Carbon isotope analyses of gases extracted from drilling muds while drilling in the Western Canada Sedimentary Basin (WCSB) can be used to create carbon isotopic depth profiles. These profiles provide essentially continuous data through the stratigraphic section, offering a unique opportunity to study the in-situ gases in various rock matrices. Carbon isotope and molecular compositions of Jurassic - Cretaceous mud gases have been examined from ten depth profiles in the undisturbed WCSB. The isotopic profiles are surprisingly complex, showing numerous inflections and deviations towards increasing and decreasing carbon isotope values (13C) and wetness index with depth that suggest a correlation with the stratigraphic framework and can be explained in terms of the origin and alteration of the gases. However, the gas isotope geochemistry must be incorporated and applied in a multidisciplinary approach in order to gain a better understanding of causes of variations. The discernible degree of correlativity of carbon isotope trends between the WCSB wells are likely to be related to the presence of major gas compartments bounded by stratigraphic surfaces, compartmentalization of the gas being strongly influenced by stratigraphic variations. The majority of these boundaries act as effective barriers to gas migration. Mudgas geochemistry is best employed in conjunction with petrophysical analysis and conversion into mineralogy, for defining details of transition zones and reservoir compartments. Combined evidence suggests that isotopic variability of WCSB gases is only partly induced by source maturity at one single location. The main shifts of carbon isotope ratios are likely to be related to the physical properties of the rocks, differences between organic precursors (type II versus type III kerogen), total organic carbon (TOC) content, gas biodegradation and mixing. The present thesis demonstrates that the carbon isotopic mud gas profiles represent a powerful tool that provide information about the compartmentalization of the gas, the effectiveness of low permeability barriers, the origin, alteration and maturity of gases, and the regional gas dynamics. Mudgas geochemistry proves to be one part of the puzzle in the investigation of regional gas dynamics, and should be integrated with geological information, lithostratigraphic-, and sequence stratigraphic information, petrographic information and geophysical data.

Integrated sequence stratigraphy and geochemistry has significantly improved our knowledge of the formation and distribution of early and late diagenetic products in North American Mississippian carbonates. Deposition of the Madison Limestone occurred in concert with a major perturbation to the global C-pool, the timing of which was constrained by comparing secular variations in the delta13C values from the Madison Limestone with limited biostratigraphy. These early constraints were then improved by peak matching of 87Sr/86Sr values from this study with European brachiopod 87Sr/86Sr. The secular variations in the delta13C values were then applied as a chronostratigraphic tool to outcrops and subsurface core. As a result, our sequence stratigraphic interpretations and knowledge regarding lateral facies variability in carbonate rocks is significantly improved. Geographic variability in the magnitude of the delta13C values is also documented along the dip-transects which suggests that marine waters experienced increasing restriction in a landward direction. These results show how local changes to the C-pool are controlled by the morphology of the depositional system which can significantly affect the original signal of the global carbon pool. The geographic variability in the delta13C and delta18O values from reservoir quality dolomites along the mid-to-upper Madison ramp suggest they also precipitated from a restricted water mass with increased salinity, temperature and alkalinity which in turn, were responsible for the distribution of massive quantities of strataform dolomite deposited during the continental transgression at the beginning of the Mississippian. Trace element and 87Sr/86Sr values from strataform dolomite suggest initial formation from Mississippian seawater and slight resetting during shallow burial diagenesis. Petrography indicates that the formation of this dolomite ceased in the shallow burial environment, between the Mississippian and Permian. These dolomites are cross-cut by comparatively small volumes of geothermal-hydrothermal dolomite associated with Laramide-age breccias and fractures. Tectonic-hydrothermal activity associated with the Laramide Orogeny was responsible for late stage calcite cemented fractures and breccias which cross-cut all carbonate rocks discussed in this thesis. Radiogenic 87Sr/86Sr, depleted delta18O and enriched delta13C values and the hottest fluid inclusions measured in this study suggest the late stage calcite formed in the hydrothermal environment and under the most open-system and water-dominated conditions. Tectonic-diagenesis is ultimately responsible for establishing vertical barriers in the otherwise porous and permeable strataform dolomites.

