This work deals with the calibration of contact and contactless thermometers. The theoretical part describes physical laws, which are important for contact and contactless measuring of temperature, requirements for thermometers, suitability of use different types of thermometers and materials used for construction of temperature sensors. The following part describes metrology with the focus on metrology system of the Czech Republic. This thesis also describes errors and uncertainties of measurments, especially on their division, sources of uncertainties and methodology of type A and type B uncertainty determination. The practical part is focused on the calibration of thermometers within the Czech Metrological Institute and the Faculty of Electrical Engineering and Communication in Brno.

Converging cylindrical shock waves have been studied experimentally. Numericalcalculations based on the Euler equations and analytical comparisons basedon the approximate theory of geometrical shock dynamics have been made tocomplement the study.Shock waves with circular or polygonal shock front shapes have been createdand focused in a shock tube. With initial Mach numbers ranging from 2 to4, the shock fronts accelerate as they converge. The shocked gas at the centreof convergence attains temperatures high enough to emit radiation which isvisible to the human eye. The strength and duration of the light pulse due toshock implosion depends on the medium. In this study, shock waves convergingin air and argon have been studied. In the latter case, the implosion lightpulse has a duration of roughly 10 μs. This enables non-intrusive spectrometricmeasurements on the gas conditions.Circular shock waves are very sensitive to disturbances which deform theshock front, decreasing repeatability. Shocks consisting of plane sides makingup a symmetrical polygon have a more stable behaviour during focusing,which provides less run-to-run variance in light strength. The radiation fromthe gas at the implosion centre has been studied photometrically and spectrometrically.Polygonal shocks were used to provide better repeatability. Thefull visible spectrum of the light pulse created by a shock wave in argon hasbeen recorded, showing the gas behaving as a blackbody radiator with apparenttemperatures up to 6000 K. This value is interpreted as a modest estimation ofthe temperatures actually achieved at the centre as the light has been collectedfrom an area larger than the bright gas core.As apparent from experimental data real gas effects must be taken intoconsideration for calculations at the implosion focal point. Ideal gas numericaland analytical solutions show temperatures and pressures approaching infinity,which is clearly not physical. Real gas effects due to ionisation of theargon atoms have been considered in the numerical work and its effect on thetemperature has been calculated.The propagation of circular and polygonal have also been experimentallystudied and compared to the self-similar theory and geometrical shock dynamics,showing good agreement. / QC 20110502

京都大学 / 新制・課程博士 / 博士(工学) / 甲第23514号 / 工博第4926号 / 新制||工||1769(附属図書館) / 京都大学大学院工学研究科物質エネルギー化学専攻 / (主査)教授 安部 武志, 教授 作花 哲夫, 教授 阿部 竜 / 学位規則第4条第1項該当 / Doctor of Philosophy (Engineering) / Kyoto University / DFAM

The purpose of this study is to find datable interstadial sediments in the core area of the LateWeicheslian ice sheet extent. Based on geomorphological evidence, three coring sites wereidentified close to the Ultevis plateau in Norrbotten, northern Sweden. Sediment coring wascarried out in two pre-Late Weichselian stream channels and in a sediment basin. Stratigraphyfrom one of the sites, a 100 meter wide meltwater channel, was chosen for further analysis. Thestudied core was 5,93 m long and ended in a lower till unit. The core contained silt and sandbelow an upper till unit, indicating presence of interstadial sediments in the stratigraphy. Thecore was subsampled for luminescence dating. Two samples from above the upper till unit andtwo samples from below this unit were chosen for initial luminescence measurements onfeldspar. These preliminary measurements indicate a significant difference in paleodosebetween the upper samples and the lower. The upper samples displayed relatively highpaleodoses, possibly representing pre-Late Weichselian ages. This could imply presence of twointerstadials in the stratigraphy. The lower samples exhibited significantly higher paleodosesthan the upper ones, possibly indicating early-Weichselian or even Saalian ages for the lowersamples.

