Several catastrophic failures have occurred during the past two decades, both in engineered as well as non-engineered landfills. In addition, there are numerous instances of significant deformations, although not failure in the sense of significant and rapid downslope mass movement, which may cause sufficient damage to buried gas and leachate collection infrastructure. One such instance was observed in 1999 near the toe of a 75 m high 4H:1V slope at the Brock West Landfill in Ontario, Canada. Significant distortion of gas collection laterals was observed at this site. The present research is an in-depth study intended to examine deformation in landfills based on a detailed study of the mechanical properties of municipal solid waste. Four research objectives were defined based on identified shortcomings and knowledge gaps in the existing literature pertaining to mechanical properties of MSW viz; (a) to develop a method for obtaining intact samples of MSW and to examine the significance of using intact and recompacted samples in characterizing the stress-deformation behaviour of MSW; (b) to characterize MSW shear strength and Youngs modulus of elasticity from interpretation of triaxial test results and to determine the parameters of a non-linear elastic constitutive model as applied to MSW; (c) to measure the evolution of compressibility behaviour of MSW with degradation and verify the mechanism of secondary compression in waste; (d) to develop a simple design chart for predicting lateral deformations in landfills. A comprehensive research program was carried out to address various research objectives - field monitoring of deformations at the Brock West site; triaxial compression tests on large intact and recompacted samples of waste; simulating waste degradation in a large laboratory compression cell; analyzing stress-strain data from various published studies and a numerical modelling study. Interpretation of the effective stress paths followed during shearing in triaxial compression tests suggested that while recompacted samples may be sufficient to characterize shear strength parameters for use in stability analysis of landfill slopes, there might be a benefit in obtaining intact samples to evaluate the deformation characteristics of MSW. A hyperbolic model is proposed to describe the stress-deformation response of waste. The required parameters for this model were determined from evaluation of the results of numerous triaxial tests, both from this study and from the published literature. Observations from the long-term degradation test suggested that degradation has a significant effect on the compressibility of waste and further verifies the mechanism of secondary compression in waste. The coefficient of at-rest lateral pressure was observed to maintain an essentially constant value during combined compression and degradation.<p>The results obtained from the experimental work were combined with the findings of a stochastic numerical modelling study and a statistical evaluation of published data and used to propose a simple design chart for estimating the maximum lateral displacement in a landfill slope. The design chart was developed using results of a finite element parametric study in which the behaviour of the municipal solid waste was modeled using a non-linear elastic hyperbolic model. The design chart incorporates nonlinear variation in unit weight as well as Youngs modulus with depth. The predictions from the design chart were compared with the results of field monitoring of lateral displacement in the instrumented slope at the Brock West landfill and were found to be in good agreement.

A survey of the theory of neutrino oscillations in dense matter and neutrino backgrounds is presented. We discuss collective neutrino systems using the gyroscopic pendulum analogy and describe the motion that results from self-induced parametric resonances. The effects of dense matter on the flavour oscillations of neutrinos are also detailed. This theory is applied to the case of continuous supernova neutrino spectra and explanations of the spectral swapping behaviour seen in numerical studies are summarized. The results of numerical simulations of supernova oscillations in turbulent supernova backgrounds are presented and discussed. We study the motion of two example supernova neutrino spectra and examine the differences in the dynamics and flavour evolution that results from adding turbulent fluctuations to the supernova matter background. We also investigate the effect that fluctuations in the neutrino density can have on the oscillation behaviour. We find that in general the final neutrino spectra emerging from the inner supernova regions are quite robust to fluctuations in the backgrounds in our model, while the intermediate dynamics can be very strongly altered. Some significant changes in the final spectra are also found to occur when the neutrino background density fluctuations are large. We give a detailed review of the resonant matter effects that determine the survival probabilities of atmospheric muon neutrinos. The differences between various Earth density models are described, and these models are then used to predict the flux of muon-type neutrino events in the Deep Core extension to the IceCube detector. We use recent results from the detector collaboration and build on previous work which considered the sensitivity of the detector to the mass hierarchy, and show that uncertainties in the Earth's density can have a significant influence on the event rates.

