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Coagulation process characteristics and pollutant removal from urban runoffNyström, Fredrik January 2019 (has links)
Many different stormwater control measures (SCMs) can be implemented in order to mitigate issues with polluted stormwater flows into receiving water bodies. The treatment function of SCMs is commonly based on the removal of particles by sedimentation, thereby also removing pollutants associated with particles. In recent years, more attention has been given to characterizing and understanding of different particle size fractions and their association with pollutants commonly found in stormwater. It has become increasingly clear that the smaller sized particles are very important pollutant transporters and should be considered when designing and implementing SCMs. However, the settling velocities for smaller sized particles are very low and may not be effectively removed in existing SCMs. One treatment process with a proven ability to enhance sedimentation is coagulation/flocculation, widespread in water and wastewater treatment, but with very few accounts of it being used in a stormwater context. This thesis aims to investigate the treatability of stormwater with a coagulation/flocculation process. This includes the determination of operating conditions, the dominating coagulation mechanism and the reduction efficiency of stormwater related pollutants. The objectives of the thesis were achieved in laboratory tests treating stormwater in a jar-testing procedure. An initial screening of primary coagulants and flocculant aids was conducted using an urban snowmelt mixture. Five of the chemicals were then selected for an extended testing regime which was setup up to determine the operating conditions where maximal turbidity reduction was attained by measuring the pH, conductivity, alkalinity and zeta-potential over the tested doses for each coagulant. Criteria used for chemical selection included high turbidity reduction, low dose requirement and low pH/alkalinity impacts. Charge reversal was observed at positive zeta-potential indicating that the dominating coagulation mechanism was charge neutralization. The content of turbidity/total suspended solids, total organic carbon, total metals and hydrocarbons by >90%. Dissolved copper was reduced by 40% on average, and the reduction rates for dissolved zinc were varying with up to a 300% increase, presumably due to changes in pH, leading to a higher mobility. Changes in the particle size distribution after coagulation/flocculation as compared to sedimentation indicated an effect on the size fraction corresponding to smaller particles. The performance of the coagulation/flocculation process was also tested on road runoff collected from a central road in Luleå with a high traffic intensity. Two coagulants were tested, iron chloride and pre-hydrolyzed aluminum chloride. Reduction rates for the total metal fraction were >90% on average for both coagulants, but for the dissolved metal fractions differences could be observed between the coagulants with the iron chloride resulting in higher reductions for dissolved chrome (57% compared to 34%) and copper (47% compared to 30%). Both products increased the dissolved fractions of nickel and zinc due to lower final pH.
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Variations in the partial pressure of carbon dioxide within the Indalsälven River system : An analysis of multi-year data of several parameters to get an insight into the functioning of sub-artic river pCO2 spikes.Cuijpers, David Leon January 2023 (has links)
Climate change has, in recent decades, warmed the climate and changed carbondynamics in land and water systems. For example, temperature and precipitation canchange carbon dynamics and cause largely unknown consequences. This researchuses data from a unique measuring station near Kattestrupeforsen, Jämtland, Sweden, in order to answer the question of how the pCO2 (ppm) concentration of the water in the local area reacts to changes in the factors of air/water temperature, solar irradiation, precipitation, turbidity, water level and water inflow into the area. This was analysed using a visual analysis of the peaks that occur in the pCO2 and a statistical regression analysis of peak pCO2 events and for each yearly quarter as well as for the identified peak events. Moreover, the limited amount of available turbidity data was visually analysed to comprehend how it correlates with the pCO2 values. The results indicate that the turbidity data available has no visible correlation, possibly due to a lack in data. Temperature data appeared to be responsible for some of the variation seen, although likely more as a conditional value. Irradiation and precipitation data gave inconsequent results and are not deemed likely to influence the peaks in pCO2 in the time scale analysed. Water level and streamflow showed the most stable and significant correlation of all parameters analysed, although they remained relatively inconsistentin their ability to explain pCO2 peaks seen. / <p>2024-03-06</p>