Cu2ZnSnS4 (CZTS) is a thin film solar cell material that only contains abundant elements and for which promising conversion efficiencies of 9.2 % have been shown. In this thesis composition measurements and reactive sputtering of precursors for CZTS films have been studied. These precursors can be annealed to create high quality CZTS films. Accurate control and measurement of composition are important for the synthesis process. The composition of a reference sample was determined using Rutherford backscattering spectroscopy. This sample was thereafter used to find the composition of unknown samples with x-ray fluorescence measurements. Pros and cons with this approach were discussed. The reactive sputtering process, and the resulting thin films, from a CuSn- and a Zn-target sputtered in H2S-atmosphere were investigated and described. A process curve of the system was presented and the influence of sputtering pressure and substrate temperature were examined. The pressures tested had little influence on the film properties but the substrate temperature affected both composition and morphology, giving less Zn, Sn and S and a more oriented film with increasingly facetted surface for higher temperatures. The precursors produced with this method are suggested to have a disordered phase with randomized cations, giving a CZTS-like response from Raman spectroscopy but a ZnS-pattern from x-ray diffraction measurements. The films have an excellent homogeneity and it is possible to achieve stoichiometric sulfur content. The complete steps from precursors, to annealed films, to finished solar cells were investigated for three controlled compositions and three substrate temperatures. The films sputtered at room temperature cracked when annealed and thus gave shunted solar cells. For the samples sputtered at higher temperatures the trend was an increased grain size for higher copper content and increased temperature. However, no connection between this and the electrical properties of the solar cells could be found.

<p>Abstract</p><p>In this thesis, a measurement system was set to perform comprehensive measurements on RF power amplifiers. Data obtained from the measurements is then processed mathematically to obtain three dimensional graphs of the basic parameters affected or generated by nonlinearities of the amplifier i.e. gain, efficiency and distortion. Using a class AB amplifier as the DUT, two sets of signals – both swept in power level and frequency - were generated to validate the method, a two-tone signal and a WCDMA signal. The three dimensional plot gives a thorough representation of the behavior of the amplifier in any arbitrary range of spectrum and input level. Sweet spots are consequently easy to detect and analyze. The measurement setup can also yield other three dimensional plots of variations of gain, efficiency or distortion versus frequencies and input levels. Moreover, the measurement tool can be used to plot traditional two dimensional plots such as, input versus gain, frequency versus efficiency etc, making the setup a practical tool for RF amplifiers designers.</p><p>The test signals were generated by computer then sent to a vector signal generator that generates the actual signals fed to the amplifier. The output of the amplifier is fed to a vector signal analyzer then collected by computer to be handled. MATLAB® was used throughout the entire process.</p><p>The distortion considered in the case of the two-tone signals is the third order intermodulation distortion (IM3) whereas Adjacent Channel Power Ratio (ACPR) was considered in the case of WCDMA.</p>

Abstract In this thesis, a measurement system was set to perform comprehensive measurements on RF power amplifiers. Data obtained from the measurements is then processed mathematically to obtain three dimensional graphs of the basic parameters affected or generated by nonlinearities of the amplifier i.e. gain, efficiency and distortion. Using a class AB amplifier as the DUT, two sets of signals – both swept in power level and frequency - were generated to validate the method, a two-tone signal and a WCDMA signal. The three dimensional plot gives a thorough representation of the behavior of the amplifier in any arbitrary range of spectrum and input level. Sweet spots are consequently easy to detect and analyze. The measurement setup can also yield other three dimensional plots of variations of gain, efficiency or distortion versus frequencies and input levels. Moreover, the measurement tool can be used to plot traditional two dimensional plots such as, input versus gain, frequency versus efficiency etc, making the setup a practical tool for RF amplifiers designers. The test signals were generated by computer then sent to a vector signal generator that generates the actual signals fed to the amplifier. The output of the amplifier is fed to a vector signal analyzer then collected by computer to be handled. MATLAB® was used throughout the entire process. The distortion considered in the case of the two-tone signals is the third order intermodulation distortion (IM3) whereas Adjacent Channel Power Ratio (ACPR) was considered in the case of WCDMA.

