Vojtěch Stejskal - Diplomová práce 2014 - Přírodovědecká fakulta UK v Praze 4 ABSTRACT The thesis describes pilot applications of combined method - combination of sodium lactate and nanoparticles of zero-valent iron and their synergic effect. Two applications of combined method are described onto two geologically different sites - in Rožmitál pod Třemšínem and Spolchemie in Ústí nad Labem. First site is contaminated by polychlorinated biphenyls; contamination is situated in hydraulically well conducted porous media formed by weathered granodiorite. Main contaminants of Spolchemie site are trichloroethylene and tetrachloroethylene, contamination is situated in geologically heterogenous quaternary terrace of Bílina river. Effects of combined method on two different sites were compared and recommendations and conclusions were done. Part of the thesis is research of scientific articles and literature on topics: polychlorinated biphenyls, chlorinated ethylenes, in situ chemical reduction by sodium lactate and nanoiron, natural conditions of both sites, history of sites. In the thesis are also processed and evaluated results of geophysical investigation, changes of groundwater level and results of groundwater monitoring in view of the application of combined method on both sites.

Chlorophyll fluorescence imaging is noninvasive technique often used in plant physiology, molecular biology and precision farming. Captured sequences of images record the dynamic of chlorophyll fluorescence emission which contain the information about spatial and time changes of photosynthetic activity of plant. The goal of this Ph.D. thesis is to contribute to the development of chlorophyll fluorescence imaging by application of advanced statistical techniques. Methods of statistical pattern recognition allow to identify images in the captured sequence that are reach for information about observed biotic stress and to find small subsets of fluorescence images suitable for following analysis. I utilized only methods for identification of small sets of images providing high performance with realistic time consumptions.

This mastes´s thesis deals with higher usage of boiler K5 in CHP plant ŽĎAS, a.s. in temporary season, when due to reduced consumption is overheating hot water return branch and there is need to change to another boiler. Main goal of thesis is reduce changes betwen boiler K5 and boiler K3 and increase usage of boiler K5 in temporary season by ekonomic profitablbe technical solution. At the beginning of thesis is described CHP plant ŽĎAS, a.s. and its equipment. Next are four methods of calculation increase year´s usage of boiler K5. And these are cooling hot water return branch using heat exchanger, condensation of part steam from back pressure, reduce minimal power of boiler K5 and usage with small condensing turbine. Thesis is finished with comparison of mentioned methods and experimental reduce of minimal power boiler K5.

This diploma thesis deals with reduction of metal artifacts in CT data with submicron resolution. The first part of this thesis briefly describes x-ray computed tomography followed by the description of artifacts of tomographic images and existing approaches of the reduction of metal artifacts. In the second part proposed methods of reduction of metal artifacts and their implementation in Matlab programming environment are described. Finally functionality of algorithms is tested on a newly created database and the results are compared, evaluated and discussed.

The aim of the thesis is to set a hydrology model based on existed methodology DesQ-MaxQ, which comes from "Designing flows from a very small catchments" established in 1989. The model is able to set a nearest meteorology station and his 24-hours rainfall depths for periods of repetition 2,5,10,20,50 and 100 years. Substitute rainfall depths are set by "reduction of 24-hours rainfall depths" methodology. According to hydraulic and hydrology conditions of catchment, duration of the critical rains for each period of repetition are set also peak flow rates and total runoffs from the catchment. Application can work in two modes - "one slope" and "two slopes". The second option also includes calculation of design duration for the model catchment and superposition of hydrograph. Application RainRunoff was develop in C# programming language with graphic user interface and option to exports hydrographs.

The scope of this dissertation work is a description of modern methods of reducing exhaust emission in diesel engines. The fundamental part is the application of these methods for diesel engines for off-road use that means for engines that are used in tractors and road machines. The mentioned evidence for the practical utility of the results of this dissertation thesis in practice and their verification on the actual engine are given in the conclusion.

This diploma thesis concerns in design and realization of assembling line of a 2/2 seat valve for commercial vehicles sector. Design is using Autodesk Inventor. Thesis describes phases and goals of project management – in this case management of technological/manufacturing transfer.

