Differences in southern yellow pine (represented by Pinus taeda) and Douglas-fir (Pseudotsuga menziesii) mature and juvenile wood were examined in terms of density, chemical composition, surface energy, shear stress, % wood failure, and delamination. Density was measured using a QTRS density scanner. Loblolly pine contained a higher average density. Chemical composition was measured using the NREL standard for identifying the chemical composition of biomass. Southern yellow pine contained a higher % hemicellulose, lignin, and extractives. Douglas-fir had higher % cellulose than southern yellow pine. Surface energy was measured using the static sessile drop contact angle method and the acid/base approach. Southern yellow pine contained a lower average contact angle than Douglas-fir. Shear stress, % wood failure, and durability were measured using ASTM-D2559 with two adhesives, a one-part moisture cure polyurethane (PU), and a two-part ambient curing phenol-resorcinol-formaldehyde (PRF). Shear stress for southern yellow pine was affected the most by the type of growth regions at the bond (juvenile to mature wood) and the assembly times of the adhesives used. Douglas-fir shear stress was affected by the type of adhesive and the growth region at the bond. Delamination results demonstrated that when using PRF the southern yellow pine has less delamination statistically than Douglas-fir. Also, the growth region at the bond with both adhesives showed to impact delamination with juvenile to mature wood having less delamination than mature to mature wood. / Master of Science

The ability to accurately measure surface and interfacial energies affects our understanding of friction, wear, bonding and adhesion. Although there are accurate ways to measure the surface energies of liquids, the surface energies of solids have been harder to characterize. In order to broaden the knowledge of adhesion of solids, a modification to the constrained blister test is proposed. Most of the previous work on constrained blisters has examined the debonding of the blister from the surface underneath as pressure is applied from below. In this thesis, the contact of the constrained blister with the flat surface above it is considered. In addition, the blister is given specified boundary conditions at its outer radius, which has a fixed value. Three models of the blister behavior are considered: linear plate, nonlinear plate, and membrane. The contact of the blister with the substrate above it is modeled with no adhesion, the JKR-type of adhesion, and the DMT-type of adhesion. Several substrate heights are considered, along with several values for the work of adhesion in the JKR analysis, and several combinations of force magnitude and gap size in the DMT analysis. The effect of adhesion on the contact radius is investigated. Sometimes the contact radius changes discontinuously as the pressure is increased or decreased. Results from the three models of blister behavior and the different models of adhesion are compared. / Master of Science

The understanding of topics such as friction, wear, lubrication, and adhesive bonds is dependent on the ability to measure surface and interfacial energies. The surface energies of liquids may be measured accurately using a variety of techniques; however, surface energies of solids are much more difficult to accurately measure. In an attempt to develop a method that can be used to measure surface and interfacial energies of solids, this thesis proposes the use of a elastica. The elastica acts as an extremely flexible beam and provides a structure that will permit measurable deformation of the solid by relatively small surface attractions. The ends of the elastica are lifted, bent, and clamped vertically at an equal height and specified distance apart. They are then moved downward, allowing the strip to make contact with a flat, rigid, horizontal surface. Two adhesion models are investigated. First, a JKR-type analysis, which examines the effect of adhesion forces that exist within the area of contact between the elastica and the rigid surface, is considered. Various values for the work of adhesion are examined. A DMT-type analysis, which assumes that the adhesion forces act in the region just outside of the contact area, is also considered. Results are obtained for linear and constant forces. Various values for the maximum DMT force and the vertical separation between the elastica and the rigid substrate at which the adhesion forces terminate are examined. Results from the two types of analyses are compared. / Master of Science

