The aim of this study was to determine if and how especially dioxins but also metals (arsenic, copper and chromium) has spread and deposited in the sediments of Lövselefjärden in northern Sweden. The study was also meant to determine if these pollutions could be related to the previous sawmill that was located near the bay. A gravity sampler was used to extract sediment cores from the bottom of Lövselefjärden. Five sample locations were used, and in one of the locations three different depths were sampled. The results show a similar distribution of the dioxin congeners between the samples taken in the sediment and the chemical preparation used at the sawmill. There was also a similarity between the proportions of metals in the sediment and the solution with metals used at the sawmill. It was there for concluded that the pollution mainly originates from the sawmill. The amount of dioxins was above the guidelines from both USA and Canada for most samples. For the metals, the guideline for arsenic in both USA and Canada was exceeded in all the samples, for copper the guideline from Canada was exceeded in all the samples and two of the samples exceeded the guideline from USA. The chromium amount did not exceed any guidelines in this study. The pollutions appear to be transported outwards towards the ocean and superimposed by sediment deposited later. Further studies to determine the bioavailability of the pollution and to determine further how the pollutions have spread and superimposed in the sediment are necessary.

This study focuses upon flow hydraulics, sediment transport and riffle-pool maintenance on the River Rede, Northumberland, UK. Analysis of bed structure indicate pools to be coarser than riffles, suggesting these to be zones of maximum tractive force at high flow. Tractive force reversal can be demonstrated using a combination of velocity, shear stress and gravel tracer data, and is therefore advocated as a mechanism for maintaining the riffle-pool form. Three dimensional flow structures are likely to increase the likelihood of reversal in pools situated on bends, which may not always be detected using one-dimensional measures of flow hydraulics. Magnetic tracing and basket trapping techniques were used to provide an insight into rates of movement, accumulation, initial motion criteria and routing, of sand. Sand is transported selectively and is mobilised at between 11-22 Nm⁻². Deposition of sub 2mm material is prevalent on morphological high points (bars/riffle margins), although greatest quantities were routed through morphological lows. Freeze core evidence shows limited intragravel storage. Gravel tracer movements showed evidence of size selective entrainment overall, however hiding effects were also found to be evident at two scales; 30-50mm and 110-140mm (for riffles) and 20- 90mm and 11O-140mm for pool. Slope exponents for log-log relations between scaled grain size (D/D₅₀) versus dimensionless shear stress (Өc) of ≈-0.9 suggest that hiding strongly influences sediment transport. Stream power estimates from pgQs demonstrate a higher threshold for motion for gravel in pools (132 Wm⁻²) compared with riffles (127 Wm⁻²). Differences in initial motion criteria (8e) between riffles and pools were found to be significant (p<0.05), indicating pool sediments to be less mobile than riffle, despite pool sediments being less compact. Reduced mobility of pool bedload sediment results from clasts being sheltered by immobile lag gravel found in the pool. It appears therefore that mobility differences between riffles and pools, related to bed structure, does not explain riffle-pool maintenance on the Rede. Scaled travel distance (L/L₅₀s) for tracers in the reach as a whole showed a convex-up relationship with scaled grain size (D/D₅₀s), demonstrating that for tracer grains progressively coarser than the surrounding D₅₀ surface grains, travel distance drops off rapidly, whereas grains progressively finer than the surrounding clasts, travel further but at a less rapid rate. Furthermore, virtual velocity (V*) of tracer grains showed a positive dependence upon D/D₅₀s. Gravel tracer movement provided important insights into riffle-pool maintenance. Transfer of material through the Rede riffle-pool sequence appeared to be influenced by flow magnitude and duration. For low magnitude high frequency flows below 25% bankfull, intra-unit movement was found to predominate. Medium magnitude and frequency flows (up to 50% bankfull) appeared capable of inter-unit transport; scour from pool troughs and deposition on pool exit slopes I riffle heads, movement of material from riffles to bar edges and from bar to bar. For higher magnitude low frequency flows up to bankfull, there was less scour from pools, and a dominance of bar-to-bar sediment transfer. Limited evidence of sediment routing and deposition in pools suggest these to be scour / sediment source zones only, with supply originating from the bed and outer bank. These data demonstrate the importance of different flow magnitude and frequency in creating / maintaining different areas of the riffle-pool structure.

