[pt] Neste trabalho desenvolveu-se um material nacional constituido de misturas de resinas poliéster CRYSTIC rígida e flexível, para ser utilizado em Fotoplasticidade. Foi feito um estudo completo sobre o método de fundição e sobre o comportamento mecânico e ótico. Através de ensaios uniaxiais de tração e compressão, compressão diametral de discos e flexão pura de barras,estudou-se as influências da composição do material (teor de resina flexível na mistura) e de parâmetros de ensaio nos comportamentos mecânico e ótico, durante ciclos de carregamento e descarregamento e após descarregamento. A Técnica Fotoplástica Tridimensional, que analisa fatias de modelos descarregados, e que procura simular problemas de Conformação Mecânica de metais, foi aplicada à compressão plana de barras. Com o objetivo de se comparar resultados, realizou-se o mesmo ensaio em barras de alumínio e empregou-se, para o mesmo exemplo, um programa não linear de elementos finitos (NONSAP), baseado nos critérios de Von Mises, Tresca e Drucker-Prager. Esta comparação de resultados permitiu concluir que a Técnica Fotoplástica, utilizando as misturas de resinas poliéster CRYSTIC, é eficiente na determinação de deslocamentos e deformações plásticas em problemas de forjamento. / [en] This thesis presents the development of a material composed of mixtures of flexible and rigid polyester resins for use in Photoplasticity. Its casting precedure and mechanical and optical behavior were fully studied. The influences of mixture composition, testing temperature and loading and unloading rates on the mechanical and optical material behavior were analysed based on tensile and compressive uniaxial testing data and also through the pure bending of bars and the diametral compression of discs. For this, specimens were observed under loading and unloading and after being unloaded. The Three-dimensional Photoplastic Technique which analyses slices of unloaded but deformed models to simulate Metal Forming problems was applied to the plane compression-of bars. This same problem was studied via a non linear finite element program (NONSAP) which employed the von Mises, Tresca and Drucker-Prager yieldind criterion and also experimentally via the plane compression of aluminun bars with the purpose of comparing results. It may be conclused from these comparisons that the Photoplastic technique employing mixtures of CRYSTIC polyester resins is suitable for determining plastic displacement and plastic strains in forging problems.

Solvent-borne thermally cured coil-coating resins contain large amounts of volatile organic solvents in order to obtain suitable flow for film application. This work describes how the expensive and environmental hazardous volatile organic solvent content of a solvent-borne thermally cured polyester/melamine coil-coating system can be reduced by introduction of fatty acid methyl esters (FAMEs) as reactive diluents and modification of the polyester binder resin. The evaluated reactive diluents, two rape seed methyl esters (RMEs), two linseed oil methyl esters (LMEs), and a tall oil methyl ester (TOME) have been evaluated both in a fully formulated clear-coat system and via model studies. Viscosity measurements of wet paint mixtures showed that formulations with hyperbranched polyester binder hold lower viscosity than conventional polyester binder resins and that FAME works as a diluent. Fully formulated clear-coats were cured under simulated industrial coil-coating cure conditions and in a convection oven at lower temperatures respectively. FAME increases the mobility of the system enhancing the film formation process. Free-standing clear-coat films were analyzed with Raman, carbon-14 dating, extraction, dynamic mechanical analysis, and visual observation. Incorporation of FAME could not be confirmed by Raman analysis. However, carbon-14 dating indicated the presence of FAME that could not be extracted from the films. The mechanical properties of the films were also affected by the addition of FAMEs, oven temperature, choice of co-solvent, and flash-off period. Conventional film characterization tests on substrate supported coatings indicated that binder resin structure and cure conditions affect the final film properties. Model studies were performed to clarify how FAME can chemically react through transesterification with the hydroxyl-groups of the polyester. The transesterification reaction between different FAMEs and primary alcohols with and without tertiary hydrogen was monitored with 1H-NMR and real time IR. Evaporation and side reactions, e.g. alkene reactions, are competing factors to the transesterification reaction. The study showed that fatty acid structure, reaction time, and temperature affect the transesterification conversion, degree of side reactions, and choice of catalyst. A pigmented fully formulated polyester/melamine formulation with a reactive diluent was cured at full scale in an industrial coil-coating production facility. Evaluation of the final film properties showed that the coating fulfills the specification of conventional polyester/melamine coil-coating systems. / QC 20100817

Made available in DSpace on 2014-12-17T14:58:15Z (GMT). No. of bitstreams: 1 JoseHBL_DISSERT_PARCIAL.pdf: 2505963 bytes, checksum: 1b82ec8a8147b2b7e13d0af6880855f0 (MD5) Previous issue date: 2012-05-02 / Conselho Nacional de Desenvolvimento Cient?fico e Tecnol?gico / Materials denominated technical textiles can be defined as structures designed and developed with function to fulfill specific functional requirements of various industrial sectors as are the cases of the automotive and aerospace industries. In this aspect the technical textiles are distinguished from conventional textile materials, in which the aesthetic and of comfort needs are of primordial importance. Based on these considerations, the subject of this dissertation was established having as its main focus the study of development of textile structures from aramid and glass fibers and acting in order to develop the manufacture of composite materials that combine properties of two different structures, manufactured in an identical operation, where each structure contributes to improving the properties of the resulting composite material. Therefore were created in laboratory scale, textile structures with low weight and different composition: aramid (100%), glass (100%) and aramid /glass (65/35%), in order to use them as a reinforcing element in composite materials with polyester matrix. These composites were tested in tension and its fracture surface, evaluated by MEV. Based on the analysis of mechanical properties of the developed composites, the efficiency of the structures prepared as reinforcing element were testified by reason of that the resistance values of the composites are far superior to the polyester matrix. It was also observed that hybridization in tissue structure was efficient, since the best results obtained were for hybrid composites, where strength to the rupture was similar to the steel 1020, reaching values on the order of 340 MPa / Os materiais denominados t?xteis t?cnicos podem ser definidos como estruturas projetadas e desenvolvidas com a fun??o de atender a requisitos funcionais espec?ficos de diversos setores da ind?stria, caso da ind?stria automotiva e aeroespacial. Nesse aspecto, distinguem-se dos materiais t?xteis convencionais, nos quais as necessidades est?ticas e de conforto t?m import?ncia primordial. Com base nessas considera??es, o tema dessa disserta??o foi estabelecido tendo como enfoque principal o estudo do desenvolvimento de estruturas t?xteis a partir de fibras de aramida e de vidro, atuando no sentido de elaborar a fabrica??o de materiais comp?sitos que combinem propriedades de duas estruturas diferentes, fabricadas em uma mesma opera??o, onde cada estrutura contribui para melhoria das propriedades do material comp?sito resultante. Para tanto foram desenvolvidas em escala laboratorial estruturas t?xteis de baixa gramatura e composi??o diferenciada de aramida (100%), vidro (100%) e aramida/vidro (65/35%) para utiliza??o como elemento refor?ante em comp?sitos com matriz de poli?ster. Os comp?sitos produzidos foram ensaiados em tra??o e sua superf?cie de fratura avaliada por MEV. Com base nas analises das propriedades mec?nicas dos comp?sitos desenvolvidos, observou-se a efici?ncia das estruturas ou elaboradas como elemento refor?ante tendo em vista que os valores de resist?ncia dos comp?sitos foram muito superiores ? matriz de poli?ster. Tamb?m foi observado que a hibridiza??o na estrutura dos tecidos foi eficiente, uma vez que os melhores resultados obtidos foram para os comp?sitos h?bridos, onde a resist?ncia na ruptura foi semelhante ? do a?o 1020, atingindo valores na ordem de 340 MPa