A simplified RDF production was made, together with a waste characterization of MSW from Hanoi area. Three experiments were done, two with active aeration and one without. A high water content was determined at all RDF, which has a negative influence on the lower heating value and a saving-effect. A accumulation of the heating value to the higher class (>40mm), was not completely possible, also no complete transfer of mineral contents to the lower class (<10mm). The RDF reach in most cases the criteria for a fuel for different limit values, heavy metals, chloride and sulfur. An economic benefit could be possible with a surplus income by using RDF instead of coal (lignite), also by avoiding landfill gas and sell emission rights via CDM. More and detailed investigations seem to be necessary to confirm these results.

No description available.

Le détecteur Borexino, situé au laboratoire souterrain du Gran Sasso (LNGS), mesure les neutrinos solaires depuis 10 ans. Parmi les neutrinos solaires, le spectre continu du 8B jusqu’à 17 MeV permet de tester la zone de transition de l’effet de résonance dans la matière dit effet MSW. Cette nouvelle analyse augmente d’un ordre de grandeur la statistique par rapport à la précédente mesure de Borexino publiée en 2011. Pour ce faire, l’ensemble du volume scintillant a été inclus dans l’analyse, aucune coupure géométrique n’ayant été effectué au dessus de 5 MeV. Cela a permis l’identification d’un nouveau bruit de fond non pris en compte précédemment. L’ensemble des bruits de fond au dessus de 3 MeV est maintenant compris et la composante neutrino peut-être extraite d’un fit radial du détecteur. Afin de tester l’existence d’un neutrino stérile léger, une source de 3-5,5 PBq de 144Ce sera installée sous Borexino au début de l’année 2018 pour un an et demi de prise de données : c’est l’expérience CeSOX. Cette source est produite par PA MAYAK par purification de combustible nucléaire usagé, par conséquent les potentiels contaminants radioactifs sont très nombreux et peu contraints. Pour tester l’hypothèse stérile, une mesure en flux, une mesure en forme et une mesure combinée seront effectuées dans l’ensemble du détecteur Borexino. Ces mesures sont fortement dépendantes de la connaissance intime de la source (composition, forme du spectre beta du 144Ce, énergie moyenne 144Ce et 144Pr). A cette fin, un spectromètre gamma a été spécifiquement étalonné et entièrement simulé au CEA, Saclay. De même un spectromètre beta a été dessiné, assemblé, simulé et est en cours d’étalonnage. Finalement, des mesures de spectrométrie alpha et de masse seront réalisés sur des échantillons représentatifs envoyés au CEA, Saclay afin de contraindre au mieux la composition de la source de 144Ce de SOX. / Located in the Gran Sasso underground laboratory (LNGS), Borexino measures solar neutrinos for 10 years. Among solar neutrinos, 8B continuous spectrum (up to 17 MeV) enables to test the transition zone between vacuum and matter regime of the MSW effect. This new measurement increases by one order of magnitude the exposure with respect to previous Borexino publication. To do so, the entire active volume is considered in this analysis above 5 MeV. A new background has been identified and a radial fit is done above 3 and 5 MeV enabling to extract the neutrino component. Existence of a light sterile neutrino would have important consequences on astrophysics and cosmology. SOX is the only experiment aiming at testing this hypothesis using a punctual radioactive source. A 3-5.5 PBq 144Ce source is actually under production and will be positioned under Borexino in 2018. Precise knowledge of the source is one of the main challenge of this experiment, based on rate and shape neutrino measurement. Two critical parameters are the heat released by the source for activity measurement and the expected neutrino spectrum in the detector. We first describe the SOX experiment insisting on 144Ce source production. Then, we focus on Saclay installations dedicated to constrain radioactive contamination inside the source using representative samples. Alpha, gamma and mass spectroscopy calibration and simulation are discussed and competitive constrains are derived. A status on 144Ce beta shape measurements is done as well as presentation of future measurement.