Digitální Fly-by-Wire systém je novým přístupem k řídícímu systému letadla, na jehož základě firma Honeywell - HTS CZ začala výzkumný projekt s názvem “Next Generation Distributed Fly-by-Wire System” a tato práce je jeho součástí. Řídící plochy letadla jsou řízeny dvěma nebo třemi elektrohydraulickými (či elektrickými) servy a každé servo je ovládáno nezávislou řídící jednotkou. Díky provozním tolerancím systému a drobným odchylkám vstupních dat v řídících jednotkách, dostává každé servo mírně odlišné povely a rozdíl v poloze serv vede k namáhání řídící plochy i k namáhání serv. Hlavním cílem této práce je navrhnout algoritmus, který bude eliminovat rozdíly mezi polohami jednotlivých serv, a tudíž sníží sílu, která namáhá řídící plochu, na přípustnou mez. Implementace řídícího systému letadla byla do detailu analyzována a algoritmus redukce síly na kontrolní ploše letadla byl navržen a implementován v prostředí Simulink. Iterační kriteriální ladící metoda byla vyvinuta a za účelem co nejlepšího nastavení algoritmu redukce síly. Práce také analyzuje vliv časových zpoždení na sběrnici na kvalitu algoritmu redukce síly.

Analysis of the regional energy supply, shows that suitable alternative may be a combination of primary energy sources with the municipal solid waste to energy plant. Starting from the fact that the regional thermal energy needs are characterized by smaller power demand, but relatively significant seasonal fluctuations in heat supply. These factors limit the processing performance of the considered waste to energy plant that could be included in the system of regional energy supply. The aim of the thesis was to propose adequate treatment capacity for regional waste to energy plant and explore alternative solutions in off-gas cleaning for exhaust gases generated during incineration of MSW. The balance sheets of two alternative solutions off gas cleaning are part of the thesis, both in terms of material and energy consumption. Presented evaluation of economic demands alternative arrangement of off gas cleaning includes operating costs and the impact on earnings from energy production.

This thesis presents results of the corrosion layers removal which could be found on the archaeological artefact surfaces. The low pressure low temperature plasma reduction was used for this purpose. Brass samples were chosen for this study. Two different ways have been used to form model corrosion layers. Several sets of corrosion layers were prepared in laboratory in two different corrosion atmospheres, namely ammonia atmosphere and atmosphere of hydrochloric acid. These samples were placed into desiccator. Small quantities of sand were added to some sets of samples so samples with sandy incrustation were prepared. The corrosion layers had been usually formed during four weeks. The second way, which was used to prepare model corrosion layer, was the natural corrosion in soil or compost. In this case, the corrosion layers had been formed approximately 2 years. The samples were treated in the low pressure (150 Pa) cylindrical Quartz reactor (90 cm long and 9.5 cm in diameter) with a pair of external copper electrodes connected via the matching network to a radiofrequency generator (13.56 MHz). The flows of working gases were set by independent mass flow controllers. Whole system was continuously pumped by the rotary oil pump which was separated from the discharge reactor by liquid nitrogen trap with aluminium chips eliminating dust and reactive species from the gas flow. Each sample was placed on a glass holder at the reactor center. Plasma was generated in pure hydrogen or in mixture of hydrogen and argon. Total flow of working gas was 50 sccm. Different ratios of gas mixture were tested, the ratio 30 sccm hydrogen and 20 sccm argon flows was the best. RF discharge was used in a continuous and pulsed regime. Pulsed mode was carried out with various duty cycle at the frequency of 1000 Hz. There were two ways of temperature monitoring. The sample temperature during the treatment was monitored by a K-type thermocouple installed inside the sample in the first case. Thermometer optical probe was connected to the sample surface by a small stainless plate and allowed continuous sample temperature monitoring in the second way. Safe object temperature for copper and copper alloys is 100–120 °C. To avoid exceeding this temperature, power control or the duty cycle in pulse mode were automatically controlled if thermometer optical probe was used. Plasma chemical treatment is based on generation of reactive atomic hydrogen in plasma discharge. The main reactions during reduction were reactions between oxygen and chloride contained in the corrosion layer and the hydrogen ions and neutral atoms generated in the plasma. These reactions create an unstable OH radical, which emits light in the region of 306–312 nm. This radiation was detected by the optical emission spectroscopy using Ocean Optics HR4000 spectrometer with 2400 gr/mm grating. Data obtained from this method were used to calculate rotational temperatures and integral intensity of OH radicals that were used for the process monitoring. Corrosion layer was not completely removed during the reduction, but due to the reactions which occur in the plasma corrosion layer became brittle and after plasma chemical treatment can be removed easily. The SEM-EDS material analyses were carried out before and after treatment of some samples. Some samples were analysed by XRD analysis. EDS analysis showed that amount of oxygen and chloride was decreased, mainly at 400 W pulse mode.