Gas separation with polymer membranes are becoming one of the mainstream separation techniques for a myriad of industrial applications. Membrane technologies are recognized as a viable and economical unit operation compared to more conventional separation processes. The design and material selection of membrane separation processes depends highly on the transport properties of separated gas molecules within the membrane material. Therefore, to use efficient methods for gas membrane characterization is paramount for the proper design of membrane separation processes. A membrane can be typically characterized by three main properties: permeability, solubility and diffusivity. The permeability of a membrane is the product of its diffusivity and solubility, therefore obtaining two of the three parameters is sufficient to fully characterize a membrane. The time-lag method is one of the oldest and most used gas membrane characterization methods. However, it suffers from various limitations that make the method not applicable for many types of membranes. The focus in this study was to develop new gas membrane characterization techniques that are based on extracting the membrane properties from the upstream gas pressure measurements rather than only from the downstream pressure measurements. It is believed that characterizing the membrane based on the upstream pressure measurements would be highly useful in characterizing barrier materials which are usually difficult to characterize using the conventional time-lag method. Moreover, glassy polymers which are widely used in industry exhibit behavior associated with nonlinear sorption isotherms and, therefore, the conventional time-lag method is incapable of obtaining an accurate estimation of glassy polymer properties. As a result, sorption experiments to generate a sorption isotherm are usually required in addition to permeation experiments to fully characterize glassy polymer membranes. To quantify the errors associated with the conventional time-lag assumptions and to fundamentally comprehend the impact of nonlinearities on the time-lag method, a comprehensive numerical investigation has been undertaken using the finite difference method. The investigation has clearly put in evidence the effect of the various Langmuir parameters on the accuracy of the time lag and on the time required to achieve steady state. This investigation also allowed assessing the errors associated with the usual assumptions made on the boundary conditions in determining the time lag. In this study, three novel gas membrane characterization methods were developed and proposed. Two of the proposed methods are concerned with the characterization of membranes that can be represented with a linear sorption isotherm. These two methods are entirely based on the upstream pressure measurements. The third membrane characterization method that is proposed is based on the dynamic monitoring of both upstream and downstream pressure measurements and is applicable to systems that exhibit a nonlinear isotherm sorption behavior. The three proposed methods are promising and further experimental validation is recommended to determine their full range of applicability.