This study examines changes in lake-water total organic carbon (LW-TOC) and lake sediment geochemistry in two lakes, Stångtjärnen and Holtjärnen in (Dalarna, Sweden), during the Holocene and the role of the historic forest grazing and farming (fäbod-system). The aims of the study were to: 1. Discern the effects of natural processes on the lake’s biogeochemistry in different position in the landscape. 2. Identify the effects and differences in intensity of historic land-use on the lakes. A multi-proxy study was conducted encompassing multi-element (15) geochemistry, biogenic silica, LW-TOC, chlorophyll a and published pollen records. The first lake, Stångtjärnen, is shaped and influenced by surrounding mires, which developed shortly after deglaciation and stabilized the LW-TOC at 19 mg L-1 throughout most of the Holocene, while Holtjärnen, a small upland lake, changed from a productive lake (BSi: 35 %), low humic (LW-TOC: 8 mg L-1) to a less productive (BSi: 4 %) more humic lake (LW-TOC: 12 mg L-1) in 7300 BP. The intensification of agricultural land-use (e.g. hay-making) in Stångtjärnen reduced the concentrations of organic associated elements (Br, Cl) and LW-TOC and increased lithogenic elements (K, Ti), while Holtjärnen showed less anthropogenic influence. The comparison between the two lakes displayed the intensive influence of land-use on the Stångtjärnen catchment, showcased by changes in the sediment geochemistry, vegetation composition and the extent of the forest-grazing system in a landscape perspective. In response to the changes of the Holocene, Stångtjärnen’s mires became the main influence, while Holtjärnen was more sensitive to changes.

Scouring is the process of soil or sediment erosion due to flowing water, which can lead to bed degradation and compromised transportation infrastructure. In the decade before 2000, over half of the 500 bridge failures in the United States were caused by flooding or scouring. To gain a better grasp of the effects of extreme weather events, such as Tropical Storm Irene, on the scouring process, this work is focused on a first principle understanding of the mechanism(s) of scour. The field of Computational Fluid Dynamics (CFD) is particu larly well suited to this task. Utilizing a Direct Numerical Simulation (DNS) code, the repeated impacts of a vortex dipole on a particle bed are simulated. The resulting scour characteristics and flow dynamics are investigated as a function of the Shields number. The vortex dipole propagates perpendicularly to the particle bed, resulting in the scouring of the bed and dissipation of the dipole. After completion of the scour event, the simulation is repeated four more times, where subsequent simulations use the scoured bed from the previous simulation as the initial bed form. This simulation series is conducted over a Shields number parameter space. The fluid phase is treated as a continuum and the discretized Navier-Stokes equations are solved down to the smallest scales of the flow on an Eulerian grid. The particles comprising the bed are represented by the Discrete Particle Model (DPM), whereby each individual particle is tracked in a Lagrangian framework. Particle-particle and particle-wall collisions are calculated using a soft-sphere model. The fluid phase and the solid phase are coupled through a forcing term in the fluid conservation of momentum equation, and a drag force in the particle equation of motion, governed by Newton's Second Law. Above the critical Shields number, the scour hole topography is not fundamentally altered with subsequent impacts until the scale of the scour hole reaches a critical value. At which point, the shape and scale of the scour hole significantly alters the behavior of the vortex dipole and results in strongly asymmetric scour topographies. This two-way coupling between the bed scour and the vortex dipole dynamics is the focus of this work.

