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This research was originally conceived under the auspices of the UK Government's Foresight Initiative, which aimed to translate the significant body of process tomography knowledge, residing in various British universities, towards applications of generic benefit to industry. In collaboration with the sponsoring life science company, Zeneca Ltd, a number of potential demonstrator projects were identified. Ultimately on-line imaging within pressure filtration was selected by virtue of its direct and broad benefit to the chemical sector and the opportunity to extrapolate the techniques developed towards other batch production processes. The research programme is centred around three empirical studies. These progress from an initial phase, where the early laboratory instrumentation was exposed to a constrained set of filtration conditions, through to the installation of a novel prototype industrial tomography system on to an existing large scale production unit, which was fabricated from an electrically conducting alloy and located in a potentially flammable atmosphere. During the course of these investigations electrical impedance tomography (EIT) was identified as the most viable modality for this class of application. The challenges associated with transferring the EIT technology into the manufacturing environment were addressed by taking advantage of the lenient frame rates acceptable within chemical batch monitoring to develop an instrument structure which was intrinsically safe, suitable for use with earthed metal vessels, tolerant to chemically aggressive media and amenable to three-dimensional image reconstruction via irregular, process compliant, electrode architectures. In the subject production filter a planar sensor array was exploited to provide a relatively uniform electrical field distribution within the process material, whilst not adversely affecting the normal operation of the plant item.

The underlying opportunity for this study is that process materials may show considerable change in their electrical properties in response to an injected signal over a wide frequency range. The use of this concept to demonstrate the construction of tomographic images for a range of frequency bands is described. These can then provide a deeper understanding and interpretation of a process under investigation. The thesis presents an in-depth review of the characteristics of the various wideband signals that could be used for simultaneous spectral measurements. This includes an objective selection process that demonstrates that a Chirp signal form offers key advantages. It then addresses the details of the developed method and algorithms for WElT systems that deploy a Chirp wideband excitation signal and a further aspect of the method, based on the time-frequency analysis, particularly wavelet transform, which is used to reveal spectral data sets. The method has been verified by simulation studies which are described. To provide measurements over a required frequency range a linear chirp is deployed as the excitation signal and corresponding peripheral measurements are synthesised using a 2D model. The measurements are then analysed using a wavelet transform algorithm to reveal spectral datasets which are exemplified in the thesis. The thesis then examines the feasibility of the presented method through various experimental trials; an overview of the implementation of the electronic system is included. This provides a single-channel EIT chirp excitation implementation, in essence simulating a real-time parallel data collection system. through the use of pseudo-static tests on foodstuff materials. The experimental data were then analysed and tomographic images reconstructed using the frequency banded data. These included results illustrate the promise of this composite approach in exploiting sensitivity to variations over a wide frequency range. They indicate that the described method can augment an EIT sensing procedure to support spectroscopic analysis of the process materials.

Neutral atom systems are an appealing platform for the development and testing of quantum control and measurement techniques. This dissertation presents experimental investigations of control and measurement tools using as a testbed the 16-dimensional hyperfine manifold associated with the electronic ground state of cesium atoms. On the control side, we present an experimental realization of a protocol to implement robust unitary transformations in the presence of static and dynamic perturbations. We also present an experimental realization of inhomogeneous quantum control. Specifically, we demonstrate our ability to perform two different unitary transformations on atoms that see different light shifts from an optical addressing field. On the measurement side, we present experimental realizations of quantum state and process tomography. The state tomography project encompasses a comprehensive evaluation of several measurement strategies and state estimation algorithms. Our experimental results show that in the presence of experimental imperfections, there is a clear tradeoff between accuracy, efficiency and robustness in the reconstruction. The process tomography project involves an experimental demonstration of efficient reconstruction by using a set of intelligent probe states. Experimental results show that we are able to reconstruct unitary maps in Hilbert spaces with dimension ranging from d=4 to d=16. To the best of our knowledge, this is the first time that a unitary process in d=16 is successfully reconstructed in the laboratory.

