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To improve photovoltaic system efficiencies, concentrating spectral dividers are used to separate solar light, and to focus each spectral portion onto photovoltaic cells of matching spectral response. In this investigation, an optical analysis is developed to study the feasibility for use of a Fresnel half-lens as a concentrating spectral divider. To facilitate the analysis, an existing curved-base linear Fresnel lens ray-trace model has been modified and expanded. Solar limb-darkening has been incorporated into the theory by means of a digitized sun model. The lens model allows for variation of lens geometrical characteristics. Transmission losses due to Fresnel reflection and bulk absorption are taken into account. The distribution of the concentrated solar flux in the lens image plane is modeled such that spectral regions may be examined separately. Concentration ratio profiles are used to derive and evaluate a quantity of spectral separation.A computer program has been used to generate data, based on the theoretical model, for example lenses. The spectral separation, transmission and concentration properties for each example lens have been systematically studied with respect to lens geometry. The effects of solar limb-darkening are determined by comparison with the data from a model that assumes a uniform solar source. Results of the study are discussed in detail.Ball State UniversityMuncie, IN 47306

Master's thesis. / Format: PDF. Bibl.

Three synthetic methods have been explored for the preparation of several novel boron-substituted amidinates and guanidinates. The extension of heterocumulene insertion chemistries to boron-aryl, boron-metallocene and boron-transition metal moieties has also been achieved and the mechanism of such insertions is addressed via density functional theory modeling techniques. The reactivity of these complexes is also explored, mainly through halide abstraction methodologies to generate boron cations, which are potent Lewis Acids and may be useful in promoting organic transformations or in the polymerization of ethylene. The synthesis and characterization of the elusive monomeric low valent carbenoid boron(I), a compound with a formal lone pair located upon the boron center, has been lacking. The suitability of the guanidinate ligand system to support such a species is also discussed and a combined experimental and theoretical approach to this highly topical problem is also presented. Thirdly, the use of photovoltaics (devices which convert solar energy directly into electricity) as an alternative source of energy outwith fossil fuel technologies is a rapidly growing area of interest. Initial efforts to use a novel approach, which incorporates inorganic nanocrystals wired into a conducting polymer matrix, are also presented. Successful synthetic approaches to the gallium, aluminum and indium monomeric precursors suitable for electropolymerization were developed. These compounds proved to be effective starting points for the generation of conducting polymers with embedded III/VI (Ga₂S₃) nanocrystals with further studies currently underway as to their III/V (InP, GaAs) compatriots. Finally, a retrospective of projects that may best be described in terms of the moniker "Loose Ends and Future Directions" will be presented. The aim of which will be to serve as a useful guidepost for further studies in the fields and topics discussed. / text

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