Phenol Formaldehyde (PF) and polymeric isocyanate (pMDI) are the two main types of adhesives used in the production of structural wood-based composites. Much is unknown about various aspects of adhesion between these two types of resins and wood. The present research describes the development of techniques which will permit an enhanced understanding of 1.) the extent of cure of PF within a wood based composite, 2.) the scale of molecular level interactions between PF and pMDI and wood, 3.) mechanical performance and durability of wood-adhesive bonds. Correlations were established between conventional methods of characterization of neat PF (thermomechanical analysis, swelling studies) and measurements made using 13C CP/MAS NMR. These correlations were then utilized to characterize PF cured in the presence of wood. The use of 13C labeled PF allowed estimates of relative degrees of resin conversion to be made. The use of 13C and deuterium labeled PF allowed qualitative estimates of resin molecular rigidity to be made. The scale of molecular level interactions between PF and pMDI and wood was probed using NMR relaxation experiments. Evidence was shown to suggest the formation of an interpenetrating polymer network (IPN) morphology existing at both types of wood-resin interphases. The formation of the IPN morphology was strongly influenced by resin molecular weight, cure temperature and the presence of solvent. A new test geometry for the evaluation of the fracture toughness of wood-adhesive bonds was developed. Consistent and reliable results were obtained. It was found that low molecular weight PF possessed enhanced durability over high molecular weight. / Ph. D.

This work reports the elucidation of the structure of a copolymer generated by the cross- catalyzed reactions of PF and pMDI prepolymers.  The electronic behavior of phenolic monomers as perturbed by alkali metal hydroxides in an aqueous environment was studied with 1H and 13C NMR.  Changes in electronic structure and thus reactivity were related to solvated ionic radius, solvent dielectric constant, and their effect on ion generated electric field strength. NMR chemical shifts were used to predict order of reactivity for phenolic model compounds with phenyl isocyanate with good success.  As predicted, 2-HMP hydroxymethyl groups were more reactive than 4-HMP in forming urethane bonds under neutral conditions and 2-HMP hydroxymethyl groups were more reactive than 4-HMP in forming urethane bonds under alkaline conditions. The structure of the reaction products of phenol, benzyl alcohol, 2-HMP, and 4-HMP with phenyl isocyanate were studied using 1H and 13C NMR under neutral organic and aqueous alkaline conditions.  Reactions in THF-d8 under neutral conditions, without catalyst, were relatively slow, resulting in residual monomer and the precipitation of 1,3-diphenyl urea from the carbamic acid reaction.  The reactions of phenol, 2-HMP, and 4-HMP in the presence of TEA catalyst favored the formation of phenyl urethanes (PU). Reactions with benzyl alcohol, 2-HMP, and 4-HMP in the presence of DBTL catalyst favored the formation of benzyl urethanes (BU).  Reactions of 2-HMP and 4-HMP led to formation of benzylphenyldiurethane (BPDU).  DBTL catalysts favored formation of BDPU strictly by a benzyl urethane pathway, while TEA favored its formation mostly via phenyl urethane, although some BU was also present.  Under aqueous alkaline conditions, 2-HMP was more reactive than 4-HMP, exhibiting an enhanced reactivity that was attributed to intramolecular hydrogen bonding and a resulting resonance stabilization of the phenolic aromatic ring. ATR-FTIR spectroscopic studies generated real time structural information for model compound reactions of the cross-catalyzed system, differentiating among reaction peaks generated by the carbamic acid reaction, PU and BU formation.  ATR-FTIR also permitted monitoring of propylene carbonate hydrolysis and accelerated alkaline PF resole condensation.  ATR-FTIR data also showed that the overall reaction stoichiometry between the PF and pMDI components drove copolymer formation.  Benzyl urethane formation predominated under balanced stoichiometric conditions in the presence of ammonium hydroxide, while phenyl urethane formation was favored in its absence.  Accelerated phenolic methylene bridge formation became more important when the PF component was in excess in the presence of sufficient accelerator.  A high percentage of free isocyanate was present in solid copolymer formed at ambient temperature. The combination of ammonium hydroxide and tin (II) chloride synergistically enhanced the reactivity of the materials, reducing the residual isocyanate. From 13C CP/MAS NMR of the copolymer, the presence of ammonium hydroxide and tin (II) chloride and the higher PF concentration resulted in substantial urethane formation.  Ammonium hydroxide favored formation of benzyl urethane from the 2-hydroxymethyl groups, while phenyl urethane formed in its absence.  The low alkalinity PF resole with ammonium hydroxide favored benzyl urethane formation.  Comparison of these results with the 13C NMR model compound reactions with phenyl isocyanate under alkaline conditions confirmed high and low alkalinity should favor phenyl and benzyl urethane formation respectively.  These cross catalyzed systems are tunable by formulation for type of co-polymer linkages, reactivity, and cost. / Ph. D.

