Masters of Science / Petrophysical evaluation of four wells within Cretaceous gas-bearing sandstone reservoirs in blocks 4 and 5 Orange Basin, South Africa. Thierry Kamgang The present research work evaluates the petrophysical characteristics of the Cretaceous gasbearing sandstone units within Blocks 4 and 5 offshore South Africa. Data used to carry out this study include: wireline logs (LAS format), base maps, well completion reports, petrography reports, conventional core analysis report and tabulated interpretative age reports from four wells (O-A1, A-N1, P-A1 and P-F1). The zones of interest range between 1410.0m-4100.3m depending on the position of the wells. The research work is carried out in two phases: The first phase corresponds to the interpretation of reservoir lithologies based on wireline logs. This consists of evaluating the type of rocks (clean or tight sandstones) forming the reservoir intervals and their distribution in order to quantify gross zones, by relating the behavior of wireline logs signature based on horizontal routine. Extensively, a vertical routine is used to estimate their distribution by correlating the gamma-ray logs of the corresponding wells, but also to identify their depositional environments (shallow to deep marine).Sedlog software is used to digitize the results. The second phase is conducted with the help of Interactive Petrophysics (version 4) software, and results to the evaluation of eight petrophysical parameters range as follow: effective porosity (4.3% - 25.4%), bulk volume of water (2.7% – 31.8%), irreducible water saturation (0.2%-8.8%), hydrocarbon saturation (9.9% - 43.9%), predicted permeability (0.09mD – 1.60mD), volume of shale (8.4% - 33.6%), porosity (5.5% - 26.2%) and water saturation (56.1% - ii 90.1%). Three predefined petrophysical properties (volume of shale, porosity and water saturation)are used for reservoir characterization. The volume of shale is estimated in all the wells using corrected Steiber method. The porosity is determined from the density logs using the appropriate equations in wells O-A1 and P-A1, while sonic model is applied in well A-N1 and neutron-density relationship in well P-F1. Formation water resistivity (Rw) is determined through the following equation: Rw = (Rmf × Rt) / Rxo, and water saturation is calculated based on Simandoux relation. Furthermore, a predicted permeability function is obtained from the crossplot of core porosity against core permeability, and it results match best with the core permeability of well O-A1. This equation is used to predict the permeability in the other wells. The results obtained reveal that average volumes of shale decrease from the west of the field towards the east; while average porosities and water saturations increase from the south-west through the east despite the decreasing average water saturation in well P-A1. A corroboration of reference physical properties selected for reservoir characterization, with predefined cut-off values result to no net pay zones identified within the reservoir intervals studied. Consequently, it is suggested that further exploration prospects should be done between well O-A1 and A-N1.

While there is growing evidence that shade/flood tolerance tradeoffs may be important in distributions of bottomland hardwood trees and indications that they should apply to herbs, no studies have definitively explored this possibility. Four years of field data following historic flooding were supplemented with a greenhouse experiment designed to identify interactions congruent with tradeoffs. Fifteen bottomland species were grown in two levels of water availability and three levels of shade over 10 weeks. Results indicate responses of Fimbristylis vahlii and Ammannia robusta are consistent with tradeoffs. Modification of classical allometric responses to shade by substrate saturation indicates a potential mechanism for the tradeoff in A. robusta. Responses indicating potential for increased susceptibility to physical flooding disturbance are also discussed.

<p> Using the reference spectrum method the G-matrix elements, and hence the binding energy of an infinite nucleus is calculated. Three modern potentials. two of which are hard core and one soft core are used. This formalism is then extended to a finite nuclei and spin orbit splittings around some closed shell nuclei are calculated. Both for binding energy and spin orbit splittings fairly good agreement with experiment is obtained. </p> / Thesis / Doctor of Philosophy (PhD)

<p> Differential Dynamic. Programming is a new method, based on Bellman's principle of optimality, for determining optimal control strategies for nonlinear systems. It has originally been developed by D.H.Jacobson. </p> <p> In this thesis a result is presented for a problem with saturation characteristics in nonlinearity solved by the Jacobson's approach. In the differential dynamic programming the principle of optimality is applied to the differential change in non-optimal cost due to small changes in state; variables instead of the cost itself. This results in modest memory requirements for its defining parameters and rapid convergence. </p> / Thesis / Master of Engineering (MEngr)

No description available.

