This study aims to assess the potential environmental risks posed by sediments in five lakes affected by present or historical metallurgy. Special attention is paid to the lakes Dammsjön and Värlingen in mid Sweden, where the sediments were contaminated after a breach in a nearby tailings dam used for storing residue from a metal processing plant. The sediments were examined for their metal content by X-ray fluorescence spectroscopy (XRF) analysis of loose powder samples. A subset of the samples from Dammsjön and Värlingen was also used for a simple pH-analysis and an experimental XRF analysis of evaporated leachate. To obtain a larger variety of samples for the XRF analysis of evaporated leachate, loose powder sediment and leachate from three additional lakes affected by extractive metallurgy, Tisken, Gruvsjön and Storjuktan, were likewise examined with XRF. The sediments from all lakes contained high levels of metals, and environmental standards for Pb (in all lakes) and Cd (in Storjuktan) were exceeded. The leachate tests showed that metals can be extracted using this method, including Cu and Ni in lake Tisken. This might indicatehigher bioavailability, but further studies are needed to confirm this interpretation. Dammsjön andVärlingen are contaminated by several metals, including Hg and As. The pH-analysis indicated that the deposited sediment is not the source of the prolonged low pH in Dammsjön, and that another source, possibly continued leaks from the tailings dam, needs to be found. The results call for close environmental monitoring, to minimise further contamination and damage to the environment.

Modeling sediment erosion is important in a wide range of environmental problems. The effects of various environmental factors on erosion rates have been studied, but the effects of surface slope on erosion rates of a wide range of sediments have not been quantified. The effects of surface slope, both in the direction of flow (pitch) and perpendicular to the flow (roll), on erosion rates of quartz particles were investigated using the Sediment Erosion at Depth Flume (Sedflume). / US Navy (USN) author.

A nested three dimensional numerical modeling application was developed to determine the fate of pathogen indicators in Lake Pontchartrain discharged from its tributaries. To accomplish this, Estuarine, coastal and ocean model with sediment (ECOMSED) was implemented to simulate various processes that would determine the fate and transport of fecal coliform bacteria in the lake. The processes included hydrodynamics, waves, sediment transport, and the decay and transport of the fecal coliforms. Wind and tidal effects were accounted along with the freshwater inflows. All the components of the modeling application were calibrated and validated using measured data sets. Field measurements of the conventional water quality parameters and fecal coliform levels were used to calibrate and validate the pathogen indicator transport. The decay of the fecal coliforms was based on the literature and laboratory tests. The sediment transport module was calibrated based on the satellite reflectance data in the lake. The north shore near-field model indicated that the fecal coliform plume can be highly dynamic and sporadic depending on the wind and tide conditions. It also showed that the period of impact due to a storm event on the fecal coliform levels in the lake can be anywhere from 1.5 days for a typical summer event to 4 days for an extreme winter event. The model studies showed that the zone of impact of the stormwater from the river was limited to a few hundred meters from the river mouth. Finally, the modeling framework developed for the north shore was successfully applied to the south shore of Lake Pontchartrain to simulate fate and transport of fecal coliforms discharged through the urban stormwater outfalls.

