Les données chronologiques disponibles pour les gisements du Paléolithique moyen du Sud-Ouest de la France font état d’un manque de jalons chronologiques fiables. Pour ces périodes anciennes, l’établissement d’un cadre chronologique nécessite un investissement méthodologique important dans le domaine de la datation numérique. Les résultats obtenus dans cette étude reposent essentiellement sur la datation par luminescence optique de grains de feldspaths et de quartz contenus dans les sédiments. En particulier, l’étude des signaux de luminescence classiquement exploités (IRSL, pIR-IRSL), nous permet de mieux évaluer la fiabilité des datations à partir des feldspaths potassiques. Un protocole de datation fondé sur l’exploitation du signal de radioluminescence (IR-RF) de ces minéraux a aussi été développé. Ainsi, la luminescence optique a été appliquée à des échantillons provenant de six gisements de référence : Les Pradelles (Marillac, Charente), Combe Brune 2 (Creysse, Dordogne), Roc de Marsal (Campagne, Dordogne), Artenac (Saint-Mary, Charente), La Quina (Gardes-le-Pontaroux, Charente) et La Ferrassie (Savignac-de-Miremont, Dordogne). La combinaison des résultats obtenus nous a permis, au sein de chaque niveau archéologique, d’évaluer la pertinence des datations et de proposer pour chaque gisement un scénario chronologique qui nous semble fiable. À l’issue de cette étude, les occupations humaines, caractérisées selon leurs industries, ont pu être replacées sur une échelle des temps en regard des variations paléoclimatiques et paléoenvironnementales régionales. Plusieurs constats ont été dressés enrichissant le registre de nos connaissances sur les cultures néandertaliennes. / Currently available chronological information for Middle Palaeolithic sites in southwestern France precludes the establishment of a robust chronological framework. For these early periods, developing such a framework relies upon important methodological advancements in numerical dating techniques. The results of this study are essentially based on the optical luminescence dating of sedimentary feldspars and quartz. Focusing on the most commonly employed luminescence signals (IRSL, pIR-IRSL), it was possible to more clearly evaluate the reliability of dates obtained on K-feldspars. A dating protocol for these materials based on their radioluminescence signal (IR-RF) was also developed. Optical luminescence dates were produced for six major archaeological sites: (Marillac, Charente), Combe Brune 2 (Creysse, Dordogne), Roc de Marsal (Campagne, Dordogne), Artenac (Saint-Mary, Charente), La Quina (Gardes-le-Pontaroux, Charente) et La Ferrassie (Savignac-de-Miremont, Dordogne). Collating the results for each archaeological level allowed the coherence of the dates to be tested and a reliable chronological sequence to be proposed for each site. The different human occupations, characterised by their industrial attribution, could be placed within a chronological framework that incorporates regional palaeoenvironmental and palaeoclimatic variations. Finally, several observations provide new insights for our understanding of Neandertal cultures.

