Traditional telephony networks with their cumbersome and costly infrastructures are being replaced with voice being transmitted over the Internet. The Internet is a very commonly used technology that was traditionally used to transmit data. With the availability of large bandwidth and high data rates the transmission of data, voice and video over the Internet is gaining popularity. Voice is a real time application and the biggest problem it faces is the loss of packets due to network congestion. The Internet implements protocols to detect and retransmit the lost packets. However, for a real time application it is too late before a lost intermediate packet is retransmitted. This causes a need for reconstruction of the lost packet. Therefore, good reconstruction techniques are being researched. In this thesis a new concealment algorithm to reconstruct lost voice packets is reported. The algorithm is receiver based and its functionality is based on Time Scale Modifications of speech and autocorrelation of a speech signal. The new techniqhe is named the Modified Waveform Similarity Overlap Add , (WSOLA) technique. All simulations were performed in MATLAB.

Hydraulic Fracturing is a technique to accelerate production and enhance ultimate recovery of oil and gas while fracture geometry is an important aspect in hydraulic fracturing design and optimization. Systematic design procedures are available based on the so-called two-dimensional models (2D) focus on the optimization of fracture length and width, assuming one can estimate a value for fracture height, while so-called pseudo three dimensional (p-3D) models suitable for multi-layered reservoirs aim to maximize well production by optimizing fracture geometry, including fracture height, half-length and width at the end of the stimulation treatment. The proposed p-3D approach to design integrates four parts: 1) containment layers discretization to allow for a range of plausible fracture heights, 2) the Unified Fracture Design (UFD) model to calculate the fracture half-length and width, 3) the PKN or KGD models to predict hydraulic fracture geometry and the associated net pressure and other treatment parameters, and, finally, 4) Linear Elastic Fracture Mechanics (LEFM) to calculate fracture height. The aim is to find convergence of fracture height and net pressure. Net pressure distribution plays an important role when the fracture is propagating in the reservoir. In multi-layered reservoirs, the net pressure of each layer varies as a result of different rock properties. This study considers the contributions of all layers to the stress intensity factor at the fracture tips to find the final equilibrium height defined by the condition where the fracture toughness equals the calculated stress intensity factor based on LEFM. Other than maximizing production, another obvious application of this research is to prevent the fracture from propagating into unintended layers (i.e. gas cap and/or aquifer). Therefore, this study can aid fracture design by pointing out: (1) Treating pressure needed to optimize fracture geometry, (2) The containment top and bottom layers of a multi-layered reservoir, (3) The upwards and downwards growth of the fracture tip from the crack center.

The mechanical and electrical properties of thin films have been become important and urgent in recent years, especially, the laminated structure made by films stacked over hundreds of layers. For example, the Multi-Layered Ceramic Capacitors (MLCCs) are such structures fabricated by one layer ceramic film interleaves with one layer electrode film repeatedly a hundred times. Thus, the advantages of MLCCs include small volume, mass product, and high capacity. That makes the MLCCs the necessary part of passive components. The Finite element method is adopted in the study. The model is built by the simulation program of ANSYS. After meshing and setting boundary conditions, the numerical process is performed. The numerical simulation was started first by applying a uniformly distributed pressure on the top of near hundred layers of MLCCs before sintering process with the bottom plate fixed. Then, the displacement and stress fields of MLCCs under five pressures were obtained and discussed. In order to visualize the results, the data of displacement and the stress fields were listed in Tables and plot in Figures. In addition to the MLCCs under vertically and uniformly distributed pressure, the slightly slant distributed pressure and gradient distributed pressure had been simulated. Next, the results of changing Young¡¦s modulus had also been received. It is found that the vertical distributed pressure and slant distributed pressure were not the main factor led to the side deformation. The lateral constraint of gradient distributed pressure would influence the deformation of the MLCCs significantly.

