Hydrolysis and adsorption-desorption reaction of pyrophosphate (PP) and orthophosphate (OP) were studied in two Quebec soils (St. Bernard and Dalhousie) and three minerals (goethite, kaolinite, and montmorillonite). Soil and soil mineral samples were fractionated by size into two separates. / Soil and goethite samples adsorbed more OP than PP whereas kaolinite and montmorillonite adsorbed similar amounts of OP and PP. Pyrophosphate and orthophosphate adsorption was found to be related significantly to extractable Fe. Furthermore, kaolinite and montmorillonite desorbed similar amounts of OP and PP whereas more OP than PP was desorbed from soil and goethite samples. Moreover, adsorption of OP and PP was found to be mainly chemical adsorption. Smaller particle size induced higher P adsorption and desorption from both P sources compared with the coarse particle size. / Goethite samples had slower rates of hydrolysis compared to soil and clay mineral samples. Furthermore, kalolinite and montmorillonite did not increase the rate of PP hydrolysis even with reduced adsorption of PP compared to soil and goethite samples. Chemical hydrolysis was found to be a significant portion of the total hydrolysis. Smaller particle size and high PP adsorption induced smaller PP hydrolysis than with coarse particles. Moreover, added OP reduced the amount of PP remaining nonhydrolyzed. First-order rates of PP hydrolysis were faster in nonautoclaved than autoclaved samples. Rate of PP hydrolysis increased with increased temperature and the effect of temperature was more obvious in the autoclaved than nonautoclaved samples.

Typescript. / Thesis (Ph. D.)--University of Hawaii at Manoa, 1974. / Bibliography: leaves 191-204. / xvii, 204 leaves ill

Thesis (M.S.)--Auburn University, 2007. / Abstract. Includes bibliographic references (ℓ. 54-62)

Thesis (Ph.D.) -- University of Western Sydney, 2003. / Includes bibliography.

Thesis (Ph.D.)--Murdoch University, 2009. / Thesis submitted to the Faculty of Sustainability, Environmental and Life Sciences. Includes bibliographical references (leaves 201-242)

Thesis (M.Sc.(Agric.))(Horticulture)--University of Pretoria, 2006. / Includes summary. Includes bibliographical references. Available on the Internet via the World Wide Web.

Made available in DSpace on 2014-06-11T19:32:21Z (GMT). No. of bitstreams: 0 Previous issue date: 2004-03-08Bitstream added on 2014-06-13T18:43:40Z : No. of bitstreams: 1 conceicao_ft_dr_rcla.pdf: 3191625 bytes, checksum: acbc3e9009e76a6712eb2befd4d5dc95 (MD5) / Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP) / Este trabalho visou estudar o comportamento geoquímico de radionuclídeos e metais pesados em solos de uso agrícola na bacia do Rio Corumbataí (SP). A concentração e variabilidade natural em rochas sedimentares na bacia do Rio Corumbataí segue a tendência Ca > Mg > K > Na, com baixa concentração natural de metais pesados e radionuclídeos. A distribuição das taxas de dose nos solos mostra que ocorre uma maior taxa de exposição na região sul da bacia do Rio Corumbataí, onde há aplicação de fertilizantes fosfatados, corretivos agrícolas e vinhaça em plantações de cana-de-açúcar. Metais pesados e radionuclídeos existentes nos fertilizantes fosfatados e corretivos agrícolas são adicionados anualmente nas plantações de cana-de-açúcar, mas se usados de acordo com as taxas recomendadas, não aumentam suas concentrações em solos para níveis perigosos. Assim, há baixa transferência destes elementos dos solos para a cana-de-açúcar na bacia do Rio Corumbataí, não oferecem nenhum risco ao ecossistema e à saúde do animal e do homem. Palavras-chave: Radionuclídeos e metais pesados, Solos e fertilizantes, Plantações de canade- açúcar, Cadeia alimentar. / The purpose of this research was to study the geochemical behavior of radionuclides and heavy metals in soils of agricultural use at Corumbataí River basin (SP). The natural concentration and variability in sedimentary rocks at Corumbataí river basin follow the trend Ca > Mg > K > Na, with the concentration of heavy metals and radionuclides. The distribution of exposure rate in soils shows the occurrence of higher values towards south of the Corumbataí river basin, region where are applied phosphate fertilizers, amendments and vinhaça in sugar cane crops. Heavy metals and radionuclides incorporated in phosphate fertilizers and amendments are annually added during the fertilization process in the sugar cane crops, but if they are utilized in accordance with the recommended rate, they do not rise the concentration levels in soils up to hazards levels. Thus, they are lower transferred from soils to sugar cane at Corumbataí river basin, not offering hazard to the ecosystem and animal or human health.