In this study southern pine scrim was treated with low molecular weight melamine formaldehyde (MF), phenolic formaldehyde (PF), and furfuryl alcohol (FA) at different loadings and formed into 25-mm thick panels. Mechanical, dimensional and biological properties were evaluated. Results showed that samples treated with 5 percent MF had the highest MOE, MOR and work to maximum load values (15.3 GPa, 54.2 MPa and 25.4 KJ/m3, respectively), while those treated with 10 percent MF had the highest internal bond and edgewise toughness values of 390 kPa and 12 N•m, respectively. With respect to dimensional stability, samples treated with 20 percent FA had the lowest swelling value (ASE = 36.8 percent), and the lowest water absorption value (27.5 percent). Dynamic swelling test revealed much higher ASE value (> 45 percent) for furfurylated samples. As for termite resistance, both untreated and treated samples had little weight loss (1.10-1.56 percent), high visual rating (8-9.3/10), and 100 percent mortality in laboratory test.

<p> High molecular weight poly(ethylene oxide) (PEO) is used in conjunction with a cofactor such as phenol formaldehyde resin (PFR) as flocculants for newsprint manufacture. The objectives of the work described in this thesis were to prepare flocculants superior to PEO and to determine the flocculation mechanism. A series of novel comb copolymers consisting of a polyacrylamide backbone with short pendant poly(ethylene glycol) (PEG) chains was prepared and characterized. Additionally, polymerization conversion curves and reactivity ratios were measured. An interesting finding was that the reactivity of the macromonomer in free radical copolymerization decreased with PEG chain length. </p> <p> Flocculation results with both model latex dispersions and commercial wood pulp suspensions showed that copolymer chain length was the most important variable ; molecular weights greater than 3 million were required for good flocculation. On the other hand, the PEG pendant chains could be as short as 9 ether repeat units. Also, only 1 to 2 PEG chains for every 100 acrylamide backbone moieties were required. </p> <p> No published flocculation mechanisms could predict all the behaviors of the PEO or copolymer system. A new mechanism called complex bridging was proposed. According to this mechanism PEO or copolymer chains aggregate in the presence of cofactor to form colloidally dispersed polymer complex which heteroflocculates with the colloidal particles. </p> <p> Given in this work is the first explanation of the requirement for extremely high PEO or copolymer molecular weights for flocculation. It is proposed that polymer chains with molecular weights less than 106 collapse in the presence of PFR to an inactive precipitate before flocculation can occur whereas complexes based on very high molecular weight PEO collapse slowly enough to permit flocculation. </p> <p> Published mechanistic studies are hindered by the fact that PFR has poorly defined structures. It is shown for the first time in this work that welldefined, linear, poly(p-vinyl phenol) (PVPh) is an effective cofactor. </p> / Thesis / Doctor of Philosophy (PhD)

No description available.

Land use issues have dramatically changed the timber supply outlook for our nation's forest products industry. Since demand for wood products shows no sign of abating, alternative products must be developed. Bamboo is a very promising alternative raw material for the manufacture of structural composite products. It is fast growing, economical, renewable and abundant throughout the world. Bamboo has physical and mechanical properties that are comparable to many commercial timber species, and thus, may easily be processed using existing technology from the wood-based composites industry. Bamboo can be cultivated in the U.S., and thus has the potential to relieve some of the harvesting pressure from our nation's forestlands. However, the use of specific bamboo species for structural composite products will require a thorough investigation of the material as well as its interaction with other components. Thus, the primary objective of this dissertation is to determine the properties of Calcutta bamboo and its interaction with adhesives. The properties investigated were relative density, dimensional stability, equilibrium moisture content, bending strength and stiffness, tensile strength, pH, buffer capacity, wettability and the adhesive penetration. In addition to this, a prototype bamboo parallel strip lumber (BPSL) was manufactured and tested for its physical and mechanical properties. The relationships among the properties of Calcutta bamboo and the prototype bamboo composite were also investigated. As the result of these investigations, it is concluded that Calcutta bamboo is technically a suitable raw material for structural composite products. This result may also be applicable for the utilization of other bamboo species, thus aiding companies in decisions regarding investment in bamboo plantations and manufacturing facilities in the U.S, Malaysia and other parts of the world. The primary benefits from this research may be the development of new products to serve growing markets, and thereby relieving some of the pressure to harvest forestlands. / Ph. D.