Resumen (Castellano) El aumento del consumo de energía global junto con las preocupaciones ambientales ha generado mucho interés por las fuentes de energía alternativas y limpias, como la energía solar fotovoltaica. Los investigadores en la comunidad fotovoltaica han estado buscando formas de reducir costos mientras mantienen o aumentan las eficiencias. Una mejor comprensión de los materiales implicados es esencial para el rápido desarrollo de nuevas tecnologías. Las películas delgadas I-III-VI2 ofrecen sistemas prometedores para lograr células solares de alta eficiencia a un costo menor. De hecho, al adaptar la composición de los compuestos, es posible cambiar la banda prohibida del material para captar la luz solar de manera más eficiente. Esta tesis se centra en la preparación y caracterización del material de la capa absorbente, especialmente las películas delgadas nanocristalinas y la consideración de las características estructurales y eléctricas de dicha capa principal absorbente de células. La tesis examina cómo las diferentes técnicas de preparación y uso del material podrían afectar las propiedades del películas delgadas sintetizadas. Películas delgadas CuInSe2 y CuInS2 se depositaron sobre sustratos de vidrio ITO usando la técnica de electrodeposición en solución acuosa. Las películas electrodepositadas se caracterizaron por difracción de rayos X (XRD), microscopía electrónica de barrido (SEM) y análisis de rayos X de energía dispersiva (EDS). Se investigaron los efectos de recocido sobre los precursores electrodepositados. La estructura de calcopirita de CuInSe2/CuInS2 mostró una mejora de la cristalinidad después del tratamiento posterior de selenización/sulfurización en atmósfera Se/S, respectivamente. Los estudios de XRD y SEM revelaron una mejora de la calidad cristalina de las películas de CIS después de los tratamientos térmicos. Las propiedades ópticas de las películas delgadas recocidas CuInSe2-Se y CuInSe2-S se han estudiado para determinar el efecto del proceso de recocido en diferentes ambientes de selenio y azufre. Además, modificamos el CuInxCryGa1-x-ySe2 de cobre indio, donde x = 0.4, y = (0.0, 0.1, 0.2, 0.3) la capa de superestrato por el proceso de recubrimiento por centrifugado. CuInxCryGa1-xySe2 donde x = 0.4, y = (0.0, 0.1, 0.2, 0.3) nanopartículas han sido sintetizadas en primer lugar usando un método hidrotermal químico húmedo que se basa en un proceso térmico sin vacío sin ningún proceso de selenización adicional. Introduciendo diferentes fuentes de metal en un autoclave con etilenamina como solvente, se obtuvieron nanopartículas de CIGS a diferentes temperaturas en un rango de 190-230 °C. Los resultados de la difracción de rayos X (XRD) confirmaron la formación de una estructura de calcopirita CuInxCryGa1-x-ySe2 tetragonal. Finalmente, se estudió el efecto de la temperatura de recocido en los materiales tipo Kesterita (como el Cu2ZnSnS4) que son materiales de muy bajo costo y que no dañan el medio ambiente. Estudiamos el crecimiento de las películas delgadas cuaternarias Cu2ZnSnS4 (CZTS) de kesterita mediante un depósito electroquímico de un solo paso seguido de un recocido a baja temperatura. La influencia de diferentes atmósferas de recocido a tiempos de recocido constantes (t = 45 min) y parámetros de control de preparación fijos; es decir, concentración de la solución de materiales de partida (sales de metales precursores), tiempo de deposición y potencial de electrodeposición. Se estudiaron las propiedades estructurales, de composición, morfológicas y ópticas, así como las propiedades fotoelectroquímicas. / Abstract Increasing global energy consumption together with environmental concerns has led to much interest in alternative, cleaner sources of energy such as solar photovoltaic. Researchers in the solar cell community have been looking for ways to reduce costs while maintaining or increasing already high efficiencies. A fundamental understanding of the materials under consideration is essential to rapid development of new technologies. The I-III-VI2 thin films offer promising systems for achieving high efficiency solar cells at lower costs. In fact, by tailoring the chemistry of the compounds it is possible to change the bandgap of the material in order to collect sunlight more efficiently. First of all, this thesis focuses on absorber layer material preparation and characterization, especially nanocrystalline thin films and consideration of both structural and electrical characteristics of such main cell absorber layer.The thesis examines how different preparation techniques and material usage could affect the properties of the synthesized thin films (absorber layer). In this study CuInSe2 and CuInS2 thin films were deposited onto ITO glass substrate using the electrodeposition technique in aqueous solution. The electrodeposited films were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) and energy dispersive X-ray analysis (EDS). The annealing effects on the electrodeposited precursors were investigated. The chalcopyrite structure of CuInSe2/CuInS2 showed an enhancement of crystallinity after subsequent selenization/sulfurization treatment in Se/S atmosphere, respectively. XRD and SEM studies revealed a dramatic improvement of the crystalline quality of CIS films after annealing treatments. The optical properties of annealed CuInSe2-Se and CuInSe2-S thin films have been studied in order to determine the effect of annealing process in different selenium and sulfur atmosphere. In the second step we modified copper indium CuInxCryGa1-x-ySe2 where x=0.4, y= (0.0, 0.1, 0.2, 0.3)superstrate layer by spin coating process. CuInxCryGa1-x-ySe2 where x=0.4, y= (0.0, 0.1, 0.2, 0.3) nanoparticles have been synthesized firstly using a wet chemical hydrothermal method that is based on a non-vacuum thermal process without any additional selenization process. Introducing different metal sources in an autoclave with ethylenediamine as solvent, CIGS nanoparticles were obtained at different temperatures range 190-230°C. The X-ray diffraction (XRD) results confirmed the formation of a tetragonal CuInxCryGa1-x-ySe2 chalcopyrite structure. Finally, we turned again to the study of the annealing temperature effect onKesterite materials but this time in those of very low-cost materials and environmentally friendly Cu2ZnSnS4. We studied the growth of quaternary Cu2ZnSnS4 (CZTS) kesterite thin films by a single step electrochemical deposition followed by annealing at low temperature. The influence of different annealing atmospheres at constant annealing times (t = 45 min) and fixed preparation controlling parameters; i.e., starting materials (precursor metal salts) solution concentration, time of deposition and electrodeposition potential. Structural, compositional, morphological, and optical properties, as well as photoelectrochemical properties were studied. / Resum (Valencià) L'augment del consum d'energia global juntament amb les preocupacions ambientals ha generat molt d'interès per les fonts d'energia alternatives i netes, com ara l'energia solar fotovoltaica. Els investigadors de la comunitat fotovoltaica han estat buscant formes de reduir costos mentre mantenen o augmenten les eficiències. Una millor comprensió dels materials implicats és essencial per al ràpid desenvolupament de noves tecnologies. Les pel·lícules primes I-III-VI2 ofereixen sistemes prometedors per aconseguir cèl·lules solars d'alta eficiència a un cost menor. De fet, en adaptar la composició dels compostos, és possible canviar la banda prohibida del material per captar la llum solar de manera més eficient. Aquesta tesi se centra en la preparació i caracterització del material de la capa absorbent, especialment les pel·lícules primes nanocristal·lines i la consideració de les característiques estructurals i elèctriques d'aquesta capa principal absorbent de cèl·lules. La tesi examina com les diferents tècniques de preparació i ús del material podrien afectar les propietats del pel·lícules primes sintetitzades. Pel·lícules primes CuInSe2 i CuInS2 es van dipositar sobre substrats de vidre ITO usant la tècnica d'electrodeposició en solució aquosa. Les pel·lícules electrodepositadas es van caracteritzar per difracció de raigs X (XRD), microscòpia electrònica de rastreig (SEM) i anàlisi de raigs X d'energia dispersiva (EDS). Es van investigar els efectes de recuit sobre els precursors electrodepositados. L'estructura de calcopirita de CuInSe2/CuInS2 va mostrar una millora de la cristal·linitat després del tractament posterior de selenització/sulfurització en atmosfera de Se o S, respectivament. Els estudis de XRD i SEM van revelar una millora de la qualitat cristal·lina de les pel·lícules de CIS després dels tractaments tèrmics. Les propietats òptiques de les pel·lícules primes recuites CuInSe2-Es i CuInSe2-S s'han estudiat per determinar l'efecte del procés de recuit en diferents ambients de seleni i sofre. A més, modifiquem el CuInxCryGa1-x-ySe2 de coure indi, on x = 0.4, i = (0.0, 0.1, 0.2, 0.3) la capa d'superstrat pel procés de recobriment per centrifugat. CuInxCryGa1-x-ySe2 on x = 0.4, i = (0.0, 0.1, 0.2, 0.3) nanopartícules han estat sintetitzades en primer lloc fent servir un mètode hidrotermal químic humit que es basa en un procés tèrmic sense buit sense cap procés de selenización addicional. Introduint diferents fonts de metall en un autoclau amb etilenamina com solvent, es van obtenir nanopartícules de CIGS a diferents temperatures en un rang de 190- 230 °C. Els resultats de la difracció de raigs X (XRD) van confirmar la formació d'una estructura de calcopirita CuInxCryGa1-x-ySe2 tetragonal. Finalment, es va estudiar l'efecte de la temperatura de recuit en els materials tipus kesterita (com el Cu2ZnSnS4) que són materials de molt baix cost i que no danyen el medi ambient. Vam estudiar el creixement de les pel·lícules primes quaternàries Cu2ZnSnS4 (CZTS) de kesterita mitjançant un dipòsit electroquímic d'un sol pas seguit d'un recuit a baixa temperatura. La influència de diferents atmosferes de recuit a temps de recuit constants (t = 45 min) i paràmetres de control de preparació fixos; és a dir, concentració de la solució de materials de partida (sals de metalls precursors), temps de deposició i potencial d'electrodeposició. Es van estudiar les propietats estructurals, de composició, morfològiques i òptiques, així com les propietats fotoelectroquímiques / Kamal Abdelhamied Saber, S. (2018). Synthesis and characterization of some nano-selenides and their applications in solar cells [Tesis doctoral]. Universitat Politècnica de València. https://doi.org/10.4995/Thesis/10251/107389