An extensive laboratory and field investigation was conducted at Santa Maria Regional Landfill (SMRL) in Santa Maria, CA to determine the effects of waste placement practices on the engineering response of municipal solid waste (MSW). Laboratory and field testing was used to determine the engineering properties and monitor field response of MSW. The specific gravity (Gs) of manufactured MSW (MMSW), fresh MSW (FMSW), and old MSW (OMSW) was determined experimentally using a modified version of standard soil testing procedures. Effects of particle size, compactive effort, and degradation on the specific gravity of waste were evaluated. Specific gravity of manufactured waste samples increased with decreasing particle size, with compaction, and with increased degradation. The average specific gravity of uncompacted MMSW samples was 1.333, 1.374, and 1.424 for coarse, medium, and fine particle sizes, respectively. Specific gravity of coarse, medium, and fine MMSW samples compacted at dry of optimum (= 30%) was determined to be 1.497, 1.521, and 1.552, respectively and at wet of optimum ( = 90%) to be 1.500, 1.542, and 1.570, respectively. The compacted and uncompacted specific gravity of fresh MSW was lower than manufactured and old MSW. The average Gs of uncompacted and compacted fresh MSW was 1.072 and 1.208, respectively whereas old MSW had Gs of 2.201. Additional physical and engineering properties of MSW were determined for fresh and old wastes. A total of 8 magnetic extensometer settlement arrays and 4 thermocouple arrays were installed in old wastes. The settlement and temperature data were collected for an approximate duration of 1 year. In addition, laboratory experiments were conducted to determine the particle size distribution, organic content, and moisture content of fresh waste sampled from the active face of the landfill and from old waste sampled from different depths. The particle size distribution of OMSW was comparable to a well-graded coarse-grained soil. The average baseline moisture content of incoming MSW at SMRL was 42.7% (dry-weight basis). The average moisture content of residential MSW, commercial MSW, and self-delivered MSW were determined to be 57.7, 46.3, and 12.0%, respectively. The organic content of fresh and old MSW was determined to be 77.2 and 23.5%, respectively. Temperature increased over time due to heat generation of the waste mass. The temperature increased on average 3 to 6°C between the initial and final day of measurements for wastes that were 0.3 to 9 years old. Fresh and old wastes at SMRL exhibited unique compression behavior. A majority of the waste was undergoing secondary compression characterized using a secondary compression ratio () ranging from 0.013 to 0.067 with an average of 0.030. In addition, the fresh and old wastes exhibited recompression behavior. Fresh waste lifts were determined to be slightly overconsolidated such that the self-weight of the fresh waste was less than the preconsolidation stress. The old waste exhibited recompression behavior during loading and unloading of an earthen embankment. The modified recompression indices () for fresh and old wastes were determined to be 0.076 and 0.012, respectively. The initial compression ratio for old wastes () was quantified for the old waste lifts to be between 0.069 and 0.332. Finally, meso- and full-scale field compaction experiments were conducted to determine the effects of systematic moisture addition prior to compaction on placement efficiency and compaction characteristics of MSW. Two 16 x 46 m test plots were constructed for the meso-scale compaction tests. Approximately 890 kN (100 tons) of residential MSW (RMSW) was placed into a test plot and compacted at target moisture contents of 55 (baseline as-received), 65, 80, 95, and 110%. Compaction curves generated for RMSW were bell shaped and similar to soil compaction curves. The maximum dry unit weight () and operational unit weight () for the meso-scale compaction study were 8.5 and 13.3 kN/m3 with corresponding optimum moisture contents of and , 78.5 and 79.5%, respectively. Moisture addition prior to compaction yielded beneficial waste placement results. An operational waste placement factor (OWPF) was defined as additional amount of waste that could be placed in one unit of volume. OWPF values were determined to be 1, 1.33, 1.66, 1.37, and 0.83 for RMSW compacted at target moisture contents of 55, 65, 85, 90, and 110%, respectively. The full scale compaction investigation was conducted in a similar manner to the meso-scale