re-establishment of submerged macrophytes due to the turbid, algal-dominated state of the lake. The present nutrient and sediment levels, wave climate and fish influence must be mitigated so charophyte plantlets can be established.

Research in the use of ozone in water treatment conducted by many authors support the idea that the nature and characteristics of natural organic matter (NOM) present in raw water determines the efficiency of ozonation in water purification. An ozone contact chamber was designed and made to allow pre-ozonation of water to take place. The concentration of ozone in the chamber was determined using the Indigo method. For the duration of one year, water samples were collected from four different sampling sites and analyzed to determine their overall ecological status with regard to several variables such as pH, chlorophyll-a, SAC254, turbidity, DOC, algal species composition and sum of NOM. Two dams sites and two riverine sites were chosen, Hartbeespoort Dam (a hyper-eutrophic impoundment), Boskop Dam (a mesotrophic impoundment), Midvaal Water Company at Orkney and Sedibeng Water at Bothaville. The samples were treated in Jar Tests with FeCI3 and the same variables were measured. Preozonation followed by Jar Tests was performed on each sample at twoconcentrations of ozone and the variables were measured to examine the efficiency of ozonation. In general, the ph was high and stayed the same for all the samples and for all the treatments. DOC was variable and showed no relationship to any other variable or to the treatments. Hartbeespoort Dam was found to be a eutrophic impoundment characterized by high algal bloom of the cyanobacteria Microcystis sp., Turbidity, SAC254, and the sum of NOM were lower than for the riverine sites but higher than for Boskop Dam. The NOM constituted more intermediate molecular weight(1MW)and low molecular weight (LMW) fractions than the riverine sites. Ozone was effective in reducing chlorophyll-a, turbidity and SAC254 from Hartbeespoort Dam, but the presence of large numbers of algal cells interferes with its efficiency. Release of cell-bound organics after ozonation can lead to increases instead of decreases in these variables. Jar Test results demonstrate that ozonation improves water quality when compared to conventional treatment although the interference of algal cells can alter results. Boskop Dam is a mesotrophic impoundment characterised by low productivity, low SAC254, tow turbidity and low sum of NOM. However, it has a large portion of the LMW fraction of NOM present. This LMW fraction affects the treatment process as this fraction is not acted upon by ozone. Therefore it was found that ozonation did not improve the quality of the water when compared to conventional treatment. The two riverine sites, Midvaal and Sedibeng were similar to each other. Both sites had high algal productivity with high chlorophyll-a values indicative of algal blooms observed at certain times. These blooms consisted either of members of Bacillariophyceae or Chlorophyceae. High turbidity and SAC254 was observed during the rainy season and was related to the high percentage HMW and IMW fractions of NOM present. There was correlation between the turbidity and SAC254 of these sites leading to the assumption that the turbidity of the river is due to the presence of HMW humic fractions of NOM. Ozonation was effective in improving water quality with respect to turbidity, SAC254 and chlorophyll-a removal, both on its own and after conventional treatment when combined with a coagulant. However, the species of algae present affects ozonation as members of Bacillariophyceae are not affected by the actions of ozone because of the presence of a silica frustule whereas members of Chlorophyceae are easily removed by ozone. In general, ozone acts upon the HMW and LMW fractions of NOM causing them to breakdown into smaller fractions. Ozone has no effect on samples that have a high percentage of the LMW fraction of NOM. This LMW fraction is more readily removed by conventional treatment than by ozonation. The presence of large numbers of algal cells as well as the species of cells can negatively affect the treatment process with regard to ozone. / Thesis (M. Environmental Science (Water Science))--North-West University, Potchefstroom Campus, 2007.

Research in the use of ozone in water treatment conducted by many authors support the idea that the nature and characteristics of natural organic matter (NOM) present in raw water determines the efficiency of ozonation in water purification. An ozone contact chamber was designed and made to allow pre-ozonation of water to take place. The concentration of ozone in the chamber was determined using the Indigo method. For the duration of one year, water samples were collected from four different sampling sites and analyzed to determine their overall ecological status with regard to several variables such as pH, chlorophyll-a, SAC254, turbidity, DOC, algal species composition and sum of NOM. Two dams sites and two riverine sites were chosen, Hartbeespoort Dam (a hyper-eutrophic impoundment), Boskop Dam (a mesotrophic impoundment), Midvaal Water Company at Orkney and Sedibeng Water at Bothaville. The samples were treated in Jar Tests with FeCI3 and the same variables were measured. Preozonation followed by Jar Tests was performed on each sample at twoconcentrations of ozone and the variables were measured to examine the efficiency of ozonation. In general, the ph was high and stayed the same for all the samples and for all the treatments. DOC was variable and showed no relationship to any other variable or to the treatments. Hartbeespoort Dam was found to be a eutrophic impoundment characterized by high algal bloom of the cyanobacteria Microcystis sp., Turbidity, SAC254, and the sum of NOM were lower than for the riverine sites but higher than for Boskop Dam. The NOM constituted more intermediate molecular weight(1MW)and low molecular weight (LMW) fractions than the riverine sites. Ozone was effective in reducing chlorophyll-a, turbidity and SAC254 from Hartbeespoort Dam, but the presence of large numbers of algal cells interferes with its efficiency. Release of cell-bound organics after ozonation can lead to increases instead of decreases in these variables. Jar Test results demonstrate that ozonation improves water quality when compared to conventional treatment although the interference of algal cells can alter results. Boskop Dam is a mesotrophic impoundment characterised by low productivity, low SAC254, tow turbidity and low sum of NOM. However, it has a large portion of the LMW fraction of NOM present. This LMW fraction affects the treatment process as this fraction is not acted upon by ozone. Therefore it was found that ozonation did not improve the quality of the water when compared to conventional treatment. The two riverine sites, Midvaal and Sedibeng were similar to each other. Both sites had high algal productivity with high chlorophyll-a values indicative of algal blooms observed at certain times. These blooms consisted either of members of Bacillariophyceae or Chlorophyceae. High turbidity and SAC254 was observed during the rainy season and was related to the high percentage HMW and IMW fractions of NOM present. There was correlation between the turbidity and SAC254 of these sites leading to the assumption that the turbidity of the river is due to the presence of HMW humic fractions of NOM. Ozonation was effective in improving water quality with respect to turbidity, SAC254 and chlorophyll-a removal, both on its own and after conventional treatment when combined with a coagulant. However, the species of algae present affects ozonation as members of Bacillariophyceae are not affected by the actions of ozone because of the presence of a silica frustule whereas members of Chlorophyceae are easily removed by ozone. In general, ozone acts upon the HMW and LMW fractions of NOM causing them to breakdown into smaller fractions. Ozone has no effect on samples that have a high percentage of the LMW fraction of NOM. This LMW fraction is more readily removed by conventional treatment than by ozonation. The presence of large numbers of algal cells as well as the species of cells can negatively affect the treatment process with regard to ozone. / Thesis (M. Environmental Science (Water Science))--North-West University, Potchefstroom Campus, 2007.