O principal objetivo deste trabalho é contribuir para o desenvolvimento de uma nova técnica de reconstrução numérica do problema de tomografia por impedância elétrica. A abordagem adotada baseia-se na minimização de um funcional de erro convenientemente definido, cujo ponto de mínimo global está relacionado com a imagem do escoamento sensoriado. Nesta formulação, o mau condicionamento se manifesta através de características topológicas dos funcionais de erro (patologia) que prejudicam o desempenho dos métodos de otimização na obtenção do mínimo. Esta abordagem tem vantagens significativas em relação às abordagens tradicionais, normalmente baseadas em hipóteses restritivas e pouco realistas como, por exemplo, considerar o campo de sensoriamento bidimensional e paralelo, além de independente do escoamento. Testes numéricos permitiram realizar estudos preliminares sobre as características topológicas do funcional de erro, necessários para a seleção de métodos de otimização passíveis de serem especializados para a solução do problema tratado neste trabalho. Nestes testes identificou-se a patologia característica do problema tratado: presença de uma região plana (inclinação virtualmente nula) circundando o mínimo global procurado. Dentre os diferentes métodos de otimização considerados, optou-se pelo desenvolvimento de uma estratégia baseada em algoritmos genéticos, devido às suas características serem melhor adaptáveis à patologia do problema em questão. O desempenho do método de otimização desenvolvido foi testado extensivamente em dois problemas básicos: a) posicionar corretamente uma inclusão de forma e contraste conhecidos e b) determinar os valores do contraste em uma sub-região do domínio de sensoriamento, no interior do qual sabe-se que existe uma inclusão. No primeiro caso, os resultados mostraram que, de fato, o algoritmo genético superou a patologia do problema e convergiu para a solução correta. No segundo caso, de dimensionalidade maior, a convergência em um tempo aceitável só pode ser alcançada com a introdução de informações à priori, seja na forma de restrições sobre o espaço de busca, seja na forma de penalidades aplicadas ao funcional de erro. / The main objective of this work is to contribute to the development of a new two-phase flow tomographic reconstruction method suited for electrical impedance tomography. The adopted approach consists in minimizing an error functional, defined so that is global minimum is related with the sensed flow image. In this formulation, the ill conditioning appears through topological features of the error functionals (pathologies) which compromises the performance of the optimization algorithms employed to determine the minimum. This approach has several important advantages over the classical ones, generally based on restrictive and unrealistic hypothesis such as the sensing field being two-dimensional, parallel and independent of the flow. Numerical simulations permitted to conduct preliminary studies about the topological features of the error functional, necessary to select possible optimization methods to be specialized to reach the solution of the problem treated in this work. The characteristic pathology of the problem was identified in these tests: the presence of a flat region (virtually null inclination) around the sought global minimum. Among the different considered methods, genetic algorithms were adopted because of their characteristics of being best adaptive to the pathologies of the current problem. The performance of the developed optimization method was tested through extensive numerical tests in two basic problems: a) to correctly place aninclusion with known shape and contrast and b) to determine the values of the contrast inside a sub-region of the sensed domain, which is known that contains the inclusion. In the first case, results show that the genetic algorithm overcame the pathologies of the problem and converged to the correct solution. In the second case, with higher dimensionality, convergence was achieved in an acceptable time only after the introduction of a priori information, either in the form of restrictions on the search space or in the form of penalties applied to the error functional.