Le Lias ardéchois montre d ' importantes variations de faciès et d'épaisseur. De plus la coexistence de faciès détritiques grossiers et de faciès carbonatés marins laisse supposer une activité tectonique synsédimentaire intense. Je me suis donc consacrée à l'étude du Lias inférieur et moyen du bassin de Privas , dans lequel les formations de cette période affleurent relativement bien. Il s'agira ici de rassembler le maximum de données (paléontologiques,stratigraphiques et sédimentolog iques) avec deux objectifs principaux : -la reconstitution paléogéographique du bassin aux divers étages étudiés; -la mise en évidence de l'activité tectonosédimentaire par l'in termédiaire de l'analyse Séquentielle de la série, basée sur des observations détaillées tant sur le terrain qu'en laboratoire.

Les sites étudiés relèvent du Paléolithique supérieur et sont situés dans le Jura . Ils sont étudiés au niveau sédimentologie.

<p>Sandstone and shale samples were selected within the systems tracts for laboratory analyses. The sidewall and core samples were subjected to petrographic thin section analysis, mineralogical analyses which include x-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), and stable carbon and oxygen isotopes geochemistry to determine the diagenetic alteration at deposition and post deposition in the basin. The shale samples were subjected to Rock-Eval pyrolysis and accelerated solvent extraction (ASE) prior to gas chromatographic (GC) and gas chromatographic-mass spectrometric (GC-MS) analyses of the rock extracts, in order to determine the provenance, type and thermal maturity of organic matter present in sediments of the Orange Basin. The results revealed a complex diagenetic history of sandstones in this basin, which includes compaction, cementation/micritization, dissolution, silicification/overgrowth of quartz, and fracturing. The Eh-pH shows that the cements in the area of the basin under investigation were precipitated under weak acidic and slightly alkaline conditions. The &delta / 18O isotope values range from -1.648 to 10.054 %, -1.574 to 13.134 %, and -2.644 to 16.180 % in the LST, TST, and HST, respectively. While &delta / 13C isotope values range from -25.667 to -12.44 %, -27.862 to -6.954% and -27.407 to -19.935 % in the LST, TST, and HST, respectively. The plot of &delta / 18O versus &delta / 13C shows that the sediments were deposited in shallow marine temperate conditions.</p>

Organic-walled microfossils are abundant and taxonomically diverse in Cambrian-Ordovician strata; some are important for biostratigraphy and for the correlation of geological successions. New assemblages of Cambrian-Ordovician acritarchs from Kolguev Island, Arctic Russia and Middle Cambrian ichnofossils of endoliths from Peary Land, North Greenland are studied. Twenty-seven acritarch species are described in detail and 10 taxa are left under open nomenclature. The diagnosis of one genus is restricted, and two other are emended. New combinations are proposed for three species and one new species is recognised. The studied acritarch assemblages are taxonomically rich and age-diagnostic and used to recognise Upper Cambrian and Tremadoc strata on Kolguev Island. The sedimentologically continuous successions provide for the first time palaeontological evidence of Cambrian strata in the north-eastern sector of Europe. The exact level of the Cambrian-Ordovician boundary was distinguished together with stratigraphic intervals equivalent to the Peltura and Acerocare zones of the Upper Cambrian of Baltica. The newly established relative age of the lowermost sedimentary succession overlying the Timanian unconformity allows verification of the minimum age of the Timanian deformation and the time-span of the hiatus bound to this unconformity. Endoliths occur in the fossil record from the Early Archean and they played an important role in the formation of stromatolites and the process of bioerosion and biodegradation. Endoliths that have actively bored into brachiopod shells or carbonate grains (euendoliths), and some that inhabited the cavities inside brachiopod shells (cryptoendoliths) are described. Borings within the carbonate grains extended with a dentritic pattern, whereas those within the brachiopod shells were formed by a multifilamentous euendolith which produced characteristic longitudinally ridged galleries. The cryptoendolithic morphologies include indeterminate coccoid masses and at least two filamentous forms. However, considerable variation in the dimensions of the currently phosphatised diagenetic crusts of the cryptoendoliths hinders discrimination.