investigation. However, the compaction tests were conducted on the active face of the landfill and representative of the entire incoming daily waste stream. A daily average of 2940 kN (330 tons) of MSW was placed and compacted at target moisture contents of 45 (baseline as-received), 65, 85, and 105%. Compaction curves for the delivered MSW were bell shaped and similar to soil compaction curves. The maximum dry and operational unit weights for the full-scale test were 7.0 and 9.8 kN/m3, respectively corresponding to optimum moisture contents of and , 76 and 75.5%, respectively. OWPFs were calculated to be 1, 1.28, 1.55, and 0.80 for target moisture contents of 45, 65, 85, and 105%, respectively. The spatial variability associated with moisture addition also was determined for the meso- and full-scale compaction tests and verified using test pits and spatial sampling of the surface of the active face. Particularly, the variations in degree of saturation (S) and volumetric moisture content () due to moisture addition were estimated. For waste compacted at target moisture contents of 55, 65, 80, and 110% during the meso-scale tests, S increased by 19, 4.5, 4.4, and 4.3%, respectively while increased by 28, 7.7, 8.1, and 5.7%, respectively. For the full scale compaction tests, S increased by an average of 43% and increased by an average of 78%. The average moisture content of waste at the surface after compaction at 45% moisture content (i.e., as-received) and at 80% moisture content (i.e., near optimum) were 34 and 133%, respectively. The results of the investigation have environmental, operational, and financial implications such as extend the life of a landfill, ability to place more wastes in a unit landfill volume, and increasing to values above field capacity with moisture addition during compaction.

Orientador: Marcelo Moraes Guzzo / Dissertação (mestrado) - Universidade Estadual de Campinas, Instituto de Fisica Gleb Wataghin / Made available in DSpace on 2018-08-09T11:03:28Z (GMT). No. of bitstreams: 1 Valdiviesso_GustavodoAmaral_M.pdf: 1768172 bytes, checksum: d1861e9e1805a2a55abc030dde4bf22b (MD5) Previous issue date: 2004 / Resumo: O objetivo deste trabalho é produzir um texto didático que sirva como base para alunos de física, ao ingressarem na área da fenomenologia de neutrinos. Introduz-se o modelo de mistura de neutrinos no vácuo, baseado no conceito de superposição de estados. Mostra-se que esta hipótese leva ao fenômeno da oscilação de sabor, o qual se propõe ser uma solução para o problema do neutrino solar. Mostra-se que a oscilação que ocorre no vácuo entre o Sol e a Terra não pode explicar os dados experimentais, sendo necessária a inclusão dos efeitos da matéria solar. O meio solar leva a uma alteração nas previsões devido a efeitos de ressonância. O conjunto de fenômenos que ocorrem devido a presença e à distribuição do meio solar, chamado efeito MSW, leva à verdadeira solução do problema do neutrino solar. Faz-se um ajuste simples no modelo, encontrando o melhor ajuste aos dados de SuperKamiokande. Com o modelo ajustado, mostra-se a concordância com os dados de Homestake / Abstract: The subject of this work is to produce a didactic text that can be used by physics students as a basis when incoming on the neutrinos phenomenology area. We introduce the neutrinos mixing model in vacuum, based on the concept of state superposition. We show that this hypothesis leads to avor oscillation phenomenon, the one is proposed to be a solution to the solar neutrino problem. We show that vacuum oscillations between the Sun and the Earth cannot explain the experimental data, making necessary the inclusion of solar matter effects. The solar medium leads to modifications on the predictions because of resonance effects. The set of phenomenon that takes place due to the presence and to the distribution of solar medium, called MSW effect, leads to the real solution of the solar neutrino problem. We make a simple fit on the models parameters, finding the best fit to de SuperKamiokande data set. With the model fitted, we show that it agrees with Homestake data / Mestrado / Teoria Geral das Particulas e Campos / Mestre em Física