<p> The formation of soluble amyloid oligomers by polypeptide chains is the main pathogenic mechanism underlying several neurodegenerative disorders including some of the most common debilitating and aging-related illnesses such as Alzheimer's and Parkinson's diseases. However, the molecular basis of polypeptide oligomerization and amyloid formation is currently not fully understood. In this thesis the focus will be on the early steps of oligomer formation that precede the nucleation of amyloid fibrils, that are still reversible. The reversibility of these initial self-association equilibria makes them an attractive target for therapeutic intervention in the treatment of amyloid diseases. Specifically three general questions will be addressed: (a) What are the residues within a given polypeptide chain that mediate self-recognition? (b) What are the driving forces for self-association? (c) Is self-recognition coupled with conformation changes? </p> <p> The objective of this thesis is to provide initial responses to these key questions using as prototypical system the Ap (12-28) peptide, which has been previously proposed as a model for the initial self-association events that are linked to Alzheimer's disease. Given the flexibility of this peptide the main tool for its investigation will be Nuclear Magnetic Resonance (NMR) spectroscopy. Specifically, both classical (i.e., TOCSY and NOESY) and more novel (i.e. saturation transfer difference and off-resonance relaxation) NMR experiments were used to probe the soluble oligomers through the comparative analysis of samples with different monomer/oligomer distributions. The combined analysis of this integrated set of experiments reveals that while the residues in the central hydrophobic core (CHC) drive self-recognition, stable oligomers require a conformational change towards more folded structures that affects residues well outside the CHC. The conformational change occurring upon self-association thus effectively couples CHC and non-CHC residues. This model may also explain why mutations outside the CHC (i.e. E22, D23) can affect significantly the kinetics of self-association. </p> <p> / Thesis / Master of Science (MSc)

Aerospace systems such as aircraft or missiles are subject to environmental and dynamical uncertainties. These uncertainties can alter the performance and stability of these systems. Adaptive control offers a useful means for controlling systems in the presence of uncertainties. However, very often adaptive controllers require more control effort than the actuator limits allow. In this thesis the original work of others on single input single output adaptive control in the presence of actuator amplitude limits is extended to multi-input systems. The Lyapunov based stability analysis is presented. Finally, the resultant technique is applied to aircraft and missile longitudinal motion. Simulation results show satisfactory tracking of the states of modified reference system. / Master of Science

Les contrôleurs à réinitialisation sont une classe de systèmes hybrides dont la valeur de tout ou partie des états peut être instantannément modifiée sous certaines conditions algébriques. Cette interaction entre dynamique temps-continu et temps-discret de ces contrôleurs permet souvent de dépasser les limites des contrôleurs temps-continu. Dans cette thèse, nous proposons des conditions constructives (sous forme d’Inégalités Matricielles Linéaires) pour analyser la stabilité et les performances de boucle de commande incluant un contrôleur à réinitialisation. En particulier, nous prenons en compte la présence de saturation en amplitude des actionneurs du système. Ces non-linéarités sont souvent source d'une dégradation des performances voir d’instabilité. Les résultats proposés permettent d’estimer le domaine de stabilité et un niveau de performance pour ces systèmes, en s’appuyant sur des fonctions de Lyapunov quadratiques ou quadratiques par morceaux. Au delà de l'aspect analyse, nous exposons deux approches pour améliorer la région de stabilité (nouvelle loi de réinitialisation et stratégie « anti-windup »). / Hybrid controllers are flexible tools for achieving system stabilization and/or performance improvement tasks. More particularly, hybrid controllers enrich the spectrum of achievable trade-offs. Indeed, the interaction of continuous- and discrete-time dynamics in a hybrid controller leads to rich dynamical behavior and phenomena not encountered in purely continuous-time system. Reset control systems are a class of hybrid controllers whose states are reset depending on an algebraic condition. In this thesis, we propose constructive conditions (Linear Matrix Inequalities) to analyze stability and performance level of a closed-loop system including a reset element. More particularly, we consider a magnitude saturation which could be the source of undesirable effects on these performances, including instability. Proposed results estimate the stability domain and a performance level of such a system, by using Lyapunov-like approaches. Constructive algorithms are obtained by exploiting properties of quadratic - or piecewise quadratic - Lyapunov functions. Beyond analysis results, we propose design methods to obtain a stability domain as large as possible. Design methods are based on both continuous-time approaches (anti-windup compensator) and hybrid-time approaches (design of adapted reset rules).

