The basic fuel unit of the High Temperature Reactor (HTR) of the Pebble Bed Modular Reactor (PBMR) is a uranium dioxide kernel coated with a buffer layer, an inner pyrolytic carbon (IPyC) layer, a silicon carbide (SiC) layer and an outer pyrolytic carbon (OPyC) layer and is commonly referred to as a TRISO particle. Thousands of these micro-spheres are embedded in a graphite matrix and pressed to form a fuel sphere. During the manufacture of the TRISO particles and the fuel spheres there is a production of TRISO particles with cracked/broken layers, especially the SiC layer. Before the irradiation of the fresh fuel in the nuclear reactor it is of the utmost importance to quantify the failed fractions in fresh fuel as this information is very useful in the general understanding of fuel behaviour, calculation of risk and safety margins, and prediction of long term fuel behaviour. For this reason the burn-leach method has been applied for the quality control of the fresh fuel. In this work, several aspects of the burn-leach method that affect the efficiency of the method were studied. Aspects that were investigated are: qualitative aspects, layer properties, quantitative aspects, variants of the burn-leach method and lastly statistical information from the burn-leach data. The results obtained were as follows: Studies in this dissertation suggest that partial leaching of uranium in TRISO particles with a defective SiC layer was a phenomenon that exists. Although UO2 kernel equivalents were successfully determined by burn-leach method for particles with fully broken SiC layers, certain particles leached uranium amounts that did not correspond to single UO2 kernel equivalents; Evidence of occurrences of ‘slow leaching’ in an acidic medium were evident for certain particles. There were remnants of uranium dioxide kernels that had been partially leached after the full 16 hours. This behaviour led to inconclusive results on the absolute number of defective particles in a given population; Investigations suggest that there is at least circumstantial evidence that the BL method combined with X-ray tomography provides information about the integrity of the SiC layer, and why one particle leaches and the other does not. Neither the burn-leach nor the leach-burn-leach analysis is sufficient to be used as a stand-alone method to quantify the number of particles with defective SiC layers in a given TRISO particle population. The two tests need to be coupled to other techniques such as high resolution tomography for an extensive quantification of the layer defects; Burn-leach has to be designed to test for the layer integrity on a microscopic level as opposed to testing for the broken shells only, as was done by the normal burn-leach based on the German program. The leach time was not sufficient in its present form; Burn-leach results indicated that oxidation times of 96 hours at 750 °C under atmospheric pressure did not negatively affect the mechanical strength of the silicon carbide layer of freshly-manufactured TRISO particles, as these particles did not have a high failure fraction. / Dissertation (MSc)--University of Pretoria, 2013. / Materials Science and Metallurgical Engineering / Unrestricted

The purpose of this thesis was to study the influence of manufacturing variations on gear performance. The manufacturing variations inherent in different manufacturing methods were studied to include the effect of real surfaces. Real surfaces have surface irregularities at least on some scale, which can significantly influence how loads are transmitted at the gear contact. To some extent, the lubricant design can help to prevent contact that could lead to tooth failures by forming a protective surface boundary layer. An experimental study was used to consider the compositions of these layers with a surface analysis method. In Paper A a robust design approach was used to find out to what extent the current standard for calculation of surface durability treats manufacturing variations and the choice of lubricant. The results show that the simplest calculation method used is not enough to predict the effect of these on surface durability. Additionally, the standard quality levels are poorly incorporated in the standard calculating procedures for surface durability, and the quality of the gear tooth is restricted to include only a few parameters. In Paper B a pin-on-disc machine was used to evaluate the tribofilm formation by the additives and the corresponding wear occurring in the boundary lubrication regime in environmentally adapted lubricants. Studies of the additive and base fluid interaction were carried out using glow discharge-optical emission spectroscopy. It was found that the chemically reacted surface boundary layers played an important role in terms of wear. More specifically, the oxide layer thickness had significant influence on wear. The findings also demonstrate the complexity of lubrication design formulations coupled to these layers. For example, it was found that the pre-existing surface boundary layer (before any lubricant had been added) played an important role in allowing the lubricant to react properly with the surfaces. The aim of Paper C was to contribute to the knowledge of how different surface topographies, tied to manufacturing methods, influence the early life contact conditions in gears. Topographical measurements of differently manufactured tooth flanks were used as data input to a contact analysis program. The variation in surface topography inherent in the manufacturing method was found to have a strong influence on the contact area ratio.

This project aims to optimise patterns in dress. Prints that rearrange forms have for example been used on warships called Dazzle ships, which disorientate the distance of the ship. Dazzle ships demonstrate the potential of prints and pattern in a dynamic depth for the viewer. Similarly, this project explores these aspects but in relation to the body and its interaction with print and colour. In this project, the method of trial and error of the materials and layers of print challenges the static archetypical print and garment. This is done through photography, color studies, layers and investigations of effects of transparency. This results in a collection that presents a dynamic spectrum of color combinations, prints, and materials.

