La molécule de méthane possède la liaison C-H la plus forte parmi les hydrocarbures (BDE = 104 kcal mol-1) : son oxydation en conditions douces représente un challenge d'importance. La Méthane Monoxygénase particulaire (pMMO) est une enzyme à cuivre qui catalyse l'oxydation du méthane (CH4) en méthanol (CH3OH). Le site actif de l'enzyme est composé d'atomes de cuivre séparés par 2.6 Å. Des recherches récentes suggèrent qu'un cluster Cu2 III,II/O2 à valence mixte soit un intermédiaire-clé du cycle catalytique. L'objectif de ce travail vise à la synthèse et caractérisation de nouveaux complexes dinucléaires à valence mixte de type bis(µ-oxo)Cu2 III,II ou (µ-OH, µ-O)Cu2 III,II. Deux familles de motifs coordinants ont été mises en oeuvre, polypyridyle ou polyamide ; les deux sites sont assemblés par des ponts courts et rigides, phenoxo, naphthyridine ou alkoxo. De nouveaux complexes ont été caractérisés par électrochimie, spectroscopies UV-visible et RPE, et par des calculs théoriques. Un dispositif original de cryo-spectroélectrochimie UV-vis-NIR a été développé en parallèle de cette étude : il permet l'identification spectroscopique d'intermédiaires transitoires, réputés très instables à température ambiante. De nouveaux composés à valence mixte, Cu2 III,II(μ-OH, μ-O) et Cu2 III,IIbis(μ-OH) ont été identifiés. Ces résultats élargissent le champ des données de cette famille d'intermédiaires instables limitée jusqu'ici à un seul exemple. / Methane has the strongest C-H bond of any hydrocarbon (BDE = 104 kcal mol-1); its oxidation under mild conditions remains a great challenge. The particulate Methane Monooxygenase (pMMO) is a copper enzyme that oxides methane (CH4) to methanol (CH3OH). In the active site of the enzyme, two copper ions are located at a short distance (2.6 Å). Recent researches have suggested a mixed-valent Cu2III,II/O2 cluster as a key intermediate in the catalytic cycle. The main objective of this work was the synthesis and characterization of new mixed-valent CuIIICuII bis(μ-oxo) and (μ-OH, μ-O) dinuclear complexes. For this purpose we designed promising symmetrical and unsymmetrical complexes based on specific and distinct scaffolds for each side of the structure. Two families of coordination pattern have been used, polypyridyle or polyamide; the two sites are shortly and rigidly bridged by phenoxo, alkoxo or naphthyridine linkers. New complexes have been characterized by electrochemistry, UV-vis and EPR spectroscopies, and by theoretical calculations. A new cryo-UV-Vis-NIR spectroelectrochemical set up, developed in parallel during this work, has allowed the spectroscopic identification of these transient intermediate species, known to be unstable at room temperature. New mixed-valence Cu2 III,II(μ-OH, μ-O) and Cu2 III,IIbis(μ-OH) complexes have been characterized. These results expand the recent knowledge on the only mixed valent CuIII(μ-OH)CuII species described so far.

Despite the fact that a preponderance of past studies in corporate finance mainly focus on capital structure decision of firms, the problems of “what factors determine the capital structure choice of firms and how firms adjust their capital structure dynamically” are still riddling. Hence, the aim of this study is to investigate the determinants of capital structure and capital structure adjustment dynamics of banks. To this end, the study employed a quantitative research approach. Specifically, secondary data have been collected through document review of annual reports of selected banks for longitudinal/panel research design. Besides, primary data have been collected through a self- administered questionnaire distributed to the selected Chief Financial Officers (CFOs) for the cross-sectional survey research design of the study. As the method of data analysis, the study estimates both static and dynamic panel models using fixed effect and GMM estimators respectively. Besides, in analyzing the cross-sectional survey responses, appropriate statistical techniques for order-ranked and nominal/categorical items of the responses have been employed. Specifically, in the univariate analysis of survey responses, mean scores and percentage of categorical responses have been computed for order-ranked and nominal items respectively. Moreover, to test the significance of differences of mean scores of order-ranked and percentage of responses of nominal items conditional on bank characteristics, the study employed the nonparametric Mann-Whitney test and the likelihood ratio test respectively. As the result, the tax shield from interest tax deductibility, profitability and/or size of free cash flows, growth opportunities and regulatory pressure factors are found to be significant determinants of capital structure decisions, consistently in estimations of panel models and cross-sectional survey. In iii examining the capital structure adjustment dynamics, both the regression estimation and survey results revealed the tendency of banks in Ethiopia to set target capital structure and adjust towards it at a relatively faster speed of adjustment. Besides, both regression model estimation and survey results disclose the asymmetrical target capital structure adjustment of banks. To be specific, overleveraged or undercapitalized banks adjust more quickly than underleveraged or overcapitalized banks. Further, the speed of target capital structure adjustment is found to be heterogeneous across banks that differ in their absolute deviations from target capital structure, size, regulatory pressure for capital adequacy and ownership. Hence, by empirically examining the determinants and dynamics of capital structure of banks in Ethiopia, the study contributes to the existing body of knowledge on the subject under study, and/or it fills a gap in the existing reference literature on the subject. Most importantly, the study tries to untangle the capital structure issues of banks, especially the dynamics, in the context of the least developed financial system where there are no secondary market and oligopolistic banking sector. / Graduate School of Business Leadership (SBL) / D.B.L.