In order to explore site formations and reconstruct environmental development in Medieval and Post-Medieval towns, urban occupational strata in Norrköping and Karlstad were studied according to biostratigraphy, sedimentology and pedology. New field procedures including continuous pilot sampling, parallel archaeological and geological stratigraphic interpretation, and on-site analysis of plant macrofossils were developed and applied at archaeological excavations in both towns. Representation of both disciplines in the field during excavations greatly contributed to more complete field interpretations. Stratigraphical analyses indicate that geological processes have been active in both towns, and reveal similarities in site formation. The earliest proto-urban phase is represented by the presence of dark earths, formed by the combination of alluvial processes and cattle tramping. Alluvial processes were common in Karlstad due to the flooding of the river delta, and in Norrköping due to the sloping topography. Both situations were enhanced by human activity, which caused drainage problems. A significant change in composition and origin of house foundation fill was also noted. The oldest foundations contained fine-grained material of local origin in contrast to younger foundations, which contained coarser material, sometimes of regional origin. This is interpreted as a professionalisation of the urban building tradition, which in Norrköping occurred during the 16th century and in Karlstad during the 18th century. Site formations of urban strata are regulated by three major factors: deposition, post-depositional soil formation and erosion/truncation, which all may occur both culturally and naturally. Plant macrofossil analyses in Norrköping and Karlstad resulted in a fossil record with a total amount of 203 and 169 different types of plant species and taxa respectively. The records indicate that site formation processes seem to have been inhibited during wintertime. The results also confirm the idea of the early Scandinavian towns as rural, also during the Post-Medieval time. The finds of cultural plants in Karlstad indicate 18th century cultivation of Fragaria moscata and 17th century import of Pimento officinalis. In Norrköping remains of beer additives confirm that the tradition of combining Humulus lupulus and Myrica gale disappeared after the 15th century, but also indicate a the use of Filipendula ulmaria as a beer addative. Finds of seeds from Nicotiana rustica suggests that tobacco cultivation occurred in Norrköping 1560-1640, which is some decades earlier than known so far in Sweden.

This thesis constrains the distribution of diagenetic alterations and their impact on reservoir-quality and heterogeneity evolution pathways in relation to depositional environments and sequence stratigraphy (systems tracts and key sequence stratigraphic surfaces) of four selected paralic and shallow marine siliciclastic successions. Typical eogenetic alterations encountered include the dissolution and kaolinitization of framework silicates, which are closely associated to shoreface facies of forced regressive systems tract (FRWST), lowstand systems tract (LST), upper part of the highstand systems tract (HST), and below the sequence boundary (SB). These alterations are attributed to incursion of meteoric water owing to rapid and considerable fall in the relative sea level. Extensive carbonate cementation is most evident below marine and maximum flooding surfaces (MFS), whereas dissolution of carbonate cement and detrital dolomite occur in LST, HST and below SB. Parameters controlling the patterns and texture (microcrystalline vs. poikilotopic) of calcite cement have been constrained within sequence stratigraphic framework of the sandstones. Coarse crystalline to poikilotopic calcite textures of meteoric water origin are thus closely linked to the FRWST, LST and upper part of the HST sandstones and occur mainly as stratabound concretions, whereas microcrystalline calcite, which was precipitated from marine porewaters, occurs as continuously cemented layers in the transgressive systems tract (TST) and lower part of the HST sandstones. Eogenetic alterations impose, in turn, profound control on the distribution pattern of mesogenetic alterations, and hence on reservoir quality evolution (destruction vs. preservation) pathways of sandstones. Eogenetic infiltrated clays, which occur in the tidal estuarine TST and HST sandstones, have helped preserving porosity in deeply buried sandstone reservoirs (≈ 5 km) through inhibition of extensive cementation by quartz overgrowths. Other essential findings of this thesis include deciphering the control on the formation of authigenic illite and chlorite by ultra-thin (≤ 1 µm thick), grain-coating clay mineral substrate.