PALICH, K. The use of fixed-base simulators in pilot training. Brno: Brno university of technology, Faculty of mechanical engineering, 2013. 80 s. Diploma thesis head: Ing. Jiří Chlebek, Ph.D. This diploma thesis deals with aircraft simulators and syntethic training devices which are used for pilot training. One of the chapters consist of division of syntethic training devices, which is defined by ordinance. In the next chapter there is general description of the basic function of those devices, history of simulators and their development from the very beggining to the present. A significant part of this diploma thesis is about flight simulator Jeppesen Flite Pro, which is at Institute of Aerospace at VUT. In the following chapters there is information about usage of this simulator in the education at this institute and there are picked specific subjects, where this simulator can be used.

The purpose of this study is to evaluate the convenience and effectiveness of using a disc filter to treat washing water from the sand filters at Sundet wastewater treatment plant. The disc filter is used aiming for the reduction of suspended solids and phosphorus. The study was divided in two main experimental stages. During the first stage laboratory jar-tests were performed in order to identify which flocculation aid was more suitable, this was further on used to improve the water treatment. Based on the laboratory trials results, two different polymers (1 and 2) were chosen to be tested at pilot scale. The second stage involved the pilot filter operation itself; this period was as well divided in two sub-stages where filter cloths with two different pore openings were tested. During the first sub-stage the pilot operated with an 18 μm pore opening filters cloth and both polymers. At the end of the first half polymer 1 showed to be more efficient and so it was further used throughout the second sub-stage in combination with a 10μm pore opening filter cloth. As from theoretical knowledge the phosphorus and suspended solid removal were expected to be between 75% and 90%, results which were achieved during both laboratory trials and pilot filter. The best results were observed with the 10μm pore opening filter cloth and polymer 1. Also, additional results from pilot trials performed at Sundet after the study period are presented.

As populations continue to grow, the demand for fresh drinking water is increasing. This puts a lot of pressure on drinking water producers to strive for more efficient solutions and techniques. Many producers worldwide use surface water as a raw water source, which they often treat through coagulation and flocculation techniques. This is done by adding coagulant (e.g. metal coagulants), creating instability in the suspension, causing flocculation. In this work, PIX-311 (a FeCl3 coagulant produced by Kemira) and Al2(SO4)3 (Kemwater ALG) were used as primary coagulants and CaCl2 (produced by TETRA Chemicals) as an adjunct in a coagulation and flocculation study. The goal of this work was to study the effects of CaCl2 additions to Fe(III) and Al(III) flocculation. The experiments were conducted at Ringsjöverket (a water treatment facility), using jar tests to simulate the treatment process on a laboratory scale. The raw water samples used in this study, were taken from Bolmen, a lake in southern Sweden. A spectrophotometer was used to monitor the efficiency of flocculation by UV-VIS absorption. In the first experiments, various CaCl2 additions were added to Fe(III) flocculation, with FeCl3 as a primary coagulant. To see if FeCl3 could be substituted with CaCl2, the amount of primary coagulant was reduced to about 80% of the optimal dosage (the dose used daily by the water treatment plant). In the next series of experiments, various amounts of CaCl2 were added with an optimal dose of FeCl3. After that, the effects of CaCl2 additions to Al(III) flocculation were conducted, using Al2(SO4)3 as a primary coagulant. The experiments followed the previous scheme used in Fe(III) flocculation. The UV-VIS results showed that no CaCl2 additions were effective enough to replace the primary coagulant. However, reduced amount of primary coagulant benefited slightly from small CaCl2 additions. A likely explanation for this is the ability of Ca2+ to aid in charge neutralization and reduce the repulsive forces between particles in suspension, aiding coagulation. Furthermore, CaCl2 additions, with reasonable certainty, did not increase the efficiency of Fe(III) flocculation. When the CaCl2 dose was increased (from about 13µl to 820 µl per liter raw water), the effect became negative. In other words, high doses of CaCl2 inhibited flocculation by, most likely, occupying adsorption sites for the primary coagulant. This was observed for an optimal FeCl3 dose, reduced FeCl3 dose and an optimal dose of Al2(SO4)3. In the more brief study on Al(III) flocculation, low CaCl2 doses did not appear to have any effect on flocculation at first.  However, when a reduced amount of Al2(SO4)3 was used, the samples with CaCl2 gave better UV-VIS results once the pH was increased from 6 to about 6.15. One explanation for this could be that the shift in flocculation mechanism at higher pH, causes CaCl2 to have an increased positive effect.