The Atlantis II Deep is a location of modern submarine hydrothermal activity along the slowly spreading Red Sea rift axis. Venting of high-temperature hydrothermal fluids, similar to those associated with black smokers, takes place in a brine pool and has led to the accumulation of 90 Mt (dry, salt free) of stratiform, metalliferous sediment. The conditions of mineralization are unique in the modern oceans, but have been widely suggested as a possible analog of some important ancient stratiform base metal ore deposits. This study shows that many of the proposed genetic models for these ancient deposits may be highly simplified and do not take into account rapid diagenetic transformations, widespread non-equilibrium processes, and many other aspects of metal deposition. Sediment cores of the Atlantis II muds were last studied more than 30 years ago. High-resolution sampling and careful re-examination of the mineralogy and geochemistry of the sediments, using modern analytical techniques has significantly improved the understanding of the different processes responsible for the formation of the finely layered metallifeous sediments. The geochemistry of the individual layers is controlled by highly variable detrital, hydrogenic and hydrothermal input. Primary depositional pathways from the brine pool are the main control on basin-wide metal distribution (e.g., increasing Cu/Zn away from the vents) including variable enrichment in trace metals via scavenging from the brine pool and from the enriched pore waters. Cu and Zn have been deposited not only as sulfides but also with poorly crystalline Si-Fe-(oxy)hydroxides. A significant proportion of the original non-sulfide Cu and Zn are diagenetically transformed into sulfides, but also carbonates and clays, in large part reflecting sulfide deficient pore waters. Negative δ34S values, previously unrecognized in the sulfide- and metal-rich units, indicate a source of bacteriogenic sulfide. Syn-diagenetic processes also appear to have been responsible for the sharp laminations in the sediments, as well as distinctive zoning of carbonate and clay minerals around the vent source. The early diagenetic transformations observed in the Atlantis II Deep may not be preserved in the ancient rock record but nevertheless have important implications for metal deposition in some of the world’s largest and richest base metal ore deposits.

京都大学 / 0048 / 新制・課程博士 / 博士(工学) / 甲第22423号 / 工博第4684号 / 新制||工||1731(附属図書館) / 京都大学大学院工学研究科都市社会工学専攻 / (主査)教授 小池 克明, 教授 三ｹ田 均, 准教授 柏谷 公希, 教授 後藤 忠徳 / 学位規則第4条第1項該当 / Doctor of Philosophy (Engineering) / Kyoto University / DGAM

京都大学 / 新制・課程博士 / 博士(工学) / 甲第23175号 / 工博第4819号 / 新制||工||1753(附属図書館) / 京都大学大学院工学研究科都市社会工学専攻 / (主査)教授 小池 克明, 教授 林 為人, 准教授 柏谷 公希 / 学位規則第4条第1項該当 / Doctor of Philosophy (Engineering) / Kyoto University / DGAM

Relative plate motion history since 30 Ma between the Pacific and the southern portion of the Nazca (Farallon) plates is examined. The history is constrained by available seafloor magnetic anomaly data and a two-minute grid of predicted bathymetry derived from satellite altimetry and shipboard sensors. These data are used to create a new plate motion reconstruction based on new magnetic anomaly identifications and finite poles of motion. The new identified magnetic isochrons and tectonic reconstruction provides greater resolution to the tectonic history between chrons 7y (24.73 Ma) and 3 (4.18 Ma) than previous interpretations. Shipboard magnetics and aeromagnetic data from over 250 expeditions were plotted and used to extrapolate magnetic anomalies picked from 2D magnetic modeling from selected cruises. Magnetic anomalies were further constrained by tectonic features evident in the predicted bathymetry. Previously published magnetic anomaly locations consistent with this work were used where interpretation could not be constrained by 2D modeling and map extrapolation. Point locations for anomalies were used as input for calculation of finite poles of motion for chrons 10y, 7y, 6c, 5d, 5b, 5aa, 5o, 4a and 3a. An iterative process of anomaly mapping, pole calculation and anomaly point rotations was used to refine the finite poles of motion. Eleven stage poles were calculated from the nine finite poles from this study and two published instantaneous Euler vectors. Tectonic reconstructions indicate a history dominated by two major southward ridge propagation events, the first starting by 28 Ma and completed by 18 Ma. The second event initiated in association with breakup of the Farallon plate around 24 Ma and ceased by about 11 Ma. Lithosphere was transferred from Nazca to Pacific during the first event and in the opposite sense during the second. Development of the Mendoza microplate east of the later propagator occurred at about 20 Ma and this dual spreading process appears to have lasted until about 15 Ma.