No description available.

With the growing threat of orbital debris impacts to space structures, the development of space shielding concepts has been a critical research topic. In this study, numerical simulations of the hypervelocity impact response of stacked aluminum 6061-T6 sheets were performed to assess the effects of layering on penetration resistance. This work was initially motivated by set of experimental tests where a stack of four aluminum sheets of equal thickness was observed to have a higher hypervelocity ballistic resistance than a monolithic aluminum sheet with the same total thickness. A set of smoothed particle hydrodynamic simulations predicted a 40% increase in the ballistic limit for a 6-layer target compared to a monolithic sheet. In addition, the effect of variable sheet thickness and sheet ordering on the impact resistance was investigated, while still maintaining a constant overall thickness. A set of thin layers in front of a thick layer generally lead to a higher predicted ballistic limit than the inverse configuration. This work demonstrates an increase in the performance of advanced space shielding structures associated with multi-layering. This suggests that it may be possible to dramatically improve the performance of such structures by tailoring the material properties, interfaces, and layering concepts.

Görtler vortices develop in boundary layer flows over concave surfaces due to the imbalance between centrifugal forces and the wall-normal pressure gradient. These vortices can be efficient precursors to transition in boundary layers exposed to free-stream disturbance or surface non-uniformities, because they can alter the mean flow causing the laminar flow to breakdown into turbulence. In this thesis, a control technique aimed at reducing the energy associated with Görtler vortices that develop in supersonic boundary layers is introduced and tested. The control algorithm is based on distributed blowing and suction, with sensors placed either in the flow or at the wall. The result show that there is a dependence between the efficiency of the control algorithm and the spanwise separation of the vortices, that is the energy reduction is more significant for larger spanwise separations. The efficiency of the control algorithm seems to be insensitive to the variation of the Mach number.

Mycoplasma gallisepticum (MG) is a major and economically significant pathogen of avian species. Different strains of MG have been used as vaccines in multiple-age commercial layer farms in an effort to protect the birds against more virulent field strains. The lower level of protection afforded by the low virulent MG strain vaccines provides an opportunity to the use of an overlay (revaccination) with an F-strain M. gallisepticum (FMG) later in their production cycles. In the present study, three trials were conducted to investigate the effects of prelay vaccinations of ts-11 strain MG, MG-Bacterin, or their combination, in conjunction with a FMG overlay after peak production in commercial layers. The following treatments were utilized at 10 wk of age (woa): 1) Control (no vaccinations); 2) ts-11 MG vaccine; 3) MG-Bacterin vaccine; and 4) ts-11 MG and MG-Bacterin combination. At 45 woa, all the birds in trial 1 and half of the birds in each treatment group in trials 2 and 3 were overlaid with an FMG vaccine. Various parameters including performance, internal egg and eggshell quality, blood, and visceral characteristics of the birds were evaluated. In this study, the ts-11 MG vaccination at 10 woa was shown to increase shell weight and the yolk lipid content of the eggs laid by the birds without affecting their performance. On the other hand, a prelay vaccination with MG-Bacterin did not prevent a drop in egg production in response to an overlay with FMG at 45 woa. A decrease in proportional infundibulum length in the control birds and MG-Bacterin vaccinated birds after being overlaid with FMG might be the underlying factor responsible for the observed decrease in egg production. Nevertheless, the prelay use of MG-Bacterin together with ts-11 MG didn’t appear to provide any additional benefit over the ts-11 MG vaccine alone on any of the parameters investigated. In conclusion, these results establish the potentially effective prelay use of the ts-11 MG vaccine in combination with an FMG overlay for the provision of continual protection against field strain MG infections, without eliciting any subsequent suppressive effects on the performance of commercial layers.

Minimally disturbed virgin forest soils in the Little Santeetlah Creek (LSC) watershed of western North Carolina were sampled along with soils from the adjacent disturbed Slickrock Creek (SRC) watershed. Soils with similar elevation/landform/vegetation/parent material characteristics were initially sampled at nine random locations each on north and south aspects within each watershed with a soil push probe. Some differences in parent materials were noted on south aspects (metasandstone vs. phyllite), but parent materials under north aspect soils were identical (metasandstone). Soils in LSC were significantly deeper and relatively free of solum coarse fragments while SRC soils were shallower and higher in coarse fragments. Subsequent auger observations of three typical pedons on each aspect indicated that soils in LSC were well-developed with gradual horizon boundaries and common diffuse transition horizons, while soils in SRC were more compact in horizonation and lacked diffuse transitional horizons. Vegetation communities were similar across both watersheds, except that SRC south sites were higher in Pinus spp. Litter layer morphology differed strongly between the two watersheds. Specifically, well-developed humus (H) layers were typical in LSC, but completely absent in all typical pedons described in SRC. Data obtained from these two watersheds indicate strong differences in surface soil (O + A horizon) properties between the two. These observed differences could be due to differential anthropogenic effects, particularly logging and associated erosion in the early 1920's. However, further study over multiple disturbed watersheds in the region, and of the distribution of sediments and colluvium within them would be required to test this hypothesis. / Master of Science

