Avec l'arrivée de l'environnement comme enjeu mondial, le secteur de l'efficacité énergétique prend une place de plus en plus importante pour les entreprises autant au niveau économique que pour l'image de la compagnie. Par le fait même, le domaine des technologies de l'énergie est un créneau de recherche dont les projets en cours se multiplient. D'ailleurs, un des problèmes qui peut survenir fréquemment dans certaines entreprises est d'aller mesurer la composition des matériaux dans des conditions difficiles d'accès. C'est le cas par exemple de l'électrolyse de l'aluminium qui se réalise à des températures très élevées. Pour pallier à ce problème, il faut créer et valider des modèles mathématiques qui vont calculer la composition et les propriétés à l'équilibre du système chimique. Ainsi, l'objectif global du projet de recherche est de développer un outil de calcul d'équilibres chimiques complexes (plusieurs réactions et plusieurs phases) et l'adapter aux problèmes électrochimiques et d'équilibres contraints. Plus spécifiquement, la plateforme de calcul doit tenir compte de la variation de température due à un gain ou une perte en énergie du système. Elle doit aussi considérer la limitation de l'équilibre due à un taux de réaction et enfin, résoudre les problèmes d'équilibres électrochimiques. Pour y parvenir, les propriétés thermodynamiques telles que l'énergie libre de Gibbs, la fugacité et l'activité sont tout d'abord étudiées pour mieux comprendre les interactions moléculaires qui régissent les équilibres chimiques. Ensuite, un bilan énergétique est inséré à la plateforme de calcul, ce qui permet de calculer la température à laquelle le système est le plus stable en fonction d'une température initiale et d'une quantité d'énergie échangée. Puis, une contrainte cinétique est ajoutée au système afin de calculer les équilibres pseudo-stationnaires en évolution dans le temps. De plus, la contrainte d'un champ de potentiel électrique est considérée pour l'évaluation des équilibres électrochimiques par des techniques classiques de résolution et fera l'objet de travaux futurs via une technique d'optimisation. Enfin, les résultats obtenus sont comparés avec ceux présents dans la littérature scientifique pour valider le modèle. À terme, le modèle développé devient un bon moyen de prédire des résultats en éliminant beaucoup de coût en recherche et développement. Les résultats ainsi obtenus sont applicables dans une grande variété de domaines tels que la chimie et l'électrochimie industrielle ainsi que la métallurgie et les matériaux. Ces applications permettraient de réduire la production de gaz à effet de serre en optimisant les procédés et en ayant une meilleure efficacité énergétique.

Construction waste generation is a global issue in the sustainable construction context and several studies have been performed in different parts of the world to develop methods and tools for waste prevention, reduction, reuse and recycling. Most of these studies adopted a linear approach by focussing on a specific project phase, such as design, procurement or construction. However, there is a consensus in the literature that factors causing construction waste span across the project life cycle and recent researchers emphasised the need for a more integrated lifecycle approach to holistically assess and evaluate causes of waste to suggest recommendations to reduce lifecycle construction waste generation. Over recent years, the UK government has been investing billions of pounds in new and refurbished healthcare projects, where the healthcare buildings are often referred to, in literature, as complex buildings. This large investment has created a number of sustainability issues including water consumption, CO2 emissions, energy consumption, and more significantly construction waste generation. However, no significant research has been undertaken to propose a systematic construction waste minimisation mechanism for healthcare construction projects. Therefore, this research aims to develop a lifecycle construction waste minimisation framework for healthcare projects (HC-WMF). In order to identify the research problem and construction waste generation issues peculiar to healthcare projects, nine preliminary interviews were conducted with healthcare clients (N=3), architects (N=3), and contractors (N=3). The findings revealed that healthcare projects generate high rates of waste compared to other building projects throughout the project lifecycle, identified complex features that have an effect on waste generation, and identified particular causes of construction