Changes in monsoon patterns not only affect ecosystems and societies but also the global climate system in terms of heat energy and humidity transfer from the equator to higher latitudes. However, understanding the mechanisms that drive monsoon variability on longer timescales remains a challenge, partly due to sparse paleoenvironmental and paleoclimatic data. This thesis, which contributes new hydroclimate data sets for the Asian monsoon region, seeks to advance our understanding of the mechanisms that contributed to Southeast Asian summer monsoon variability in the past. Moreover, it explores how past climatic conditions may have impacted societies and ecosystems. In this study lake sediment and peat sequences from northeastern and southern Thailand have been investigated using organic geochemistry, and more specifically the stable carbon and hydrogen isotopic composition of specific biomarkers (n-alkanes, botryococcenes, and highly branched isoprenoids). The hydrogen isotopic composition of leaf waxes (δDwax) in Thailand was shown to relate to the amount of precipitation and the extent of the El Niño Southern Oscillation.  Higher values of δDwax can be interpreted as reflecting relatively dry climatic conditions, whereas lower values relate to wetter conditions. The hydroclimate reconstruction for northeastern Thailand, based on the sedimentary record of Lake Kumphawapi, suggests higher moisture availability between ca. 10,700 cal. BP and ca. 7,000 cal. BP likely related to a strengthened early Holocene summer monsoon. Moisture availability decreased during the mid-Holocene, but seems to have increased again around 2,000 years ago and has fluctuated since. The high-resolution Lake Pa Kho peat sequence, which allows for a sub-centennial reconstruction of moisture availability, indicates that the wettest period occurred between ca. 700 and ca. 1000 CE whereas driest intervals were from ca. 50 BCE to ca. 700 CE and from ca. 1300 to ca. 1500 CE. Hydroclimate comparison of Pa Kho’s δDwax record with other paleoclimate records from the Asian-Pacific region suggests that El Niño-like conditions led to Northeastern Thailand being wetter, whereas La Niña-like conditions led to drier conditions. Regional hydroclimate variability also greatly influenced the Angkor Civilization, which flourished between ca. 845 and ca. 1450 CE. The shift from drier to wetter conditions coincided in time with the rise of the Angkor Civilization and likely favored the intense agriculture needed to sustain the empire. The gradual decline in moisture availability, which started after ca. 1000 years CE, could have stretched the hydrological capacity of Angkor to its limit. It is suggested that Angkor’s population resorted to unconventional water sources, such as wetlands, as population growth continued, but summer monsoon rains weakened. The 150-year long record of Lake Nong Thale Prong in southern Thailand offers insights into decadal-scale hydroclimatic changes that can be connected to the instrumental record. δDwax-based hydroclimate was drier from ~1857 to 1916 CE and ~1970 to 2010 CE and wetter from ~1916 to 1969 CE. Drier climatic conditions between ~1857 and 1916 CE coincided with oligotrophic lake waters and a dominance of the green algae Botryococcus braunii. Higher rainfall between ~1916 and 1969 CE concurred with an increase in diatom blooms while eutrophic lake water conditions were established between ~1970–2010 CE. / <p>At the time of the doctoral defense, the following papers were unpublished and had a status as follows: Paper 2: Submitted. Paper 3: Manuscript.</p> / Monsoon project

The presented paper aims at the problems of fluvial lakes in middle course of the Elbe River which has been influenced by the human activity since the Middle Ages. The oxbow lakes which are extremely precious ecosystems contributing to the stability of the river ecosystem show not only the changes of the course of the Elbe River. With regard to sedimenting a great amount of pollutants, these lakes also tell about the industrial pollution to which the river was exposed mainly in the second half of the 20th century due to insufficient precautions on industrial sources causing contamination. 5 cut lakes between Hradec Králové and Mělník have been studied within this research. These lakes differ in the intensity of communication with the river, in the distance from significant sources of industrial pollution and in the use of nearby land. The research included morphometric and bathymetric measures, observation of hydrological regime, seasonal measures in the water column and regular analysis of surface water samples. Profiles of sediments in the length that the used technology allowed were sampled, so that older anthropogenic load could be found out. The amount of organic carbon and concentration of selected metal and arsenic (Ag, Cd, Cr, Cu, Fe, Hg, Mn, Pb and Zn) were stated apart from grain size...

