A field test using diethylstilbestrol was conducted on the 13,000-acre Havens area on Fort Lewis Mountain, Roanoke County, Virginia; reference areas were also selected. Foxes were pre-conditioned to bait acceptance using molded beef suet. A total of 614 suet baits each containing diethylstilbestrol (50 mg) and oral marker (35 mg of demethylchlortetracycline) were distributed seven times from late January to late March. After a 3-week delay, animals were trapped on all areas and examined for reproductive success and marker evidence. Foxes consumed at least 20 percent of all baits and other identifiable species consumed 12 percent; however, unidentified visitors consumed 43 percent. Twenty-one gray foxes (11 marked) and four red foxes (one marked) were trapped on the treated area. Two female red foxes from the treated.area and one from a reference area successfully reproduced. None were marked. All (six) female gray foxes from the treated area were barren and anovulatory. Two of five marked females probably were yearlings; the unmarked female was 4 or more years old. Five of six female gray foxes from reference areas successfully reproduced. The barren female was an anovulatory yearling. At the P<0.025 level (l d.f., chi-square = 5.17) unsuccessful reproduction was associated with the treatment. No other species showed evidence of marker or effects of treatment. / Master of Science

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Made available in DSpace on 2014-06-12T23:00:48Z (GMT). No. of bitstreams: 2 arquivo9162_1.pdf: 552018 bytes, checksum: b3c75fc91aaeb5a680e3cd99444a25d9 (MD5) license.txt: 1748 bytes, checksum: 8a4605be74aa9ea9d79846c1fba20a33 (MD5) Previous issue date: 2002 / Conselho Nacional de Desenvolvimento Científico e Tecnológico / A ausência de uma descrição teórica e experimental conclusiva sobre a geometria e estabilidade do tetracicloxigênio (O4) motivou o presente trabalho de Mestrado. Inicialmente aplicamos métodos interação de configuração (QCISD(T)) para determinar o grupo pontual de simetria e estado de spin da molécula. Em seguida utilizamos cálculos ab initio sofisticados do tipo CASSCF, incluindo teoria de perturbação, correção do erro de superposição de bases e diversos conjuntos de funções base, para tratar com mais precisão o estado de spin da molécula, sua geometria e estabilidade. Os valores da energia de dissociação e distâncias de ligação estão numa concordância muito boa com os dados experimentais mais recentes. Também desenvolvemos um mecanismo para a reação 2 O2(3&#931;g -) &#1048774; O4(D2h,1A1) baseado na teoria da ressonância não-sincronizada das ligações químicas (RVB) de Pauling. Construímos uma curva de potencial para a reação de dimerização e determinamos a energia de ativação para esta reação, um resultado pioneiro para este sistema

We present gross, net and productive capital stock estimates for 20 industries of the Austrian manufacturing sector based on the perpetual inventory method for the period 1969-1994. The estimation of the net capital stocks and the volume index of capital services follows an integrated method derived from the neoclassical theory of investment. Based on the estimates we calculate capital intensity and capital productivity measures for the 20 industries and provide estimates of capital productivity developments. We find that capital productivity decreased only for 5 out of the 20 industries. The other industries showed in part marked increases in both capital and labor productivity. (author's abstract) / Series: Working Papers Series "Growth and Employment in Europe: Sustainability and Competitiveness"

