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Em janeiro de 2011, o grande número de escorregamentos naturais e induzidos que afetaram a Região Serrana do Estado do Rio de Janeiro, durante o Megadesastre, são processos destruidores de grande impacto, mas com tempo de recorrência maior. Em particular a bacia do rio Vieira (noroeste de Teresópolis), afetada pelo evento, apresentou magnitude espetacular do desastre registrado, com os materiais mobilizados em fluxos gravitacionais de massa atingindo quilômetros de distâncias das suas escarpas principais, o que causou, horas depois, prejuízos significativos. A pesquisa da presente dissertação discutiu a caracterização destes processos e dos ambientes deposicionais, a partir da análise das feições sedimentológicas e apreciação das características mecânicas, do vale do rio Vieira para estabelecer base de conhecimento da evolução da paisagem local. O método de trabalho utilizou o reconhecimento dos condicionantes geológicos e a leitura do registro sedimentar. A corrida de massa do Vieira foi zoneada em diferentes estágios de comportamento baseado na classificação de fluxos gravitacionais de massa de Middleton e Hampton (1973). Esta classificação é adequada para linha de pesquisa, pois os autores definem fluxos gravitacionais de sedimentos como um termo geral para fluxos de sedimentos ou misturas sedimentos/fluidos, que fluem sob a ação da gravidade. Os resultados obtidos caracterizam o fenômeno do ponto de vista geológico, estratigráfico e geomorfológico. Uma corrida de massa afetou o canal do rio Vieira desde a sua nascente, na cota 1750m, até o fim da sua planície de inundação, na cota 900m; o movimento de massa com extensão de 7,5km, 30-100m de largura máxima e 4m de espessura média, causou diretamente 86 mortes e a destruição de casas e lavouras da zona rural do bairro Vieira, Teresópolis-RJ. O fluxo gravitacional do Vieira aparentemente contou com diferentes condicionantes e envolveu diferentes fases, passando pelo debrisflow e pelo mudflow, provavelmente em diferentes pulsos, e no seu estágio final para o waterflow. / In January 2011, a large number of natural and induced landslides hit the mountainous region of Rio de Janeiro State, during the megadesastre, which is destructive processes of great impact, but with greater recurrencetime. In particular, the Vieira River basin (northwest of Teresópolis), affected by the event, registered a big magnitude of the disaster with mobilized materials in mass flows reaching distances of kilometers from their main scarps, what caused hours later, significant damages. This dissertation research discussed these processes characterization and its depositional environments, from a sedimentological analysis of those features and assessing their mechanical characteristics of Vieira river valley to establish the knowledge of local landscape evolution. The results characterize the phenomenon in geological, geomorphological and stratigraphicterms. Vieira river channel was afcted by a gravity flow from its source, at 1750m in elevation, to its end on its floodplain, at elevation 900m, was carachterized as a mass movement with an extension of 7.5 km, 30-100m wide and 4m thick, directly caused 86 deaths and alsohouses and crops destruction at rural neighborhood from Vieira, Teresópolis, Rio de Janeiro. The gravity flow of Vieira River apparently had different conditions and different stages involved, from debrisflow to mud-flow, probably in different pulses, and in its final stage being water flow.

