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Hydrogeochemical studies are generally qualitative in nature. The goal of this study is to investigate the possibility of quantitative interpretation of hydrogeochemistry by considering the chemical characteristics and the isotopic compositions of oxygen, hydrogen, and carbon of the water. This study examines ephemeral stream and well waters from Canada del Oro valley, southern Arizona. By chemical and isotopic considerations, this study finds that the change of chemical composition of the wash water was mainly due to water-rock interaction. The concentrations of dissolved constituents increase between 10 to 50% from upstream to downstream samples, while the evaporation loss of water is less than 3%. By chemical and isotopic considerations of the well waters, this study identifies three recharge waters in the CDO ground-water system. The chemical and water isotopic compositions of the well waters are results of mixing between these three recharge waters and subsequent dissolution of the aquifer. By thermodynamic consideration, albite, kaolinite, montmorillonite, and calcite are the main phases that influence the chemical characteristics of this ground-water system. Simulations with the computer program PHREEQE verifies the above conclusions. The mechanisms that influence the chemical and carbon isotopic compositions of the water are quite different in a system open to a CO2 gas reservoir than in a closed system. Deines, Langmuir, and Harmon (1974) derived a set of chemical-isotopic equations to calculate the carbon isotopic composition of water under open system condition. Wigley, Plummer, and Pearson (1978) formulated a mass transfer equation to calculate the change of carbon isotopic composition of natural water in closed system environment. This study implements these two type of equations as a subroutine--CSOTOP to the computer program PHREEQE. With this PHREEQE-CSOTOP package, the evolution of carbon chemical and isotopic composition of natural water can be conveniently modeled from open to closed system conditions. This study also uses this package to date water samples from the Tucson basin, and finds that choice of reaction path may cause a difference in carbon-14 age of up to a few thousand years. This study concludes that it is possible to rigorously interpret hydrogeochemistry in a quantitative way. With sufficient measurements to define the reaction path, followed by thermodynamic consideration, chemical-isotopic evaluation, and computer modeling, one should be able to achieve this goal.

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The Mountain Pima of the Sierra Madre Occidental of Chihuahua, Mexico, utilize a variety of domesticated and nondomesticated resources. Part of their agricultural system consists of shifting, or swidden, cultivation on steep hillsides. Wild edible plants contribute significant amounts of vitamins and minerals to the diet on a seasonal basis. The drought of 1988 caused a decrease in the availability of many resources, but an increase in availability of roots of saraviqui (Prionosciadium townsendii). A dynamic, nonlinear optimization study of Mountain Pima diet included requirements for adequate amounts of energy, protein, calcium, and vitamins A and C. Oxalate content of several plant foods and seasonal variation in resource availability were incorporated into the study. Two methods were compared: time minimization and a nutrient indexing method minimizing the product of the absolute value of the natural logarithm of the ratio of recommended intake to actual intake rates. This method allowed simultaneous optimization of several different parameters. The nutrient indexing model matched the actual diet of the Mountain Pima somewhat better than the traditional energy minimization model. It predicted higher use of noncultivated plant species and of animal resources than the time minimization model. Analyses were conducted for years of adequate rainfall and for the drought year. A list of 612 plant species collected in the community of Nabogame is also included.

The northeastern Rincon Mountains record a superposed history of low-angle normal-slip shear strain. Moderate- to low-angle faults, mapped previously as Laramide thrust faults, are recognized as normal faults of Tertiary age. Two faults are predominant: a younger-overolder ductile fault forms the base of a metasedimentary carapace, a ductile shear zone (decollement zone) of southwest vergent slip, and an older-over-younger (locally younger-over-older) fault named herein as the San Pedro basal detachment fault forms a brittle shear surface of west-southwest slip. The decollement zone is characterized by passive-slip folding, flexural-flow folding, boudinage, stretched pebbles, and low-angle ductile normal faults. Structural analysis reveals southwest- ergent simple shear strain with a component of superimposed pure shear strain (vertical flattening). The San Pedro basal etachment fault underlies a faulted, distended allochthon. The internal structure of the allochthon is characterized by an imbricate shingling of tilted fault blocks against west-dipping normal faults, suggesting emplacement from the east by an extensional and/or gravitional mechanism. Detachment faulting involved Late Oligocene sedimentary rocks yet cuts ∼26 m.y. old dikes. Mid-Miocene (?) faults form north-trending fault blocks which have rotated rocks of the metamorphic basement and the allochthon eastward. High-angle normal faults of the Basin and Range disturbance form an eastern fault margin across which the northeastern Rincon Mountains have been uplifted. The deformation recorded in the northeastern Rincon Mountains is interpreted to reflect mid-Tertiary crustal extension. Early structural elements define a ductile shear zone which is either truncated or overprinted by a subsequently thinner zone of brittle shear. The shear zone descends stratigraphically westward across the Rincon Mountains. Reconstructions of its mid-Tertiary configuration show the shear zone to be a surface of normal-slip. Displacement near the surface is by brittle shear, but is progressively replaced by ductile shear down-dip. Evolution of the surface superimposes the region of brittle shear against the region of ductile shear. Late Cenozoic block faulting has segmented, tilted, and exhumed the surface.

The main rock unit exposed in the southern part of the Tucson Mountains, Pima County, Arizona, is the Cat Mountain rhyolite. It forms the eastward dipping slope and the western escarpment of the mountain range, capping the large fault blocks which make up the range. Petrographic and radiometric data combine to show that the Cat Mountain rhyolite, as originally defined, consists of two major ash flow eruption sequences. The lower sequence is less uniform and continuous than the highly welded characteristically jointed upper unit. A basal non welded unit is found along the western escarpment, a partly welded transition zone is found between the welded units, and a capping partly-to-non-welded unit is exposed in protected parts of the eastern slope. The volcanic history of the area began with the emplacement of a nuee ardente deposit forming the “chaos” unit. This was followed by two ash flow pulses through the same vents, and the sequence was terminated by the intrusion of spherulitic rhyolite sealing up the vents.

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