Cette thèse expérimentale traite du transport sédimentaire provoqué par un fluide (généralement l’air ou l’eau) s’écoulant sur un matériau érodable (lit de sable par exemple) et lui transmettant une force suffisante pour soulever les particules solides et les emporter avec lui en aval. Ici, on se focalise uniquement sur le charriage aquatique : dans ce mode de transport, les grains en mouvement roulent les uns sur les autres, glissent, effectuent une succession de bonds et d’arrêts tout en restant confinés près du fond. On réalise différents types d’expériences dans un canal de laboratoire avec, à chaque fois, plusieurs types de grains (3 tailles, 2 densités) afin d’étudier en détails le charriage sous l’eau. Tout d’abord, on s’intéresse aux trajectoires de grains isolés transportés sur le fond plat et lisse du canal. Alors que les écoulements sont pour la plupart hydrauliquement lisses (les grains sont immergés dans la sous-couche visqueuse), on montre que la turbulence proche paroi impacte fortement la dynamique des grains. Les données accumulées permettent d’estimer les moyennes et les dispersions de la vitesse des particules ainsi que de construire les fonctions de densité de probabilité. On compare ces résultats avec ceux obtenus par Vélocimétrie Laser Doppler (VLD) concernant l’écoulement fluide proche du fond. Dans un second temps, on quantifie le transport par la mesure de la quantité de sédiments charriés sur des lits plats pour différentes contraintes de cisaillement. L’idée qui motive ces expériences est la détermination empirique de la loi de transport(la relation entre le flux de grains et le cisaillement) pour notre configuration expérimentale. Nos résultats diffèrent assez largement des lois de transport habituelles du type Meyer-Peter et Müller et s’interprètent plus aisément dans le cadre des lois pour le charriage de faible intensité. Ensuite, une méthode de Profilométrie par Transformée de Fourier (PTF) est implémentée pour mesurer avec précision les surfaces 3D de petites dunes aquatiques (les barkhanes) et leur évolution au cours du temps. On s’intéresse, entre autres, à la formation des barkhanes, à leur morphologie, à leur vitesse de migration ainsi qu’au phénomène d’érosion. On apporte la preuve que les barkhanes aquatiques se déplacent sans se déformer et dès lors, on montre qu’il devient facile d’évaluer le flux de grains sur le dos des dunes (dans le plan de symétrie). Pour finir, on caractérise l’écoulement au-dessus d’une "maquette" de barkhane par VLD et on en déduit le cisaillement sur le dos de la dune (du pied à la crête). Ces mesures de cisaillement couplées aux lois de transport pour notre canal et aux résultats concernant les barkhanes obtenus par PTF nous permettent de discuter du phénomène de saturation du flux de grains. On estime la valeur de la longueur de saturation pour le charriage tout en restant prudent quant à la fiabilité de notre conclusion à ce sujet. / This experimental thesis deals with sediment transport induced by a fluid (air or water generally)flowing over an erodible bottom (sand bed for example) and providing a sufficiently high strengthto whip up solid particles and carry them downstream. Here, one focuses only on aquatic bedload: in this transport regime, moving grains roll, slip, jump or stop alternatively while staying confinedclose to the bed. We achieve different kinds of experiments in a laboratory flume involving everytime several grain types (3 sizes, 2 densities) in order to study underwater bedload in details. First,one considers trajectories of isolated beads transported over the flat and smooth bottom of theflume. Although the studied flows are hydraulically smooth (grains are fully embedded in theviscous sublayer), one shows that near wall turbulence highly impact grains dynamics. From ourdata, we extract mean particle velocities, standard deviations and also probability densityfunctions. One compares these results with those obtained by Laser Doppler Velocimetry (LDV)concerning the near wall fluid flow. Second, one quantifies the bedload by measuring the volumeof grains transported at the surface of flat granular beds for different shear stresses. The goal ofthese experiments is the empirical determination of the transport law (the relationship between thegranular flux and the fluid shear) for the present experimental configuration. Our results differsignificantly from usual transport laws like the one of Meyer-Peter and Müller and are bestunderstood within the framework of weak sediment transport. Then, one implements a FourierTransport Profilometry (FTP) method in order to measure with a good resolution the 3D surfacesof small aquatic dunes (called barchans) and their time evolution. One takes an interest in, amongothers, barchans formation, their morphology, their displacement velocity and the erosionphenomenon. One shows that subaquatic barchans move downstream without deforming and thusit becomes easier to estimate the granular flux on the back of the dunes (in the symmetry plane).Eventually, one characterizes the flow above a barchan "model" by LDV and deduces the shearstress along the dune’s back (from foot to crest). These shear stress measurements coupled withthe empirical transport laws and results concerning barchans obtained by FTP permit us todiscuss saturation effects of the granular flux. One estimates the saturation length for the bedloadand highlights that our conclusion on this point must be taken with care.