Em janeiro de 2011, o grande número de escorregamentos naturais e induzidos que afetaram a Região Serrana do Estado do Rio de Janeiro, durante o Megadesastre, são processos destruidores de grande impacto, mas com tempo de recorrência maior. Em particular a bacia do rio Vieira (noroeste de Teresópolis), afetada pelo evento, apresentou magnitude espetacular do desastre registrado, com os materiais mobilizados em fluxos gravitacionais de massa atingindo quilômetros de distâncias das suas escarpas principais, o que causou, horas depois, prejuízos significativos. A pesquisa da presente dissertação discutiu a caracterização destes processos e dos ambientes deposicionais, a partir da análise das feições sedimentológicas e apreciação das características mecânicas, do vale do rio Vieira para estabelecer base de conhecimento da evolução da paisagem local. O método de trabalho utilizou o reconhecimento dos condicionantes geológicos e a leitura do registro sedimentar. A corrida de massa do Vieira foi zoneada em diferentes estágios de comportamento baseado na classificação de fluxos gravitacionais de massa de Middleton e Hampton (1973). Esta classificação é adequada para linha de pesquisa, pois os autores definem fluxos gravitacionais de sedimentos como um termo geral para fluxos de sedimentos ou misturas sedimentos/fluidos, que fluem sob a ação da gravidade. Os resultados obtidos caracterizam o fenômeno do ponto de vista geológico, estratigráfico e geomorfológico. Uma corrida de massa afetou o canal do rio Vieira desde a sua nascente, na cota 1750m, até o fim da sua planície de inundação, na cota 900m; o movimento de massa com extensão de 7,5km, 30-100m de largura máxima e 4m de espessura média, causou diretamente 86 mortes e a destruição de casas e lavouras da zona rural do bairro Vieira, Teresópolis-RJ. O fluxo gravitacional do Vieira aparentemente contou com diferentes condicionantes e envolveu diferentes fases, passando pelo debrisflow e pelo mudflow, provavelmente em diferentes pulsos, e no seu estágio final para o waterflow. / In January 2011, a large number of natural and induced landslides hit the mountainous region of Rio de Janeiro State, during the megadesastre, which is destructive processes of great impact, but with greater recurrencetime. In particular, the Vieira River basin (northwest of Teresópolis), affected by the event, registered a big magnitude of the disaster with mobilized materials in mass flows reaching distances of kilometers from their main scarps, what caused hours later, significant damages. This dissertation research discussed these processes characterization and its depositional environments, from a sedimentological analysis of those features and assessing their mechanical characteristics of Vieira river valley to establish the knowledge of local landscape evolution. The results characterize the phenomenon in geological, geomorphological and stratigraphicterms. Vieira river channel was afcted by a gravity flow from its source, at 1750m in elevation, to its end on its floodplain, at elevation 900m, was carachterized as a mass movement with an extension of 7.5 km, 30-100m wide and 4m thick, directly caused 86 deaths and alsohouses and crops destruction at rural neighborhood from Vieira, Teresópolis, Rio de Janeiro. The gravity flow of Vieira River apparently had different conditions and different stages involved, from debrisflow to mud-flow, probably in different pulses, and in its final stage being water flow.

A selective combination of the principles of a thermal mass flow meter and constant temperature anemometry was used to develop a solid mass flow meter that improves significantly on the flow meter developed by De Vos et al (2010). The flow meter has a measurement plate that is kept at a constant temperature. Due to conductive heat transfer between the entrained solids and the measurement plate, additional power is needed to maintain the plate at this setpoint temperature value. This additional power was correlated against the average solids flow rate. The calibration curve shows a linear relationship between the power measurement and the entrainment flux for entrainment fluxes between 3.4 x 10-4 kg/(m2.s) and 7.5 x 10-3 kg/(m2.s). Deviation from a linear response at lower entrainment fluxes may be caused by a longer residence time of fine particles on the measurement plate due to lower shear forces. At higher entrainment fluxes the power measurements were unreliable due to poor temperature control. The turndown ratio of the linear section of the calibration curve is approximately 3 times that of the linear part of the calibration curve of the flow meter developed by De Vos et al (2010). Even further improvement is possible with better temperature control. In a case study to test the applicability of the flow meter to measure changes in entrainment rate associated with hydrodynamic properties other than a change in gas superficial velocity, small amounts of ethanol were dosed to the inlet air. The continuously measured entrainment rate increased at lower ethanol dosing rates but decreased as the dosing rate of ethanol was increased. The increase in entrainment rate may be explained by a reduction in static electricity in the bed, while the decrease at higher dosing rates may be as a result of increased powder cohesivity. / Dissertation (MEng)--University of Pretoria, 2012. / Chemical Engineering / unrestricted

Indiana University-Purdue University Indianapolis (IUPUI) / This study contributes to a better understanding of ignition by hot combustion gases which finds application in internal combustion chambers with pre-chamber ignition as well as in wave rotor engine applications. The experimental apparatus consists of two combustion chambers: a pre chamber that generates the transient hot jet of gas and a main chamber which contains the main fuel air blend under study. Variables considered are three fuel mixtures (Hydrogen, Methane, 50\% Hydrogen-Methane), initial pressure in the pre-chamber ranging from 1 to 2 atm, equivalence ratio of the fuel air mixture in the main combustion chamber ranging from 0.4 to 1.5, and initial temperature of the main combustion chamber mixture ranging from 297 K to 500 K. Experimental data makes use of 4 pressure sensors with a recorded sampling rate up to 300 kHz, as well as high speed Schlieren imaging with a recorded frame rate up to 20,833 frame per seconds. Results shows an overall increase in ignition delay with increasing equivalence ratio. High temperature of the main chamber blend was found not to affect hot jet ignition delay considerably. Physical mixing effects, and density of the main chamber mixture have a greater effect on hot jet ignition delay.