Within this work a study of the vibrations of laminated composite cantilevers exhibiting structural uncertainties and damage is accomplished. The study is performed within both the Classical Lamination (CLT) and the First-order Transverse Shear Deformation Theories (FSDT). Upon comparing the natural frequencies and mode shapes obtained by both theories, the effects of transverse shear deformation will be emphasized. Other nonclassical effects as e.g. the bending-twist coupling and the warping restraint on the cantilevered structure are also considered. As passive techniques of vibration control, structural tailoring and optimization are implemented. To deal with structural uncertainties, a probabilistic discretization technique for the governing system is developed. Statistical properties of natural frequencies are obtained by means of a second-moment method and a first-order perturbation technique. Structural tailoring is reconsidered to reduce the sensitivity of the dynamic behavior to parameter uncertainties. Next, the damage effect on the structure is considered in the design process. As a result, the problem of the robustness of structures in the presence of damage is addressed. This work also deals with the active feedback control of cantilevered structural systems. An efficient control technique for continuous structures, namely modal control, is adopted and the control gain is obtained by an optimal control law. The comparison of controlled and uncontrolled dynamic responses is made between two models based on CLT and FSDT with emphasis on the influence played by transverse shear deformation and warping restraint. / Ph. D.

Submitted by Maike Costa (maiksebas@gmail.com) on 2016-05-12T13:11:00Z No. of bitstreams: 1 arquivo total.pdf: 5933598 bytes, checksum: f90080e0529915a4c5c37308259bee89 (MD5) / Made available in DSpace on 2016-05-12T13:11:01Z (GMT). No. of bitstreams: 1 arquivo total.pdf: 5933598 bytes, checksum: f90080e0529915a4c5c37308259bee89 (MD5) Previous issue date: 2015-03-09 / Coordenação de Aperfeiçoamento de Pessoal de Nível Superior - CAPES / Conselho Nacional de Pesquisa e Desenvolvimento Científico e Tecnológico - CNPq / Zinc stannate (Zn2SnO4) and zinc titanate (Zn2TiO4) are inverse spineltype oxides and stand out due to their optical, electrical, magnetic, semiconductor and photocatalytic properties. In this work, the two materials were combined in order to obtain a solid solution, Zn2Sn1-xTixO4 (x= 0; 0.25; 0.50; 0.75; 1.0), using the modified-Pechini method, in order to evaluate the influence of the Sn4+ ions substitution by Ti4+ ones in the spinel lattice for application as catalysts in the photodiscoloration of the golden yellow remazol. Catalysts were characterized by the X-ray diffraction (XRD), infrared spectroscopy (IR), ultraviolet-visible spectroscopy (UV-Vis), Raman spectroscopy and surface area measurements (BET). XRD results showed that the materials presented a high long range order when heat treated at 700 °C, using zinc acetate and pH = 1. IR and Raman spectra confirmed the presence of the [TiO6] and [SnO6] octahedra and (ZnO4) tetrahedron. The parameters used in the dye discoloration were: catalyst mass and irradiation times. The results showed that a higher irradiation time provided a better efficiency. Zn2SnO4 presented the best result, with 81 % of discoloration after 4 h of irradiation. As tin was replaced by titanium in the spinel structure, the catalyst efficiency decreased, achieving 37 % for the Zn2TiO4. / O estanato (Zn2SnO4) e o titanato de zinco (Zn2TiO4) são óxidos do tipo espinélio inverso, destacam-se devido a suas propriedades óticas, elétricas, magnéticas, semicondutoras e fotocatalíticas. Nesse trabalho, os dois materiais foram combinados com a finalidade de obter uma solução sólida, Zn2Sn1-xTixO4, (x= 0; 0,25; 0,50; 0,75; 1,0), utilizando o método Pechini modificado, de modo a investigar a influência da substituição dos íons Sn4+ por íons Ti4+ na rede do espinélio para aplicação como catalisadores na fotodescoloração do corante amarelo remazol ouro. Os catalisadores foram caracterizados pelas técnicas de difração de raios-X (DRX), espectroscopia na região do infravermelho (IV), espectroscopia na região do ultravioleta visível (UV-Vis), espectroscopia Raman e medida de área superficial por BET. Os resultados de DRX mostraram que os materiais apresentaram alta organização a longo alcance, quando calcinados a 700 °C, utilizando acetato de zinco e pH 1. Os espectros de IV e Raman confirmaram a presença dos octaedros [ZnO6], [TiO6],[SnO6] e tetraedro (ZnO4). Os parâmetros utilizados na descoloração do corante foram: massa fixa de catalisador e tempos de radiação. Os resultados mostraram que um maior tempo de radiação proporcionou maior eficiência. O Zn2SnO4 apresentou o melhor resultado, com descoloração de 81% após 4 h de radiação. À medida que o estanho foi substituído pelo titânio na estrutura do espinélio, a eficiência do catalisador foi decrescendo, chegando a 37% para o Zn2TiO4.

