This thesis presents results of investigations on fields and multipole expansion coefficients in axially symmetric (referred to as 3D)and two dimensional (2D)ion trapmass analysers. 3D mass analysers have a three-electrode geometry with two (electrically shorted) endcap electrodes and one central ring electrode. rf-only or rf/dc potential applied across the electrodes creates a linear trapping field in the central cavity of the mass analyser.2Dmass analysers have four longitudinal electrodes in which the opposite pairs of electrodes are electrically shorted. Here, rf-only or rf/dc potential applied across the pair of electrodes creates a linear trapping field and fragment ions of the analyte gas are trapped along the central axis of the mass analyser. Both these mass analysers have apertures machined on the electrodes (holes in case of 3D traps and slits in case of 2D traps) to permit entry of electrons for ionizing the analyte gas and for collection of destabilized fragment ions. This thesis is concerned with how these apertures influence the fields and multipole expansion coefficients within the traps. This thesis is divided into five chapters. Chapter 1 provides the background information which is required for the thesis. It begins with a description of the geometry of the 3D and the 2D mass analysers used in the present work.These include the quadrupole ion trap (QIT) and cylindrical ion trap (CIT) for 3D structures and the linear ion trap (LIT) and the rectilinear ion trap (RIT) for 2D structures. This is followed by a brief description of the numerical method, the boundary element method (BEM), used in the thesis. Also presented here are the Green’s function for 3D and 2D geometries. In the final section, the scope of the thesis is presented. Chapter 2 presents two approximate analytical expressions for nonlinear electric fields in the principal direction in axially symmetric (3D) and two dimensional (2D) ion trap mass analysers with apertures on the electrodes. Considered together (3D and 2D), we present composite approximations for the principal unidirectional nonlinear electric fields in these ion traps. The composite electric field E has the form E= EnoAperture + EdueToAperture where EnoAperture is the field within an imagined trap which is identical to the practical trap except that the apertures are missing; and where EdueToAperture is the field contribution due to apertures on the two trap electrodes. The field along the principal axis of the trap can in this way be well approximated for any aperture that is not too large. To derive EdueToAperture, classical results of electrostatics have been extended to electrodes with finite thickness and different aperture shapes. EnoAperture is a modified truncated multipole expansion for the imagined trap with no aperture. The first several terms in the multipole expansion are in principle exact (though numerically determined using the BEM), while the last term is chosen to match the field at the electrode. This expansion, once computed, works with any aperture in the practical trap. The composite field approximation for axially symmetric (3D) traps is checked for three geometries: the quadrupole ion trap (QIT), the cylindrical ion trap (CIT) and an arbitrary other trap. The approximation for 2D traps is verified using two geometries: the linear ion trap (LIT)and the rectilinear ion trap (RIT). In each case, for two aperture sizes (10% and 50% of the trap dimension), highly satisfactory fits are obtained. These composite approximations may be used in more detailed nonlinear ion dynamics studies than have been hitherto attempted. In Chapter 3we complement and complete the work presented in Chapter 2 by considering off-axis fields in the axially symmetric (3D) and the two dimensional (2D) ion traps whose electrodes have apertures. Our approximation has two parts. The first, EnoAperture, is the field obtained numerically for the trap under study with no apertures. We have used the boundary element method (BEM) for obtaining this field. The second part, EdueToAperture, is an analytical expression for the field contribution of the aperture. In EdueToAperture, aperture size is a free parameter. A key element in our approximation is the electrostatic field near an infinite thin plate with an aperture, and with different constant valued far field intensities on either side. Compact expressions for this field can be found using separation of variables, wherein the choice of coordinate system is crucial. This field is, in turn, used four times within our trap specific approximation. The off-axis field expressions for the 3D geometries were tested on the quadrupole ion trap (QIT) and the cylindrical ion trap (CIT), and the corresponding expressions for the 2D geometries were tested on the linear ion trap (LIT) and rectilinear ion trap (RIT). For each geometry, we have considered apertures which are 10%, 30% and 50% of the trap dimension. We have found that our analytical correction term EdueToAperture, though based on a classical small-aperture approximation, gives good results even for relatively large apertures. Chapter 4 presents approximate analytical expressions for estimating the variation in multipole expansion coefficients with the size of apertures in axially symmetric (3D) and two dimensional (2D) ion trap mass analysers. Following the approach adopted in Chapter 2 and Chapter 3 which focused on the role of apertures to fields within traps, here too, the analytical expression is a sum of two terms, An,noAperture, the multipole expansion coefficient for a trap with no apertures and An,dueToAperture, the multipole expansion coefficient contributed by the aperture. An,noAperture has been obtained numerically and An,dueToAperture is obtained from the nth derivative of the potential within the trap. The expressions derived have been tested on two 3D geometries and two 2D geometries. These include the quadrupole ion trap (QIT) and the cylindrical ion trap (CIT) for 3D geometries and the linear ion trap (LIT) and the rectilinear ion trap (RIT) for the 2D geometries. Multipole expansion coefficients A2 to A24, estimated by our analytical expressions were compared with the values obtained numerically (using the boundary element method) for aperture sizes varying up to 50% of the trap size. In all the plots presented, it is observed that our analytical expression for the variation of multipole expansion coefficients versus aperture size closely follows the trend of the numerical evaluations for the range of aperture sizes considered. The maximum relative percentage errors, which provide an estimate of the deviation of our values from those obtained numerically for each multipole expansion coefficient, are seen to be in the range of 10% to 15%. The leading multipole expansion coefficient, A2, however, is seen to be estimated very well by our expressions, with most values being within 1% of the numerically determined values, with larger deviations seen for the QIT and LIT only at larger aperture sizes. Chapter 5 presents a few concluding remarks.