Loess is a silty material produced via glacial grinding and its deposition is usually associated with colder periods when there is a considerable increase in atmospheric dust transport. The magnetic susceptibility of loess-palaeosol sequences has been the subject of extensive research within palaeoclimatology as it has proven to be reliable climate proxy. Most research on magnetic susceptibility has been focused on thick deposits found in Europe and Asia, in particular the Chinese Loess Plateau where it is possible to discern more than 2.5 million years of climate variation in deposits several hundred meters thick. The climate development throughout the Quaternary has been characterized by glacials where there has been a significant ice growth, and interglacials where ice sheets have retreated. The Last Glacial Maximum was the most recent time of ice sheets reaching their maximum extent, occurring at some point between 26.5 and 18 ka BP. Aeolian reworking of material produced in conjunction with the Irish Sea Ice Stream (ISIS) occurred approximately 5000 years after the LGM. The ISIS limit were located just north of the Lizard Peninsula, and impinged on the Isles of Scilly. Loess deposits in SW England has largely been ignored in previous research in favour of the previously mentioned Chinese loess, but may be important climate archives in understanding the climate development of the North Atlantic. As such, the scope of this thesis is investigating the magnetic susceptibility of loess deposits in Cornwall and the Isles of Scilly in the far SW England. This is done by analyzing 36 samples from Lowland Point and 24 samples from Chynhalls Point, both located at the Lizard Peninsula in Cornwall, as well as 20 samples from Porthcressa and 14 samples from Gimble Porth, both located at the Isles of Scilly. The instruments used for analysis are the Bartington MS2B and the Agico MFK-1 FA Kappabridge, where all 96 samples were analyzed on the former while the 36 Lowland Points samples and the 20 Porthcressa samples were also analyzed on the latter. The Bartington MS2B operates at two frequencies, 465 Hz and 4650 Hz, while the Agico MFK-1 FA Kappabridge operates at three frequencies, 976 hz, 3904 Hz, and 15616 Hz. The results from this study suggest that the Lizard Peninsula sample sites exhibit signs of magnetic enhancement through pedogenic processes while the sample sites at the Isles of Scilly consist of mainly unaltered material, likely due to an overlying sollifluction unit inhibiting magnetic enhancement. As a consequence of the different frequencies, the results were lognormalized to permit a direct comparison between the instruments. While the variability in magnetic susceptibility was strikingly similar, the results of the Kappabridge were shifted to ~20% higher values than those of the Bartington which may be attributed to the Kappabridges higher precision when analyzing weakly magnetic material. A similar shift is not evident when measuring the calibration samples of each instrument. In determining the mean annual precipitation after deposition, the Lizard Peninsula samples sites suggest an exposure to an annual precipitation between 300-400 mm/yr, compared to modern rainfall between 900-1000 mm/yr. The data from the Isles of Scilly were insufficient for calculating the mean annual precipitation due to the lack of evidence for magnetic enhancement. / Loess är benämningen för material i siltstorlek som produceras då glacial aktivitet maler ned den underliggande berggrunden. Detta material är tillräckligt litet för att fångas upp av vindar och därefter transporteras i atmosfären, för att därefter avsättas då vindhastigheten minskar. Under kalla perioder i jordens historia ökar denna transport då vindhastigheten ofta varit högre än under varma perioder. Under de varmare perioderna och med tiden så utsätts loess för jordmånsbildande processer och bildar palaeosoler. Den magnetiska susceptibiliteten hos loess-palaeosol-sekvenser har under flera årtionden varit ämnet för utbredd forskning då detta har visat sig vara en tillförlitlig klimatproxy för att förstå klimatutvecklingen under jordens gångna historia. I synnerhet har loess-palaeosol-sekvenser i Kina varit av intresse då det går att utröna mer än 2,5 miljoner år av klimatutveckling i avlagringar som på sina platser är flera hundra meter tjocka. Under den senaste istidens maximala utbredning mellan 26500 och 18000 år sedan passerade en isström över den Irländska sjön (Irish Sea Ice Stream, sammankopplad med inlandsisen), förbi Cornwalls norra kust och stötte samman med Scillyöarna. Det tog sedan ungefär 5000 år tills vindtransport av avsatt material påbörjades. Loessavlagringar i sydvästra England har känts till under årtionden men har till stor del ignorerats till fördel för de tidigare nämnda avlagringarna i Kina, men de kan agera som viktiga klimatarkiv för tiden efter den senaste istiden och därmed klimatutvecklingen i Nordatlanten. Denna rapport undersöker således den magnetiska susceptibiliteten i loess från två platser på Lizard-halvön i Cornwall, och två platser på Scillyöarna. Totalt analyserades 96 prover, 36 av dem från Lowland Point, 24 av dem från Chynhalls Point, båda belägna på Lizard-halvön, samt 20 prover från Porthcressa och 14 prover från Gimble Porth, båda belägna på Scillyöarna. Resultaten från denna studie påvisar att provplatserna på Lizard-halvön visar tecken på magnetisk förstärkning på grund av jordmånsbildande processer, medan provplatserna på Scillyöarna huvudsakligen består av oförändrat material, troligen på grund av att dessa täckts av annat material under isens tillbakadragning, vilket förhindrat jordmånsbildning. Resultaten från Lizard-halvön möjliggör beräkning av årsmedelnederbörden sedan materialet först avsattes, vilket beräknades till mellan 300-400 mm/år jämfört med modern årsmedelnederbörd mellan 900-1000 mm/år. Dessvärre möjliggjorde inte resultaten från provplatserna på Scillyöarna en liknande beräkning.