Please read the abstract in the section 00front of this document / Dissertation (MSc (Soil Science))--University of Pretoria, 2007. / Plant Production and Soil Science / MSc / unrestricted

Vermicomposting is an eco-friendly waste management strategy. Its successful performance necessitate that key functioning parameters like earthworm stocking density, nutrient enrichment be established for each target waste/waste mixture. One main target waste mixture in South Africa, and in the University of Fort Hare in particular is waste paper mixed with cow dung and rock phosphate (RP) for phosphorus (P) enrichment. This study was carried out to address the following specific objectives, to determine (i) the effect of Eisenia fetida stocking density on the bioconversion of cow dung waste paper mixtures enriched with rock phosphate, (ii) an optimum application rate of low grade South African Rock Phosphate and time required for efficient vermicomposting of cow dung-waste paper mixtures, and (iii) to determine if the phosphorus in RP is responsible for improved biodegradation during the vermicomposting of cow dung-waste paper mixtures. Results of this study revealed that bioconversion of cow dung waste paper mixtures enriched with RP was highly dependent on E. fetida stocking density and time. The stocking density of 12.5 g-worms kg-1 feedstock of the mixtures resulted in highest earthworm growth rate and humification of the waste mixture as reflected by a C: N ratio of < 12, polymerization index (PI) or humic acid/fulvic acid ratio of > 1.9, and a humification index of >13 for the cow dung waste paper mixtures. A germination test carried out also revealed that the resultant vermicompost had no inhibitory effect on the germination of tomato, carrot, and radish. Extractable P increased with stocking density up to 22.5 g-worm kg-1 feedstock, suggesting that for maximum P release from RP enriched wastes, a high stocking density should be considered. Informed by an earlier study which demonstrated that RP improved vermidegration, a follow up study was done to determine the optimum amount of rock phosphate necessary for efficient vermidegradation of cow dung waste paper mixtures while ensuring a phosphorus rich vermicompost. The results showed that addition of RP at rates ≤ 1% P as RP efficiently enhanced the bioconversion of cow dung waste paper mixtures as reflected by low C: N ratio, high polymerization index (PI), HI and HR used as maturity indicators for matured compost. Final vermicompost products obtained at minimum amounts of RP application rates resulted highly humified vermicompost with finer morphological structure, with no inhibitory effect on the germination of tomato, carrot, and radish similar to the ones obtained at higher RP rates. The findings suggest that 1%P as RP application rate is optimum for efficient vermidegradation of cow dung waste paper mixtures. Since P or Ca happen to be the most prevalent elements in most rock phosphate used for compost enrichment, a study was carried out to determine if P or Ca in RP is predominantly responsible for the improved biodegradation of cow-dung waste paper mixture observed during vermicomposting. Phosphorus sources in form of triple superphosphate (TSP), phosphoric acid (PHA) and Ca in form of calcium chloride (CaCl2) salt were compared with rock phosphate. The results from the study indicated that TSP, a water soluble P source, resulted in greater and faster degradation of the waste mixtures than RP while the Ca source had the least effect. With TSP incorporation the compost maturity C: N ratio of 12 was reached within 28 days while RP, PHA and CaCl2 needed 42, 56 and more than 56 days, respectively. The results indicated that P was largely responsible for the enhanced bioconversion of the waste mixtures. This appeared linked to the effect of P to stimulate microbial growth as reflected by higher microbial biomass carbon levels where water soluble P sources were applied. The C: N ratios of the final vermicomposts at day 56 were 10, 11.5, 13, 14, and 23 for TSP, RP,PHA, Control (No P added) and CaCl2 treatments, respectively. Although TSP gave superior superior performance, RP may still be the preferred additive in the vermicomposting of cow dung waste paper mixtures as it is cheaper and produces mature compost in a shorter period of 8 weeks. Generally, the results of this study have shown that the vemidegradation of cow dung waste paper mixtures can be optimized through adoption of an E. fetida stocking density of 12.5g- worm kg-1 and an RP incorporation rate of 1% P as RP. However, higher rates of RPincorporation may be adopted where final vermicomposts with higher P fertilizer value are desired. Phosphorus appears to be the RP constituent responsible for its ability to enhance the vermidegradation of cow dung waste paper mixtures. Future studies should explore the effectiveness of other P-bearing minerals for their effectiveness in enhancing vemidegradation.

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