Water-based resol phenol formaldehyde, PF, and organic polymeric methylenebis(phenylisocyanate), pMDI, are the two primary choices for the manufacture of exterior grade wood-based composites. This work addresses simple physical blends of pMDI dispersed in PF as a possible hybrid wood adhesive. Part one of this study examined the morphology of hybrid blends prepared using commercially available PF and pMDI. It was found that the blend components rapidly reacted such that the dispersed pMDI droplets became encased in a polymeric membrane. The phase separation created during liquid/liquid blending appeared to have been preserved in the cured, solid-state. However, substantial interdiffusion and copolymerization between blend components also appeared to have occurred according to measured cure rates, dynamic mechanical analysis, and atomic force microscopy. In the second part of this study a series of PF resins was synthesized employing the so-called "split-cook" method, and by using a range of formaldehyde/phenol and NaOH/phenol mole ratios. These neat PF resins were subjected to the following analyses: 1) steady-state flow viscometry, 2) free formaldehyde titration, 3) non-volatile solids determination, 4) size exclusion chromatography, 5) quantitative solution-state ¹³C nuclear magnetic resonance, NMR, 6) differential scanning calorimetry, 7) parallel-plate oscillatory cure rheology, and 8) dielectric spectroscopy. The neat PF analytical results were unremarkable with one exception; NMR revealed that the formaldehyde/phenol mole ratio in one resin substantially differed from the target mole ratio. The neat PF resins were subsequently used to prepare of series of PF/pMDI blends in a ratio of 75 parts PF solids to 25 parts pMDI solids. The resulting PF/pMDI blends were subjected to the following analyses: 1) differential scanning calorimetry, 2) parallel-plate oscillatory cure rheology, and 3) dielectric spectroscopy. Similar to what was inferred in part one of this study, both differential scanning calorimetry (DSC) and oscillation cure rheology demonstrated that cure of the PF continuous phase was substantially altered and accelerated by pMDI. However within actual wood bondlines, dielectric analysis detected little variation in cure speed between any of the formulations, both hybrid and neat PF. Furthermore, the modulated DSC curing experiments detected some latent reactivity in the hybrid system, both during initial isothermal curing and subsequent thermal scanning. The latent reactivity may suggest that a significant diffusion barrier existed between blend components, preventing complete reaction of hybrid blends even after thermal scanning up to 200 °C. Part three of this work examined the bonded wood mode-I fracture performance of hybrid resins as a function of the resol formaldehyde/phenol ratio and also the alkali content. A moderate increase in unweathered fracture toughness was observed for hybrid formulations relative to neat PF. Following accelerated weathering, the durability of the hybrid blends was promising: weathered hybrid toughness was equivalent to that of weathered neat PF. While the resol F/P ratio and alkali content both influenced hybrid fracture toughness, statistical modeling revealed interaction between these variables that complicated result interpretation: the influence of hybrid alkali content depended heavily on each formulation's specific F/P ratio, and vice versa. / Master of Science