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Analyse des effets de la végétation sur le couvert de neige dans la zone de transition arctique-subarctique par mesures in-situ et télédétection optique (Nunavik)Busseau, Bruno-Charles January 2017 (has links)
Plusieurs études récentes démontrent que la prolifération de la végétation dans le Nord a augmenté sous un climat en réchauffement lors des quatres dernières décennies, surtout dans la zone de transition entre toundra et taïga. L’accroissement des arbustes a un effet sur les propriétés de la neige et du bilan d’énergie de surface. L’objectif de cette recherche est d’améliorer la caractérisation de l’impact des arbustes sur l’évolution de la neige (accumulation et fonte) en utilisant des données terrains et la télédétection. La recherche a été réalisée sur le site d’Umiujaq, au Nunavik, représentatif de la zone de transition entre l’Arctique de basse latitude et les zones subarctiques. La profondeur de neige, mesurée le long de nombreux transects qui couvrent plusieurs types de végétation (toundra arbustive, toundra de lichen, forêt ouverte et forêt fermée d’épinettes) démontre l’effet d’emprisonnement de la neige dans la zone de transition entre une zone de toundra arbustive vers une zone de forêt d’épinettes. Cet effet est lié à la hauteur de la végétation et à la perte de densité (la profondeur de neige augmente par des facteurs de 2,5 à 3). De plus, des mesures de profondeur de neige en continue ont été prises par deux stations météorologiques situées l'une en zone de toundra arbustive et l'autre en zone de forêt. Les résultats montrent que la neige réagit de façons très différentes selon la couverture du sol, mais reste très dépendante des sites considérés. Des analyses spatiales à très haute résolution (Pléiades) et à moyenne résolution (Landsat et MODIS) suggèrent un délai dans la fonte entre les zones de forêts et les zones de toundra de lichen et arbustives. Une technique de mesure de profondeur de neige par télédétection à haute résolution est aussi discutée. / Abstract : Recent studies have shown that northern vegetation has been growing in relation to a warming climate over the last four decades, especially across the transition zone between tundra and taiga. Shrub growth affects snow properties and the surface energy budget, which must be better studied to quantify shrub-snow-climate feedbacks. The objective of this research is to improve the characterization of the impact of shrubs on snow evolution, from its accumulation to its melt, using in-situ and satellite measurements. The research is presented for the Umiujaq site, Nunavik, representative of the low Arctic – Subarctic transition zone. Snow depth, measured along numerous transects spanning different land cover types is found to increase by a factor 2.5 to 3 between tundra and forest, while snow density decreases. This illustrates the trapping effect of vegetation well. Complementary continuous snow depth measurements using weather stations from two sites (tundra with low shrubs and a small clearing with shrubs within the forest) show different site-dependent behaviors. Spatial analysis from high-resolution Pleiades images combined with Landsat (Normalized Difference Snow Index) and MODIS (Fractional Snow Cover) images suggest a slight delay in melt over open and dense forest areas compared to tundra and dense high shrubs. A technic to measure snow depth using high resolution is also discussed.
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Změny podílu pevných a kapalných srážek v chladném půlroce a jejich vliv na jarní odtok z vybraných horských povodí / Changes in snowfall fraction in cold season and their impact on spring runoff in selected mountain catchmentsBlšťák, Adam January 2018 (has links)
The precipitation falling as rain or snow has different impact on regional water resources and their annual distribution. Shift from solid to liquid form of precipitation following the increase of the surface air temperatures could be important because such change could influence the timing of spring runoff and cause water scarcity in summer. In this study, the spatial and temporal variations of ratio of snowfall to total precipitation (Sf), mean air temperature, day of year of melt-out and winter and spring runoff is analysed. Data were examined for 11 meteorological and 6 hydrological stations in the mountains catchment in Czechia for November-April 1965-2014. Data were analyzed using the Mann-Kendall trend test. Major results show that Sf has been decreasing strongly throughout the whole examined area, with the strongest decrease in the foothill area of the northern mountains of Czechia. Stronger decrease is observed in lower elevations, at the stations with meant air temperature close to melt temperature. Strongest decrease was observed in March and the weakest decrease was observed in December and April, The significant decreases in Sf are associated with large increase in mean winter air temperatures. Due to the increasing mean air temperature in the cold season, the total rainfall is...