The presence of the sea ice diatom biomarker IP25 in Arctic marine sediments has been used in previous studies as a proxy for past spring sea ice occurrence and as an indicator of wider palaeoenvironmental conditions for different regions of the Arctic over various timescales. The current study describes a number of analytical and palaeoceanographic developments of the IP25 sea ice biomarker. First, IP25 was extracted and purified from Arctic marine sediments. This enabled the structure of IP25 to be confirmed and enabled instrumental (GC-MS) calibrations to be carried out so that quantitative measurements could be performed with greater accuracy. Second, palaeo sea ice reconstructions based on IP25 and other biomarkers were carried out for a suite of sub-Arctic areas within the Greenland, Norwegian and Barents Seas, each of which represent contrasting oceanographic and environmental settings. Further, an evaluation of some combined biomarker approaches (e.g. the PIP25 and DIP25 indices) for quantifying and/or refining definitions of sea ice conditions was carried out. Temporally, particular emphasis was placed on the characterisation of sea ice conditions during the Younger Dryas and the Holocene. Some comparisons with other proxies (e.g. foraminifera, IRD) were also made. A study of a sediment core from Andfjorden (69.16˚N, 16.25˚E), northern Norway, provided unequivocal evidence for the occurrence of seasonal sea ice conditions during the Younger Dryas. The onset (ca. 12.9 cal. kyr BP) and end (ca. 11.5 cal. kyr BP) of this stadial were especially clear in this location, while in a study from the Kveithola Trough (74.52˚N, 16.29˚E), western Barents Sea, these transitions were less apparent. This was attributed to the presence of colder surface waters and the occurrence of seasonal sea ice both before and after this stadial at higher latitudes. Some regional differences regarding the severity of the sea ice conditions were also observed, although an overall general picture was proposed, with more severe sea ice conditions during the early-mid Younger Dryas and less sea ice observed during the late Younger Dryas. A shift in the climate towards ice-free conditions was recorded in northern Norway during the early Holocene (ca. 11.5 – 7.2 cal. kyr BP). Milder conditions were also observed during the Holocene in the western Barents Sea, with three main climate periods observed. During the early Holocene (ca. 11.7 – 9.5 cal. kyr BP), the position of the spring ice edge was close to the study area which resulted in high productivity during summers. During the mid-late Holocene (ca. 9.5 – 1.6 cal. kyr BP), sea ice was mainly absent due to an increased influence of Atlantic waters and northward movement of the Polar Front. During the last ca. 1.6 cal. kyr BP, sea ice conditions were similar to those of the present day. In addition to the outcomes obtained from the Norwegian-Barents Sea region, comparison of biomarker and other proxy data from 3 short cores from Kangerdlugssuaq Trough (Denmark Strait/SE Greenland) with historical climate observations allowed the development of a model of sea ice conditions which was then tested for longer time-scales. It is suggested that the IP25 in sediments from this region is likely derived from drift ice carried from the Arctic Ocean via the East Greenland Current and that two main sea surface scenarios have existed over the last ca. 150 yr. From ca. AD 1850 – 1910, near perennial sea ice conditions resulted in very low primary productivity, while from ca. AD 1910 – 1986, local sea ice conditions were less severe with increased drift ice and enhanced primary productivity. This two-component model was subsequently developed to accommodate different sea surface conditions that existed during the retreat of the Greenland Ice Sheet during the deglaciation (ca. 16.3 – 10.9 cal. kyr BP).