À la fois procédé artistico-littéraire et réflexion intellectuelle, la mise en abyme est une des stratégies de création favorites du romancier Umberto Eco. Certains auteurs ont utilisé cette technique uniquement pour de créer de « simples » jeux de miroirs (comme c’est le cas des Nouveaux Romanciers). Chez Umberto Eco, la mise en abyme est destinée à faire saillir aussi bien l’intelligibilité que la structuration de l’oeuvre. Elle est un principe récursif de la génération de figures et de formes narratives fractales : elle est pour ainsi dire le raisonnement servant comme base dans la création d’un univers romanesque par excellence autoréflexif. Selon une représentation très succincte (mais essentielle), la mise en abyme est ce dispositif narratif consistant à insérer un (ou plusieurs) récit(s) dans le Récit, qui, en reproduisant les caractéristiques de ce dernier va (vont) l’illustrer, l’expliquer et mettre en évidence le/les thème(s) de l’oeuvre. / An artistic and literary procedure and, at the same time, an intellectual reflexion, mise en abyme is one of the favorite strategies of creation of the novelist U. Eco. Certain authors have used this technique just to create "simple" games of mirrors (such as the French writers called "Nouveaux Romanciers"). In the case of Umberto Eco, mise en abyme is destined to emphasize both the intelligibility of his work, as well as its being structured in multiple layers of narrativity. We reckon that this is the recursive principle, serving at the generating of fractal shapes and characters: this is therefore the reasoning laying at the foundation of creating a fictional universe self-reflective par excellence. If we want a very concise (but essential) representation, we will say that the mise en abyme is that device consisting of the insertion of one or many more stories into The Story, which, by reproducing the characteristics of the latter, provides us with an explanation and will shed light on the theme / themes of the work.

In this thesis, a Sb/C composite electrode for sodium-ion batteries isprepared by a simple high energy ball milling and calenderingmethod. The prepared Sb/C composite electrode was assembled in ahalf-cell and symmetrical cell setups in order to perform avariety of electrochemical measurements.The composite electrode showed a reversible specific capacity of595 mAh/g, at a discharge/charge current rate of 15 mA/g. Theelectrode also showed a relatively good performance (compared toprevious studies) of 95% capacity retention after more than 100cycles, at a higher discharge/charge current rate of 60 mA/g. Theelectrode furthermore showed excellent self-dischargecharacteristics, in pause tests implemented over 200 hours (overeight days), which underlined the electrode materials good shelflife properties. A series of Sb/C symmetrical cells assembledthrough-out the project, furthermore, highlighted the stability ofthe solid electrolyte interface (SEI) layer formed on the Sb/Ccomposite electrode during cycling. Scanning electron microscopy(SEM) and Energy-dispersive X-ray spectroscopy (EDS) were used tocharacterize the surface morphology and composition of the Sb/Celectrode, respectively.A non-milled and milled (12 hours) graphite electrodes were alsoprepared for reference and comparison. The milled graphite matrixelectrode provided a reversible capacity of 95 mAhg-1 and acoulombic efficiency (CE) of 99% in over 250 cycles, at a currentrate of 30 mA/g. Milled and non-milled graphite were characterizedwith SEM and Raman spectroscopy, to help have a fundamentalunderstanding of the particle size and material phase,respectively.