M. Tech. (Department of Mechanical Engineering, Faculty of Engineering and Technology), Vaal University of Technology. / Presently, the current membrane technologies used in oil/water separation are inefficient with poor controllability and stability during oil/water separation. The has led to the current problem of membrane fouling and degradation during oil/water separation. Several approaches have been used to modify or design a better wettable surface with limited success since the current problem of membrane fouling is persisting. It is, therefore, necessary for scientists, engineers, and researchers to come up with a new membrane technology that will be more efficient with stable wettability and controllability during oil/water separation. Membranes are made up of nanoparticles on their surface, which are both random in nature. Furthermore, the collection of membrane particles to form mesh membranes are made of pores with further ransom spatial distribution. Thus, it was necessary to use the tools of stochastic processes to theoretically characterize these parameters. These parameters affect both internal and external factors as well as characteristics of random membrane particle and pores on wettability like surface tension and surface energy were established in the current project. Design and production of the membrane material according to established relationships was by both low and high-pressure spay jet coating in a controlled laboratory environment, and microscopic characterization performed using SEM. TEM, EDS, statistical analysis, and Image J particle analyzer. The spread, orientation, morphology, spatial distribution, inter-separation distances, surface roughness, surface smoothness, contact angles, surface density of the particle, mean size of the coated nanoparticle on the membrane surface after different coating rounds were analyzed so as to establish conditions for optimal wettability. The testing of produced membranes under the application of external and internal factors was done. A centrifugal pump was used to pump contaminated oil and water mixture through the membrane under a steady flow rate of 10 L/s with a gauge pressure of 180 kPa at room temperature conditions. The membrane materials from different coating rounds were tested for their abilities to produce pure collected water or oil particles in the collected water. The separated water was analyzed using oil and grease analysis US EPA method 1664B with the SPE-DEX 1000 oil and grease system. As revealed theoretically and validated experimentally, it was found that the random natures of nanoparticle size, the spatial distribution of membrane channels, and their morphology have impacts on surface energy-driven separability of oil and water mixture. It was also observed that the scattering of nanoparticles on the membrane surface during coating lowered surface energy, which enhanced oil/water separation. It was also revealed that there is an optimal nanoparticle size, scattering, morphology, and spatial distribution of membrane channels that offer better separation of water from oil. From the microscopy analysis, different microstructures were revealed for glass, ceramics, and sediment during LP and HP coating. The microstructure characterization showed different surface densities of nanoparticles, mean particle sizes, surface roughness or smoothness, and nanoparticles inter-separation distances. It was also revealed that the materials, which were more stable and efficient with more controlled wettability were glass, sediment, and ceramic HP 3rd rounds of coating. Clusters were observed on the membrane surface during HP and LP coating rounds with more clusters observed in LP coating when compared with HP coating. These clusters increased surface energy, which negatively affected oil/water separation. It was concluded that to improved the wettability surface. membrane clusters must be minimized during coating rounds. This thesis contributed new knowledge to existing body knowledge of membrane technology used in oil/water separation in a number of ways by: (1) Designing a new membrane surface with a more controlled, efficient, and stable wettability process during oil/water separation. (2) Applying the logic of surface energy-driven separability, which has not been previously used extensively to study membrane wettability. (3) Establishing a model for the optimal membrane pore sizes that offer optimal membrane wettability during oil/water separation. (4) Establishing a model for optimal nanoparticle coating that offers optimal membrane wettability during oil /water separation. (5) A great attempt was made in characterizing nanoparticle surface densities, spread, particle coating, and nanoparticles intensity on a wettable membrane surface.

Yes / Two different types of dry powder inhalers (Easyhaler® and RS01®) were used in this work to evaluate the ex vivo and in vitro performance of a budesonide inhaled formulation with recrystallised mannitol, commercial DPI-grade mannitol, or lactose. The aerodynamic performance of the budesonide formulation with recrystallised mannitol was superior when RS01® was used (FPF = 45.8%) compared to Easyhaler® (FPF = 14%). However, the aerodynamic profile was very poor in both devices when commercial mannitol was used. Interestingly, the aerosol performance of the marketed budesonide formulation significantly improved when RS01® was used compared to Easyhaler® (the original device for the formulation). Due to the significant increases in the surface energy of the commercial mannitol formulation, the aerodynamic performance of the formulation was very poor. This work demonstrates the impact of inhaler devices on the performance of inhaled formulations and considers the particle surface energy during formulation development.

<p>With the use of a process-orientated ecosystem model andmeasurements conducted at different Swedish coniferous forestsites, abiotic and biotic interactions between tree and soilwere identified and related to governing factors. Two differentmodelling approaches to describe soil temperatures at two sitesincluding hydrological transects were tested (I). The approachin which both canopy and soil were considered proved to be amore flexible tool to describe soil temperatures, especiallyduring snow-free winter periods. Five sites along a climatetransect covering Sweden were used to describe soil carbon poolchanges during an 80-year period simulation (II). The dynamicmodelling approach, with a feedback between abiotic and bioticsub-models, was successful in describing simplified patterns offorest stand dynamics and furthermore in differentiatingbetween climate and nitrogen availability factors. The largereffect of nitrogen availability compared to climate on soilcarbon pool changes was clearly shown.</p><p><b>Keywords:</b>SPAC; soil surface energy balance; Norwayspruce; canopy; LAI; climate; nitrogen; CoupModel</p>