High-resolution records of early Holocene deposits are rare, and as a consequence reconstruction of terrestrial environments very soon after the deglaciation has often been difficult. In this study the palaeoenvironmental conditions of early Holocene (c. 10600-7500 cal. yr BP) are reconstructed in the Värriötunturit area of northeastern Finland, using evidence from plant macrofossils and pollen preserved in a lake sediment sequence retrieved from the small lake Kuutsjärvi. Special emphasis is put on the environment immediately following the deglaciation as the base of the sediment sequence is rich in minerogenic material interpreted to have been deposited by meltwater pulses from the retreating ice sheet. The abundance and variety of fossil remains in these early meltwater deposits provide evidence for a very productive ice-marginal environment in the area between the lake and the ice sheet, and the presence of tree-type Betula macro remains as well as high percentage values of tree-type Betula pollen suggests that a subarctic birch forest established just a few years after the deglaciation. In the following centuries the birch forest around the lake became rich in an under growth of ferns, and at c. 9400 cal. yr BP a transition into a mixed pine and birch forest took place. Due to absence of indicator plant taxa in the sediment it was not possible to reconstruct temperature conditions for any parts of the sequence in this study. However, the rapid colonisation of birch forests suggests that the climate was warm already during deglaciation, which is also in accordance with climatic conditions reconstructed for the early Holocene in the nearby Sokli area just 10 km away, as well as in other parts of Fennoscandia and Russia.

Triple oxygen and hydrogen isotope analysis of the structurally-bound water in gypsum can provide a direct measure of past hydrologic variability. This thesis presents the development of the water extraction and isotopic measurement procedures, the calculation of the gypsum-water isotope fractionation factors, and the application of the method to constrain the palaeohydrologic conditions in two temporally and geographically disparate sites. Measurement of the isotopic composition of gypsum hydration water is used to examine the hydrological changes that occurred during the Terminal Classic Drought of the Maya lowlands (~800-1000 CE), coincident with the period when the Classic Maya Civilization of Mesoamerica collapsed. The data provide a complete and direct archive of hydrological conditions that have previously been limited to ice core records. Mean annual rainfall is shown to have decreased by between 41% and 54%, with intervals of up to 70%, compared to present-day conditions. This study has also shown for the first time that relative humidity was 2%-7% lower during the Terminal Classic Drought compared to today. The methodology is also applied to the massive gypsum deposits in the marginal and deep basins of the Mediterranean to interpret the chemical evolution of parent water bodies during the Messinian Salinity Crisis (5.97-5.3 Ma). By combining the measurement of gypsum hydration water with other traditional (e.g. strontium) and novel (e.g. calcium and barium) isotope tracers, the hydrological changes during the deposition of Primary Lower Gypsum units of the Sorbas Basin in southeastern Spain, the Upper Gypsum units of Sicily, and deep basin deposits have been constrained. The results indicate that all deposits experienced a significant freshwater contribution to the mother fluids from which they formed. It is proposed that obliquity-controlled sea level and eccentricity-modulated precession, superimposed on longer-term tectonic restriction of the Mediterranean-Atlantic exchange, together controlled the varying depositional environments during the formation of the Messinian Salt Giant. This thesis demonstrates that the analysis of gypsum hydration water is a powerful tool for palaeoclimate reconstruction. The methodology can be applied to gypsum (and other hydrated minerals) in a wide range of settings across geological space and time, providing a rich source of information about the environmental conditions under which they formed.