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The Study of Temporal and Spatial Variability of Degree Day Factor of Snowmelt in ColoradoPokhrel, Pranav 05 1900 (has links)
Snowmelt is one of the major sources of surface water supply and ground-water recharge in high elevation areas and can also cause flooding in snow dominated watersheds. Direct estimation of daily snowmelt requires daily snow water equivalent (SWE) measurements that are not always available, especially in places without monitoring stations. There are two alternative approaches to modeling snowmelt without using direct measurements of SWE, temperature-based and energy-based models. Due to its simplicity, computational efficiency, and less input data requirement, the temperature-based method is commonly used than the energy-based method. In the temperature-index approach snowmelt is estimated as a linear function of average air temperature, and the slope of the linear function is called the degree-day factor (DDF). Hence, the DDF is an essential parameter for utilizing the temperature-based method to estimate snowmelt. Thereby, to analyze the spatial properties of DDF, 10 years DDF from the entire state of Colorado was calculated for this research. Likewise, to study the temporal properties, DDFs for 27 years from the White Yampa water basin and the Colorado Headwaters water basin were calculated.
As a part of the spatial analysis, the calculated DDFs were correlated with spatial variables (slope, aspect, latitude and elevation) and a spatial correlation graph was created to observe the possibility of predicting DDF. Also a multivariate regression model was prepared using these spatial variables to predict the DDF using spatial variables. Further, the DDFs calculated from Colorado headwaters and the White Yampa water basins were correlated for annual temporal variation, daily variation, variation with peak snow water equivalent and variation with important temporal cycles like accumulation period and melting period of snowmelt. The result obtained from this study showed that the variability of DDF is more dependent upon temporal factors compared to the spatial factors. Also, the results showed that predicting DDF is a difficult process and requires complex methods than simple linear models or multivariate models.
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Environmental and Adaptive Buffers that Mediate the Response of Subalpine Ecosystems to Environmental ChangeConner, Lafe G. 01 June 2015 (has links)
This document reports the results of 4 studies of subalpine ecosystem ecology, describing ways that spatial heterogeneity in soils and plant communities mediate ecosystem responses to environmental change. Ecosystem responses to environmental change are also mediated by regional climate patterns and interannual variability in weather. In the first chapter we report the results of an experiment to test for the mediating effects of associational resistance in a forest community that experienced wide-spread beetle kill. We found that Engelmann spruce were more likely to survive a beetle outbreak when growing in low densities (host dilution) and not through other types of associational resistance that relate to higher tree-species richness or greater phylogenetic diversity of the forest community. In the second chapter we report the effects of early snowmelt on soil moisture in subalpine meadow and aspen communities. We found that soil organic matter, soil texture, and forest cover mediated the effects of early snowmelt and were more important drivers of growing-season soil moisture than was snow-free date. In the third chapter we report the effect of early snowmelt on growth and seed production of early-season and midsummer herbaceous species. We found that the primary effect that snowmelt timing had on plant growth was through its effect on species distribution. Changes in the timing of snowmelt had limited effect on the growth, flowering, and seed count of species after they were established. In the final chapter, we report the effect of early snowmelt on soil respiration, microbial biomass, dissolved organic carbon and soil organic carbon. We found that early snowmelt resulted in warmer soil temperatures compared to neighboring snow-cover plots, and that microbial biomass and soil respiration showed no signs of a snowmelt legacy effect during the growing season. Soil organic carbon in rapid and slow-turnover pools was affected more by plant community than by snowmelt timing, and the primary drivers of soil respiration during the snow-free period were first soil organic matter and second soil temperature. Taken together, this dissertation reports our findings that subalpine ecosystems are resilient to environmental change in part because organisms in these systems are adapted to environmental conditions that are highly variable between sites, seasons, and years.
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Investigation of techniques for improvement of seasonal streamflow forecasts in the Upper Rio GrandeLee, Song-Weon 01 November 2005 (has links)
The purpose of this dissertation is to develop and evaluate techniques for improvement of seasonal streamflow forecasts in the Upper Rio Grande (URG) basin in the U.S. Southwest. Three techniques are investigated. The first technique is an investigation of the effects of the El Ni??o/Southern Oscillation (ENSO) on temperature, precipitation, snow water equivalent (SWE), and the resulting streamflow at a monthly time scale, using data from 1952 to 1999 (WY). It was seen that the effects of ENSO on temperature and precipitation were confined to certain months, predominantly at the beginning and end of the winter season, and that the effect of these modulations of temperature and precipitation by ENSO can be seen in the magnitude and time variation of SWE and streamflow.