<p>På grund av världens växande befolkning och urbaniseringen blir problem relaterade till fenomenet urbana värmeöar mer och mer påtagliga. Eftersom urbana parker kan minska påfrestningen skapad av urbana värmeöar kan de vara ett kraftfullt verktyg vid klimatdesign i städer. Temperaturen nära en yta bestäms av energiutbytet mellan ytan och luften ovanför och det är därför nödvändigt att man förstår energibalansen vid markytan för att kunna hantera parkernas mikroklimat. Syftet med det här arbetet var att studera skillnaderna mellan energibalansen för olika ytor i parken och i dess omgivning och att relatera skillnaderna i energibalanserna till temperaturskillnaderna.</p><p>Mätningarna utfördes under tre klara sommardagar i parken Humlegården i centrala Stockholm. Mätutrustningen var monterad på en kärra som flyttades från mätplats till mätplats. Mätplatserna representerade olika typiska ytor i Humlegården och i dess omgivning: en skuggad och en öppen gräsmatta, en öppen och en skuggad grusyta och två asfaltytor, varav en löper i nord-sydlig riktning och en i öst-västlig riktning.</p><p>Energiflödena beräknades med hjälp av data för luft- och yttemperatur, vindhastighet, luftfuktighet och nettostrålning.</p><p>Resultaten visade att den tydligaste skillnaden mellan gräs- och grusytorna i parken var att gräsytorna hade ett större nedåtriktat latent värmeflöde under natten och ett mindre markvärmeflöde under hela dygnet. Den mest distinkta skillnaden mellan de skuggade och öppna ytorna i parken var att de skuggade ytorna hade mindre energiflöden under dagen och att de till skillnad från de andra ytorna hade ett nedåtriktat sensibelt värmeflöde under dagen. Den största skillnaden mellan ytorna i och utanför parken var att asfaltytorna hade ett större uppåtriktat sensibelt värmeflöde och markvärmeflöde under natten.</p><p>Under natten var den svalaste mätplasten den öppna gräsmattan, vilken också var den enda mätplasten med ett nedåtriktat sensibelt värmeflöde under natten. Jämfört med de andra ickeskuggade mätplasterna hade den öppna gräsmattan ett mindre markvärmeflöde. Varmaste mätplasterna under natten var asfaltytorna som även hade ett större uppåtriktat sensibelt och markvärmeflöde än de andra ytorna. Under dagen var de skuggade ytorna i parken de svalaste platserna. De var de enda ytorna med ett nedåtriktat sensibelt värmeflöde och nettostrålningen vid ytan var mindre än för de flesta andra mätplatser.</p> / <p>The world’s growing population and the increasing urbanization has made problems related to the urban heat island phenomenon to become more pronounced and since urban parks reduce the stress produced by the urban heat island they can be powerful tools in urban climate design. The temperature near the surface in a park is determined by the energy exchanges between the surface and the air above and it is therefore necessary to understand the surface energy balance of parks to intelligently manage their thermal microclimate. The objectives of this work were to study how the energy balances differ between different surfaces inside parks and in their built-up surroundings and to relate the surface energy balances to temperature differences.</p><p>Measurements were conducted during three clear summer days in the park Humlegården located in central Stockholm. The measuring instruments were mounted on a cart, which was transported from observation site to observation site. The observation sites represented typical surfaces found in an urban park and its surroundings: one shaded and one open grass surface, one open and one shaded gravel surface and two paved surfaces representing streets running in the north-south and east-west directions respectively. The energy fluxes were calculated using air and surface temperatures, wind speed, air humidity and net radiation data.</p><p>The most pronounced differences between the shaded and open surfaces in the park was that the shaded surfaces in general had smaller energy fluxes during daytime and that they had a downward directed sensible heat flux while the open surfaces had an upward directed sensible heat flux during the day. The most significant difference between the grass and the gravel surfaces in the park was that the grass surfaces had a bigger downward directed latent heat flux during the night and a smaller ground heat flux during both day and night. The largest differences between the surfaces inside the park and those in its built-up vicinities were that the paved surfaces had a larger upward directed sensible and ground heat flux during the night than the other surfaces. During the day the north-south directed paved site had a downward directed ground heat flux that was much larger than the ground heat flux for the other sites.</p><p>The coolest site during the night was the non-shaded grass surface, which was the only site with a downward directed sensible heat flux during the night. Compared to the other nonshaded sites the open grass surface had a much smaller ground heat flux. Warmest sites during the night were the paved surfaces, which had a larger upward directed sensible and ground heat flux than the other surfaces. At the built-up sites the walls also contributed with sensible heat flux, i.e. the total sensible heat flux in the built-up area was larger than what comes from the street surface only. During the day the shaded surfaces in the park were the coolest sites. The shaded surfaces had less net radiation compared to the other non-shaded surfaces and were the only sites that had a downward directed sensible heat flux.</p>

No description available.