This dissertation explores the influence of the environment on the lateral spatial patterning of facies in modern isolated carbonate platforms through six studies. The first study describes the creation of a database of benthic habitat and bathymetric maps derived from multispectral satellite imagery and the field data used calibrate and validate the mapping algorithms. The second study develops and assesses a new approach for remotely-deriving water depth from multispectral satellite imagery without the need for ground-truth information. The third study identifies a criterion for distinguishing between facies belts and mosaics and deploys the criterion to investigate the co-occurrence of these arrangements within modern carbonate depositional systems. The fourth study explores the geologic history of an isolated carbonate platform in the Bahamas, Cay Sal Bank, to understand why the lateral spatial pattering observed in this site differs from the patterns observed in neighboring platforms. The fifth study explores the distribution of carbonate facies in relation to wave energy and water depth for two detached ramps in the Red Sea, Ras Al-Qisbah and Al Wajh. The last study investigates the recovery of scleractinian communities along the coasts of two islands in the Galapagos archipelago, Darwin and Wennman (Wolf) Islands, following a large-scale disturbance in the 1980s. Together, these six studies provide new insight into the spatial patterning of facies within modern carbonate depositional systems and the influence of the environment on the observed arrangements.

No description available.

Ever since the discovery of seafloor hydrothermal systems at mid ocean ridges, scientists have been trying to understand the complex dynamic processes by which thermal energy is transported advectively by chemically reactive aqueous fluids from Earth's interior to the surface. Hydrothermal systems are generally assumed to consist of a heat source and a fluid circulation system. Understanding the interconnected physical, chemical, biological, and geological processes at oceanic spreading centers is important because these processes affect the global energy and biogeochemical budgets of the Earth system. Despite two decades of focused study of hydrothermal systems, several key questions remain concerning the behavior and evolution of hydrothermal vent systems. Among these are: (a) the partitioning of heat transport between focused and diffuse flow, and (b) the spatial extent and distribution of hydrothermal recharge. These are the main topics of investigation in this thesis. To address these issues, I first use a single-pass modeling approach using a variety of observational data in a simple parametric scale analysis of a hydrothermal vent field to determine fundamental parameters associated with the circulation and magmatic heat transfer for a number of seafloor hydrothermal systems for which the constraining data are available. To investigate the partitioning of heat flux between focused high temperature and diffuse flow I extend the one-limb single pass model to incorporate two single-pass limbs to represent deep and shallow circulation pathways. As a result, I find that 90% of the heat output is from high temperature fluid circulating in the deep limb even though much of the heat loss appears at the seafloor as low-temperature diffuse flow. Next, I use the parametric description of hydrothermal circulation to investigate hydrothermal recharge at the East Pacific Rise 9°50′ N hydrothermal site. Using a 1-D model of recharge through an area of 10⁵ m² elucidated by microseismicity in the oceanic crust I find that anhydrite precipitation is likely to result in rapid sealing of pore space in the recharge zone. This would lead to rapid decay of hydrothermal venting, which is contrary to observations. Then I consider two-dimensional numerical models of hydrothermal circulation in a porous box heated from below. The preliminary results of these models suggests that the anhydrite precipitation zone will be more diffuse, but additional work is needed to test whether anhydrite precipitation will seal the pore space. / Master of Science

We present 2-D numerical simulations of two phase flow in seafloor hydrothermal systems using the finite control volume numerical scheme FISHES. The FISHES code solves the coupled non-linear equations for mass, momentum, energy, and salt conservation in a NaCl-H2O fluid to model the seafloor hydrothermal processes. These simulations use homogeneous box geometries at a fixed seafloor pressure of 25 MPa with constant bottom temperature boundary conditions that represent a sub-axial magma chamber to explore the effects of permeability, maximum bottom temperature and system depth on the evolution of vent fluid temperature and salinity, and heat output. We also study the temporal and spatial variability in hydrothermal circulation. The two-phase simulation results show that permeability plays an important role in plume structure and heat output of hydrothermal systems, but it has little effect on vent fluid temperature and salinity, given the same bottom temperature. For some permeability values, multiple plumes can vent at the seafloor above the simulated magma chamber. Temporal variability of vent fluid temperature and salinity and the complexity of phase separation suggest that pressure and temperature conditions at the top of the axial magma chamber cannot be easily inferred from vent fluid temperature and salinity alone. Vapor and brine derived fluids can vent at the seafloor simultaneously, even from neighboring locations that are fed by the same plume. / Master of Science