Master of Science / Department of Geology / Abdelmoneam Raef / Geotechnical site characteristics are a function of the subsurface elastic moduli and the geologic structures. This study integrates borehole, surface and laboratory measurements for a geotechnical investigation that is focused on investigating shear-wave velocity (Vs) variation and its implication to geotechnical aspects of the Ogden test site in eastern Kansas. The area has a potential of seismicity due to the seismic zone associated with the Nemaha formation where earthquakes pose a moderate hazard. This study is in response to recent design standards for bridge structures require integrating comprehensive geotechnical site characterization. Furthermore, evaluation of dynamic soil properties is important for proper seismic response analysis and soil modeling programs. In this study, near surface geophysical site characterization in the form of 2D shear-wave velocity (Vs) structure that is compared with laboratory measurements of elastic moduli and earth properties at simulated in situ overburden pressure conditions and synergy with downhole Acoustic Televiewer time and amplitude logs, proved very robust “validated” workflow in site characterization for geotechnical purposes. An important component of a geotechnical site characterization is the evaluation of in-situ shear modulus, Poisson’s ratio and reliable and accurate elastic modulus ([lambda]) and shear modulus ([mu]) estimates are important in a good geotechnical site characterization. The geophysical site characterization, undertaken in this study, will complement and help in extrapolating drilling and core-based properties deduced by the geotechnical engineers interested at the test site.