This portfolio of work contributes to the remit of the National Physical Laboratory (NPL) to develop the underpinning expertise and tools for validating nascent and future optical quantum technologies based on the discrete and quantum properties of photons. This requirement overlaps with the requirement to provide validation for devices operating in the photon-counting regime. A common theme running through the portfolio is photon pairs generated through spontaneous parametric downconversion (SPDC). A Hong-Ou-Mandel (HOM) interferometer sourced with visible wavelength photon pairs from an SPDC process in beta-barium borate (BBO) was designed, built and characterised. The visibility of the HOM interference is dependent on the indistinguishability of the interfering photons, but is also influenced by imperfections of the interferometer; therefore an investigation was carried out to quantify the effects of the interferometer imperfections on the measured visibility so that the true photon indistinguishability could be measured with a quantified uncertainty. A bright source of correlated pair photons in the telecoms band based upon a pump enhanced SPDC process in periodically-poled potassium titanyl phosphate (PPKTP) was designed, built and characterised. From the characterisation measurements the source brightness was estimated to be 6.2×10⁴ pairs/ s/ mw pump. The photon pairs were further characterised through their incorporation as a source in a HOM interference experiment. The developed correlated photon pair source was at the heart of a novel scheme for the generation of polarisation entangled photon pairs, for which the design, build and characterisation work is presented. The source was demonstrated to produce two of the four maximally entangled Bell states with quantum interference visibilities of around 0.95. The generated states were also shown to break a form of Bell's inequality by around six standard deviations. The polarisation entangled photon pair source was originally built at the University of St Andrews and was later transferred to the NPL where it will extend NPL's capabilities to this key spectral region. Finally a study was carried out to investigate the possibility of a wavelength tuneable device for the absolute measurement of single photon detector quantum efficiencies based upon an established SPDC technique.

Semiconductor based micro- and nano-structures grown in a systematic and controlled way using selective area growth are emerging as a promising route toward devices for integrated optical circuitry in optoelectronics and photonics field. This dissertation focuses on the experimental investigation of the nonlinear optical effects in selectively grown gallium nitride micro-pyramids that act as optical cavities, zinc oxide submicron rods and indium gallium nitride multiple quantum well core shell submicron tubes on the apex of GaN micro pyramids that act as optical antennae. Localized spatial excitation of these low dimensional semiconductor structures was optimized for nonlinear optical light (NLO) generation due to second harmonic generation (SHG) and multi-photon luminescence (MPL). The evolution of both processes are mapped along the symmetric axis of the individual structures for multiple fundamental input frequencies of light. Effects such as cavity formation of generated light, electron-hole plasma generation and coherent emission are observed. The efficiency and tunability of the frequency conversion that can be achieved in the individual structures of various geometries are estimated. By controlling the local excitation cross-section within the structures along with modulation of optical excitation intensity, the nonlinear optical process generated in these structures can be manipulated to generate coherent light in the UV-Blue region via SHG process or green emission via MPL process. The results show that these unique structures hold the potential to convert red input pulsed light into blue output pulsed light which is highly directional.

The growing speed and bandwidth requirements of telecommunication systems demand all-optical on-chip solutions. Microphotonic devices can deliver low power nonlinear signal processing solutions. This thesis looks at the slow light photonic crystals in chalcogenide glasses to enhance low power nonlinear operation. I demonstrate the development of new fabrication techniques for this delicate class of materials. Both, reactive ion etching and chemically assisted ion beam etching are investigated for high quality photonic crystal fabrication. A new resist-removal technique was developed for the chemical, mechanical and light sensitive thin films. I have developed a membraning method based on vapor phase etching in combination with the development of a save and economical etching tool that can be used for a variety of vapour phase processes. Dispersion engineered slow light photonic crystals in Ge₃₃As₁₂Se₅₅ are designed and fabricated. The demonstration of low losses down to 21±8dB/cm is a prerequisite for the successful demonstration of dispersion engineered slow light waveguides up to a group index of around n[subscript(g)] ≈ 40. The slow light waveguides are used to demonstrate highly efficient third harmonic generation and the first advantages of a pure chalcogenide system over the commonly used silicon. Ge₁₁.₅As₂₄24Se₆₄.₅ is used for the fabrication of photonic crystal cavities. Quality factors of up to 13000 are demonstrated. The low nonlinear losses have enabled the demonstration of second and third harmonic generation in those cavities with powers up to twice as high as possible in silicon. A computationally efficient model for designing coupled resonator bandpass filters is used to design bandpass filters. Single ring resonators are fabricated using a novel method to define the circular shape of the rings to improve the fabrication quality. The spectral responses of the ring resonators are used to determine the coupling coefficient needed for the design and fabrication of the bandpass filters. A flat top bandpass filter is fabricated and characterized as demonstration of this method. A passive all-optical regenerator is proposed, by integrating a slow-light photonic crystal waveguide with a band-pass filter based on coupled ring resonators. A route of designing the regenerator is proposed by first using the dispersion engineering results for nonlinear pulse propagation and then using the filter responses to calculate the nonlinear transfer function.