<p>The main conclusion of this dissertation is that global H2 production within young ocean crust (<10 Mya) is higher than currently recognized, in part because current estimates of H2 production accompanying the serpentinization of peridotite may be too low (Chapter 2) and in part because a number of abiogenic H2-producing processes have heretofore gone unquantified (Chapter 3). The importance of free H2 to a range of geochemical processes makes the quantitative understanding of H2 production advanced in this dissertation pertinent to an array of open research questions across the geosciences (e.g. the origin and evolution of life and the oxidation of the Earth’s atmosphere and oceans).</p><p>The first component of this dissertation (Chapter 2) examines H2 produced within young ocean crust [e.g. near the mid-ocean ridge (MOR)] by serpentinization. In the presence of water, olivine-rich rocks (peridotites) undergo serpentinization (hydration) at temperatures of up to ~500°C but only produce H2 at temperatures up to ~350°C. A simple analytical model is presented that mechanistically ties the process to seafloor spreading and explicitly accounts for the importance of temperature in H2 formation. The model suggests that H2 production increases with the rate of seafloor spreading and the net thickness of serpentinized peridotite (S-P) in a column of lithosphere. The model is applied globally to the MOR using conservative estimates for the net thickness of lithospheric S-P, our least certain model input. Despite the large uncertainties surrounding the amount of serpentinized peridotite within oceanic crust, conservative model parameters suggest a magnitude of H2 production (~1012 moles H2/y) that is larger than the most widely cited previous estimates (~1011 although previous estimates range from 1010-1012 moles H2/y). Certain model relationships are also consistent with what has been established through field studies, for example that the highest H2 fluxes (moles H2/km2 seafloor) are produced near slower-spreading ridges (<20 mm/y). Other modeled relationships are new and represent testable predictions. Principal among these is that about half of the H2 produced globally is produced off-axis beneath faster-spreading seafloor (>20 mm/y), a region where only one measurement of H2 has been made thus far and is ripe for future investigation.</p><p>In the second part of this dissertation (Chapter 3), I construct the first budget for free H2 in young ocean crust that quantifies and compares all currently recognized H2 sources and H2 sinks. First global estimates of budget components are proposed in instances where previous estimate(s) could not be located provided that the literature on that specific budget component was not too sparse to do so. Results suggest that the nine known H2 sources, listed in order of quantitative importance, are: Crystallization (6x1012 moles H2/y or 61% of total H2 production), serpentinization (2x1012 moles H2/y or 21%), magmatic degassing (7x1011 moles H2/y or 7%), lava-seawater interaction (5x1011 moles H2/y or 5%), low-temperature alteration of basalt (5x1011 moles H2/y or 5%), high-temperature alteration of basalt (3x1010 moles H2/y or <1%), catalysis (3x108 moles H2/y or <<1%), radiolysis (2x108 moles H2/y or <<1%), and pyrite formation (3x106 moles H2/y or <<1%). Next we consider two well-known H2 sinks, H2 lost to the ocean and H2 occluded within rock minerals, and our analysis suggests that both are of similar size (both are 6x1011 moles H2/y). Budgeting results suggest a large difference between H2 sources (total production = 1x1013 moles H2/y) and H2 sinks (total losses = 1x1011 moles H2/y). Assuming this large difference represents H2 consumed by microbes (total consumption = 9x1011 moles H2/y), we explore rates of primary production by the chemosynthetic, sub-seafloor biosphere. Although the numbers presented require further examination and future modifications, the analysis suggests that the sub-seafloor H2 budget is similar to the sub-seafloor CH4 budget in the sense that globally significant quantities of both of these reduced gases are produced beneath the seafloor but never escape the seafloor due to microbial consumption.</p><p>The third and final component of this dissertation (Chapter 4) explores the self-organization of barchan sand dune fields. In nature, barchan dunes typically exist as members of larger dune fields that display striking, enigmatic structures that cannot be readily explained by examining the dynamics at the scale of single dunes, or by appealing to patterns in external forcing. To explore the possibility that observed structures emerge spontaneously as a collective result of many dunes interacting with each other, we built a numerical model that treats barchans as discrete entities that interact with one another according to simplified rules derived from theoretical and numerical work, and from field observations: Dunes exchange sand through the fluxes that leak from the downwind side of each dune and are captured on their upstream sides; when dunes become sufficiently large, small dunes are born on their downwind sides (“calving”); and when dunes collide directly enough, they merge. Results show that these relatively simple interactions provide potential explanations for a range of field-scale phenomena including isolated patches of dunes and heterogeneous arrangements of similarly sized dunes in denser fields. The results also suggest that (1) dune field characteristics depend on the sand flux fed into the upwind boundary, although (2) moving downwind, the system approaches a common attracting state in which the memory of the upwind conditions vanishes. This work supports the hypothesis that calving exerts a first order control on field-scale phenomena; it prevents individual dunes from growing without bound, as single-dune analyses suggest, and allows the formation of roughly realistic, persistent dune field patterns.</p> / Dissertation