Title from PDF of title page. / Document formatted into pages; contains 64 pages. / Thesis (M.S.E.E.)--University of South Florida, 2003. / Includes bibliographical references. / Text (Electronic thesis) in PDF format. / ABSTRACT: Traditional telephony networks with their cumbersome and costly infrastructures are being replaced with voice being transmitted over the Internet. The Internet is a very commonly used technology that was traditionally used to transmit data. With the availability of large bandwidth and high data rates the transmission of data, voice and video over the Internet is gaining popularity. Voice is a real time application and the biggest problem it faces is the loss of packets due to network congestion. The Internet implements protocols to detect and retransmit the lost packets. However, for a real time application it is too late before a lost intermediate packet is retransmitted. This causes a need for reconstruction of the lost packet. Therefore, good reconstruction techniques are being researched. In this thesis a new concealment algorithm to reconstruct lost voice packets is reported. / ABSTRACT: The algorithm is receiver based and its functionality is based on Time Scale Modifications of speech and autocorrelation of a speech signal. The new techniqhe is named the Modified Waveform Similarity Overlap Add , (WSOLA) technique. All simulations were performed in MATLAB. / System requirements: World Wide Web browser and PDF reader. / Mode of access: World Wide Web.

This research project investigated the physical aging of glassy polymers in confined environments. Many recent studies of aging in glassy polymers have observed that aging behavior is often strongly affected by confinement. Understanding aging in confined environments (e.g., thin polymer films and nanocomposites) is vital for predicting long-term performance in applications that use confined glassy polymers, such as gas separation membranes and advanced nanocomposite materials. Aging in bulk and layered films produced via layer-multiplying co-extrusion was studied using gas permeability measurement and differential scanning calorimetry (DSC). The layered films consisted of polysulfone (PSF) and a rubbery co-layering material, with PSF layers ranging in thickness from ~185 nm to ~400 nm. Gas permeation aging studies at 35 °C revealed that the PSF layers in layered films aged in a manner that was similar to bulk PSF and independent of layer thickness. This finding differs from what was observed previously in freestanding PSF films, in which aging depended strongly on thickness and was accelerated relative to bulk. Isothermal aging studies at 170 °C and cooling rate studies were performed on both bulk and layered samples using DSC. The aging of the PSF layers was similar to aging in bulk PSF for films having PSF layer thicknesses of ~640 nm and ~260 nm, while the film with 185 nm PSF layers showed a slightly higher aging rate than that of bulk PSF. The results of the DSC studies generally support the conclusions of our gas permeation aging studies. The absence of strong thickness dependence in aging studies of layered films tends to support the idea that the effect of film thickness on physical aging stems from interfacial characteristics and not merely thickness per se. The physical aging of thin polystyrene (PS) films at 35 °C was also investigated using gas permeation techniques. PS films of 400 nm and 800 nm did not exhibit aging behavior that was highly accelerated relative to bulk or strongly dependent on film thickness. At the thicknesses and aging temperature considered, the aging of PS shows much weaker thickness dependence than that seen in polymers like PSF and Matrimid. / text

Li-ion batteries are widely used in electronics and automotives. Despite their success, improvements in cost, safety, cycle life, and energy density are necessary. One way to enhance the energy density is to find advanced cathodes such as Li-rich layered oxides, which are similar to the commonly layered oxide cathodes (e.g., LiCoO2), except there are additional Li ions in the transition-metal layer, due to their higher charge-storage capacity. Another way of advancing is to design new battery chemistries, such as those involving multivalent-ion systems (e.g., Mg2+ and Zn2+) as they could offer higher charge-storage capacities and/or cost advantages. Li-rich layered oxides have a complex first charge-discharge cycle, which affects their other electrochemical properties. Ru doping was expected to improve the performance of Li-rich layered oxides due to its electroactivity and overlap of the Ru4+/5+:4d band with the O2-:2p band, but it unexpectedly decreased the capacity due to the reduction in oxygen loss behavior. Preliminary evidence points to the formation of Ru-Ru dimers, which raises the Ru4+/5+:4d band, as the cause of this behavior. Li-rich layered oxides suffer from declining operating voltage during cycling, and it is a huge challenge to employ them in practical cells. Raising the Ni oxidation state was found to reduce the voltage decay and improve the cyclability; however, it also decreased the discharge capacity. Increasing the Ni oxidation state minimized the formation of Mn3+ ions during discharge and Mn dissolution, which led to the improvements in voltage decay and cyclability. Extraction of lithium from spinel oxides such as LiMn2O4 with acid was found to follow a Mn3+ disproportionation mechanism and depend on the Mn3+ content. Other common dopants like Cr3+, Fe3+, Co3+, or Ni2+/3+ did not disproportionate, and no ion-exchange of Li+ with H+ occurred in the tetrahedral sites of the spinel oxides. Extraction with acid of Mg and Zn from spinel oxides, such as MgMn2O4 and ZnMn2O4, were also found to follow the same mechanism as Li-spinels. The Mg-spinels, however, do experience ion exchange when Mg ions are in the octahedral sites. Chemical extraction of Mg or Zn with an oxidizing agent NO2BF4 in acetonitrile medium, however, failed due to the electrostatic repulsion felt by the migrating divalent ions. In contrast, extraction with acid was successful as Mn dissolution from the lattice opened up favorable pathways for extraction. / text