The focus of my thesis is the examination of the formal layers of a building through their material and temporal natures and the interactions of these layers. The examination of the interplay between the new and the old, the coarse and the refined, the organic and the man-made, form the boundaries of my study. Rooting my study in an existing foundry building in Pulaski, Virginia, a new public library is allowed to unfold through the interaction of concrete, steel, and wood interventions into a masonry shell. / Master of Architecture

Neste trabalho, camadas de elevadas durezas e resistentes ao desgaste, constituídas de NbC, VC ou Fe-B, foram produzidas nos aços AISI H13 e D2, por meio de tratamentos termo-reativos em banhos de bórax, com adição de Fe-Nb, Fe-V, Fe-Ti e Al. As amostras foram caracterizadas por meio de microscopias ótica e eletrônica de varredura com EDS (espectroscopia de dispersão de energia), difração de raios-X, GDOS (“Glow discharge optical spectroscopy"), microdureza Vickers, e ensaios de adesividade e desgaste em micro-escala. Para os banhos contendo Fe-Nb/Al, foram obtidas camadas de NbC nos dois aços, com espessuras médias de 6,2 mícrons, quando produzida no aço AISI H13, e 15,6 mícrons para o aço AISI D2. No caso do banho com adição de Fe-V/Al, produziram-se camadas de VC, com espessuras médias de 5,8 e 14,2 mícrons, para os aços AISI H13 e D2, respectivamente. As durezas das camadas de NbC e VC situaram-se na faixa de 2338 a 2471HV. No caso dos banhos contendo Fe-Ti e Al ou apenas Al, foram produzidas camadas de boretos, principalmente FeB e Fe2B, com espessuras variando de 30 a 130 mícrons, e durezas médias na faixa de 1583 a 1742HV. Os ensaios de adesividade evidenciaram as excelentes aderências das camadas com os substratos. Todas as camadas apresentaram resistências ao desgaste muito superiores as dos substratos, destacando-se as camadas de NbC e VC. Os ensaios de desgaste em micro-escala foram realizados sob carga elevada e sem uso de abrasivo, simulando condições de desgaste adesivo-abrasivo, uma vez que inexistem dados a respeito desse comportamento. Com o decorrer do ensaio, o modo de desgaste passou de adesivo para abrasivo, o que foi registrado pela presença de sulcos paralelos e de superfícies polidas nas calotas de desgaste. / In the present work, hard and wear resistant layers, consisting of NbC, VC or Fe-B, were produced on AISI H13 and D2 steels, by thermo-reactive treatments in borax baths, added with Fe-Nb, Fe-V, Fe-Ti and Al. Samples were characterized by optical and scanning electron microscopy, energy dispersive X-ray spectrometry (EDS), X-ray diffraction (XRD), Glow discharge optical spectroscopy (GDOS), Vickers microhardness, and adhesion and micro-scale wear tests. For the baths containing Fe-Nb/Al, the layers obtained on both steels consisted of NbC, with an average thickness of 6.2 micrometers, when formed on AISI H13 steel, and 15.6 micrometers for the AISI D2 steel. In the case of borax bath added with Fe-V/Al, the produced layers contained VC, which had average thicknesses of 5.8 and 14.2 micrometers, for the AISI H13 and D2 steels, respectively. The hardness of the NbC and VC layers varied from 2338 to 2471HV. In the case of the borax bath containing Fe-Ti and Al or only Al, boride layers were produced, mainly FeB and Fe2B, with depths ranging from 30 to 130 micrometers, and average hardnesses varying from 1583 to 1742HV. The obtained layers presented excellent adhesion to the substrates. All layers presented wear resistance superior to the substrates, mainly the NbC and VC layers. The micro-scale wear tests were performed under high applied loads and without addition of abrasive, thus simulating adhesive-abrasive wear conditions, as there is no existing data concerning this wear behavior. During the micro-scale wear test, the wear mode changed from adhesive wear to abrasive wear, which was verified by the presence of parallel grooves and smooth surfaces in the wear craters.