Hillslopes comprise the majority of unglaciated upland landscapes; they are the primary source for the production of sediment from bedrock, and the routing system by which sediment is delivered to the channel network. Yet the nature of hillslope response to changes in tectonic, climatic or base-level boundary conditions is poorly understood in terms of the spatial and temporal distribution of hillslope morphology. Here I exploit a previously published framework for exploring hillslope morphology in high relief landscapes (Roering et al., 2007), to address several critical questions: Does high resolution topography allow understanding of the processes and rates by which sediment is redistributed on hillslopes? If so, can hillslope morphology be used to map the spatial distribution of erosion rates and facilitate interpretation of the timing and magnitude of tectonic forcing, particularly in transient landscapes which are adjusting their erosion rates? And to what extent does variation in lithology influence hillslope evolution and morphology, and the ability to interpret process rates from hillslope form? In this thesis I sought to explain hillslope adjustment to changing boundary conditions through combining the predictions of analytical and numerical models with detailed analysis of real, high resolution topographic datasets (derived from LiDAR), focusing on two landscapes where the influence of tectonic forcing on base-level history is relatively well constrained, the Middle Fork Feather River in the northern Sierra Nevada, and the Dragon’s Back Pressure Ridge, on the Carrizo Plain, both in California. The Sierra Nevada of California is a west-tilted fault block composed primarily of granitoids formed during Mesozoic arc volcanism. The block underwent acceleration in uplift 5 - 3.5 Ma which is hypothesised to be caused be the drop-off of a dense root from the lower crust and replacement by hot asthenosphere, causing crustal buoyancy. A relict landscape has thus been uplifted and dissected by the major drainage routes crossing the range, which have eroded rapidly to form deep canyons. The fluvial network is characterised by breaks in slope (knickpoints) which migrate into the landscape to transmit the signal of increased erosion, setting baselevel conditions for adjacent hillslopes. Theoretical predictions for the morphology of hillslopes governed by a nonlinear sediment transport law, if the hillslopes have attained steady state (i.e. they are eroding in concert with base-level fall in adjacent valleys) reveal that the curvature of hilltops will be linearly proportional to erosion rates or rate of base-level fall. I present innovative techniques to extract hilltop networks and sample their adjacent hillslopes in order to test the utility of hilltop curvature for estimating erosion rates. This work is carried out in granitoid lithologies where the influence of bedrock heterogeneity is assumed no to be a first order control on hillslope morphology. Existing and new cosmogenic radionuclide analyses in the Feather River basin, California, suggest that erosion rates vary by over an order of magnitude from the remnant upland landscape to the incised river canyon. Hilltop curvature increases with erosion rates, allowing calibration of the hillslope sediment transport coefficient, which controls the relationship between hillslope gradient and sediment flux. This in turn allows the estimation of erosion rates throughout the landscape by mapping the spatial distribution of hilltop curvature. Additionally, despite the landscape containing gradient-limited hillslopes, hilltop curvature continues to increase with rising erosion rates, reflecting higher erosion rates than can be predicted by hillslope gradient. The distribution of hillslope morphology conforms well to predictions of a nonlinear sediment transport model, with measured values of hillslope relief varying with the product of hilltop curvature and hillslope length (proxy for erosion rate) in a manner similar to that predicted by Roering et al. (2007). Hilltop curvature can thus be used to estimate erosion rates in landscapes undergoing a transient adjustment to changing boundary conditions provided that the response timescale of hillslopes is short relative to channels. Having focused on a landscape with roughly uniform bedrock geology to isolate drivers of geomorphic change, I sought to evaluate whether these techniques could be extended across lithologic contacts and throughout the landscape. Underlying geology influences the efficacy of soil production and transport on hillslopes, and resistance to erosion by valley-forming processes. Here, quantitative analysis of LiDAR digital terrain models was performed to search for a topographic signature in two distinct lithologies in the Feather River catchment in northern California; granodiorite and deformed volcanics. The two sites, separated by <2 km and spanning similar elevations, are assumed to have similar climatic and denudation histories. Responding to increased erosion rates, transient hillslopes exhibit high gradient but low hilltop curvature in the metavolcanics relative to theoretical predictions for steady state hillslopes. However, hillslopes in the granodiorite have, for the most part, variation in hilltop curvature, hillslope length and hillslope relief similar to model predictions for steady state hillslopes. The curvature of hilltops adjacent to main stem channels implies that the coefficient of sediment transport is two times larger in the granodiorite (c. 8.8 m2 ka-1) than in the metavolcanics (c. 4.8 m2 ka-1). The data suggest that hillslopes get shorter as erosion rates increase due to the increased influence of debris flows in valley incision, suggesting that drainage density increases with erosion rate. The incision wave associated with more rapid erosion in the Feather River has propagated further into a basin developed on the metavolcanics and hence this substrate is less resistant to channel incision. I review an inventory of values for the transport coefficient for hillslope sediment transport but find that no clear patterns emerge with varying lithology. However in unconsolidated substrates, precipitation may play an important role in modulating sediment transport through variation in rain splash impact frequency and the frequency of wetting/drying, freeze/thaw, and expansion/contraction cycles. Finally I apply the same techniques to study hillslope morphology to a landscape where the tectonic history has a documented influence on landscape development. The Dragon’s Back pressure ridge, Carrizo Plain, CA, consists of a series of small catchments adjacent to the San Andreas fault, where previous detailed geologic mapping has allowed the spatial and temporal distribution of uplift to be constrained. This landscape offers a hitherto unique opportunity to study the temporal evolution of hillslope morphology via ergodic substitution. I show that the time evolution of a sensitive indicator of erosion rate, hilltop curvature, can be predicted using a nonlinear sediment flux law. Further to this, the temporal evolution of relief and hilltop curvature experiences hysteresis as the landscape grows and decays. Relative to steady-state predictions, hillslope morphologies exhibit higher than expected values for relief during active uplift or landscape growth, and lower than expected relief during landscape decay. Therefore landscapes growing due to fault activity can be distinguished from those with quiescent faults undergoing topographic decay.