The second part is a comparison of the use for snowmelt-runoff modeling of the newly available snowcover product based on imagery from the satellite-borne Moderate Resolution Imaging Spectroradiometer (MODIS) with the long-time standard snowcover product from the National Hydrological Remote Sensing Center (NOHRSC). This comparison is made using the Snowmelt Runoff Model (SRM) in two watersheds located inside the URG basin. This comparison is important because the MODIS snowcover product could greatly improve the availability of snowcover information because of its high spatial (500m) and temporal (daily) resolutions and extensive (global) coverage. Based on the results of this comparison, the MODIS snowcover product gives comparable snowcover information compared to that from NOHRSC.
The final part is an investigation of streamflow forecasting using mass-balance models. Two watersheds used in the comparison of MODIS and NOHRSC snowcover products were again used. The parameters of the mass-balance models are obtained in two different ways and streamflow forecasts are made on January 1st, February 1st, March 1st and April 1st. The first means of parameter estimation is to use the parameter values from 1990 to 2001 SRM streamflow simulations and the second means is by optimization. The results of this investigation show that mass-balance models show potential to improve the long-term streamflow forecasts in snowmelt-dominated watersheds if dependable precipitation forecasts can be provided.
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Geochemical and isotopic mixing models : two case studies in a snow-dominated and semi-arid environmentHuth, Anne M. Kramer. January 2003 (has links)
The influence of climate and antecedent moisture conditions on hydrological and biogeochemical fluxes was studied and contrasted in three nested, high-elevation, snowmelt-dominated catchments in the Sierra Nevada, California and one basin-floor, semi-arid catchment in southeastern Arizona. Investigations were completed within a different two-year period at each site, with the second year being climatically different (typically drier) than the first. Spring snowmelt, widespread winter frontal precipitation, and episodic summer rains induce surface water flow in these catchments, though the timing and magnitude of nutrient redistribution among soil and stream compartments varies in each. Surface water flow from spring snowmelt in high-elevation catchments travels through the subsurface or across the surface as direct runoff A more typical process producing surface water flow in semi-arid catchments is flooding during episodic or widespread rainfall. Hydrograph separations at Emerald Lake, Topaz Lake and Marble Fork catchments in Sequoia National Park, California, revealed that the majority of snowmelt flowed through soil before entering the stream in both average and highsnow years. The Emerald Lake watershed had a higher fraction of old water in its outflow in the average accumulation year because of the previous year's high accumulation and longer melt season. A mixing model analysis performed of the upper San Pedro River, Arizona, for wet and dry years showed that summer flood hydrographs were composed mainly of precipitation and surface runoff in both years, though a higher soil-water input occurred in the wetter year and in early season floods in the dry year. Stream and soil water nitrate concentrations were higher during floods in the dry year. Early season floods in the dry year exhibited more variability in stream water nitrate and sulfate, whereas late season flood concentrations reflected a well-mixed system and therefore less variation of these species during flood hydrographs. These data showed that periods of below average precipitation preceding major runoff periods result both in less soil water and solute export during summer floods in basin-floor catchments and less direct snowmelt in high-elevation catchments. Hydrologic and solute export in each catchment, despite their differing geographical locations, responds in similar ways to climate variability.