Η διόρθωση λαθών με κώδικες LDPC είναι μεγάλου ενδιαφέροντος σε σημαντικές νέες τηλεπικοινωνιακές εφαρμογές, όπως δορυφορικό Digital Video Broadcast (DVB) DVB-S2, IEEE 802.3an (10GBASE-T) και IEEE 802.16 (WiMAX). Οι κώδικες LDPC ανήκουν στην κατηγορία των γραμμικών μπλοκ κωδικών. Πρόκειται για κώδικες ελέγχου και διόρθωσης σφαλμάτων μετάδοσης, με κυριότερο χαρακτηριστικό τους τον χαμηλής πυκνότητας πίνακα ελέγχου ισοτιμίας (Low Density Parity Check), από τον οποίο και πήραν το όνομά τους. Η αποκωδικοποίηση γίνεται μέσω μιας επαναληπτικής διαδικασίας ανταλλαγής πληροφορίας μεταξύ δύο τύπων επεξεργαστικών μονάδων. Η υλοποίηση σε υλικό των LDPC αποκωδικοποιητών αποτελεί ένα ραγδαία εξελισσόμενο πεδίο για τη σύγχρονη επιστημονική έρευνα. Σκοπός της παρούσας διπλωματικής εργασίας υπήρξε ο σχεδιασμός, η υλοποίηση και η βελτιστοποίηση αρχιτεκτονικών αποκωδικοποιητών VLSI για κώδικες LDPC. Έχουν αναπτυχθεί διάφοροι αλγόριθμοι αποκωδικοποίησης, οι οποίοι είναι επαναληπτικοί. Μελετήθηκαν αρχιτεκτονικές βασισμένες σε δύο αλγόριθμους, τον log Sum-Product και τον Min-Sum. Ο πρώτος είναι θεωρητικά βέλτιστος, αλλά ο Min-Sum είναι αρκετά απλούστερος και έχει μεγαλύτερο πρακτικό ενδιαφέρον στα πλαίσια μιας ρεαλιστικής εφαρμογής. Συγκεκριμένα, αναπτύχθηκαν δύο αλγόριθμοι αποκωδικοποίησης, οι οποίοι χρησιμοποιούν ως δομικά στοιχεία, τους δύο προαναφερθέντες αλγορίθμους και τη φιλοσοφία του layered decoding. Η μελέτη μας επικεντρώθηκε σε κώδικες, η δομή των πινάκων ελέγχου ισοτιμίας των οποίων, προσφέρεται για υλοποίηση. Για αυτό το λόγο, χρησιμοποιήσαμε κώδικες του προτύπου WiMax 802.16e. Η συνεισφορά της παρούσας εργασίας έγκειται στο σχεδιασμό και την υλοποίηση αποδοτικών αρχιτεκτονικών σε επίπεδο επιφάνειας και ταχύτητας αποκωδικοποίησης (Mbps), καθώς και η διερεύνηση του σχετικού σχεδιαστικού χώρου, χρησιμοποιώντας ως σχεδιαστικές παραμέτρους, τον αλγόριθμο αποκωδικοποίησης, τη χρονοδρομολόγηση των πράξεων, το βαθμό παραλληλίας της αρχιτεκτονικής, το βάθος του pipelining και την αριθμητική αναπαράσταση των δεδομένων. Επιπλέον, είναι σημαντικό να αναφέρουμε πως, στα πλαίσια της σχεδίασης του LDPC αποκωδικοποιητή και με τη βοήθεια του εργαλείου Matlab, αναπτύχθηκαν παραμετρικά scripts για την παραγωγή του VHDL κώδικα. Οι δύο βασικές παράμετροι που χρησιμοποιήθηκαν ήταν το πλήθος των επεξεργαστικών μονάδων και το μήκος λέξης των δεδομένων. Τα scripts αυτά αποτέλεσαν ένα πολύ χρήσιμο εργαλείο κατά τη διαδικασία ανάπτυξης και βελτιστοποίησης της αρχιτεκτονικής, δίνοντας μας τη δυνατότητα να παράγουμε με αυτοματοποιημένο και γρήγορο τρόπο τον VHDL κώδικα, για τις επιμέρους μονάδες του αποκωδικοποιητή. Η υλοποίηση ενός μοντέλου αποκωδικοποιητή σε υλικό, μας δίνει τη δυνατότητα να διεξάγουμε ταχύτατες εξομοιώσεις, σε σχέση με αντίστοιχες υλοποιήσεις σε λογισμικό (π.χ. σε Matlab περιβάλλον). Διαθέτουμε, έτσι, ένα ισχυρό εργαλείο για τη μελέτη της επίδοσης διαφόρων ρεαλιστικών υλοποιήσεων αποκωδικοποιητών. Κατά τη διάρκεια της υλοποίησης, αξιοποιήθηκε αναπτυξιακό σύστημα βασισμένο σε virtex-4 fpga. / LDPC (low-density parity-check) codes are widely applied for error correction, in the development of highly efficient modern digital communication systems, as satellite Digital Video Broadcast (DVB) DVB-S2, IEEE 802.3an (10GBASE-T) and IEEE 802.16 (WiMax). LDPC codes are linear block codes, characterized by a sparse parity-check matrix. They are error detection and correction codes. The most typical decoding procedure is the message passing algorithm that implements the iterative exchange of node-generated messages between two types of processing units, called check and variable nodes. Hardware implementation of an LDPC decoder is a fast growing field for contemporary scientific research. This work presents the results of the design, implementation and optimization of a VLSI decoder for LDPC codes. Several iterative decoding algorithms have been developed. At this work we present architectures based on the log Sum-Product (Log-SP) and Min-Sum algorithm. Log-SP is theoretically optimal; however Min-Sum is substantially simpler and reduces the hardware complexity. Two alternative decoding algorithms have been developed, that use these two algorithms for the check-node LLR update, and the philosophy of layered decoding for the exchange of messages. Our study focused on WiMax 801.16e LDPC codes, whose form, based on permuted identity matrices, is suitable for a hardware realization. The contribution of this work lays within the design and implementation of area and decoding throughput efficient architectures, as well a detailed investigation of design space, using decoding algorithm, message exchange scheduling, pipelining and quantization schemes as design parameters. Furthermore, important to mention is, -the development of parametric Matlab scripts, in order to achieve easy and automated structural VHDL code production. The two key parameters are the number of the processing units and the data length. A hardware realization of a LDPC decoder, gives us a simulation tool that is much faster than corresponding software implementations (for example, a matlab implementation). During the implementation procedure, development board based in virtex-4 fpga has been used.

