In this thesis there were two main purposes, the first one being to investigate effects of zinc borate (ZB) on the flammability behavior of ABS when used with and without a traditional brominated flame retardant (BFR) / antimony trioxide (AO) system. The second purpose was to investigate contribution of nanoclays (NC) to the flame retardancy performance of the same traditional BFR compound with various combinations of AO and ZB again in ABS matrix. For these purposes, materials were melt compounded by using a laboratory scale twin-screw extruder, while specimens were produced by injection or compression molding. Flame retardancy of the specimens were investigated by Mass Loss Cone Calorimeter (MLC), Limiting Oxygen Index (LOI) measurements and UL-94 vertical burning tests. Other characterization techniques required in this thesis were / X-ray diffraction analysis, scanning and transmission electron microscopy, thermogravimetric analysis and tensile tests. Studies for the first purpose indicated that almost all flame retardancy parameters were preserved when antimony trioxide were replaced with zinc borate as much as in the ratio of 1:3. Residue analyses revealed that predominant flame retardancy mechanism of traditional system was gas phase action, while zinc borate contributes especially in the condensed phase action by forming thicker and stronger char layer. Investigations for the second purpose basically concluded that use of nanoclays improved all flame retardancy parameters significantly. Residue analyses pointed out that nanoclays especially contribute to the formation of stronger and carbonaceoussilicate char acting as a barrier to heat and flammable gases and retarding volatilization via tortuous pathway. As an additional third purpose in this thesis, usability of three boron compounds (zinc borate ZB, boric acid BA, boron oxide BO) with two traditional flame retardants (organic phosphinate OP and melamine cyanurate MC) in neat PET and recycled PET were also examined leading to some promising results in MLC parameters.

In this thesis, there were four purposes. The first one was to investigate effects of nanoclays (NC) on the flammability behavior of polystyrene (PS). The second purpose was to investigate contribution of nanoclays to the flame retardancy performance of conventional phosphorus based flame retardant / triphenyl phosphate (TPP) and its synergist melamine cyanurate (MCA). For the third purpose contribution of nanoclays to the flame retardancy performance of another conventional halogenated flame retardant / brominated epoxy polymer (BE) and its synergist antimony trioxide (AO) was investigated. As the fourth purpose, effects of another nanoadditive / carbon nanotubes (CNTs) on the flammability behavior of PS with and without BE-AO flame retardant system was investigated. Materials were prepared via &ldquo / solution mixing&rdquo / method, while test specimens were shaped by compression and injection molding. Flammability behaviors were investigated by Mass Loss Cone Calorimeter (MLC), Limiting Oxygen Index (LOI) and UL-94 Vertical Burning tests. Other characterization techniques required in this thesis were / X-ray diffraction analyses, scanning and transmission electron microscopy, thermogravimetric analyses and tensile tests. It was revealed that use of nanoclays improved flame retardancy of PS significantly, mainly with &ldquo / condensed phase&rdquo / mechanism via formation of strong char barrier layers inhibiting mass and heat transfer. When nanoclays were used together with conventional flame retardant systems TPP-MCA and BE-AO, flame retardancy parameters improved further, this time due to the &ldquo / synergistic action&rdquo / of &ldquo / condensed phase mechanism&rdquo / of nanoclays and &ldquo / gas phase mechanism&rdquo / of the conventional systems. Use of carbon nanotubes also resulted in improvements in the flame retardancy of PS. However, &ldquo / condensed phase mechanism&rdquo / of CNTs were not as effective as the NCs, which might be due to the lower performance of 1D geometry (CNTs) compared to higher efficiency of 2D geometry (NC) in barrier formation. As an additional purpose, effects of mixing methods in the production of PS-Nanoclay composites were also investigated. It was seen that compared to &ldquo / solution mixing&rdquo / use of &ldquo / in-situ polymerization&rdquo / resulted in poorer flame retardancy parameters that might basically be due to residual monomers or oligomers left during polymerization.