The presence of volatile methylsiloxanes (VMS) in the environment has raised concerns among environmental chemists and regulators about their persistence and the risks they may pose to the environment. This thesis explores the partitioning and persistence of VMS in aquatic environments. In Paper I, we reported new measurements of the organic carbon/water (KOC) and dissolved organic carbon/water (KDOC) partition ratios of three cyclic volatile methylsiloxanes (cVMS) and of three polychlorinated biphenyls (PCBs), which were used as reference chemicals. We combined new measurements with existing data to construct polyparameter linear free energy relationships (PP-LFER) that describe the KOC and KDOC of diverse sets of chemicals. The findings suggest that cVMS do not conform to single-parameter regressions that relate the chemicals’ KOC to their octanol/water partition ratio (KOW). PP-LFERs can accurately describe the KOC and KDOC of cVMS but only if cVMS are included in their training sets. In Paper II, we studied the effect of salinity on the KOC and KDOC of three cVMS, two linear volatile methylsiloxanes (lVMS) and three PCBs. We also evaluated the predictive power of the PP-LFERs constructed in Paper I by testing them on the newly measured KOC values of lVMS. The KOC and KDOC increased with increasing salinities similarly to those of the PCBs. PP-LFERs that were trained with datasets that included siloxanes could predict the KOC and KDOC of other siloxanes more accurately than PP-LFERs without siloxanes in the training set. In Paper III, we evaluated the effect of temperature on the KOC of VMS and we compared our measurements of the enthalpy of sorption to organic carbon (ΔHOC) to existing measurements of the enthalpy of phase change between octanol and water (ΔHOW). Due to the scarcity of ΔHOC data in the literature it is common practice in modeling calculations to use ΔHOW instead when correcting for temperature changes. The KOC of cVMS increased with decreasing temperatures. Moreover, our results indicate that ΔHOC and ΔHOW may be intrinsically different and hence replacing ΔHOC with ΔHOW in modeling calculations could lead to substantial errors, especially for VMS. In Paper IV, we explored the environmental fate of VMS in aquatic environments using multimedia models. In particular, we assessed the differences that may occur in calculations of persistence due to (i) the reported KOC measurements of VMS differing by one log unit (ii) the influence of salinity on KOC, and (iii) the differences in the reported ΔHOC and ΔHOW measurements of VMS. The calculated residence times for decamethylcyclopentasiloxane (D5) in a site-specific scenario for a Norwegian fjord receiving siloxanes in wastewater ranged from 200 to 1000 days, and demonstrated that the selection of KOC values can result in substantially different calculated persistence. Future partitioning measurements of VMS in the real environment and mass-balance modeling studies in aquatic environments combined with field measurements could help us to deepen our understanding about their persistence and to assess the risks VMS may pose to the environment. / <p>At the time of the doctoral defense, the following papers were unpublished and had a status as follows: Paper 1: Manuscript. Paper 3: Submitted.</p>

Thesis advisor: Noah P. Snyder / Large-scale human modification of the northeastern U.S. landscape began in the 17th century with forest clearing and milldam construction. In the mid-Atlantic Piedmont region of the U.S., Walter and Merritts (2008) found that millpond deposits persist for centuries after dam breaching, resulting in fill terraces composed of legacy sediment. Stratigraphic observations in the mid-Atlantic indicate that these laminated to massive fine-grained layers typically overly a prominent Holocene hydric soil that overlies a Pleistocene basal gravel. I test whether this set of processes applies to glaciated New England. This study focuses on two New England watersheds: the South River in Massachusetts and the Sheepscot River in Maine. I use stratigraphic analysis and radiocarbon dating to identify legacy deposits, and then use lidar digital elevation models to map planar terrace extents in each watershed. Finally, I use lidar digital elevation models to estimate thickness of legacy sediment found behind breached or removed milldams and estimate volumes of legacy sediment storage in valley bottoms over entire watersheds. The South River watershed has 32 historic dam sites; 18 have been field checked and 14 show evidence for legacy sediment storage. The Sheepscot River watershed has 33 historic dam sites; 13 have been field checked and six show evidence of legacy sediment storage. Stratigraphic analyses of bank exposures in both watersheds show a brown fine sand and silt layer (up to 2.19 m thick in the South River watershed and up to 2.30 m thick in the Sheepscot River watershed) which sometimes is underlain by gravel and/or clay; no buried Holocene hydric soil has been found. Further evidence for legacy milldam sedimentation comes from radiocarbon dating. Three radiocarbon dates from the South River watershed and six from the Sheepscot River watershed are less than 300 years old; no underlying Holocene material has been dated. The maximum volume of legacy sediment estimated using lidar methods for the South River watershed is 2.5 x 106 m3 and for the Sheepscot River watershed the volume is 3.7 x 106 m3. These volumes of legacy sediment can be translated to maximum mean thickness of sediment eroded from each landscape: 37 mm for the South River watershed and 7 mm for the Sheepscot River watershed. The Sheepscot River watershed has most of its legacy sediment terraces in the lower section of the watershed with many lakes and wetlands disturbing sediment transport in the upper section of the watershed. Compared to the Sheepscot River watershed, the South River watershed has more widespread glacial deposits contributing to legacy sediment with few lakes and wetlands. / Thesis (MS) — Boston College, 2017. / Submitted to: Boston College. Graduate School of Arts and Sciences. / Discipline: Earth and Environmental Sciences.