The master thesis deals with national accounts, particularly with symmetric input-output tables and utilisation for research of investments change impact. The main aim is to show national accounts exploitation for economical modelling and a manual for modelling of concrete impact. This thesis concentrates on the topic of calculation of static model with application on real data of Czech Republic. The base of calculation is technical coefficients analyse.

Os modelos normais de regressão têm sido utilizados durante muitos anos para a análise de dados. Mesmo nos casos em que a normalidade não podia ser suposta, tentava-se algum tipo de transformação com o intuito de alcançar a normalidade procurada. No entanto, na prática, essas suposições sobre normalidade e linearidade nem sempre são satisfeitas. Como alternativas à técnica clássica, foram desenvolvidas novas classes de modelos de regressão. Nesse contexto, focamos a classe de modelos em que a distribuição assumida para a variável resposta pertence à classe de distribuições simétricas. O objetivo geral desse trabalho é a modelagem desta classe no contexto bayesiano, em particular a modelagem da classe de modelos não-lineares heterocedásticos simétricos. Vale ressaltar que esse trabalho tem ligação com duas linhas de pesquisa, a saber: a inferência estatística abordando aspectos da teoria assintótica e a inferência bayesiana considerando aspectos de modelagem e critérios de seleção de modelos baseados em métodos de simulação de Monte Carlo em Cadeia de Markov (MCMC). Uma primeira etapa consiste em apresentar a classe dos modelos não-lineares heterocedásticos simétricos bem como a inferência clássica dos parâmetros desses modelos. Posteriormente, propomos uma abordagem bayesiana para esses modelos, cujo objetivo é mostrar sua viabilidade e comparar a inferência bayesiana dos parâmetros estimados via métodos MCMC com a inferência clássica das estimativas obtidas por meio da ferramenta GAMLSS. Além disso, utilizamos o método bayesiano de análise de influência caso a caso baseado na divergência de Kullback-Leibler para detectar observações influentes nos dados. A implementação computacional foi desenvolvida no software R e para detalhes dos programas pode ser consultado aos autores do trabalho / The normal regression models have been used for many years for data analysis. Even in cases where normality could not be assumed, was trying to be some kind of transformation in order to achieve the normality sought. However, in practice, these assumptions about normality and linearity are not always satisfied. As alternatives to classical technique new classes of regression models were developed. In this context, we focus on the class of models in which the distribution assumed for the response variable belongs to the symmetric distributions class. The aim of this work is the modeling of this class in the bayesian context, in particular the modeling of the nonlinear models heteroscedastic symmetric class. Note that this work is connected with two research lines, the statistical inference addressing aspects of asymptotic theory and the bayesian inference considering aspects of modeling and criteria for models selection based on simulation methods Monte Carlo Markov Chain (MCMC). A first step is to present the nonlinear models heteroscedastic symmetric class as well as the classic inference of parameters of these models. Subsequently, we propose a bayesian approach to these models, whose objective is to show their feasibility and compare the estimated parameters bayesian inference by MCMC methods with the classical inference of the estimates obtained by GAMLSS tool. In addition, we use the bayesian method of influence analysis on a case based on the Kullback-Leibler divergence for detecting influential observations in the data. The computational implementation was developed in the software R and programs details can be found at the studys authors