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Impact of climate change on the snow covers and glaciers in the Upper Indus River basin and its consequences on the water reservoirs (Tarbela reservoir) – Pakistan / Impact du changement climatique sur les couvertures neigeuses et les glaciers dans le Haut Bassin de l'Indus et ses conséquences sur les ouvrages hydrauliques (Réservoir de Tarbela) – PakistanTahir, Adnan Ahmad 21 September 2011 (has links)
L'économie du Pakistan, fondée sur l'agriculture, est hautement dépendante de l'approvisionnement en eau issu de la fonte de la neige et des glaciers du Haut Bassin de l'Indus (UIB) qui s'étend sur les chaînes de l'Himalaya, du Karakoram et de l'Hindukush. Il est par conséquent essentiel pour la gestion des ressources en eau d'appréhender la dynamique de la cryosphère (neige et glace), ainsi que les régimes hydrologiques de cette région dans le contexte de scénarios de changement climatique. La base de données satellitaire du produit de couverture neigeuse MODIS MOD10A2 a été utilisée de mars 2000 à décembre 2009 pour analyser la dynamique du couvert neigeux de l'UIB. Les données journalières de débits à 13 stations hydrométriques et de précipitation et température à 18 postes météorologiques ont été exploitées sur des périodes variables selon les stations pour étudier le régime hydro-climatique de la région. Les analyses satellitaires de la couverture neigeuse et glaciaire suggèrent une très légère extension de la cryosphère au cours de la dernière décade (2000‒2009) en contradiction avec la rapide fonte des glaciers observée dans la plupart des régions du monde. Le modèle « Snowmelt Runoff » (SRM), associé aux produits neige du capteur MODIS a été utilisé avec succès pour simuler les débits journaliers et étudier les impacts du changement climatique sur ces débits dans les sous-bassins à contribution nivo-glaciaire de l'UIB. L'application de SRM pour différents scénarios futurs de changement climatique indique un doublement des débits pour le milieu du siècle actuel. La variation des écoulement de l'UIB, la capacité décroissante des réservoirs existants (barrage de Tarbela) à cause de la sédimentation, ainsi que la demande croissante pour les différents usages de l'eau, laissent penser que de nouveaux réservoirs sont à envisager pour stocker les écoulements d'été et répondre aux nécessités de l'irrigation, de la production hydro-électrique, de la prévention des crues et de l'alimentation en eau domestique. / Agriculture based economy of Pakistan is highly dependent on the snow and glacier melt water supplies from the Upper Indus River Basin (UIB), situated in the Himalaya, Karakoram and Hindukush ranges. It is therefore essential to understand the cryosphere (snow and ice) dynamics and hydrological regime of this area under changed climate scenarios, for water resource management. The MODIS MOD10A2 remote-sensing database of snow cover products from March 2000 to December 2009 was selected to analyse the snow cover dynamics in the UIB. A database of daily flows from 13 hydrometric stations and climate data (precipitation and temperature) from 18 gauging stations, over different time periods for different stations, was made available to investigate the hydro-climatological regime in the area. Analysis of remotely sensed cryosphere (snow and ice cover) data during the last decade (2000‒2009) suggest a rather slight expansion of cryosphere in the area in contrast to most of the regions in the world where glaciers are melting rapidly. The Snowmelt Runoff Model (SRM) integrated with MODIS remote-sensing snow cover products was successfully used to simulate the daily discharges and to study the climate change impact on these discharges in the snow and glacier fed sub-catchments of UIB. The application of the SRM under future climate change scenarios indicates a doubling of summer runoff until the middle of this century. This variation in the Upper Indus River flow, decreasing capacity of existing reservoirs (Tarbela Dam) by sedimentation and the increasing demand of water uses suggests that new reservoirs shall be planned for summer flow storage to meet with the needs of irrigation supply, increasing power generation demand, flood control and water supply.
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Analýza rozhodujících příčinných faktorů z hlediska tvorby erozního smyvu z tání sněhové pokrývky / Analysis of the decisive causal factors from the viewpoint of erosion creation from the melting of the snow coverMoravcová, Aneta Unknown Date (has links)
Currently there is no suitable and commonly used device for volumetric quantification of snowmelt erosion in the Czech Republic (CR). The determination of erosion rate in the catchment is a essential prerequisite for the correct design of conservation measures. The thesis tries to offer the possible ways of monitoring the snowmelt erosion, compares individual methods and defines their optimal use. In the first year of the research, a runoff plot was developed to capture sheet erosion. The thesis compares also the methods using mobile devices - erosion bridge method and UAV photogrammetry - as effective instrument for snowmelt erosion monitoring. So far, no attention has been paid to snowmelt erosion in CR. Therefore, the thesis focuses mainly on the analysis of causal factors specific to this type of erosion - the erosion potential of snow cover and the possible soil erodibility changes due to freeze-thaw cycles. The thesis assesses the rate of snowmelt erosion risk in selected climatically different catchments and its changes in recent years. shows the timeliness of the problem. In the end, the thesis presents possibilities for solving the problem. The thesis claims the problem of snowmelt erosion actual and offers its possible solution.
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