waste in healthcare projects. A further in-depth study based on four case studies was undertaken to understand the impact of waste generation due to the causes of waste, the relationship between complex features in healthcare projects and the causes of waste, and best waste minimisation practices to be implemented throughout a healthcare project lifecycle to address construction waste causes. Three interviews (client, architect, and contractor) from each case study were undertaken during the data collection stage. A Healthcare Construction Waste Minimisation Framework (HC-WMF) and Self-Assessment Tool (SAT) were then developed based on the findings of the literature review, preliminary data collection study and case studies, and adoption of the key concepts of problem solving methodology. This HC-WMF comprised six waste minimisation strategies (project documents management, stakeholders waste awareness, communication and coordination, buildability, materials selection and procurement, and change management) to be followed throughout the lifecycle stages of a healthcare project. SAT provides a means to assess the effectiveness in implementing HC-WMF and to obtain feedback and learning outcomes for continuous further improvements. In order to validate the developed HC-WMF and SAT a validation questionnaire (N=26) and validation interviews (N=4) were conducted. The validation results showed that the HC-WMF and SAT would be very useful in reducing construction waste generation from healthcare projects. The research contributes to construction waste minimisation research introducing a novel approach to lifecycle waste reduction. Also, the research revealed the complex features in healthcare projects that affect construction waste generation, causes and origins of waste peculiar to healthcare projects, and best waste minimisation strategies to implement to reduce construction waste generation from healthcare projects. Most importantly, through HC-WMF, this research produced a set of guidelines to be followed throughout the healthcare project lifecycle to reduce construction waste generation. The study has made recommendations which, if adopted, will lead to significant improvements in sustainable healthcare construction due to construction waste minimisation. The content should be of interest to clients, designers, and contractors dealing with construction waste minimisation and sustainable construction in healthcare projects. Key words: Construction waste, Healthcare, Causes of waste, Healthcare complexities, Waste minimisation, UK.

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A chromium plating line used by a local company was monitored to identify any potential waste minimisation opportunities. Plating of the workpiece surface is carried out by immersing the workpiece in seven process (treatment) solutions including nickel and chromium plating baths. Between each process step the workpieces are rinsed. The chromium plating process was evaluated using the results of a waste minimisation audit. This involved gathering data on the composition, flow rates and costs of the inputs of the process. Two types of data were collected namely new and existing data. The new data included chemical monitoring (concentration levels of Ni, Cr, Na, S, B, P, Si, Fe, Cu, Zn, Pb as well as conductivity, TDS, SS and pH measurements) and water usage data. The existing data included raw materials, utility inputs, composition of process solutions and product outputs. The data were analysed using three established waste minimisation techniques. The Water Economy Assessment (a form of Monitoring and Targeting) results were determined using an empirically derived model. The Water Balance and True Cost of Waste results were obtained through more detailed calculations using the results of the chemical analysis. The results from the audit showed that the water usage on the chromium plating line has the highest waste minimisation potential. The True Cost of Waste analysis showed there is no significant chemical wastage in the effluent stream. The potential savings of the effluent stream was negligible (approximately R10 for 238 days). Drag-out calculations were also performed and showed that the drag-out volumes were in good agreement with the typical volumes found in the metal finishing industry. Intervention using simple lowcost and no-cost waste minimisation opportunities were recommended as a first step before contemplating further focus areas for technical or feasibility studies. / Thesis (M.Sc.)-University of KwaZulu-Natal, Pietermaritzburg, 2009.