Despite recent interest in understanding long-term trends in ocean acidity, natural variations of carbon chemistry on short timescales are still poorly understood. Unfortunately, historical observations of the oceanic CO2 system are relatively few in number. Such data are particularly scarce along the highly productive Canadian Pacific coast. However, hydrographic data such as temperature, salinity, oxygen and nutrients have been collected regularly in this region. I developed a fully cross-validated statistical model to predict the aragonite saturation state (Ωarag), a biologically relevant measure of the carbonate system. Different sensitivity tests were performed to assess the robustness of the statistical modelling skill to different model structures. In particular, this study found that in situ temperature and O2 used together were strong predictors of Ωarag. The carbon data used to build this statistical model came from five hydrographic surveys along the Pacific coast of Canada (in July 1998, August 2004, late May 2007, February 2010 and early August 2010) that contain direct measurements of CO2 system parameters. Only data from a depth range of 0-750 m were used, as data from below 750 m showed biases due to calcium carbonate dissolution. Although processes such as solar warming and gas exchange occur in the surface and could possibly introduce biases in the model, I show that these surface data can be included. The ability of the statistical models to compute robust estimates of Ωarag was assessed by exploring the generalizability of the model through cross-validation procedures using different partitions of the data. By predicting lnΩarag rather than Ωarag directly, I obtained a strong and robust predictive relationship. This MLR model form yielded a high value in the squared correlation coefficient between predicted and observed values (0.96) and a low percentage in erroneous prediction of undersaturated conditions (3.1%). This relationship was found to be insensitive to changes in spatial domain or interannual variability in the data. These results suggest that the model can be used to estimate the distribution of Ωarag along the outer west coast of Canada when basic hydrographic data on temperature and O2 are available. Predictions of Ωarag from historical observations (1980-2009) in this region reveal that the saturation horizon (Ωarag=1) tended to be more stable in winter and spring and highly variable and occasionally shallow in summer and fall during and following the upwelling season. Undersaturation with respect to aragonite was more likely to occur at shallower depths over the shelf relative to adjacent offshore waters likely as a result of upwelling. The Ωarag saturation horizon tended to be more variable in depth on the shelf compared to offshore waters. The saturation horizon tended to occur at deeper depths over the Queen Charlotte Sound (QCS) shelf and be more stable with respect to the west coast of Vancouver island (WCVI). Thus, the WCVI may experience adverse effects of ocean acidification more acutely than QCS. The use of this approach may provide insight into natural variability and the key controls of Ωarag in future studies at a low cost. However, this predictive model cannot hind-cast data to evaluate the presence of the anthropogenic signal. / Graduate