There are many calculation methods for layered structures in scientific literature, but in most cases these calculation methods are complicated and inapplicable for layered structures made of reinforced concrete. Moreover, most of the calculation methods do not estimate the possibility of appearance of the cracks in the internal layers before the cracks in external layer in which the tensile stresses are higher. The internal layers could be made of lightweight concrete type materials (e.g. foamed concrete) which shrinkage deformations are several times higher if compared to the external layers. Therefore, the cracks in the internal layer may appear even before actual loading of the structure. The flexural layered members may have very complex state of stress and strain. Such state of stress and strain should be estimated when designing the effective and reliable building structures. The proposed method for the calculation of carrying capacity and cracking moment of the external layer of flexural layered reinforced concrete structures estimates the cracking of the internal layer, concrete shrinkage deformations and the physical and mechanical properties of used materials.

There are many calculation methods for layered structures in scientific literature, but in most cases these calculation methods are complicated and inapplicable for layered structures made of reinforced concrete. Moreover, most of the calculation methods do not estimate the possibility of appearance of the cracks in the internal layers before the cracks in external layer in which the tensile stresses are higher. The internal layers could be made of lightweight concrete type materials (e.g. foamed concrete) which shrinkage deformations are several times higher if compared to the external layers. Therefore, the cracks in the internal layer may appear even before actual loading of the structure. The flexural layered members may have very complex state of stress and strain. Such state of stress and strain should be estimated when designing the effective and reliable building structures. The proposed method for the calculation of carrying capacity and cracking moment of the external layer of flexural layered reinforced concrete structures estimates the cracking of the internal layer, concrete shrinkage deformations and the physical and mechanical properties of used materials.

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