The premise of this paper is that in a monetary production economy, policy decisions of the central bank, or more generally the 'monetary authority', set the tone not only for nominal interest rates but also for 'real' interest rates defined in the usual way. This is a different question than that of which institution(s) acquire the status of monetary authority at any particular stage of socioeconomic or technological development. Rather the suggestion is that the existence of some such social structure is a prerequisite if anything resembling capitalist monetary production is to be viable. The paper demonstrates that a coherent macroeconomic theory can be elaborated on this basis, including an explanation of economic growth, the business cycle, inflation, the functional distribution of income, the 'Keynesian' problem of the impact of demand growth on economic growth, endogenous money, cumulative causation, and endogenous technical change. (author's abstract) / Series: Working Papers Series "Growth and Employment in Europe: Sustainability and Competitiveness"

This is a short summary of a recent survey [FR03] focusing on the observed evidence, that Internet connectivity is positively correlated with spread of democracy at high levels of significance. The results of multivariate correlation analysis and probabilities regression estimate models are based on the combined analysis of mid - 1991's, to 2001 data series of the Eurostat's and US Census Bureau, the World Bank, and OECD's statistical data service which track the growth of information technology and rating of freedom and democracy worldwide.(author's abstract)

This dissertation focuses on nonlinear modal interactions in plates. Our first investigation involved the activation of a two-to-one internal resonance in the response of a metallic cantilever plate. Although the plate was excited around the frequency of its second bending mode, its response contained a contribution from its first torsional mode. The frequency ratio between the bending and torsional modes was nearly two-to-one. Next, we investigated the energy transfer from high-frequency to low-frequency modes in a cantilever graphite-epoxy composite plate (90/30/ — 30/ — 30/30/90)_s. The plate was excited around the natural frequency of its seventh (third torsional) mode. For some excitation amplitudes and frequencies, we observed the activation of a low-frequency (first bending) mode accompanied by an amplitude and phase modulation of the seventh mode. We studied combination resonances in the responses of cantilever composite plates with the layups (90/30/ — 30/ — 30/30/90)_s and (—75/75/75/ — 75/75/ — 75)_s to harmonic base excitations. We activated the combination resonance f_e≈ ω₂ + ω₇ in the (90/30/ — 30/ — 30/30/90)_s plate, where the w; are the natural frequencies of the plate and f<sub>e<sub> is the excitation frequency. In the (—75/75/75/ — 75/75/ — 75)_s plate, we activated the external combination resonance f<sub>e<sub>≈ 1/2(ω₂+ω₅) and the combination internal resonance f_e≈1/2(ω₂+ω₁₃) ≈ ω₈. We carried out an experimental-modal analysis (EMA) of a nonclassically supported plate with and without a constrained-layer damping (CLD) patch attached on its upper left-hand side surface. The natural frequencies and mode shapes were used to ascertain the effect of the CLD patch. / Ph. D.

This paper gives an overview on the research done in the fields of tax competition, coordination and harmonisation. The survey is divided in two main parts, in the first section we compare the standard tax competition literature that sees tax competition as a bad, to public choice contributions that advocate tax reductions. In the second part we consider theories of endogenous growth, which focus on analysing the taxation question. After introducing the fundamental contributions, we discuss extensions in the line of an open economy, an OLG setting and the transitional dynamics in greater detail. (author's abstract) / Series: Discussion Papers SFB International Tax Coordination