The Late Cretaceous–early Paleogene is the most recent period of Earth history with a dynamic carbon cycle that experienced sustained global greenhouse warmth and can offer a valuable insight into our anthropogenically-warmer future world. Yet, knowledge of ambient climate conditions and evolution of the carbon cycle at this time, along with their relation to forcing mechanisms, are still poorly constrained. In this thesis, I examine marine sediments recovered from the South Atlantic Walvis Ridge (ODP Site 1262) and Indian Ocean Ninetyeast Ridge (IODP Site U1443 and ODP Site 758), to shed new light on the evolution of the climate and carbon cycle from the Late Maastrichtian through to the Early Eocene (~67.10–52.35 Ma). The overarching aims of this thesis are: 1) to identify the long-term trends and principle forcing mechanisms driving the climate and carbon cycle during this time period, through construction of 14.75 million-year-long, orbital-resolution (~1.5–4 kyr), stratigraphically complete, benthic stable carbon (δ13Cbenthic) and oxygen (δ18Obenthic) isotope records; 2) to investigate in more detail the climatic and carbon-cycle perturbations of the Early–Middle Paleocene (e.g., the Dan-C2 event, Latest Danian Event and the Danian/Selandian Transition Event) and place these in their proper (orbital) temporal context; 3) to investigate the Late Maastrichtian warming event and its relationship to the eruption of the Deccan Traps Large Igneous Province, as well as its role (if any) in the subsequent Cretaceous/Paleogene (K/Pg) mass extinction; 4) to provide the first orbital-resolution estimates of temperature and carbonate chemistry variability from the low latitude Indian Ocean spanning the Late Paleocene–Early Eocene, through analysis of trace element and stable isotope data from multiple foraminiferal species. Taken together, the results presented in this thesis provide a critical new insight into the dynamic evolution of the climate and carbon cycle during the greenhouse world of the early Paleogene, and shed light on the potential forcing mechanisms driving the climate and carbon cycle during this time.

This thesis presents investigations on sediments from two African lakes which have been recording changes in their surrounding environmental and climate conditions since more than 200,000 years. Focus of this work is the time of the last Glacial and the Holocene (the last ~100,000 years before present [in the following 100 kyr BP]). One important precondition for this kind of research is a good understanding of the present ecosystems in and around the lakes and of the sediment formation under modern climate conditions. Both studies therefore include investigations on the modern environment (including organisms, soils, rocks, lake water and sediments). A 90 m long sediment sequence was investigated from Lake Tswaing (north-eastern South Africa) using geochemical analyses. These investigations document alternating periods of high detrital input and low (especially autochthonous) organic matter content and periods of low detrital input, carbonatic or evaporitic sedimentation and high autochthonous organic matter content. These alternations are interpreted as changes between relatively humid and arid conditions, respectively. Before c. 75 kyr BP, they seem to follow changes in local insolation whereas afterwards they appear to be acyclic and are probably caused by changes in ocean circulation and/or in the mean position of the Inter-Tropical Convergence Zone (ITCZ). Today, these factors have main influence on precipitation in this area where rainfall occurs almost exclusively during austral summer. All modern organisms were analysed for their biomarker and bulk organic and compound-specific stable carbon isotope composition. The same investigations on sediments from the modern lake floor document the mixed input of the investigated individual organisms