The polymer laminated sheet metal (PLSM) is a layered material which involves a sheet metal substrate, a thin polymer film and an adhesive layer between the film and the substrate. The adhesion properties between the bonded materials are among the most important issues in PLSM forming operations. In this thesis, the main focus has been devoted to characterizing and improving the adhesion properties of the PLSM system for forming applications. Metallic surface roughness evolution and residual stress development in polymer adherends are two consequences of the plastic deformation of the PLSMs. In chapter 2, the effect of these factors on interfacial adhesion strength between metallic substrate and polymer adherend (polymer film with a thin uniform pressure-sensitive adhesive layer on one side) is investigated by devising a new experimental methodology. This methodology is based on two different protocols for preparation of peel sample, one involving pre-straining in uniaxial tension of the metallic substrate prior to lamination and the other involving post-lamination pre-straining of the PLSM. In chapter 3, the peel test results of two different types of PLSMs at different peel speeds are analyzed with two different approaches common in cohesive zone modeling in the literature, namely linear elastic stiffness approach and critical maximum stress approach. The modeling results revealed the significance of the peel speed in determining the interface strength between the adhesive and metallic substrate. In chapter 4, two mechanical treatment techniques of grinding and knurling are implemented to alter the metallic substrate surface roughness before lamination. Peel strength of these samples are investigated at different peel speeds and at different peel loading directions with respect to the grinding and knurling directions. / Thesis / Doctor of Philosophy (PhD) / The polymer laminated sheet metal (PLSM) is a layered material which involves a sheet metal substrate, a thin polymer film and an adhesive layer between the film and the substrate. In this thesis, the main focus has been devoted to characterizing and improving the adhesion properties of the PLSM system for forming applications. A new experimental methodology has been devised for analyzing the effects of deformation-induced surface roughness of metallic substrate and deformation-induced residual stress in polymer adherends on interfacial peel properties of PLSMs. A novel interpretation of the results obtained from rate-independent cohesive zone modeling of peel test has revealed the significance of peel speed in determining the interface strength between the adhesive and the metallic substrate. In another part of this thesis, the effects of two substrate surface alteration techniques, grinding and knurling, on peel properties of PLSMs have been studied.