Raspberry-like polystyrene particles were fabricated through the covalent linkage of small epoxy-functionalized polystyrene particles (PS-GMA) with large amino-functionalized polystyrene particles (PS-NH2). These covalent bonds yielded more stable and robust particle clusters than would be anticipated from non-covalent interactions. While the structures of these raspberry-like particles provided them with a dual-scale hierarchical roughness and re-entrant sites, they were further functionalized with a fluorinated random copolymer to provide them a low surface tension. The fluorinated random copolymer used to functionalize these raspberry-like particles was poly(glycidyl methacrylate20%)-co-2(perfluorooctyl)ethyl methacrylate80%)25 or P(GMA20%-co-FOEMA80%)25, where the subscript 25 denotes the total number of the respective GMA and FOEMA units, while the subscript 20% and 80% denote the molar fractions of GMA and FOEMA, respectively. The epoxy groups of the GMA units could react with the amino groups of the raspberry-like particles, thus incorporating the fluorinated polymer onto the surfaces of the raspberry-like particles. In addition, the FOEMA component provided the particles with enhanced amphiphobicity. Subsequently, these fluorinated raspberry-like particles were cast onto glass slides to demonstrate their superamphiphobic properties. These coatings exhibited superhydrophobic behavior when they were tested against water droplets. Additionally, the oil-repellency of these coatings was tested against various liquids, including diiodomethane, cooking oil, and hexadecane. The coatings exhibited superoleophobic behavior against diiodomethane and cooking oil, as well as highly oleophobic behavior against hexadecane. This work demonstrates a simple and efficient route for the fabrication of superamphiphobic surfaces. Additionally, these surfaces are among the first examples of coatings prepared via self-assembly techniques that exhibited high repellency against hexadecane. These materials could have potential in various applications that require protection of a surface against wetting by either water or oils. / Thesis (Master, Chemistry) -- Queen's University, 2013-10-18 12:36:39.039

<p>Surface energy-powered motion is useful for a variety of autonomous functions such as passive cooling and self-cleaning, where independence from external forces is highly desirable. Drop coalescence offers a convenient process to release surface energy, which can be harvested to power self-propelled fluid motion. </p><p>On superhydrophobic surfaces, out-of-plane jumping motion spontaneously results from drop coalescence. However, less than 4\% of the released surface energy is converted to useful kinetic energy giving rise to the jumping motion. Using three-dimensional interfacial flow simulations that are experimentally validated, we elucidate the mechanism of low energy conversion efficiency. The non-wetting substrate interferes with the expanding liquid bridge between the coalescing drops at a relatively late stage, forcing a small fraction of the merged drop to "bounce" back from the non-wetting substrate. The substrate breaks the symmetry of surface energy release, leading to self-propelled jumping that is perpendicular to the solid substrate. The intercepting substrate imparts a relatively small translational momentum on the overall merged drop, giving rise to a small energy conversion efficiency. </p><p>This mechanistic understanding has provided guidance on how to increase the energy conversion efficiency by changing the geometry of the intercepting solid surface, e.g. to a pillared substrate which has additional intercepting planes, or to a cylindrical fiber which interferes with the coalescence process at a much earlier stage. These topographical changes have already led to a 10-fold increase in energy conversion efficiency. The directional control of surface energy-powered motion is achieved by breaking the symmetry of oscillations induced by drop coalescence, such as by adding additional intercepting planes on pillared substrates. The work has applications ranging from self-sustained dropwise condensers, drop coalescers to ballistospore discharge in some fungi species in nature. </p><p> The ballistospore discharge process is powered by surface energy released from the coalescence between a spherical Buller's drop and an adaxial drop on the spore. The disturbance to the adaxial drop from coalescing Buller's drop results in the capillary-inertial oscillations of the liquid system. The oscillations redirect the mass and momentum transfer and yields a tensile force along the adaxial direction with negligible momentums in other directions, ensuring the preferable launching along the adaxial direction. The findings offer insights for applications of biomimicry involving self-propelled jumping with payloads which takes advantage of the high power density of the process.</p> / Dissertation