O principal objetivo deste trabalho é contribuir para o desenvolvimento de uma nova técnica de reconstrução numérica do problema de tomografia por impedância elétrica. A abordagem adotada baseia-se na minimização de um funcional de erro convenientemente definido, cujo ponto de mínimo global está relacionado com a imagem do escoamento sensoriado. Nesta formulação, o mau condicionamento se manifesta através de características topológicas dos funcionais de erro (patologia) que prejudicam o desempenho dos métodos de otimização na obtenção do mínimo. Esta abordagem tem vantagens significativas em relação às abordagens tradicionais, normalmente baseadas em hipóteses restritivas e pouco realistas como, por exemplo, considerar o campo de sensoriamento bidimensional e paralelo, além de independente do escoamento. Testes numéricos permitiram realizar estudos preliminares sobre as características topológicas do funcional de erro, necessários para a seleção de métodos de otimização passíveis de serem especializados para a solução do problema tratado neste trabalho. Nestes testes identificou-se a patologia característica do problema tratado: presença de uma região plana (inclinação virtualmente nula) circundando o mínimo global procurado. Dentre os diferentes métodos de otimização considerados, optou-se pelo desenvolvimento de uma estratégia baseada em algoritmos genéticos, devido às suas características serem melhor adaptáveis à patologia do problema em questão. O desempenho do método de otimização desenvolvido foi testado extensivamente em dois problemas básicos: a) posicionar corretamente uma inclusão de forma e contraste conhecidos e b) determinar os valores do contraste em uma sub-região do domínio de sensoriamento, no interior do qual sabe-se que existe uma inclusão. No primeiro caso, os resultados mostraram que, de fato, o algoritmo genético superou a patologia do problema e convergiu para a solução correta. No segundo caso, de dimensionalidade maior, a convergência em um tempo aceitável só pode ser alcançada com a introdução de informações à priori, seja na forma de restrições sobre o espaço de busca, seja na forma de penalidades aplicadas ao funcional de erro. / The main objective of this work is to contribute to the development of a new two-phase flow tomographic reconstruction method suited for electrical impedance tomography. The adopted approach consists in minimizing an error functional, defined so that is global minimum is related with the sensed flow image. In this formulation, the ill conditioning appears through topological features of the error functionals (pathologies) which compromises the performance of the optimization algorithms employed to determine the minimum. This approach has several important advantages over the classical ones, generally based on restrictive and unrealistic hypothesis such as the sensing field being two-dimensional, parallel and independent of the flow. Numerical simulations permitted to conduct preliminary studies about the topological features of the error functional, necessary to select possible optimization methods to be specialized to reach the solution of the problem treated in this work. The characteristic pathology of the problem was identified in these tests: the presence of a flat region (virtually null inclination) around the sought global minimum. Among the different considered methods, genetic algorithms were adopted because of their characteristics of being best adaptive to the pathologies of the current problem. The performance of the developed optimization method was tested through extensive numerical tests in two basic problems: a) to correctly place aninclusion with known shape and contrast and b) to determine the values of the contrast inside a sub-region of the sensed domain, which is known that contains the inclusion. In the first case, results show that the genetic algorithm overcame the pathologies of the problem and converged to the correct solution. In the second case, with higher dimensionality, convergence was achieved in an acceptable time only after the introduction of a priori information, either in the form of restrictions on the search space or in the form of penalties applied to the error functional.

Quantum memories are key components in photonics-based quantum information processing networks. Their ability to store and retrieve information on demand makes repeat-until-success strategies scalable. Warm alkali-metal vapours are interesting candidates for the implementation of such memories, thanks to their very long storage times as well as their experimental simplicity and versatility. Operation with the Raman memory protocol enables high time-bandwidth products, which denote the number of possible storage trials within the memory lifetime. Since large time-bandwidth products enable multiple synchronisation trials of probabilistically operating quantum gates via memory-based temporal multiplexing, the Raman memory is a promising tool for such tasks. Particularly, the broad spectral bandwidth allows for direct and technologically simple interfacing with other photonic primitives, such as heralded single photon sources. Here, this kind of light-matter interface is implemented using a warm caesium vapour Raman memory. Firstly, we study the storage of polarisation-encoded quantum information, a common standard in quantum information processing. High quality polarisation preservation for bright coherent state input signals can be achieved, when operating the Raman memory in a dual-rail configuration inside a polarisation interferometer. Secondly, heralded single photons are stored in the memory. To this end, the memory is operated on-demand by feed-forward of source heralding events, which constitutes a key technological capability for applications in temporal multiplexing. Prior to storage, single photons are produced in a waveguide-based spontaneous parametric down conversion source, whose bespoke design spectrally tailors the heralded photons to the memory acceptance bandwidth. The faithful retrieval of stored single photons is found to be currently limited by noise in the memory, with a signal-to-noise ratio of approximately 0.3 in the memory output. Nevertheless, a clear influence of the quantum nature of an input photon is observed in the retrieved light by measuring the read-out signal's photon statistics via the g⁽²⁾-autocorrelation function. Here, we find a drop in g⁽²⁾ by more than three standard deviations, from g⁽²⁾ ~ 1.69 to g⁽²⁾ ~ 1.59 upon changing the input signal from coherent states to heralded single photons. Finally, the memory noise processes and their scalings with the experimental parameters are examined in detail. Four-wave-mixing noise is determined as the sole important noise source for the Raman memory. These experimental results and their theoretical description point towards practical solutions for noise-free operation.

No description available.