An algorithm that is capable of estimating the parameters of non-stationary sinusoids in real-time lends application to various branches of engineering. Non-stationary sinusoids are sinusoidal signals with time-varying parameters. In this dissertation, a nonlinear filter is applied to power system applications to test its performance. The filter has a structure which renders it fully adaptive to tracking time variations in the parameters of the targeted sinusoid, including its phase and frequency. Mathematical properties of the differential equations which govern the proposed filter are presented. The performance of the proposed filter in the field of power systems is demonstrated with the aid of computer simulations and practical experimentations. The filter is applied to synchronous generator excitation control, voltage dip mitigation as well as the real-time estimation of symmetrical components. The parameter settings of the filter are tested and optimized for each of the applications. This dissertation demonstrates the simulation and experimental results of the filter when applied to the various power system applications. AFRIKAANS : 'n Filter wat bevoeglik is met die beraming van die parameters van beweeglike sinusoïdale in ware-tyd, kan bruikbaar aangewend word in verskeie takke van ingenieurswese. Beweeglike sinuskrommes is sinusoïdale seine met tyd-wisselende parameters. In hierdie verhandeling word `n nie-liniêre filter aangewend in verskeie kragstelseltoepassings om die werksverrigting van die filter te toets. Die filter het 'n struktuur wat dit toelaat om wisselende tydvariasies in die parameters van die teikensinusoïdaal op te spoor, insluitende die fase en frekwensie. Wiskundige eienskappe van die differensiaalvergelykings wat die voorgestelde filter beheer is ondersoek. Die werksverrigting van die voorgestelde filter in die veld van kragstelsels is gedemonstreer met die hulp van rekenaarsimulasies asook praktiese eksperimente. Die filter is toegepas tot opgewekte, sinkrone eksitasie-beheer, spanningsverlaging versagting, asook die ware tyd estimasie van simmetriese komponente. Die parameter verstellings van die filter is getoets en geoptimeer vir elk van die toepassings. Hierdie verhandeling demonstreer die simulering en eksperimentele resultate van die filter wat aangewend is vir verskeie kragstelseltoepassings. Copyright / Dissertation (MSc)--University of Pretoria, 2010. / Electrical, Electronic and Computer Engineering / unrestricted

This thesis deals with a design of a power supply for a measuring equipment for a geophysical mapping intended to do a reconstruction of an electrical impedance of a ground environment of water reservoirs. The power source is going to be used for laboratory measurements and for outdoor experiments. The thesis describes the selection of suitable components, equipment design and testing. The theoretical part explains the functions of used components and the principle of an electrical impedance tomography. The conclusion summarizes the properties of the proposed solution and evaluates the final product.

The thesis describes the radiation of dipole antennas in near field area. More methods for evaluation of spatial dipole field arrangement are compared. The work target for practical use is to create software for simulation of near field values placed in planar or cylindrical observation plane. The computer programme is applicable to single dipole or dipole array. The limits for human body exposition of non-ionizing radiation are here implemented for compliance purpose in hygienic evaluations. The simulated results of field distribution are possible to display as graphs or save to data file. The results of own calculation are compared with results obtained by some commercial software as well by measurement of field components under model conditions.

Distribution network 110 kV owned by E. ON in the area Otrokovice; powered by 110 kV and two variants of involvement contained.The first option is basic involvement, without the use of the bridge. The second option includes involvement with the bridge. The aim of this study is to compare; by calculating the steady-state network operation and short circuit conditions of the network, the involvement of these two options. The thesis is divided into two parts, theoretical and practical. The theoretical part consists of a description of the steady operation of networks of high-voltage and short circuit ratio calculations. Load flow calculations are described by the Gauss-Seidel and Newton iterative method. In the case of short-circuit conditions, the effects of their characteristic values, processes and various methods of calculation are described.In the second part, this theoretical knowledge is applied to input data and dispatching programme with the appropriate calculations of network operation and short circuit conditions. The calculated values are listed in the thesis, on the basis of which an evaluation of the two possible connections is made.

There was solved reinforced concrete cooling tower in the diploma thesis. This is a rotationally symmetrical construction. The cooling tower is concrete shell on columns. The cooling tower was solved using the finite element method, computer program Midas FEA. The work includes: calculation using the program Midas FEA, comparison of load between eurocode and foreign literature, the design of shell and columns, drawings form

Pour mieux comprendre la combustion en mode stratifié, la propagation de flammes au sein de stratifications de richesse laminaire ou turbulente a été étudiée par des mesures simultanées de richesse et de vitesse effectuées par couplage de la PIV et de la PLIF. L’accent a été mis sur le développement de méthodes permettant d’améliorer la qualité des mesures locales. En particulier, un nouvel algorithme de PIV permettant la mesure locale de la vitesse des gaz frais véritablement à l’entrée de la zone de préchauffage a été développé. Pour améliorer la résolution,les mailles de calcul s’adaptent localement à la topologie de la flamme, pour tenir compte de la forme du front de flamme et de l’expansion des gaz. L’analyse statistique des mesures conditionnée sur la richesse locale a permis de caractériser les propriétés de la flamme soumise à une stratification de richesse dans un écoulement laminaire et turbulent, en particulier en mettant en évidence un effet mémoire. / In order to better understand the stratified combustion, the propagation of flame through stratified mixture field in laminar and turbulent flow conditions has been studied by using combined PIV/PLIF techniques. A great emphasis was placed on developing methods to improve the accuracy of local measurements of flame propagation. In particular, a new PIV approach has beendeveloped to measure the local fresh gas velocity near preheat zone of flame front. To improve the resolution of measurement, the shape of interrogation window has been continuously modified based on the local flame topology and gas expansion effect. Statistical analysis of conditioned local measurements by the local equivalence ratio of flames allows the characterization of theproperties of flame propagation subjected to the mixture stratification in laminar and turbulentflows, especially the highlight of the memory effect.