Industries (food, beverage, petrochemical, etc.) normally use various gravitational separation echniques in their processes. Such separation processes often suffer from the deposition of undesirable material on the active surfaces of the process equipment, e.g. a high-speed separator or decanter, causing a slew of problems with the process or product quality. To restore operational efficiencies, additional cleaning steps using both water and chemicals are required, making the process more expensive and less environmentally friendly. Other than operating time and concentration of the process fluid there are several factors such as surface nature, surface roughness, type of material, surface charge, etc which influence the fouling deposition of surfaces. Fouling on the surfaces can grow following different mechanisms. The goal of this research work is to learn more about the nature of foulant interactions with stainless steel surfaces and eventually design some antifouling methodology. It is too difficult to study foulingfor all kinds of solutions and industries, so we tried to investigate the organic deposition in dairy and brewery industries by using lab-scale synthesized milk and beer solutions, For quantitative and statistical examination of these characteristics, several experimental approaches (FTIR, percent weight change, surface roughness, surface energy) were used. It was confirmed that fouling grows on the surfaces in a non-linear fashion irrespective of the time and concentration of the solution. The fouling of surfaces can be improved by producing more hydrophilic surfaces or by reducing surface roughness. Steric hindrance, electrostatic charge, and water barrier or hydration layer theories can be used to modify the surface nature and hence the fouling deposition. For antifouling purposes, PMMA (organic) and tungsten oxide (inorganic) coatings were employed. The PMMA was deposited using a dip-coating technique using (6%,10%, and 12%) PMMA solution, and the tungsten oxide coating was carried out by using a standard two electrode electrochemical system under different voltage (3.5V and 4.5V) and time (5min, 10 min, and 20 min) conditions. The coatings were characterized by using different techniques and their antifouling effects were studied in model milk and model beer solutions / Vid industriella processer (livsmedel, petrokemisk etc.) används ofta olika tekniker för separation med hjälp av gravitation. Sådana separationsprocesser drabbas ofta av oönskade beläggningar och påväxt på processutrustningens aktiva ytor så som t.ex. i en separator eller en dekanter, vilket orsakar problem med processen eller produktkvaliteten. För att återställa driftseffektivitet krävs särskilda rengöringssteg med både vatten och kemikalier vilket gör processen dyrare och mindre miljövänlig. Förutom drifttid och processvätskans sammansättning finns det flera faktorer såsom ytbeskaffenhet, ytjämnhet, materialtyp, ytladdning m.m. som påverkar mängden oönskade beläggningar på ytor. Föroreningarna på ytor kan tillväxa med olika mekanismer. Målet med detta forskningsarbete är att studera interaktionen mellan olika former av påväxt och ytan på rostfritt stål och senare utforma metoder för att förhindra bildandet av sådana oönskade beläggningar. Det är en stor utmaning att studera olika typer av påväxt för alla typer av flöden och industrier. I studien undersöktes organisk påväxt inom mejeri- och bryggeriindustrin genom att använda syntetiserade mjölk- och ölprodukter i laboratorieskala, för kvantitativa och statistiska undersökningar av dessa egenskaper. Flera olika experimentella metoder användes (FTIR, viktförändring, ytjämnhet, ytenergi). Det bekräftades att tillväxten på ytorna var olinjärt oavsett tid och lösningens koncentration. Bildandet och tillväxt av oönskade beläggningar kan minskas med hjälp av mera hydrofila ytor eller genom att minska ytans ojämnhet. Steriska hinder, elektrostatisk laddning och vattenbarriär eller hydratiseringsskal kan användas för att modifiera ytan och därmed fördröja bildandet av oönskade beläggningar. För att förhindra påväxt belades ytan med PMMA (organisk) och volframoxid (oorganisk). PMMA deponerades genom en doppbeläggningsteknik med användning av (6%, 10% och 12%) PMMA-lösning och volframoxidbeläggningen utfördes med ett elektrokemiskt tvåelektrodssystem med olika spänningar (3,5V och 4,5V) och tider (5min, 10min och 20min). Ytbeläggningarna karakteriserades genom att använda olika tekniker och deras förmåga att förhindra snabb påväxt studerades i modellösningar av mjölk och öl.

The method for developing a soil moisture inversion algorithm using Radar data can be approached in two ways: the multiple-incident angle approach and the change detection method. This thesis discusses how these two methods can be used to predict surface soil moisture. In the multiple incident angle approach, surface roughness can be mapped, if multiple incident angle viewing is possible and if the surface roughness is assumed constant during data acquisitions. A backpropagation neural network (NN) is trained with the data set generated by the Integral Equation Method (IEM) model. The training data set includes possible combinations of backscatter obtained as a result of variation in dielectric constant within the period of data acquisitions. The inputs to the network are backscatter acquired at different incident angles. The outputs are correlation length and root mean square height (rms). Once the roughness is mapped using these outputs, dielectric constant can be determined. Three different data sets, (backscatter acquired from multiplerequencies, multiple-polarizations, and multiple-incident angles) are used to train the NN. The performance of the NN trained by the different data sets is compared. The next approach is the application of the change detection concept. In this approach, the relative change in dielectric constant over two different periods is determined from Radarsat data using a simplified algorithm. The vegetation backscatter contribution can be removed with the aid of multi-spectral data provided by Landsat. A method is proposed that minimizes the effect of incident angle on Radar backscatter by normalizing the acquired SAR images to a reference angle. A quantitative comparison of some of the existing soil moisture estimation algorithms is also made

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京都大学 / 新制・課程博士 / 博士(工学) / 甲第23860号 / 工博第4947号 / 新制||工||1773(附属図書館) / 京都大学大学院工学研究科都市社会工学専攻 / (主査)教授 岸田 潔, 教授 三村 衛, 教授 木村 亮 / 学位規則第4条第1項該当 / Doctor of Philosophy (Engineering) / Kyoto University / DGAM