The purpose of this research was to determine the effects of cellulose nanocrystals (CNCs), as potential additives, on the properties and performance of phenol–formaldehyde (PF) adhesive resin. The steady-state viscosity of a commercial PF resol resin and three CNC–resin mixtures, containing 1–3 wt % CNCs, based on solids content, was measured with a rheometer as a function of shear rate. The viscosity of the PF resin itself was independent of shear rate. The viscosity–shear rate curves of the CNC–resin mixtures showed two regions, a shear thinning region at lower shear rates and a Newtonian region at higher shear rates. The low-shear-rate viscosity of the resin was greatly increased by the CNCs. The structure of the CNC–resin mixtures under quiescent conditions was analyzed by polarized light microscopy. The mixtures contained CNC aggregates, which could be disrupted by ultrasound treatment. The curing progressions of the resin and CNC–resin mixtures were analyzed by non-isothermal differential scanning calorimetry (DSC). The DSC curves showed two exotherms followed by an endotherm. The energy of activation for the first exotherm was reduced by the CNCs whereas the energy of activation for the second exotherm was not affected by the CNCs. Increasing CNC contents caused higher degrees of reaction conversion during the first curing stage and a greater loss of sample mass, attributed to formaldehyde release during resin cure. For analysis of the mechanical properties during and after cure, sandwich-type test specimens were prepared from southern yellow pine strips and the resin and CNC–resin mixtures. The mechanical properties of the test specimens were measured as a function of time and temperature by dynamic mechanical analysis (DMA). The time to incipient storage modulus increase decreased and the rate of relative storage modulus increase increased with increasing CNC content. The ultimate sample stiffness increased with increasing CNC content for CNC contents between 0 and 2 wt %, which was attributed to mechanical reinforcement of the resin by the CNCs. At a CNC content of 3 wt %, the ultimate sample stiffness was lower than at a CNC content of 2 wt % and the second tan δ maximum occurred earlier in the experiment, indicating an earlier onset of vitrification. The lower ultimate sample stiffness was attributed to premature quenching of the curing reactions through CNC-induced depression of the vitrification point. For analysis of the fracture performance, double cantilever beam test specimens were prepared from southern yellow pine beams and the resin and CNC–resin mixtures, using different hot-pressing times. Fracture energies were measured by mode I cleavage tests. Bondline characteristics were analyzed by light microscopy. At a hot-pressing time of 10 min, the fracture energy decreased with increasing CNC content, whereas it stayed constant for CNC contents between 1 and 3 wt % at a hot-pressing time of 8 min. The bondlines of resin mixtures containing CNCs exhibited voids, whereas those of the pure resin did not. CNCs had both benefitial and detrimental effects on the properties and performace of PF resin. / Master of Science

Diploma's thesis describes resolution of cause technological problems in mineral wool manufacturig in company Saint-Gobain Orsil. Main attention is paid to thermal and volatile process in mineral wool from filtration chamber and common commercial sales. Samples of mineral wool were characterizated by thermal analysis (simultaneous TG-DTA), effluent gas analysis (EGA), infrared spectroscopy (FT-IR), electron microscopy (SEM) and X-ray diffraction (XRD). Thermal analysis experiments was used to check thermal volatile processes. Technological problem of burning is linked with rise of isocyanic acid.

The aim of this study was to investigate rubber toughening of resol type phenol-formaldehyde resin. For this purpose, phenolic resin was first modified by only acrylonitrile butadiene rubber, and then by using nitrile rubber together with 3-aminopropyltriethoxysilane. Test specimens were prepared by mixing and casting of liquid phenolic resin in three groups. In the first one, neat phenolic resin specimens were produced. In the second group, phenolic resin was modified with 0.5, 1, 2, and 3 wt.% nitrile rubber, while in the last group modification was carried out by using 0.5 wt.% nitrile rubber together with 1, 2, and 4wt.% amino silane (with respect to nitrile rubber). All specimens were heat cured in the oven. In order to observe behaviors of the specimens, Three-Point Bending, Charpy Impact, Plane-Strain Fracture Toughness, and Dynamic Mechanical Analysis tests were conducted according to the related ISO standards for all specimens groups. Scanning Electron Microscopy was also used for the fractographic analysis of some samples. It can be concluded that, although there were problems in mixing and casting of liquid resol type phenolic resin, its toughness could be improved by using nitrile rubber and amino silane. Modification by using nitrile rubber and amino silane together was much more effective than by using only nitrile rubber. In this synergistic case for instance, Charpy impact strength and fracture toughness values of the neat phenolic specimens were increased 63% and 50%, respectively. SEM studies indicated that the main rubber toughening mechanism was shear yielding observed as deformation lines especially initiated at the domains of nitrile rubber and amino silane.