Both construction Waste Minimisation (WM) and construction procurement activities play an effective role in attaining sustainability by giving due consideration to the environment, community and social conditions in delivering built assets. The construction industry has a major impact on the environment, both in terms of resource consumption and increasing waste production. Recent figures published by the UK government reveal that construction and demolition activities produce approximately 32% of total waste generated: three times the waste produced by all households combined. However, the current and on-going research in the field of construction WM and management focuses mainly on onsite waste quantification and management; and stakeholders‟ source identification. Little research has been undertaken to evaluate the relationship between Construction Procurement Systems (CPS) and construction waste generation. However, literature emphasises the need for research in this context. This research aims to develop a Procurement Waste Minimisation Framework (PWMF) to enhance WM practices by evaluating the relationship between CPS and construction waste generation. Objectives of the research include: examine construction WM drivers, WM approaches, waste origins and causes; critically review and evaluate current CPS and sustainable procurement practices in the UK; assess the relationship between CPS and construction waste generation; investigate and synthesis Procurement Waste Origins (PWO); examine the most suitable CPS that could potentially embed and sustain WM; develop and validate the PWMF. This research has adopted a survey research design and mixed methods sequential procedure. Data has been gathered through a cross sectional, self-administered postal questionnaire survey (N=258 distributed, n=65 received) and semi-structured interviews (N=17) with procurement managers and sustainability managers from the top 100 UK contracting organisations and quantity surveyors from the top 100 UK quantity surveying organisations. Data analysis techniques include: descriptive statistics; non-parametric tests; and constant comparative method. The PWMF has developed based on the findings of literature review, questionnaire survey and semi-structured interviews and adopting key concepts of problem solving methodology. The PWMF validation method includes: validation questionnaire (N=8) and follow-up semi-structured interviews (N=6) with procurement managers, sustainability managers and quantity surveyors. Key findings which emerged from the study include: CPS do have an impact on waste generation in construction; integrated CPS have major potential to integrate WM strategies; four PWO identified (i.e. uncoordinated early involvement of project stakeholders; ineffective communication and coordination; unclear allocation of WM responsibilities; and inconsistent procurement documentation) and associated sub-waste causes; and the developed PWMF enables to diagnose potential waste origins and causes, and WM improvement measures for design and build projects. The study has made recommendations which, if adopted, will lead to significant improvements in WM practices and sustainable procurement practices in construction. The content should be of interest to contractors, clients, and organisations dealing with procurement, waste and sustainability.

Thèse numérisée par la Direction des bibliothèques de l'Université de Montréal.

Dans ce travail, la modélisation, la simulation, l'optimisation dynamique et la commande nonlinéaire d'un procédé industriel de polymérisation en émulsion produisant du polyacétate de vinyle (PVAc) sont étudiées. La réaction est modélisée comme un système à deux phases constitué d'une phase aqueuse et une phase particulaire. Un modèle détaillé est développé pour calculer la masse molaire moyenne en poids, la masse molaire moyenne en nombre et la dispersité. Les moments de chaînes en croissance et terminés sont utilisés pour représenter l'état du polymère et pour calculer la distribution de masse molaire (MWD). L'étude de cas correspond à un réacteur industriel fonctionnant dans une entreprise de produits chimiques à Bogotá. Un réacteur à l'échelle industrielle (11 m3 de capacité) est simulé dans lequel une réaction semi-batch de polymérisation en émulsion de l'acétate de vinyle est effectuée. Le problème d'optimisation dynamique est résolu directement en utilisant un solveur de programmation non linéaire. L'intégration des équations différentielles est faite en utilisant la méthode de Runge-Kutta. Trois problèmes d'optimisation différents sont résolus, depuis le plus simpliste (une seule variable d'optimisation : la température du réacteur) au plus complexe (trois variables d'optimisation : la température du réacteur, le débit de l'amorceur et le débit du monomère) en vue de minimiser le temps final de réaction. Une réduction de 25% du temps de traitement par batchs est réalisée par rapport aux conditions normales de fonctionnement appliquées dans