The topic of this thesis is about experimental study of phenomena which are associated with light propagation in nonlinear dielectric media. In the first part of this work, we study experimentally the snake instability of the bright soliton stripe of the (2+1)-dimensional hyperbolic nonlinear Schrödinger equation. The instability is observed, through spectral measurements, on spatially extended femtosecond pulses propagating in a normally dispersive self-defocusing semiconductor planar waveguide. The second part of this thesis is about light propagation in nonlinear periodic media. We experimentally observe a stationary spatial gap (or Bragg) soliton in a periodic semiconductor planar waveguide. Based on the interference pattern of the soliton beam, we measure the power parameter of the soliton which is related to the position of the spatial spectrum in the linear band gap. <p><p><p>Cette thèse de doctorat a pour sujet l’étude expérimentale de phénomènes associés à la propagation de la lumière dans les milieux diélectriques non linéaires. La première partie porte sur la démonstration expérimentale de l’instabilité serpentine d’une bande solitonique dans un système décrit par une équation de Schrödinger non linéaire à (2+1)-dimensions. L’instabilité est observée sur base de mesures du spectre spatial ainsi que du profil spatio-fréquentiel d’une impulsion femtoseconde après propagation dans un guide plan semi-conducteur qui présente une dispersion normale et une non-linéarité défocalisante. Le second thème abordé concerne la propagation de la lumière dans les milieux non linéaires périodiques. Les expériences réalisées ont montré l’existence du soliton de Bragg spatial stationnaire sous forme de faisceaux se propageant dans des guides plans semi-conducteurs périodiquement gravés. Sur base du profil de la distribution modale en intensité du faisceau soliton, il a été possible de mesurer le paramètre de puissance du soliton de Bragg qui détermine la position du spectre spatial dans la bande interdite linéaire. <p> / Doctorat en sciences appliquées / info:eu-repo/semantics/nonPublished

Dissertation (PhD)--University of Stellenbosch, 2006. / Please refer to full text for abstract.

The two-photon absorption (TPA) coefficient is measured in indium phosphide (InP) using femtosecond pulses to be 45cm/GW at 1.32μm. Nanosecond pulses are subsequently used to find the free-carrier refractive index cross-section, σ_r, and the free-carrier absorption coefficient, σ_fca. The quantity βσ_r is measured to be -113x10⁻²ºcm⁴/GW at 1.064μm and -84x10⁻²ºcm⁴/GW at 1.534μm. At 1.064μm, with β assumed to be 22cm/GW, the value suggested by theory, σ_r is -5.1x10⁻²ºcm³. Similarly, at 1.534μm, assuming β to be 20cm/GW gives a σ_r value of -4.1x10⁻²ºcm³. Due to refraction affecting the measurements of σ_fca, only an upper limit of 1x10⁻¹⁵cm² can be put on its value. The free-carrier experiments are repeated on two samples of cadmium mercury telluride (CMT) having bandgaps of 0.89eV and 0.82eV. For the first sample, β_σr is measured to be -148x10⁻²ºcm⁴/GW. Assuming β to be 89cm/GW gives a σ_r value of -1.7x10⁻²ºcm³ whilst σ_fca is found to be at most 3x10⁻¹⁵cm². Significant linear absorption occurs in the second sample which generates a large free-carrier population. It is shown that this significantly enhances the nonlinearities. Finally, the results of the work are tested by modelling a nonlinear transmission experiment, and the results found in this work give a closer fit to experimental results than the result of theory. Four-wave mixing (FWM) in a photonic crystal fibre is exploited to create a high output power optical parametric amplifier (OPA). To optimise the OPA conversion efficiency, the fibre length has to be increased to 150m, well beyond the walk-off distance between the pump and signal/idler. In this regime, the Raman process can take over from the FWM process and lead to supercontinuum generation. The OPA exhibits up to 40% conversion efficiency, with the idler (0.9μm) and the signal (1.3μm) having a combined output power of over 1.5W.