After undergoing an extensive study about engine air mass flow measurement approaches as well as engine modelling for air mass flow prediction, a major problem found to exist is that engineers have still not found a suitable technique to accurately measure the air mass flow entering the cylinder of an internal combustion engine. The engine air mass flow is the most important parameter needed during engine development so the fuel control can be accurately calibrated and as a result increase performance and reduce emission output of an engine. The current methods used to determine the air mass flow lead to inaccuracies due to the large amount of mathematical assumptions and also sensor errors and as a result the mapping and calibration process of a new engine family takes approximately 2 years due to extensive modelling and testing required overcoming the above drawbacks. To improve this, the distributed lumped modelling technique (D-L) of the inlet manifold was chosen, where the intake system is separated into very small sections which are distributed continuously throughout the volume of the intake until entering the cylinder. This technique is validated against a CFD model of the engine’s intake system and real engine data as well as a 1D engine model.

An examination of various methods for mass flow rate measurements was undertaken to evaluate their applicability for measuring refrigerant R-134a two-phase mass flow in refrigeration and air-conditioning equipment. An experimental apparatus was constructed to generate the required two-phase flow conditions. A turbine and a venturi flowmeter were used together with either a capacitance transducer or a gamma densitometer to determine the two-phase mass flow rate. The time-averaged void fraction was measured using a capacitance transducer and a gamma densitometer. Their measurements were in good agreement. Hence, for mass flow rate measurements, the capacitance transducer was used as the void fraction meter because of its ease of operation. A number of models were used to combine the output of either the turbine flowmeter or the venturi flowmeter, with the void fraction measurement to estimate the mass flow rate. It was found that, within the range of experimental data tested in the present work, the venturi flowmeter, in conjunction with Chisholm's model, provided the best agreement with the experimental results. / Thesis / Master of Engineering (MEngr)

Considerable effort worldwide has gone into monitoring heat and mass transfer at active volcanoes, as this information may provide clues about changes in volcanic activity and impending eruptions. One method used is the self-potential (SP) method, which has been employed on volcanoes to map hydrothermal systems and structural features and to monitor changes in the hydrothermal system due to volcanic activity. Continuous monitoring of SP has been employed on a few volcanoes and has produced encouraging results. This study presents new time series data collected from continuous monitoring stations at Masaya and Telica, and spatial series data from Masaya, Telica, and Cerro Negro, three active volcanoes in Nicaragua. The primary goals of this study were to determine whether correlations between SP anomalies and CO2 flux exist and to investigate temporal variations in temperature, SP, rainfall, and barometric pressure. To achieve these goals, SP and CO2 flux surveys were conducted on Masaya, Telica, and Cerro Negro, and continuous monitoring stations were installed on Masaya and Telica. The continuous monitoring station on Masaya recorded temperature, SP, rainfall, and barometric pressure. The station on Telica recorded temperature and SP. Profiles collected on Masaya and Cerro Negro show broad correlation between SP and CO2 flux. However, profiles on Telica revealed virtually no SP anomaly or CO2 flux for the majority of the profile, at the time of data collection. Data collected from the continuous monitoring station at Masaya showed a persistent positive SP anomaly that fluctuated between 60 and 240 mV. Rainfall was seen to supress the anomaly for time scales of several hours to several days. Correlations between temperature, SP, and barometric pressure were also seen at Masaya. Curiously, no increases in SP were seen during two temperature transients that occurred during volcanic activity in June and October. Continuous monitoring data from Telica showed only decreases in temperature and SP, which coincided with rainfall. The continuous monitoring data collected in this study and others have begun to provide a better understanding of the nature of SP anomalies, which may aid in the development of the SP method as a volcano monitoring tool.

