If these macro inclusions are not detected before the material is put in used, its mechanical properties are greatly affected and this can lead to outrageous consequences in the engineering application.

Stainless steel family grades are very famous for their combined corrosion resistance and high mechanical properties. These properties can be improved further by decreasing the content of impurities like carbon and oxygen. The main purpose of this research work is to study the possibility of stainless steel powder decarburization by vacuum annealing. The influence of different process parameters like treatment time, temperature, fraction size and depth of the powder layer on the decarburization process was analyzed. The investigation results showed that it is possible to achieve extra low values of carbon and oxygen in steel powder by processing it with optimum process parameters.

This report is about continuous temperature measurements of pig-iron at tapping from blast furnace 2 in Oxelösund, SSAB. Nowadays the temperature is only checked once at every tapping. The purpose of this project is to see if the process stability increases by continuously knowing the temperature and to compare the costs of this new technique with the technique used today. Possible savings due to less consumption of coke/coal if the silicon amount and the temperature are closer to their aim values will be regarded and if as little steam consumption as possible are used. The process stability can be divided into different sub goals. The ordinary measuring techniques were investigated as a part of the main goal; such as the ordinary measured temperature, the pig-iron and slag samples. The new continuous temperature measuring technique was compared with the ordinary temperature measurement and investigations of the life length were done. How representative the pig-iron and slag samples are, when taking them at the time they are today, are also looked into. The continuous measured temperature showed around 0,37 % higher temperature than the ordinary measured temperature. The pig-iron and slag samples should be taken as they are today, for mainly safety aspects. By using continuous temperature measurement, some of the sub goals can be achieved for a more stable process. The economy on the other hand has shown that large savings can be done by using this continuous temperature method due to a more stable process. This is mainly because of a decrease in steam usage in the experimental period. By regarding only the material of the methods the continuous temperature equipment is a bit more expensive, but the savings are much larger so the continuous temperature method is beneficial. With time this method could probably improve the process stability even more since the operators will deal with the information and the probe better.

The mechanical properties of components made by PM steels are normally inferior to those made by alternative processes. One of the main reasons is that a large amount of pores are present in sintered components. The other main reason is that the alloying elements, particularly Ni, are not uniformly distributed after conventional sintering procedures.  This work is aimed at a better understanding of the influence of alloying additions on mechanical properties and homogeneity of the microstructure. The experimental work has been carried out in two trials. Trial 1 was performed to investigate mechanical properties of Distaloy powders (commercial grades) and second trial to examine influence of alloying additions on homogeneity of microstructure.  For trial 1, as-sintered and heat treated specimens were produced by mixing commercial powders with two different carbon levels. Whereas, alloying elements were admixed to base iron powder for producing  sintered specimens for trial 2. Mechanical properties including dimensional changes, micro-hardness, tensile strength and impact resistance were measured. Distribution of alloying elements was studied using LOM and SEM-EDS analysis. The results obtained show that additions of alloying elements enhance the mechanical properties. Moreover, interaction of C with Cu and Ni as well as interaction between Cu and Ni have a deceive role in determining final properties of the components. The metallographic investigation indicated that major reasons of heterogeneous microstructure are slow diffusion of Ni in Fe matrix and interaction of other alloying elements with Ni.  The results of trial 2 showed that addition of Mo and Cu to Ni-containing PM steels improves the distribution of Ni in Fe matrix. Mo results in improved uniformity of microstructure by lowering the chemical potential of carbon. In Ni and Cu containing alloys, the interaction between Ni and Cu is responsible for enhanced distribution of Ni. However, the improved Ni distribution is achieved at the expense of non-uniform distribution of Cu. In Ni-containing PM steels, improved microstructure homogenization can be attained by increasing Ni-Cu interaction, lowering the surface energy of Ni-Cu liquid and decreasing the chemical potential of carbon.

This study aims on characterization of non-metallic inclusions (oxides and sulfides) in steel with and without Calcium treatment. In this paper, the three-dimensional (3-D) investigation method of inclusions on film filter after Electrolytic Extraction (EE) of steel samples is applied on two different steel grades (280, 316L). Image analysis of non-metallic inclusions is carried out on Scanning Electron Microscope (SEM) images following with inclusion characteristic analysis. Steel samples with calcium treatment in the production process and reference samples was investigated and compared in density, size and composition. It shows that higher magnification and larger inclusion size correspond to more accurate result. With restriction of equipment and measurement, 2μm is the smallest size could be measured in ×500 magnification within 5% error. The comparison of distribution of inclusions varies with different zones: center has the largest size with least number of NMI; surface has the smallest size with largest number of NM; middle part has the median properties. In 316L steel, Ca treatment increases the number of oxides inclusions significantly; the content of Ca and Si in oxides inclusions is also increased. Two shapes of oxides inclusions, oval and elongated ones, are found with Ca treatment. In 280 steel, the total amount of NMI decreases slightly with Ca treatment; CaS is found in spherical inclusions; Because of earlier formation of larger size spherical inclusions, higher Ca content is found than that in smaller size spherical inclusions.