<p>This thesis explores the use of nonlinear crystals from theKTiOPO₄(KTP) family with the aim to extend the possibleapplications for laser sources and to gain more knowledge aboutthe material’s benefits and limits. The work focussed onoptical parametric oscillators (OPOs) and optical parametricamplifiers (OPAs), which employ second order nonlinearprocesses. Both devices transfer energy from a laser beam at aparticular wavelength to a different wavelength, which istuneable. In OPOs two new beams at different wavelengths aregenerated, whereas in OPAs an existing weak beam is amplified.The essential part of these devices, which enables theoccurrence of the energy conversion, is a nonlinear crystal. Inthis work the ferroelectric crystals KTP and RbTiOPO₄(RTP) have been utilized.</p><p>By modifying the material’s structure,quasi-phasematching can be obtained, which is a crucialrequirement for achieving efficient energy conversion betweenthe incident and the generated waves. The fabrication ofquasi-phasematched crystals is dependent on the controlledreversion of the material’s spontaneous polarisation,which is accomplished by periodic electric field poling.</p><p>Nanosecond pulses of more than 200 kW were generated in the“eye-safe”region by employing a double pass OPA.Small signal gains exceeding 75 dB were obtained for anessentially diffraction limited beamwithout spectralbroadening of the seed. By subsequent signal coupling intofibres substantial broadening was accomplished. A systematicmeasurement series of several RTP crystals allowed us toaccurately determine the wavelength and temperature dispersionof the refractive index, which are two essential requirementsfor further employment of this material. The OPOs based on RTPwere widely tuneable by controlling the temperature. It wasalso concluded that RTP behaves similar to KTP in parametricdevices, thus being a material, which can sustain high powers,possesses large nonlinear coefficients and can operate in abroad wavelength region.Efficient Raman oscillation concurrent with parametricoscillation was observed and analysed in several KTP samples.This gave further insight into the processes taking placeinside the material when performing as a frequency converter,if the generated idler lies in the absorption band.This thesis also covers the investigation of afemtosecond optical parametric chirped pulse amplifier.Temporally stretched seed pulses were amplified to 85 µJ,resulting in a gain above 60 dB, and subsequent recompressionresulted in 270 fs pulses.</p><p><b>Keywords:</b>nonlinear optics, KTiOPO₄, optical parametric oscillator, optical parametricamplifier, RbTiOPO₄, quasi-phasematching, electric field poling,stimulated Raman scattering.</p>

No description available.

No description available.

We have conducted a detailed experimental and theoretical study of nonlinear absorption in semiconductors. Experimental measurements were made on a variety of materials at wavelengths of 1.06 and 0.53 microns using a picosecond Nd:YAG laser. Both two- and three-photon processes were investigated. Values of nonlinear absorption coefficients extracted from these measurements show excellent agreement with recent theory and scaling rules. Our theoretical investigation has been carried out for two-, three-,and n-photon absorption, for both continuous and pulsed sources. Expressions are obtained for the transmission of the sample in terms of the incident irradiance for each case. The physical interpretation of these results is discussed. We have also considered the effects of the photogenerated carriers on the measurements. Equations are developed that include linear absorption by these carriers. We have observed severe distortions on the transmitted beam, caused by changes in the refractive index of the material, due to the presence of these carriers. We present a model that accurately describes these effects in terms of the photogenerated carrier density. We have developed several novel techniques for monitoring nonlinear absorption. In particular, we have adapted the photoacoustic technique to the measurement of nonlinear absorption in semiconductors. We have also developed a technique employing irradiance modulation to greatly enhance the sensitivity to nonlinear processes and simultaneously discriminate against linear background signals. A related technique has been used to observe coherent mixing effects in semiconductors with cw, modelocked dye lasers.