The long term goal of this research is to improve the fire resistance of gypsum wallboard (GWB). Gypsum wallboard consists mainly of gypsum, i.e. calcium sulfate dihydrate, CaSO4•2H2O. In buildings, the chemical, mechanical and thermal properties of gypsum wallboard play an important role in delaying the spread of fire. To build a fire resistant GWB, it is very important to study the thermal, mechanical, physical and chemical properties of regular GWB and various types of fire-resistant wallboards available commercially in the market. Various fire-resistant GWBs have been compared and contrasted with reference to a standard wallboard in this study. Regardless of the type of wallboard, the main component is gypsum. The fire resistance property is mainly attributed to the absorption of energy related with the loss of hydrate water going from the dihydrate (CaSO4•2H2O) form to the hemihydrate (CaSO4•½H2O) and from the hemihydrate to the anhydrous form (CaSO4) in a second dehydration. The present paper is a comparative study of commercially available standard, fire-rated Type X and firerated Type C gypsum wallboards. Type X wallboards are typically reinforced with noncombustible fibers so as to protect the integrity of the wallboard during thermal shrinkage, while the Type C wallboards are incorporated with more glass fibers and an additive, usually a form of vermiculite. These Type C wallboards have a shrinkage adjusting element that expands when exposed to elevated temperature. Differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), thermomechanical analysis (TMA), scanning electron microscopy (SEM) and powder X-ray diffraction (XRD) were used to characterize and compare the materials. Various properties, such as the heat flow, weight loss, dimensional changes, morphology and crystalline structures of the gypsum wallboards were studied using these techniques.

Context. At the end of their lives, most stars lose a significant amount of mass through a stellar wind. The specific physical and chemical circumstances that lead to the onset of the stellar wind for cool luminous stars are not yet understood. Complex geometrical morphologies in the circumstellar envelopes prove that various dynamical and chemical processes are interlocked and that their relative contributions are not easy to disentangle. Aims. We aim to study the inner-wind structure (R < 250 R-star) of the well-known red supergiant VY CMa, the archetype for the class of luminous red supergiant stars experiencing high mass loss. Specifically, the objective is to unravel the density structure in the inner envelope and to examine the chemical interaction between gas and dust species. Methods. We analyse high spatial resolution (similar to 0 ''.024 x 0 ''.13) ALMA science verification (SV) data in band 7, in which four thermal emission lines of gaseous sodium chloride (NaCl) are present at high signal-to-noise ratio. Results. For the first time, the NaCl emission in the inner wind region of VY CMa is spatially resolved. The ALMA observations reveal the contribution of up to four different spatial regions. The NaCl emission pattern is different compared to the dust continuum and TiO2 emission already analysed from the ALMA SV data. The emission can be reconciled with an axisymmetric geometry, where the lower density polar/rotation axis has a position angle of similar to 50 degrees measured from north to east. However, this picture cannot capture the full morphological diversity, and discrete mass ejection events need to be invoked to explain localized higher-density regions. The velocity traced by the gaseous NaCl line profiles is significantly lower than the average wind terminal velocity, and much slower than some of the fastest mass ejections, signalling a wide range of characteristic speeds for the mass loss. Gaseous NaCl is detected far beyond the main dust condensation region. Realising the refractory nature of this metal halide, this hints at a chemical process that prevents all NaCl from condensing onto dust grains. We show that in the case of the ratio of the surface binding temperature to the grain temperature being similar to 50, only some 10% of NaCl remains in gaseous form while, for lower values of this ratio, thermal desorption efficiently evaporates NaCl. Photodesorption by stellar photons does not seem to be a viable explanation for the detection of gaseous NaCl at 220 R-star from the central star, so instead, we propose shock-induced sputtering driven by localized mass ejection events as an alternative. Conclusions. The analysis of the NaCl lines demonstrates the capabilities of ALMA to decode the geometric morphologies and chemical pathways prevailing in the winds of evolved stars. These early ALMA results prove that the envelopes surrounding evolved stars are far from homogeneous, and that a variety of dynamical and chemical processes dictate the wind structure.

No description available.