l'entreprise. Les résultats montrent qu'il est possible de minimiser la durée de réaction alors que certaines qualités de polymères souhaitées (conversion, masse molaire et contenu en solides) satisfont les contraintes définies. Une technique de commande non linéaire géométrique à l'aide de la linéarisation entrée/sortie est adaptée à la régulation de la température du réacteur. Un filtre Kalman étendu (EKF) est mis en oeuvre pour estimer les états non mesurés et il est testé dans différents cas, dont une étude de robustesse où des erreurs du modèle sont introduites pour vérifier son bon fonctionnement. Après vérification des performances du régulateur, certains changements d'opération du procédé ont été proposés afin d'améliorer la productivité du procédé et la qualité du polymère. Enfin, le profil de température optimale et les politiques d'alimentation optimales de débits du monomère et de l'amorceur, obtenues dans l'étape d'optimisation dynamique, ont fourni les consignes optimales pour la commande non linéaire. Les résultats montrent que le régulateur non linéaire conçu ici convient pour suivre les trajectoires optimales de température calculées précédemment / In this work, modeling, simulation, dynamic optimization and nonlinear control of an industrial emulsion polymerization process to produce poly-vinyl acetate (PVAc) are proposed. The reaction is modeled as a two-phase system composed of an aqueous phase and a particle phase. A detailed model is used to calculate the weight average molecular weight, the number average molecular weight and the dispersity. The moments of the growing and dead chains are used to represent the state of the polymer and to calculate the molecular weight distribution (MWD). The case study corresponds to an industrial reactor operated at a chemical company in Bogotá. An industrial scale reactor (11 m3 of capacity) is simulated where a semi-batch emulsion polymerization reaction of vinyl acetate is performed. Dynamic optimization problem is solved directly using a Nonlinear Programming solver. Integration of differential equations is made using Runge-Kutta method. Three different optimization problems are solved from the more simplistic (only one control variable: reactor temperature) to the more complex (three control variables : reactor temperature, initiator flow rate and monomer flow rate) in order to minimize the reaction time. A reduction of 25% of the batch time is achieved with respect to the normal operating conditions applied at the company. The results show that is possible to minimize the reaction time while some polymer desired qualities (conversion, molecular weight and solids content) satisfy the defined constraints. A nonlinear geometric control technique by using input/output linearization is adapted to the reactor temperature control. An extended Kalman filter (EKF) is implemented to estimate unmeasured states and it is tested in different cases including a robustness study where model errors are introduced to verify its good performance. After verification of controller performance, some process changes were proposed in order to improve process productivity and polymer quality. Finally, the optimal temperature profile and optimal feed policies of the monomer and initiator, obtained in a dynamic optimization step, are used to provide the optimal set points for the nonlinear control. The results show that the nonlinear controller designed here is appropriate to follow the optimal temperature trajectories calculated previously

ABSTRACT Sustainable development has become part of Government policy across the world. In the construction industry it has been introduced through the promotion of “sustainable construction” or “green construction”. International trends show a gradual move away from wasteful construction industry practices that include high resource consumption, material wastage, inefficiencies in construction processes and a high percentage of waste that find its way to waste disposal sites and illegal dumps. This research report seeks to promote sustainable construction and waste minimisation as preferred models for achieving a balance in the economic, social and environmental impacts of development. It reviews South Africa’s construction and demolition site practice from the perspective of construction and demolition waste management, assessing waste management practice and the resultant waste disposal. To gauge South Africa’s performance it benchmarks South African practice against those of the United States, United Kingdom, Germany and the Netherlands. This approach highlights gaps in South Africa’s current practice and also provides some valuable lessons that can be used to ensure compliance with sustainable construction principles. Finally the research report proposes a framework for developing a self-sustaining secondary construction materials market in South Africa, which can prove to be a valuable tool for ensuring the absorption of sustainable construction in the construction industry.