Thesis advisor: Noah Snyder / While it has been shown that extensive sedimentation in historic millponds has greatly affected streams in the Mid-Atlantic Piedmont region (Walter and Merritts, 2008), much less is known about the phenomenon in the heavily dammed areas of post-glacial New England. Some research has found similar deposits behind breached historic dams in the Sheepscot River watershed in mid-coast Maine, but at a smaller scale than those seen in the Mid-Atlantic region (Strouse, 2013; Hopkins, 2014). I attempt to further explore millpond sedimentation in New England by quantifying the volume of millpond sediment, also called legacy sediment, in the 171.3 km² upper Charles River watershed in eastern Massachusetts. Twenty three milldams were located in the watershed on 1850s maps, giving a damming density of 0.177 dams/km². Each historic dam that had since breached, 14 in total, was visited in the field to identify possible legacy sediment deposits. Legacy sediments were identified by their meter or higher terraces made of fine sands and silt and verified by comparison to sedimentary patterns found in other legacy sediment deposits and radiocarbon dating of material both within the legacy sediment and in the underlying layer. Legacy sediment terraces with an area of 1.68*10⁴ m² and a total volume of 1.29 - 2.57*10⁴ m³ were found upstream of two adjacent breached historic dam sites on the Charles River in Medway, MA. Radiocarbon dates from a coarse sand and gravel lower at 1.8 m depth returned pre-settlement dates of 1281-1391 cal AD (two σ). These dams were immediately downstream of a large glacial feature with steep banks along the river. The lack of legacy sediment at other dam sites and the lack of sedimentation behind intact dams suggest that a low sediment supply to millponds prevented legacy sediment deposits from forming in most of the watershed. / Thesis (BS) — Boston College, 2016. / Submitted to: Boston College. College of Arts and Sciences. / Discipline: Departmental Honors. / Discipline: Earth and Environmental Sciences.

Thesis advisor: Gail C. Kineke / This study characterizes the bed of the Connecticut River estuary in terms of grain size and bedforms, and relates these to river discharge, tidal currents, and sediment transport. Over four field excursions, sediment cores were collected, in addition to bathymetry surveys, and water column measurements. A three-dimensional circulation and sediment transport model calculated boundary shear stress over the same time. The bed of the estuary is composed mostly of sand, with small amounts of fine sediments. Deposition of fine sediments is limited by the landward extent of the salt intrusion. Large bedforms are oriented seaward. The critical shear stress for the median grain size is exceeded each tidal cycle. Bedload transport is dominantly seaward during high discharge conditions, but varies during low discharge. Bathymetry surveys from previous studies and this study show consistent bedform fields over 25 years. Bedforms observed in the field reflect typical conditions rather than extreme events. / Thesis (MS) — Boston College, 2015. / Submitted to: Boston College. Graduate School of Arts and Sciences. / Discipline: Earth and Environmental Sciences.

Only a small body of work currently exists regarding the geomorphology of humid tropical montane rivers. The research that does exist reports rapid geomorphic processes and high sediment loads compared to other montane rivers. This research applies traditional field survey methods combined with new applications of remote sensing techniques to examine the geomorphology and sediment dynamics of the montane portions of the Rio Pacuare in Costa Rica. A suite of geomorphic components (channel slope and width, lateral contributions and planform) are examined and a model presented that illustrates the complexity of the Rio Pacuare’s geomorphology and how the distribution of alluvial sediment varies in relation to geology (tectonics and lithology) and flow hydraulics (stream power). Next, average annual bedload sediment transport capacity is estimated using fifty-one years of daily discharge data at six different locations within the study area, including the temporal (monthly) variability of sediment flux due to dry versus wet season discharge regimes. Then, a time-step hydraulic model is created that simulates observed (modern) and potential future discharge scenarios based on regional climate change model results. The simulated discharge data for two locations within the study area is then integrated into the sediment transport model to examine how sediment flux, and thus channel geomorphology, is likely to change in response to changes in the river’s discharge regime.