This study deals with the influence of topography on glacial dynamics and the genesis of till in an area of moder-ate bedrock relief. An area 25 km west of Lycksele, northern Sweden, was investigated using geomorphological and sedimentological methods. The bedrock is dominated by coarse-grained granites and the topography, ranging in altitude between 310 and 490 m. a.s.l., is characterized by relatively wide, free-lying hills. The erosional and depositional features provide evidence of several glacial events, with regional ice flows from approximately the same direction (NW-NNW). The gravel fraction of the till is dominated by material transported more than 10 km. However, the total glacial erosion has been modest, as indicated by the frequent occurrence of residual pre-glacial weathering features. There is no evidence of warm-based conditions during the period when the ice divide of the Late Weichselian ice sheet was situated E-SE of the study area. The major mor-phological impact is most likely by pre-Late Weichselian ice sheets. The general stratigraphy at the valley floors is a complex sequence of heterogeneous till and beds of sorted sediments with some evidence of glacial deformation covered by an up to 2.5-m-thick, texturally homogeneous till layer with distinct fissility structure and clast fabric orientation. The lower unit is interpreted as pre-Late Weichselian marginal deposits, and the upper till as mainly formed during rigid-bed conditions, i.e. by lodgement, during the last deglaciation. The role of pervasive deformation and melt-out in the formation of the upper till are discussed. Inferred mainly from till fabrics it is evident that the ice flow was strongly topographically controlled within a relatively wide marginal zone of the retreating ice. At the summits of the hills there are only signs of very weak glacial abrasive and depositional activity, sug-gesting frozen based conditions over the summits until a very late stage of the deglaciation. The very thin till at the summits, which also lay as a drape over the thick lee-side deposits, consists of a mixture of relatively fine-grained, distantly derived debris and of local bedrock fragments entrained during a very late phase of plucking. On the stoss- and lateral slopes of the hills the till is thin and discontinuous. The irregular bedrock surface in these areas created a “mosaic” of small-scale subglacial depositional environments, which were superimposed on the changes in the conditions for deposition along the hillslope. This till is comparatively coarse-grained, which is interpreted as an effect of syn-depositional winnowing of fines, and locally also because of the incorporation of local bedrock material largely from pre-glacially weathered zones. On the lee-sides of the hills the deposits are considerably thicker than on slopes facing other directions. They are characterized by highly variable texture and structure, suggesting a depositional environment characterized by large temporal and spatial variations in meltwater activity and stress/strain conditions. The lee-side tills are inter-preted as mainly pre-Late Weichselian in age. The overall conclusion is that the local topography strongly controlled the basal ice flow and produced a com-plex pattern of thermal variations within a relatively wide marginal zone of the ice sheet during the last deglacia-tion. The study supports the view that there are complete transitions between the different genetical types of sub-glacial tills, although the role of deformation by pervasive shearing is uncertain in this type of coarse-grained till.

A study of the distribution of diagenetic alterations and their impact on reservoir-quality evolution in four deep-water turbidite successions (Cretaceous to Eocene) from basins in active (foreland) and passive margins revealed the impact of tectonic setting, depositional facies, and changes in the relative sea level. Diagenetic modifications encountered in the turbiditic sandstones from the passive margin basins include dissolution and kaolinitization (kaolin has δ18OV-SMOW = +13.3‰ to +15.2‰; δDV-SMOW = -96.6‰ to -79.6‰) of framework silicates, formation of grain coating chloritic and illitic clays, cementation by carbonates and quartz, as well as the mechanical and chemical compaction of detrital quartz. Kaolinitization, which is most extensive in the lowstand systems tracts, is attributed to meteoric-water flux during major fall in the relative sea level. Preservation of porosity and permeability in sandstones from the passive margin basins (up to 30% and 1 Darcy, respectively) is attributed to the presence of abundant rigid quartz and feldspar grains and to dissolution of carbonate cement as well as mica and feldspars. Diagenetic modifications in turbidites from the foreland basins include carbonate cementation and mechanical compaction of the abundant ductile rock fragments, which were derived from fold-thrust belts. These diagenetic alterations resulted in nearly total elimination of depositional porosity and permeability. The wide range of δ13CV−PDB values of these cements (about -18‰ to +22‰) in passive margin basins is attributed to input of dissolved carbon from various processes of organic matter alterations, including microbial methanogenesis and thermal decarboxylation of kerogen. The narrower range of δ13CV−PDB values of these cements (about -2‰ to +7‰) in the foreland basins suggests the importance of carbon derivation from the dissolution of carbonate grains. The generally wide range of δ18O values (about -17‰ to -1‰) of the carbonate cements reflect the impact of oxygen isotopic composition of the various fluid involved (including marine depositional waters, fluxed meteoric waters, evolved formation waters) and the wide ranges of precipitation temperatures. Results of this study are anticipated to have important implication for hydrocarbon exploration in deep-water turbidites from passive and active margin basins and for pre-drilling assessment of the spatial and temporal distribution of reservoir quality in such deposits.