Les gestes de la main représentent un moyen naturel et intuitif de communication chez l'homme lui permettant d'interagir avec son environnement dans la vie de tous les jours. Ils permettent notamment de ponctuer et de renforcer l'expression orale d'un dialogue entre personnes. Outre la communication entre individus, les gestes de la main permettent de manipuler des objets ou encore d'interagir avec des machines. Avec le développement de la vision par ordinateur, on assiste à un véritable engouement pour de nouveaux types d'interactions qui exploitent le mouvement de la main et qui passent par une étape d'analyse et de reconnaissance du mouvement afin d'aboutir à l'interprétation des gestes de la main. La réalisation d'un tel objectif ouvre un large champ d'applications. C'est dans ce cadre que se positionne le travail réalisé au cours de cette thèse. Les objectifs visés étaient de proposer des méthodes pour: 1) permettre le transfert d'animation depuis une séquence réelle vers un modèle 3D représentant la main. Dans une telle perspective, le suivi permet d'estimer les différents paramètres correspondant aux degrés de liberté de la main. 2) identifier les gestes de la main en utilisant une base de gestes prédéfinie dans le but de proposer des modes d'interactions basés sur la vision par ordinateur. Sur le plan technique, nous nous sommes intéressés à deux types d’approches : le premier utilise un modèle 3D de la main et le deuxième fait appel à une base de gestes / Hand gestures take a fundamental role in inter-human daily communication. Their use has become an important part of human-computer interaction in the two last decades. Building a fast and effective vision-based hand motion tracker is challenging. This is due to the high dimensionality of the pose space, the ambiguities due to occlusion, the lack of visible surface texture and the significant appearance variations due to shading. In this thesis we are interested in two approaches for monocular hand tracking. In the first one, a parametric hand model is used. The hand motion tracking is first formulated as an optimization task, where a dissimilarity function between the projection of the hand model under articulated motion and the observed image features, is to be minimized. A two-step iterative algorithm is then proposed to minimize this dissimilarity function. We propose two dissimilarity functions to be minimized. We propose also in this thesis a data-driven method to track hand gestures and animate 3D hand model. To achieve the tracking, the presented method exploits a database of hand gestures represented as 3D point clouds. In order to track a large number of hand poses with a database as small as possible we classify the hand gestures using a Principal Component Analysis (PCA). Applied to each point cloud, the PCA produces a new representation of the hand pose independent of the position and orientation in the 3D space. To explore the database in a fast and efficient way, we use a comparison function based on 3D distance transform. Experimental results on synthetic and real data demonstrate the potentials of ours methods

Existing theories and literature seeking to explain small business reticence to engage in enterprise bargaining, at times adopt a generalised approach which precludes or at least limits their relevance and ability to explain small business choice at the industry and even organisational level. Such explanations cannot be detached from the external contextual framework in which an organisation operates and its own, often unique, strategic corporate response to the environmental influences which are challenging it. Labour flexibility vehicles including bargaining, if chosen to facilitate broader corporate strategies, can thereby, be regarded as functionally dependent upon and interactive with the corporate orientations and objectives of the organisation which in turn are environmentally influenced and shaped. The research principally provides a focused description and analysis of the experiences of Clothingco, a small, up market, vertically integrated clothing manufacturer and retailer, which has undergone various strategic readjustments at the corporate and industrial relations level throughout the 1990s, in response to externally driven pressures. The research presents firm evidence to suggest that Clothingco has selected its labour flexibility mechanisms so that they are consistent with and able to accomodate prevailing corporate strategies and orientations. Its strategic corporate readjustments throughout the 90s, which can be perceived as falling along the continuum of cost minimisation to productivity enhancement, have in particular registered differing choices with respect to labour flexibility vehicle and strategies. In the light of the findings, the research as a preferred labour flexibility vehicle at Clothingco. These are identified as: an increasing corporate focus towards cost minimisation throughout the 1990s, coupled with an inability by management to countenance union intervention in enterprise bargaining procedures. The interaction of both these factors, rendered enterprise bargaining from the point of view of management, both a strategically and industrially inferior labour flexibility vehicle to the use of contract labour. The research's strength lies in these areas which have been highlighted and which can be monitored and tested more comprehensively in future research. / Master of Commerce (Hons)