Measurements of secular period change probe real-time stellar evolution of classical Cepheids making these measurements powerful constraints for stellar evolution models, especially when coupled with interferometric measurements. In this work, we present stellar evolution models and measured rates of period change for two Galactic Cepheids: Polaris and l Carinae, both important Cepheids for anchoring the Cepheid Leavitt law (period-luminosity relation). The combination of previously-measured parallaxes, interferometric angular diameters and rates of period change allows for predictions of Cepheid mass loss and stellar mass. Using the stellar evolution models, We find that l Car has a mass of about 9 M S™ consistent with stellar pulsation models, but is not undergoing enhanced stellar mass loss. Conversely, the rate of period change for Polaris requires including enhanced mass-loss rates. We discuss what these different results imply for Cepheid evolution and the mass-loss mechanism on the Cepheid instability strip.

Circular polarization from the Zeeman effect is difficult to detect whenever the ratio of the magnetic field strength to the linewidth is small, as might be expected in the winds of hot stars. However, globally structured fields, such as radially swept fields, do present a characteristically complex Zeeman signature that can be distinguished from noise even when small, because of its telltale features that are antisymmetric about the line. If the emission lines are skewed blueward, a signature of photospheric occultation of the redshifted hemisphere, we find that occultation will also reduce the detectability of the Zeeman effect on the red side of the line, further limiting our ability to detect weak magnetic fields in hypersonic winds. Hence, as instrumental precision improves sufficiently, symmetric emission lines will present advantages over lines skewed blueward by occultation, when seeking a Zeeman signal.

The stellar winds of hot stars have an important impact on both stellar and galactic evolution, yet their structure and internal processes are not fully understood in detail. One of the best nearby laboratories for studying such massive stellar winds is the O4I(n)fp star ζ Pup. After briefly discussing existing X-ray observations from Chandra and XMM, we present a simulation of X-ray emission line profile measurements for the upcoming 840 kilosecond Chandra HETGS observation. This simulation indicates that the increased S/N of this new observation will allow several major steps forward in the understanding of massive stellar winds. By measuring X-ray emission line strengths and profiles, we should be able to differentiate between various stellar wind models and map the entire wind structure in temperature and density. This legacy X-ray spectrum of ζ Pup will be a useful benchmark for future X-ray missions.

Massive binary evolution is crucial for our understanding of many pheno- mena in the Universe, such as high-mass X-ray binaries or the formation of compact systems emitting gravitational waves. In this work, we study the loss of angular momentum from binary systems caused by radiation driven stellar winds, which are characteristic for hot, massive stars. Calculating numerically ballistic trajectories of particles ejected from the binary surface, we establish the average specific angular momentum loss as a function of the system's mass ratio for binaries in semidetached and contact stages. We initiate the outflow on the Roche lobes or even on further equipotentials of the Roche potential in case of over-contact systems. Moreover, we implement two models of the radiation driven wind. Firstly, we eject particles from the surface of the binary with a non-zero initial velocity, but we then let them evolve only under the influence of the system's gravity. In the second model, we develop a simple method for computing the radiative acceleration due to the radiation pressure from the bi- nary surface. Our results can be used in further calculations of the evolution of massive binary systems.

This thesis is focused on determining the durability characteristics of asphalt mixtures containing bio-based additives for the purpose of more effective use of recycled materials. Fifty mixtures were evaluated by Cantabro Mass Loss testing in their virgin state, after 1 year of field aging, and after laboratory conditioning to determine the effectiveness of bioditives in dense graded asphalt and sand asphalt mixtures. Key findings from this work demonstrated that considerable amounts of recycled asphalt shingles (i.e. 5% of the total mixture) significantly affect the brittleness of dense graded asphalt mixtures when used in conjunction with reclaimed asphalt pavement (RAP). Furthermore, brittleness was not improved with the use of bioditives at high dosages (e.g. greater than 7.5% of the total binder content), but was improved in some cases at lower dosage rates (e.g. 2.5-5%). Additional testing of similar mixtures and bioditives evaluated in this thesis are recommended.