The procurement of ores and metals necessitates consideration of the sustainability of both the productand of the producer. Current trends in procurement practices move toward assuring the lowestenvironmental, social and economic impacts feasible. In order to ensure a high level of sustainability inthe raw materials acquired, the practices and methods of the producers must be evaluated. To this enddifferent assessment models may be used. This report aims to, through an investigation ofcontemporary assessment models; develop an assessment model which facilitates the sustainableprocurement of ores and metals with a reduced need for compliance from the assessed parties. Theevaluation is carried out based on the triple bottom line (TBL) definition of sustainability and considersthe practices and needs of the ores and metals industry. A number of desirable traits were found in themodels evaluated. A design for a novel assessment model is proposed for scoring ore and metalproducers. The proposed model features recommendations for weighing methods and specifications forimpact indicators, measurement methods, and grading methods. / Malm- och metallindustri arbetar allt mer med hållbar utveckling. Detta kräver metoder för attsäkerställa att potentiella underleverantörer använder sig av procedurer och strategier som anses sundaur ett hållbarhetsperspektiv. För att undersöka detta finns etablerade bedömningsmodeller. Syftet meddenna rapport är att utvärdera dessa modeller för få en grund på vilken en ny modell, anpassad förmalm- och metallindustrin, kan utformas. Denna nya modell utformas för att minska krav av storaeftergifter från de aktörer som undersöks. Utvärderingen baseras på ”triple bottom line” -definitionenav hållbar utveckling och tar hänsyn till behoven som finns i industrin, och de metoder som redananvänds. Arbetet resulterade i att ett antal egenskaper som är önskvärda för en bedömningsmodellidentifierades. Med dessa egenskaper i beaktande utformades en ny bedömningsmodell medrekommendationer för viktning av betyg och specifikationer för mätpunkter, mätmetoder, ochbetygsmodeller.

The carburizing atmosphere during the case hardening process contains a large proportion of hydrogen. Due to the rapid diffusion of hydrogen a high amount of hydrogen can be absorbed by the carburizing component. The amount of absorbed hydrogen is dependent on some factors such as for example the carburizing time and component dimensions. Hydrogen diffused in material can then cause hydrogen embrittlement and in some cases cause cracking under a static load. This hydrogen must therefore be removed. High amounts of hydrogen diffuse out spontaneously at room temperature. Tempering accelerates the process. The aim of this study was to experimentally measure the amount of absorbed hydrogen after case hardening and hydrogen content after storage at room temperature and also after tempering. The effect of the enriching gas in carburizing furnace on hydrogen absorption was investigated in this study. Three steel grades with different content of alloying elements were used in this investigation. Steel samples were case hardened by gas carburizing and tempering. The hydrogen content analyses included the measurement of hydrogen content before case hardening, after case hardening and after tempering using Leco-RHEN602. Based on the results in this study it was concluded that all steel grades used in this investigation absorb hydrogen during case hardening by gas carburizing. A major part of the absorbed hydrogen is then released by effusion after being stored at room temperature and during tempering. Around 50% of the absorbed hydrogen content during gas carburizing is due to the presence of the enriching gas in the carburizing atmosphere. Around 50 % of hydrogen diffuses out of the steel specimens after one day. It is likely that all of free diffusible) hydrogen has diffused out of the specimens of two steel grades after one week at room temperature or after tempering. / Vid sätthärdning består den uppkolande atmosfären till stor del av vätgas och p.g.a. vätets snabba diffusion kan stora mängder av väte absorberas i komponenten. Halten av absorberade väte beror bl.a. på sätthärdningstid och komponentens dimensioner. Väte i materialet kan sedan leda till sprickbildning vid statisk belastning. Detta väte måste därför avlägsnas. En stor del av väte diffunderar ut spontant vid rumstemperatur. Vid anlöpning går processen fortare. Syftet med denna studie var att experimentellt mäta halten av väte som absorberas under sätthärdning, samt efter att metallen har lagrats i luft vid rumstemperatur. Dessutom mättes vätehalten efter anlöpning. Dessutom undersöktes effekten av ugnsatmosfärens tillsatsgas på mängden absorberad väte efter uppkolning. Tre olika höghållfasta och låg legerade stål sorter sätthärdades genom gas uppkolning. Mängden väte analyserades innan sätthärdning, efter sätthärdning, efter lagring i rumstemperatur och efter anlöpning med hjälp av Leco-RHEN602. Enligt resultaten i denna studie, absorberar alla av de tre undersökta stålsorterna väte under sätthärdning. En stor del av det absorberade vätet diffunderar ut efter att stålet har lagrats i luft vid rumstemperatur och under anlöpning. Omkring 50 % av den absorberade vätehalten under uppkolningen är på grund av reaktionen med tillsatsgasen i ugnsatmosfären. Omkring 50 % av vätet diffunderar ut ur proverna efter en dag. Möjligen all fritt (diffunderbart) väte har diffunderat ut ur proverna i två av stålsorterna efter en vecka i rumstemperatur eller efter anlöpning.