Dans cette thèse nous rappelons la notion de L-algèbre, qui a pour objet d'être un modèle algébrique des types d'homotopie. L'objectif principal de cette thèse est la description d'une structure de E-infini-coalgèbre sur l'élément principal d'une L-algèbre. Ceci peut être vu comme une généralisation de la structure de E-infini-coalgèbre sur le complexe des chaînes d'un ensemble simplicial, telle que décrite par Smith dans Iterating the cobar construction, 1994. Nous construisons une E-infini-opérade, notée K, utilisée pour construire la E-infini-coalgèbre sur l'élément principal d'une L-algèbre. Cette structure de E-infini-coalgèbre montre que la L-algèbre canoniquement associée à un ensemble simplicial contient au moins autant d'information homotopique que la E-infini-coalgèbre couramment associée à un ensemble simplicial / In this thesis we recall the notion of L-algebra. L-algebras are intended as algebraic models for homotopy types. L-algebras were introduced by Alain Prouté in several talks since the eighties. The principal objective of this thesis is the description of an E-infinity-coalgebra structure on the main element of an L-algebra. This can be seen as a generalization of the E-infinity-coalgebra structure on the chain complex associated to a simplicial set given by Smith in Iterating the cobar construction, 1994. We construct an E-inifity-operad, denoted K, used to construct the E-inifity-coalgebra on the main element of a L-algebra. This E-inifity-coalgebra structure shows that the canonical L-algebra associated to a simplicial set contains at least as much homotopy information as the E-inifity-coalgebras usually associated to simplicial sets.

The main goal of this master's thesis is building of web portal for presentation basic cryptography algorithms. Those algorithms would be explained in the theoretical page in the first place. After that, they would be demonstrated by scripts. One part of this project is designing simplified theoretical element for basic impletion portal of information. Next part is creating web portal by one of the free available CMS´s systems. Programming language JAVA would be used as an instrument for creating demonstration scripts. For creating animations will be used the Flash animation tool. Target of formed web portal is creating community of expert public. It would make new articles, scripts and knowledge. This way, the portal would be kept current. The section which would include failure the most widely used algorithms and instructions how to eliminate it will be part of portal.

The master’s thesis outlines the problem of authentication. It describes authentication factors like ownership, knowledge and inherent. There are described properties of each of that. Authentication based on ownership focuses on authenticators - the smartcards. The thesis also describes different types of smartcards (contact, contactless and hybrid smartcards) and refers to their basic properties. Emphasis is placed on the description of contact and contactless smartcard, specifically focusing on .NET smartcards. It describes their internal components such as memory (RAM, ROM, EEPROM), crypto processor etc. Smartcards are also examined in terms of support for cryptographic primitives. The thesis also introduces the cryptographic methods and principles describing symmetric and asymmetric ciphers. Symmetric ciphers are divided in to stream and block ciphers. There is description of asymmetric cipher, digital signature etc. This work also touches on the fundamental principles required for safe programming. Part of this work is also practical implementation (programs). Practical part aims to implement the communication between the user and AC (Access Control) AASR system. The first suite of applications provides encrypted communication between the PC and smartcards. These applications should create on smartcard services that will be able to perform operations on the client side, which are necessary to authenticate in the AASR system. The paper also presents algorithms for working with big numbers - addition, subtraction, multiplication, and Montgomery's algorithm for multiplication. The second application implements the functionality of AC components (Access Control). This functionality is for example – authenticate received token, digital signature authentication, generating random numbers, logging etc.

The objective of the thesis is to design and implement in the VHDL language a simple multiprocessor supporting parallel computing. Furthemore, the author has designed and realized universal transparent generic interconnection layer with the objective to connect any given number of processor cores to shared address space using arbitrated bus. Parametrized cache has been allocated to each core in the layer. MSI protocol was used to deal with the issue of memory coherence of the implemented system. Direct and indirect synchornisation support is available to the user. In order to verify the functionality of the system, simple processor core has been designed and implemented, and its copies were connected to the interconnection layer. Various testing programmes have been used to verify the functionality of the system, which also confirmed that the acceleration of computing has been achieved successfully. Virtex6 chip has been used to test the whole system.