and reveal additional influences by methanotrophic bacteria. A comparison of modern sediment characteristics with those of sediments covering the time 14 to 2 kyr BP shows changes in the productivity of the lake and the surrounding vegetation which are best explained by changes in hydrology. More humid conditions are indicated for times older than 10 kyr BP and younger than 7.5 kyr BP, whereas arid conditions prevailed in between. These observations agree with the results from sediment composition and indications from other climate archives nearby. The second lake study deals with Lake Challa, a small, deep crater lake on the foot of Mount Kilimanjaro. In this lake form mm-scale laminated sediments which were analyses with micro-XRF scanning for changes in the element composition. By comparing these results with investigations on thin sections, results from ongoing sediment trap studies, meteorological data, and investigations on the surrounding rocks and soils, I develop a model for seasonal variability in the limnology and sedimentation of Lake Challa. The lake appears to be stratified during the warm rain seasons (October – December and March – May) during which detrital material is delivered to the lake and carbonates precipitate. On the lake floor forms a dark lamina with high contents of Fe and Ti and high Ca/Al and low Mn/Fe ratios. Diatoms bloom during the cool and windy season (June – September) when mixing down to c. 60 m depth provides easily bio-available nutrients. Contemporaneously, Fe and Mn-oxides are precipitating which cause high Mn/Fe ratios in the light diatom-rich laminae of the sediments. Trends in the Mn/Fe ratio of the sediments are interpreted to reflect changes in the intensity or duration of seasonal mixing in Lake Challa. This interpretation is supported by parallel changes in the organic matter and biogenic silica content observed in the 22 m long profile recovered from Lake Challa. This covers the time of the last 25 kyr BP. It documents a transition around 16 kyr BP from relatively well-mixed conditions with high detrital input during glacial times to stronger stratified conditions which are probably related to increasing lake levels in Challa and generally more humid conditions in East Africa. Intensified mixing is recorded for the time of the Younger Dryas and the period between 11.4 and 10.7 kyr BP. For these periods, reduced intensity of the SW monsoon and intensified NE monsoon are reported from archives of the Indian-Asian Monsoon region, arguing for the latter as a probable source for wind mixing in Lake Challa. This connection is probably also responsible for contemporaneous events in the Mn/Fe ratios of the Lake Challa sediments and in other records of northern hemisphere monsoon intensity during the Holocene and underlines the close interaction of global low latitude atmospheric circulation. / In dieser Arbeit werden Ergebnisse von Untersuchungen an den Sedimenten zweier afrikanischer Seen vorgestellt, die ein Archiv für Klimaveränderungen über einen Zeitraum von mehr als 200.000 Jahren darstellen. Der Schwerpunkt liegt in dieser Arbeit auf dem letzten Glazial und dem Holozän (ca. 100.000 Jahre vor heute [nachfolgend als 100 kyr BP bezeichnet] bis heute). Grundlegende Voraussetzung für solche Studien ist ein gutes Verständnis der Ökosysteme in und um den See, sowie des gegenwärtigen Sedimentationsgeschehens. Deswegen beinhalten beide Seestudien Untersuchungen der heutigen Organismen, Böden, Gesteine, Wasserchemie und Sedimentablagerungen. Im Tswaing-See im nordöstlichen Südafrika wurden anhand eines 90 m langen Sedimentprofils Studien zur Sedimentzusammensetzung und Untersuchungen der Zusammensetzung und Qualität des organischen Materials durchgeführt. Sie zeigen einen Wechsel zwischen Phasen hohen detritischen Eintrags, während derer v.a. kaum autochthones organisches Material im See erhalten blieb, mit Phasen