Non renseigné / Most mega-earthquakes (i.e. earthquakes with Mw ≥ 8.5) occur along subduction mega-thrusts, the interfaces between the subducting - and the overriding plates in convergent margins. These events may have catastrophic impact on human societies due to their destructive potential. For this reason being able to predict the timing and size of these earthquakes became one goal of the international scientific community. The subduction seismic cycle is influenced by many different parameters. The interplay between these parameters governing the frequency and size of megathrust earthquakes still remains unclear, mainly due to the short (i.e. limited to the last century) seismic record.The seismogenic part of the subduction thrust fault spans between depths of 11±4 and ± 51 km (Heuret et al. 2011). In this zone a combination of temperature, pressure and rocks characteristics creates conditions favourable for seismic behaviour. Whether a specific area in the subduction thrust fault has the ability to trigger mega-earthquakes can be expressed using the degree of seismic coupling, i.e. the amount of slip that occurs with respect to the total amount of plate convergence (e.g. Scholz 1998; Scholz & Campos 2012). When a fault is fully coupled, all of the fault slip occurs during earthquakes instead of also during aseismic behaviour (e.g. slow slip events). The internal structure of the interplate fault zone mainly determines whether an area within a subduction zone behaves seismic or aseismic (Wang & Bilek 2011). This is influenced by the topography of the plate interface (e.g. subducting seamounts; Wang & Bilek 2014), but also subducted sediments and fluids in the subduction channel may play an important role.The main goal of this project is to understand which parameters affect the behaviour of mega-earthquake ruptures. This will be done by comparing natural data (e.g. seafloor roughness, sediment thickness and fluid content in the subduction channel) to rupture characteristics of major recent earthquakes. With this analysis also more knowledge can be gained on the triggering of slow earthquakes instead of mega-earthquakes. These are slow slip events with lower frequencies and longer durations than ‘regular’ earthquakes (Saffer & Wallace 2015).The database of natural data, implemented by the long-term scientific joint venture between the Univ. Montpellier and the LET (Roma Tre) will be used for the analysis. Ongoing work is done on determining a method for estimating the seafloor roughness, i.e. the distribution of high, low and smooth areas (by Michel Peyret in collaboration with Serge Lallemand, Univ. Montpellier). Also data is available on the trench sediment thickness around the world (Heuret et al. 2011). In the frame of this project, information on the roughness of the seafloor will be added to the database. In addition the rupture characteristics of major recent earthquakes will be collected. By performing a multiparametric statistical analysis of the database, a conceptual model will be realized, exploring the possible link between all the different parameters. The aim is to validate this model in the lab using scaled 3D analogue models. This will be done both at the LET and at Univ. Montpellier by using a broad range of geometries and contact materials with different rheologies (e.g. gelatin, foam rubber and a new analogue material; Caniven et al. 2015; Corbi et al. 2013). This jointed experimental approach with both the Univ. Montpellier and the LET involved creates a rich environment where differences and similarities of the two different approaches can be used to validate the results.