After water vapour, CO₂ is the most abundant gas associated with magmatic hydrothermal systems. The detection of anomalous soil temperature gradients, and/or a significant flux of magmatic volatiles, is commonly the only surface signature of an underlying high temperature reservoir. For both heat (as water vapour) and gas to ascend to the surface, structural permeability must exist, as the unmodified bulk permeability of reservoir rock is too low to generate the focussed fluid flow typical of magmatic hydrothermal systems. This thesis reports the investigation into the surface heat and mass flow of the Ohaaki hydrothermal field using detailed surface measurements of CO₂ flux and heat flow. Detailed surface measurements form the basis of geostatistical models that quantify and depict the spatial variability of surface heat and mass flow, across the surface of both major thermal areas, as high resolution pixel plots. These maps, in conjunction with earlier heat and mass flow studies, enable: (i) estimates of the pre-production and current CO₂ emissions and heat flow for the Ohaaki Field; (ii) interpretation of the shallow permeability structures governing fluid flow, and; (iii) the spatial relationships between pressure-induced ground subsidence and permeability. Heat flow and CO₂ flux surveys indicate that at Ohaaki the soil zone is the dominant (≥ 70% and up to 99%) pathway of heat and mass release to the atmosphere from the underlying hydrothermal reservoir. Modelling indicates that although the total surface heat and mass flow at Ohaaki is small, it is highly focused (i.e., high volume per unit area) relative to other fields within the Taupo Volcanic Zone (TVZ). Normalised CO₂ emissions are comparable to other volcanic and hydrothermal fields both regionally and globally. Despite 20 years of production, there is little difference between pre-production and current CO₂ emission rates. However, the similarity of CO₂ emission rates masks a 40% increase in CO₂ emissions from new areas of intense steaming ground that have developed in response to production of the field for electrical energy production. This increase in thermal ground emissions is offset by emission losses associated with the drying up of all steam heated pools and alkali-Cl outflows from the Ohaaki West (OHW) thermal area, in response to production-induced pressure decline. The location of surface thermal areas is governed by the occurrence of buried or partially emergent lava domes, whereas the magnitude of CO₂ flux, mass flow, and heat flow occurring within each thermal area is determined by the proximity of each dome (thermal areas) to major upflow zones. Buried or partially emergent silicic lava domes act as cross-stratal pathways for fluid flow, connecting the underlying reservoir to the surface, and bypassing several hundred metres of the poorly permeable Huka Falls Formation (HFF) caprock. For each dome complex the permeable structures governing fluid flow are varied. At Ohaaki West, thermal activity is controlled by a deep-rooted concentric fracture zone, developed during eruption of the Ohaaki Rhyolite dome. Within the steam-heated Ohaaki East (OHE) thermal area, flow is controlled by a high permeability fault damage zone (Broadlands Fault) developed within the apex of the Broadlands Dacite dome. Structures controlling alkali-Cl fluid flow at OHW also iii appear to control the occurrence and shape of major subsidence bowls (e.g., the Main Ohaaki Subsidence Bowl), the propagation of pressure decline to surface, and the development and localization of pore fluid drainage. Across the remainder of the Ohaaki field low amplitude ground subsidence is controlled by the extent of aquifer and aquitard units that underlie the HFF, and proximity to the margins of the hot water reservoir. The correlation between the extent of low amplitude ground subsidence and the margins of the field reflects the coupled relationship between the hot water reservoir and reservoir pressure. Only where thick vapour-phase zones buffer the vertical propagation of deep-seated pressure decline to the surface (i.e., OHE thermal area), is ground subsidence not correlated with subvertical structural permeability developed within the HFF. This thesis makes contributions to regional and global research on geothermal and hydrothermal systems by: (i) quantifying the origin, mass, and upward transport of magmatic carbon from geothermal reservoirs; (ii) assessing the changes to the natural surface heat and mass flow of the Ohaaki Field following 20 years of production; (iii) establishing the utility of surface CO₂ flux and heat flow surveys to identify major upflow zones, estimate minimum mass flow, and determine the enthalpy of reservoirs; (iv) providing insight into the hydrothermal, structural and lithological controls over hydrothermal fluid flow; (v) demonstrating the influence of extinct silicic lava domes as important structural elements in the localisation of hydrothermal fluid flow; (vi) identifying the hydrostructural controls governing the spatial variability in the magnitude of pressure-induced ground subsidence, from which predictive models of subsidence risk may be defined, and; (vii) developing new technologies and characterising methods used for detailed assessment of surface heat and mass flow.