The biochemical methane potential (BMP) of a substance is a measure of the volume of methane gas produced per unit mass of that substance, through the process of anaerobic biodegradation. As the socio-economic consequences of climate change have become more apparent, the ability to predict the long-term cumulative environmental impact of various human activities has become more necessary. Landfills can be a substantial source of methane (a greenhouse gas) to the atmosphere, and consequently BMP is an important tool for predicting the potential cumulative long-term impacts of a landfill to the environment. From a strictly economic perspective, the practice of landfill methane extraction for industrial uses is becoming much more common. In this case, BMP is an important tool for predicting the economic feasibility of such a project. Current methods for determining the BMP of municipal solid wastes (MSW) are both time-consuming and inconsistent. A review of literature on the topic yields many different descriptions of the test, with large variations in sample sizes, incubation times, procedures, etc. Most of these methods also require expensive, and specialized equipment. This thesis describes a simple approach to the BMP test that might be carried out in a variety of laboratory settings, such as an on-site lab equipped with basic, simple, and inexpensive equipment. The method relies on a much larger than typical sample mass to produce large volumes of gas that are measured for composition multiple times over the course of the test. The volume and composition data is then used to produce a cumulative methane potential curve which can be fitted to a first-order decay model in order to predict an ultimate BMP value. The taking of multiple measurements on large volumes of gas, allows for the use of a portable field instrument called the GEMTM2000 to measure gas composition. By fitting the data to a curve in order to determine ultimate methane potential, individual measurement errors are averaged out and the final result has a precision similar to more traditional BMP methods, which rely on bulky and expensive gas chromatographs. Testing has been conducted on MSW samples from 3 separate sites. The method used involved comparatively large samples of waste (~200 g) and no limit was set on incubation time. The use of large waste samples produces large quantities of gas that must be collected and analyzed often. The method provided favourable results, consistent within acceptable limits of variability when compared with other BMP methods. There is even some evidence suggesting that the use of large waste samples improves the accuracy of the test, despite the use of equipment which provides less precise measurements of gas concentration. Given the long duration required for testing, the results were also evaluated for possible correlations between loss on ignition data and specific gravity measurements; two simple tests that can be conducted rapidly. Both data sets show a rough correlation with BMP, and may be used to quickly estimate ultimate BMP values, but the loss on ignition relationship provides the better correlation. Lastly, initial steps were taken in the development of what has been dubbed the Biochemical CO2 Potential (BCP) test, taking advantage of the relatively quicker rate of aerobic degradation. There are preliminary indications that the BCP method may be a viable alternative to the BMP, but the data set so far is small and further research is required to confirm that hypothesis.

Incineration with energy recovery is the main disposal strategy for waste that cannot be reused or recycled, and a well-established source of energy in Europe, especially in Sweden where 2.2 Mtonnes of waste including domestic and imported municipal solid waste (MSW) and waste wood (WW) were combusted during 2015. However, owing to its inherent heterogeneous composition, inclusion of such waste in Waste-to-energy (WtE) technologies is challenging. These heterogeneities may lead to operationally-related issues in the WtE facilities and contribute to toxic emissions, which can be reduced by waste pre-treatment technologies.    This thesis examines the variations in the composition of MSW and WW streams used as a fuel supply in WtE facilities after undergoing waste pre-treatment technologies, and the effect of fuel composition on its combustion behaviour and formation of persistent organic pollutants (POPs) such as polychlorinated dibenzo-p-dioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs). The overall objective is to contribute to a more thorough understanding of the selection of waste pre-treatment technologies to mitigate harmful emissions into the atmosphere when waste fuels are combusted in WtE facilities.    