The purpose of this master thesis was to evaluate variations in solidification and cooling rate in compacted graphite iron prototype cylinder blocks and for each position relate this to the microstructure and also relate the microstructure to mechanical properties. This has been done to increase the knowledge to predict mechanical properties in cast iron components. There were three sample categories; reference-, tensile test- and thermocouple samples. The investigation included analysis of cooling curves, SinterCast parameters, image analysis, measured hardness and tensile strength. Thermocouples of type N were used at interesting positions for observation of the cooling behaviour and the image analysis was carried out by the software Axio Vision SE64 by Carl Zeiss GmbH. The hardness was measured according to Brinell HBW 5/750 and tensile testing was performed according to standard SS-EN ISO 6892-1:2009. It is concluded that the microstructure depend on many parameters, one of them is the position in the cylinder block. A relation between solidification time and the microstructure features; secondary dendrite arm spacing and eutectic cell size was observed. Because of dissimilarity in microstructure between the tensile test samples and thermocouple samples it is believed that the thermocouples have contributed with a cooling and/or nucleation effect. Considering the mechanical properties there is not solely the nodularity, eutectic cell size or secondary dendrite arm spacing that are the controlling microstructure feature, more research needs to be made.

No description available.

The purpose of this thesis has been to evaluate the use of a swirl blade in the uphill teeming process through plant trials. Two series of trials were carried out at Scana Steel Stavanger AS. In the trials a divergent entrance nozzle with a 62° outlet angle were used when casting duplex stainless steel on a base plate with two 6.2 tons ingots. All molds were burned onto the ingots; leading to problems with emptying the ingots from the molds and severe damages on the molds. To get a better insight during the casting and understand why the molds were burned onto the ingots; during the second series of trials one mold on each base plate were filmed in the beginning of the casting process. Evaluation of the castings indicated that splashing on the mold wall at an initial stage was one reason for the mold burned onto the ingot. Further, material samples were collected to evaluate the non-metallic inclusion composition and distribution with SEM when casting with a swirl blade compared to when casting without. The area percentage of the inclusions in the samples was 1% and 2% for samples casted with and without swirl blade respectively with d=2.8 mm. The inclusion size also varied for samples casted with and without swirl blade; 98% of the inclusions were in the size range of 0-10 μm when casted with and in the size range 0-20 μm when casted without swirl blade. / Syftet med denna uppsats har varit att utvärdera användningen av swirlblad i götgjutningsprocessen. Två serier med försök har utförts på Scana Steel Stavanger AS. I försöken användes en inloppssten med 62°-vinklat utlopp, där duplexa rostfria stål göts på stigplan med två 6,2 tons kokiller. Alla kokiller brände fast på göten, vilket ledde till svårigheter vid urtag av göten samt skador på kokillerna. För att få en bättre förståelse av varför kokillerna brände fast, filmades ett göt på vardera stigplan under den andra försöksserien. Utvärdering av försöken indikerar att en anledning till att kokillerna brände fast på göten var att det stänkte upp stål på kokillväggen i ett tidigt stadium. Vidare har materialprover samlats in för att utvärdera sammansättningen samt utspridningen av icke-metalliska inneslutningar i SEM då göt gjutits med swirlblad jämfört med utan. Area procenten i proverna var 1% och 2% då proverna gjutits med respektive utan swirlblad, med d=2.8 mm. Även storleken på inneslutningarna i prover som gjutits med och utan swirlblad skiljde sig åt, 98% av inneslutningarna var i storleksintervallet 0-10 μm för prover gjutna med swirlblad medan de som gjutits utan var i storleksintervallet 0-20 μm. / JK24053