Les batteries à électrolyte circulant ou redox flow batteries (RFB) représentent une technologie prometteuse pour répondre aux besoins grandissants de stockage d'énergie. Elles seraient particulièrement adaptées aux réseaux électriques qui comptent une part grandissante d'énergie d'origine renouvelable, produite en intermittence. L'objet de ce travail est l'étude d'un nouveau type de RFB, actuellement développé par l'entreprise Kemiwatt. Il repose sur l'utilisation de molécules organiques, qui sont abondantes et recyclables. Le but de cette étude est d'améliorer la compréhension fondamentale de la batterie grâce à l'utilisation d'outils d'analyse précis et innovants. Chaque composant du système a d'abord été analysé via des moyens expérimentaux ex-situ. Les deux électrolytes composant la batterie ont ensuite été étudiés séparément en conditions réelles de circulation dans une cellule symétrique. Couplées à un modèle d'électrode volumique, les données ont été analysées pour identifier les facteurs limitants de chaque solution. La batterie entière a ensuite été étudiée dans un dispositif segmenté, permettant l'accès à la distribution interne du courant. Une étude paramétrique, réalisée avec la cellule segmentée a permis d'observer les effets du courant, du débit et de la température sur le fonctionnement de la cellule, puis d'établir une cartographie des conditions de fonctionnement idéales, suivant la puissance et l'état de charge de la batterie. L'aspect hydrodynamique du système a finalement été abordé en développant un modèle fluidique ainsi qu'une maquette expérimentale de cellule transparente pour visualiser l'écoulement. / Redox Flow Batteries (RFBs) are a promising solution for large-scale and low-cost energy storage necessary to foster the use of intermittent renewable sources. This work investigates a novel RFB chemistry under development at the company Kemiwatt. Based on abundant organic/organo-metallic compounds, this new technology promises the deployment of sustainable and long-lived systems. The study undertakes the building of a thorough knowledge base of the system by developing innovative reliable analytical tools. The investigation started from the evaluation of the main factors influencing the battery performance, which could be conducted ex-situ on each material composing the cell. The two electrolytes were then examined independently under representative operating conditions, by building a symmetric flow cell. Cycling coupled with EIS measurements were performed in this set-up and then analyzed with a porous electrode model. This combined modeling-experimental approach revealed unlike limiting processes in each electrolyte along with precautions to take in the subsequent steps (such as membrane pretreatment and electrolyte protection from light). A segmented cell was built and validated to extend the study to the full cell system. It provided a mapping of the internal currents, which showed high irregularity during cycling. A thorough parameter study could be conducted with the segmented platform, by varying successively the current density, the flow rate, and the temperature. The outcome of this set of experiments would be the construction of an operational map that guides the flow rate adjustment, depending on the power load and the state of charge of the battery. This strategy of flow rate optimization showed promising outcomes at the lab-cell level. It can be easily adapted to real-size systems. Ultimately, an overview of the hydrodynamic behavior at the industrial-cell level was completed by developing a hydraulic modeling and a clear cell as an efficient diagnostic tool.

The field of statistics is becoming increasingly more important as the amount of data in the world grows. This thesis studies the Growth Curve model in multivariate statistics which is a model that is not widely used. One difference compared with the linear model is that the Maximum Likelihood Estimators are more complicated. That makes it more difficult to use and to interpret which may be a reason for its not so widespread use. From this perspective this thesis will compare the traditional mean estimator for the Growth Curve model with the unweighted mean estimator. The unweighted mean estimator is simpler than the regular MLE. It will be proven that the unweighted estimator is in fact the MLE under certain conditions and examples when this occurs will be discussed. In a more general setting this thesis will present conditions when the un-weighted estimator has a smaller covariance matrix than the MLEs and also present confidence intervals and hypothesis testing based on these inequalities.

S-boxes are key components of many symmetric cryptographic primitives. Among them, some block ciphers and hash functions are vulnerable to attacks based on differential cryptanalysis, a technique introduced by Biham and Shamir in the early 90’s. Resistance against attacks from this family depends on the so-called differential properties of the S-boxes used. When we consider S-boxes as functions over finite fields of characteristic 2, monomials turn out to be good candidates. In this Master’s Thesis, we study the differential properties of a particular family of monomials, namely those with exponent 2ͭᵗ-1 In particular, conjectures from Blondeau’s PhD Thesis are proved. More specifically, we derive the differential spectrum of monomials with exponent 2ͭᵗ-1 for several values of t using a method similar to the proof Blondeau et al. made of the spectrum of x -<img src="http://www.diva-portal.org/cgi-bin/mimetex.cgi?%5Crightarrow" /> x⁷. The first two chapters of this Thesis provide the mathematical and cryptographic background necessary while the third and fourth chapters contain the proofs of the spectra we extracted and some observations which, among other things, connect this problem with the study of particular Dickson polynomials.