This thesis describes the high variability of contaminants in domestic and imported WW and suggests adaptation of WW pre-treatment techniques to produce fuels with a low potential for generating pollutants. A comparison of mechanical solid waste pre-treatments revealed that screening and shredding is more efficient than extrusion for reducing emissions of pollutants such as PCDDs and PCDFs in combustion. The evaluation of the combustion behaviour of MSW-based fuels showed a three-stage oxidative decomposition, and an acceleration of the decomposition of the MSW compared to the lignocellulosic materials, which may be attributed to the presence of food waste and plastics in the MSW. Combustion tests of fuel blends containing WW and MSW-based fuels with different food waste content suggested that WW, not food waste content, is the key factor for the formation of PCDDs, PCDFs, and polychlorinated biphenyls (PCB), benzenes (PCBzs) and phenols (PCPhs). Torrefaction may be a suitable technology for improving the properties of waste as a fuel e.g. due to its low PCDD and PCDF emissions. / Förbränning med energiåtervinning är det huvudsakliga sättet att ta hand om avfall som inte kan återanvändas eller återvinnas. Det är en väletablerad energikälla i Europa och särskilt i Sverige där 2,2 miljoner ton avfall, däribland inhemskt och importerat hushållsavfall och returträ, förbrändes under 2015. På grund av den heterogena sammansättningen hos hushållsavfall och returträ är förbränning av dessa material i anläggningar med energiåtervinning (så kallade WtE-anläggningar) förknippade med en del driftsrelaterade utmaningar. Det kan även ge upphov till miljöfarliga utsläpp, som dock kan reduceras genom förbehandling av avfallet. I denna avhandling har variationer i sammansättningen hos hushållsavfall och returträ som förbränns i WtE-anläggningar undersökts. Effekten av bränslemixens sammansättning och ev förbehandling på bränslets förbränningsegenskaper samt bildning av långlivade organiska föroreningar (så kallade POPar) såsom polyklorerade dibenso-p-dioxiner och polyklorerade dibensofuraner vid förbränning har utvärderats. Det övergripande målet är att bidra till en djupare förståelse av hur valet av förbehandlingsteknik för avfall kan bidra till att minska skadliga utsläpp till luft när avfallsbränslen förbränns i WtE-anläggningar. Denna avhandling beskriver den stora variabiliteten av metall- och materialföroreningar i inhemskt och importerat returträ och föreslår förbehandlingstekniker för att producera bränslen med låg potential att generera föroreningar. En jämförelse av mekaniska förbehandlingstekniker visade att mekanisk sönderdelning och separering (krossning och siktning) är mer effektivt än s.k. högtrycks-pressning för att minska utsläppen av föroreningar som dioxiner och furaner vid förbränning. Utvärderingen av bränslemixar innehållande hushållsavfall uppvisade en oxidativ nedbrytning i tre steg vid förbränning, och en accelererad nedbrytning av avfallsmaterialet jämfört med vedmaterialet i bränslet, troligen som effekt av innehållet av matavfall och plast i hushållsavfallet. Förbränningsförsök med bränsleblandningar av returträ och hushållsavfall med olika innehåll av matavfall visade att mängden returträ, och inte mängden matavfall, är den viktigaste faktorn för bildning av dioxiner, furaner, klorbifenyler, klorbensener, och klorfenoler. Torrefiering kan vara en lämplig teknik för att förbättra avfallets bränsleegenskaper, t.ex. på grund av dess låga emissioner.

A kinetic study of the pyrolysis of municipal solid waste (MSW) was carried out bythermogravimetric analysis (TGA). Different runs were performed at heating rates of 5, 10and 150C/min. The effect of the N2, CO2 and O2 gas with different combination in theprocess was also evaluated. The results show that the most weight loss was obtained whenthe MSW was treated at a temperature interval of (20-750)0C which led to a weigh loss of95%. The kinetic study of the pyrolysis process showed also the gas mixture used in theprocess effect also the activation energy of the process and the presence of the CO2 in theincreased the activation energy (Ea) to 56 kJ/mol. Higher concentration of CO2 in the processlead to increase in the activation energy which is not optimal for the reaction. The treated andthe untreated samples were incubated and the biological activity was observed. The resultsshow that the pretreated samples did not have any biological activity. From these results itcould be concluded that the thermal pretreatment could be an alternative way for of waste forlong period of time, which could have significant impact in i.e. for transportation anddurability during storage. / Program: Högskoleingenjörsutbildning i kemiteknik