Reservoir sediment flushing is increasingly considered beneficial to reduce sedimentation of reservoirs and maintain sediment supply downstream of impounded rivers. Nevertheless, flushing of the accumulated sediments downstream of the dam also bears numerous negative impacts. In this study, first the most important downstream impacts of fine sediment releases of flushing were identified based on previously published research of twenty case studies in eleven countries. The results showed that the long-term as well as short term biological and physical impacts decreased with distance from the dam. The temporal scale of impacts on macro-invertebrates could span from few weeks or a month to several months while the effect on fish could last for a number of years. The impacts on downstream vegetation dynamics is driven by many years of flushing activities. The study also enabled proposing generic management strategies aimed to reduce the impacts. Second, fine sediment transport in coarse immobile bed, which is a common phenomenon downstream of dams during flushing releases, dam removal and also in many mountain and canyon rivers, was investigated. Particularly, the dynamics of the downstream erosion and transport of fine sediments released during sediment flushing was investigated based on a series of flume experiments that were carried out in immobile gravel bed and using a one-dimensional (1-D) suspended sediment transport model developed in the present study. In the framework of the flume experiment, firstly gravel bed roughness, porosity and roughness density were exclusively extracted from gravel surface elevation data in which developing a spatial filter to overcome elevation errors was carried out. Secondly a new technique to acquire fine sediment erosion in immobile coarse bed in running water condition was developed. The method proved to be the back bone of all fine sediment erosion experiments conducted in the present study and could be used for similar studies. This study presents a first work of direct measurement of erosion rate and characterizing its spatial heterogeneity in gravel bed. The experimental data of erosion rate of fine sediments showed that it varied spatially with high erosion rate on the stoss side of gravels and less on the lee side conforming to sweeps and ejections characteristics in coherent flow structure of gravel bed flows. Erosion rate was significantly affected by increase in roughness of immobile gravel bed with high erosion rate noticed when sand level was reduced although the effect on stream-wise velocity was not significant. The vertical profile of erosion rate was found to decrease linearly and showed an exponential decay in time in the gravel matrix. Third, a new non-equilibrium erosion rate relation is proposed. Drag force profile in the interfacial sublayer of clean gravel bed was found to be scaled well with roughness density and allowed predicting the effective shear stress distribution available for fine sediment entrainment with an empirical equation. vi The new relation is a modified version of the pick-up rate function of van Rijn (1984b) in which the predicted shear stress in the roughness layer was implemented. The most important finding was that if the shear stress distribution in the interfacial sublayer is predicted, a relation for sand bed condition can be applied to predict fine sediment erosion rate in immobile gravel bed. This approach is conceptually superior to previous approaches where erosion rate in sand bed condition was scaled empirically for various fine sediment bed level within the interfacial sublayer. Finally, the effect of the interaction between hydrodynamic and sediment wave dynamics of sediment flushing on spatial pattern of sediment deposition was investigated. The 1-D model was developed to include major processes observed in sediment flushing: sediment wave celerity correction, variable bed roughness, bed exchange in immobile bed, hindered settling velocity and rough bed porosity. The proposed erosion rate relation showed encouraging results when implemented in the 1-D model. The wave celerity factor did not show significant effect on the spatial lag in immobile bed condition although was significant in sand bed condition. Variable bed roughness modified both the flow field and sediment deposition in which larger length of sediment deposit was noted. The immobile bed porosity allowed modelling clogged depth of fine sediments. The model was also found to be very valuable to investigate flushing scenarios that reduce significant deposition through the analysis of the dependence of deposition on peak-to-base flow and intermittence of releases. The highest peak-to-base flows produced the longest and thickest region of deposition while those with the lowest ratio produced the shortest and thinnest. A single flushing release followed by clear water release reduced area or length of sediment deposition more than intermittent flushing followed by inter- and post-flushing clear water releases. In the latter case, the peak of concentration reduced but remained higher for longer duration than the former, which suggests that a large quantity of clear water release has to be available. Overall, the present research represents a step forward in understanding relevant processes involved in the downstream transport of fine sediments released during sediment flushing and the associated impacts that can help the development of better management strategies and predictive tools.

The 9 km thick Lower Old Red Sandstone succession of the northern part of the Midland Valley Basin, Scotland, ranges from Wenlock to Emsian in age and largely comprises conglomerates in the east passing westwards into sandstones and siltstones. Previously, the depositional and tectonic setting of the basin has been poorly constrained, as has the relationship between sediments of the northern Midland Valley and the Grampian outliers at Aberdeen, Rhynie, Cabrach, Tomintoul and New Aberdour. This study focuses on establishing the stratigraphic framework of the areas and outlining the key controls and source of sedimentation during deposition of the Lower Old Red Sandstone, placing the geological history within the larger Caledonian framework. Sedimentological investigation alongside petrographical point count, heavy mineral and detrital zircon analysis allows the reconstruction of a large distributive fluvial system sourced from the NE within the Caledonian foreland, within which the Lower Old Red Sandstone of the northern Midland Valley Basin was deposited. Sedimentation was continuous across the line of the Highland Boundary Fault. Sedimentation within the Grampian outliers was locally influenced, however facies association development is comparable with the base of the laterally time-equivalent northern Midland Valley Basin stratigraphy. Sedimentary provenance analysis indicates a similar source terrane for the sediments of both areas, with detrital zircon age spectra comparable to those of the Dalradian Supergroup and localised contemporaneous volcanism, with conglomerate clast-size indicating a proximal source. Sedimentation of the Lower Old Red Sandstone of the northern Midland Valley Basin and Grampian outliers is thus attributed to Siluro-Devonian basement uplift in the Caledonian foreland driven by thick-skinned tectonics.