Mountain watersheds recently burned by wildfire often experience greater amounts of runoff and increased rates of sediment transport relative to similar unburned areas. Given the sedimentation and debris flow threats caused by increases in erosion, more work is needed to better understand the physical mechanisms responsible for the observed increase in sediment transport in burned environments and the time scale over which a heightened geomorphic response can be expected. In this study, we quantified the relative importance of different hillslope erosion mechanisms during two postwildfire rainstorms at a drainage basin in Southern California by combining terrestrial laser scanner-derived maps of topographic change, field measurements, and numerical modeling of overland flow and sediment transport. Numerous debris flows were initiated by runoff at our study area during a long-duration storm of relatively modest intensity. Despite the presence of a well-developed rill network, numerical model results suggest that the majority of eroded hillslope sediment during this long-duration rainstorm was transported by raindrop-induced sediment transport processes, highlighting the importance of raindrop-driven processes in supplying channels with potential debris flow material. We also used the numerical model to explore relationships between postwildfire storm characteristics, vegetation cover, soil infiltration capacity, and the total volume of eroded sediment from a synthetic hillslope for different end-member erosion regimes. This study adds to our understanding of sediment transport in steep, postwildfire landscapes and shows how data from field monitoring can be combined with numerical modeling of sediment transport to isolate the processes leading to increased erosion in burned areas.

Morphological changes along several channels have raised concerns in the Province of Manitoba. This thesis presents a comprehensive study of fluvial morphological processes in open channels. Due to the recent concerns in the Province of Manitoba, the study mainly focused on the Red River in the city of Winnipeg, and two diversion channels in northern Manitoba. Morphodynamic conditions of these channels have become more complicated due to the cohesive nature of the channels bed and bank material and significant effects of subaerial processes. Several field measurement techniques, experimental setups, and numerical models were used to gain a better understanding of these complicated processes within the study reaches. Field measurements include soil sampling, water sampling, hydrometric surveys using an ADCP; the experimental setup includes several standard soil properties tests as well as an erosion measurement test; numerical modelling includes hydrodynamic and thermal modelling to quantify applied shear stress and seasonal freeze-thaw processes. Moreover, the effect of deposition processes on the final geomorphology of the study areas is discussed. / October 2016

On August 29, 2005 Hurricane Katrina struck the Gulf Coast and storm surges breached levees flooding much of New Orleans, Louisiana. One month after the storm, sediment was collected and toxicity was tested using Japanese medaka (Oryzias latipes) embryos. Sediments with the highest contaminant levels showed the highest embryonic mortality and most delayed development. However, no sediment caused an increased mutant frequency. When the most contaminated site was resampled in February, 2006 contaminant levels and toxicity decreased. During toxicity testing, approximately 20% of embryos incubated with sediment from one of these sites died and turned red. A red bacterium was isolated that is Gram-negative, cocco-baccilus, non-motile, and most similar to Hahella chejuensis based on genetic and metabolic tests. This bacterium caused 100% infection at 108 bacterial cells per ml and variable infection at lower doses. This study was the first to examine biological effects of exposure to post-Hurricane Katrina sediments.