geringen Eintrags und dafür karbonatischer oder evaporitischer Sedimentation, die hohe Gehalte v.a. autochthonen organischen Materials aufweisen. Diese Phasen werden als relativ feuchte bzw. trockene Perioden interpretiert und folgen bis vor ca. 75 kyr BP Schwankungen der lokalen solaren Einstrahlung. Dieser Einfluss nimmt nach 75 kyr BP ab und azyklische feuchte Phasen werden beobachtet. Mögliche Ursachen sind Veränderungen in der ozeanischen Zirkulation und Verschiebungen in der Lage der Innertropischen Konvergenzzone (ITCZ); beides sind auch heute Haupteinflussfaktoren auf die Niederschläge in der Region. Die heute lebenden Organismen des Tswaing-Kraters wurden mittels Analysen der Biomarkerzusammensetzung und der Kohlenstoffisotopie charakterisiert und ihr Einfluss auf die heutigen Seeablagerungen untersucht. Dabei konnten zusätzlich Indikatoren für die Aktivität methanotropher Bakterien nachgewiesen werden. Der Vergleich heutiger Sedimente mit denen des Zeitraumes 14 bis 2 kyr BP zeigt deutliche Veränderungen sowohl in der Zusammensetzung, als auch in der Kohlenstoffisotopie der Biomarker, die mit Veränderungen in der Hydrologie erklärt werden können. Die gefundenen Hinweise auf feuchtere Bedingungen im Zeitraum älter als 10 kyr BP, für trockenere Verhältnissen zwischen 10 und 7.5 kyr BP und für die nachfolgende Wiederzunahme an Feuchtigkeit werden durch die sedimentologischen Ergebnisse unterstützt. Objekt der zweiten Seestudie ist der Challa-See am Fuß des Kilimanjaro. Hier werden heute im mm-Maßstab laminierte Sedimente gebildet, die mit Mikro-XRF-scanning auf Veränderungen in der Elementzusammensetzung untersucht wurden. Zusammen mit Untersuchungen der Mikrofazies und im Vergleich mit ersten Ergebnissen noch laufender Sedimentfallenstudien, mit meteorologischen Daten und Analysen des Umgebungsgesteins werden die saisonalen Veränderungen in der Temperaturverteilung, der Durchmischungstiefe, dem detritischen Eintrag und der Bioproduktivität des Sees in den Sedimenten nachvollziehbar. Der See ist in den feucht-warmen Perioden von Oktober bis Dezember und von März bis Mai stratifiziert. Während dieser Zeit erfolgt der Eintrag detritischen Materials und Kalziumkarbonat fällt aus; eine dunkle Lage mit hohen Gehalten an Fe und Ti und mit hohen Ca/Al- und niedrigen Mn/Fe-Verhältnissen bildet sich am Boden des Sees. Diatomeen blühen während der kühlen, windigen Periode von Juni bis September, wenn die Durchmischung bis auf etwa 60 m Tiefe Nährstoffe verfügbar macht. Die Ausfällung von Fe- und Mn-oxiden sorgt für hohe Mn/Fe-Verhältnisse; es bildet sich eine helle Lage auf dem Sediment. Trends im Mn/Fe-Verhältnis werden als Signal für Veränderungen in der Intensität oder Dauer der saisonalen Durchmischung interpretiert. Dies wird unterstützt durch parallele Trends im Gehalt an organischem Material und an biogenem Silizium, wie durch Analysen an einem 22 m langen Bohrkern gezeigt werden kann. Nach gut durchmischten und von erhöhtem Eintrag von außen geprägten Verhältnissen während des letzten Glazials erfolgt gegen 16 kyr BP ein Übergang zu stärker stratifizierten Bedingungen. Diese korrespondieren mit einem steigenden Seespiegel und verbreiteten Hinweisen auf feuchte Bedingungen im tropischen Ostafrika. Stärkere Durchmischung herrschte während der Jüngeren Dryas und von 11.4 bis 10.7 kyr BP. Diese Perioden entsprechen Zeiten verringerter Südwest- und vermutlich verstärkter Nordostmonsunintensität im Bereich des Indisch-Asiatischen Monsuns und spiegeln eine global beobachtete südliche Verschiebung der ITCZ wider. Nach einer kurzen stabilen, feuchten Phase im frühen Holozän nimmt die Durchmischung des Sees im Verlauf des Holozän wieder zu. Abrupte Ereignisse während des Holozän scheinen im Challa-See zeitgleich mit Veränderungen der Monsunintensität der Nordhemisphäre aufzutreten und bezeugen die starke klimatische Kopplung der niederen Breiten in globalem Maßstab.

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This thesis examines the role of rock avalanches in tectonically active terrains including the effects of the deposits on glacier behaviour and their contribution to moraine formation. The chronologies of mountain glacier fluctuations, based on moraine ages, are widely used to infer regional climate change and are often correlated globally. In actively uplifting mountain ranges rock avalanches that travel onto the ablation zone of a glacier can reduce ice-surface melting by insulating the ice. This can cause buried ice to thicken due to slower ablation and can significantly alter the overall glacier mass balance. This glacier response to supraglacial rock avalanche deposits can confound apparent climatic signals extracted from moraine chronologies. This thesis investigates the processes through which rock avalanche deposits may affect glaciers and develops a new technique to identify the presence of rock avalanche debris in glacial moraines. From laboratory experiments on the effects of debris on ice ablation it is demonstrated that the rate of underlying ice ablation is controlled by diurnal cyclicity and is amplified at high altitude and in lower latitudes. The relatively low permeability of rock avalanche sediment in comparison with non-rock avalanche supraglacial debris cover contributes to the suppression of ablation, at least partly because it greatly reduces the advection of heat from rain water to the underlying ice. The laboratory findings are supplemented by field investigations of two recent rock avalanche deposits on glaciers in the Southern Alps of New Zealand. This work demonstrates that the rock avalanche deposits are very thick (10 m at Aoraki/Mt. Cook and 7m at Mt. Beatrice) and almost stopped the ablation of the overlying ice. This resulted in the formation of an ice-platform more than 30 m high. This led to a reduction of the existing negative mass balance of the affected Tasman and Hooker Glaciers. There was little noticeable alteration of the overall glacial regime due to the small scale of the debris covered area (4 and 1% of the ablation zones for the Tasman and Hooker Glaciers, respectively) but there is a significant contribution to supraglacial debris, which is passively transported toward the terminus. A conceptual model of the response of mountain valley glaciers to emplacement of extensive rock avalanche debris on the ablation zone has been proposed for the effect of this type of debris on terminal moraine formation based on enhanced ‘dumping’ of supraglacial sediments. A new technique has been developed to distinguish rock-avalanche-derived sediment from sediment of glacial origin, based on the sedimentary characteristics of the finest fraction. Examination of rock avalanche sediment under the Scanning Electron Microscope showed that finer particles tend to form strong clumps, which comprise many smaller (down to nanometre-scale) clasts, named here ‘agglomerates’. These agglomerates are present in the fine fraction of all examined rock avalanche deposits and absent in known non-rock-avalanche-derived glacial sediments. The agglomerates are characteristics of sediment produced under the high-stress conditions of rock avalanche emplacement and contrast with lower-stress process sub- and en-glacial environments. It is demonstrated that these agglomerates are present in some moraines in the Southern Alps of New Zealand that have been attributed to climate fluctuation. Consequently, this technique has the potential to resolve long-standing arguments about the role of rock avalanches in moraine formation, and to enhance the use of moraines in palaeoclimatological studies.

Rice grows in saturated soil water condition and its requirement for water is highest amongst other cereal crops. In India, the southwest monsoon wind regime brings rainfall that provides a favourable environment for rice cultivation. Thus, there is significant dependency ofrice production on the southwest monsoon rainfall. Being a crop that grows across diverse climatic regions in India ranging from the humid to semi-arid, it offers possibility to explore therelationship between stable isotopic compositions in the grain organic matter with the climaticfactors relevant for its growth. In this thesis, we measured the isotopic compositions of oxygen, hydrogen and carbon of several rice genotypes that were cultivated during the southwest monsoon in diverse climatic regions across the Indian landmass. These isotopic values were then compared with the seasonalaverage values of climate factors such as relative humidity and temperature. Together with thiswe also studied the dependency of the oxygen isotope composition of the grain OM (δ18OOM) onthat of the source water (δ18OSW). Upon removal of δ18OSW effect from δ18OOM, we obtained astrong and significant relationship between the 18O enrichment in grain organic matter (definedas 18OOM) with relative humidity. The gradient recorded was 0.45‰ shift in 18OOM with 1%change in the relative humidity level. This relationship can potentially be used to estimate thepast variations in relative humidity (and by extension, can provide a measure of monsoon rainfallvariations). We further validated this relationship based on experiments carried out in aglasshouse where all the physical factors were well-monitored. Together with this, carbonisotopic composition measured in the rice grain organic matter were used to infer the water useefficiency of rice grown in different climatic settings. The stable isotope approach was furtherimplemented for studying the archaeological rice grains recovered from archaeological sites. Analysis of carbon isotopic composition of archaeological rice grains from seven archaeologicalsites (Balu, Kanmer, Ojiyana, Lahuradewa, JognaKhera, Hulas and Kunal), belonging to theHarappan civilization and other contemporary cultures provided a new suit of data on quantitativeestimate of the hydroclimatic condition (specifically relative humidity) and water availabilityduring the existence of this civilization.