Philosophiae Doctor - PhD / Low thermal conductivity is a primary limitation in the development of energy-efficient heat transfer fluids that are required in numerous industrial sectors. Recently submicron and high aspect ratio particles (nanoparticles and nanotubes) were introduced into the heat transfer fluids to enhance the thermal conductivity of the resulting nanofluids. The aim of this project was to investigate the physico-chemical properties of nanofluids synthesized using submicron and high aspect ratio particles suspended in heat transfer fluids. / South Africa

Thermal barrier coatings have been widely used to provide thermal protection to components in the hot section of gas turbines. This research focuses on two influencing factors on coating behavior: thermal gradient and cyclic oxidation. The delamination mechanics under thermal gradient is analyzed, taking thermally grown oxide into consideration. Coatings experience thermal gradients at different stages during actual service flight. One is due to engine power shut down when landing and the other due to internal cooling of the substrate. Thermally grown oxide (TGO) also acts as a critical factor in delamination mechanics. The induced stress gradient and corresponding energy release rate for interface delamination and shallower delamination are presented. Mechanism maps that explain the criteria for preventing delamination from developing and propagating are established. Three cooling trajectories are envisaged to analyze the variation in the possibility of delamination. Multilayer coatings used in components of the hot section of aero turbine engines also experience cyclic temperature variation during flight cycles. As experiment conditions vary and coating performance is improved, the time required to run through the test of coating failure can be both time-consuming and prohibitive. Therefore, protocols providing prediction of quantified coating behavior are in demand to shorten life-time tests. Curves of mass change are obtained from quantifying scale growth and loss by different models such as Cyclic Oxidation Spall Program (COSP). A modification is made by combining COSP and a mechanic based model to obtain critical parameters for lifetime prediction from short time experiment. The time for coatings to reach peak temperature during cycling is discovered to influence prominently on modeling results. Predictions for several coating compositions and cycling conditions are consistent with the data from the existing experiments of the coating system.

Made available in DSpace on 2014-06-11T19:25:27Z (GMT). No. of bitstreams: 0 Previous issue date: 2011-06-27Bitstream added on 2014-06-13T19:32:34Z : No. of bitstreams: 1 souza_lmp_me_bauru.pdf: 1572366 bytes, checksum: b4f3b5bc0ddb17fad3e39f5f59ec6a72 (MD5) / Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES) / No estudo de reaproveitamento de energia térmica, os refrigeradores domésticos dissipam calor para o meio ambiente, através do seu condensador, e esse calor pode ser reciclado, ou seja, recuperado através de escoamento de água, como fluido refrigerante escoando pelo condensador e armazenada em um reservatório. Para isto, construi-se um aparato experimental contendo um refrigerador doméstico, duplex com capacidade de 263 litros para o gabinete de refrigeração e 74 litros para o gabinete de congelamento. O refrigerador tem seu condensador acrescido por um trocador de calor tipo tubos concêntricos em contra corrente, cuja fruição é condensar o fluido refrigente utilizando água em circulação. Dessa forma, caso ocorra o carregamento térmico total do tanque de armazenagem, o calor será originalmente dissipado para o meio ambiente, através do condensador aletado. A água aquecida é então armazenada em um reservatório térmico via estratificação térmica. Assim calculou-se as vazões de água aquecida e fluido refrigerante, como também o coeficiente de desempenho do sistema acumulado. Os resultados mostraram que a vazão de água bem como o coeficiente de desempenho do sistema aumenta de acordo com o aumento da pressão hidrostática. Desta maneira, dos resultados obtidos pode-se concluir que a otimização do experimento se dá de forma eficaz e que, o reaproveitamento da água quente proveniente do condensador é perfeitamente possível, reduzindoo consumo de energia elétrica com aquecedores de água e ainda, minimizando a dissipação de calor para o meio ambiente, sem alterar o funcionamento do refrigerador / In the study of recycling thermal energy it is know that domestic refrigerators dissipate heat to environment through the condenser. This heat can be recycled by a water flow, as a coolant in a modified condenser, and stored in a Domestic Hot Water Storage Tanks (DHWST). Thereby, an experimental apparatus was built containing one domestic refrigerator, each one with capacity of 263 liters in the cooling cabinet and 74 liters in the freezing cabinet. The refrigerators had the condenser increase by a type heat exchanger concentric tubes with a counter-current flow, which has the function of replace the original finned exchanger, condensing the coolant with water flow. Thus, in case the total thermal loading of the storage tank, the heat is dissipated to the original environment through the condenser finned. The heated water is then stored in a thermal reservoir via thermal stratification. In these conditions, the flow of heated water and refrigerant was calculated, as well as the coefficient of performance of the system. The results show that the water flow rate and the coefficient of performance of the system increases with the increase in hydrostatic pressure. According to these results, the experiment optimization is effective and it is totally possible to reuse the warm from modified condenser system, what could reduce the electric energy consumption in water beater and minimize the heat dissipation to environment, without modifying the refrigerator operation

abstract: This research effort focuses on thermal management system (TMS) design for a high-performance, Plug-in Hybrid Electric Vehicle (PHEV). The thermal performance for various components in an electrified powertrain is investigated using a 3D finite difference model for a complete vehicle system, including inherently temperature-sensitive components. The components include the electric motor (EM), power electronics, Energy Storage System (ESS), and Internal Combustion Engine (ICE). A model-based design approach is utilized, where a combination of experimental work and simulation are integrated. After defining heat sources and heat sinks within the power train system, temporal and spatial boundary conditions were extracted experimentally to facilitate the 3D simulation under different road-load scenarios. Material properties, surface conditions, and environmental factors were defined for the geometrical surface mesh representation of the system. Meanwhile the finite differencing code handles the heat transfer phenomena via conduction and radiation, all convective heat transfer mode within the powertrain are defined using fluid nodes and fluid streams within the powertrain. Conclusions are drawn through correlating experimental results to the outcome from the thermal model. The outcome from this research effort is a 3D thermal performance predictive tool that can be utilized in order to evaluate the design of advanced thermal management systems (TMSs) for alternative powertrains in early design/concept stages of the development process. For future work, it is recommended that a full validation of the 3D thermal model be completed. Subsequently, design improvements can be made to the TMS. Some possible improvements include analysis and evaluation of shielding of the catalytic converter, exhaust manifold, and power electronics, as well as substituting for material with better thermal performance in other temperature-sensitive components, where applicable. The result of this improvement in design would be achieving an effective TMS for a high-performance PHEV. / Dissertation/Thesis / Masters Thesis Engineering 2017

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Made available in DSpace on 2014-10-09T12:30:57Z (GMT). No. of bitstreams: 0 / Made available in DSpace on 2014-10-09T13:58:17Z (GMT). No. of bitstreams: 1 01386.pdf: 5820506 bytes, checksum: 6308c9f7dae1ed503a75ddfa5a2542db (MD5) / Dissertacao (Mestrado) / IPEN/D / Instituto de Pesquisas Energeticas e Nucleares - IPEN/CNEN-SP

Dimethylsilene, generated from the thermal gas phase reaction of 1,1-dimethyl-1-silacyclobutane, reacts with alkynes to produce silacyclobutenes or acyclic silanes. The temperature dependence of the product ratios have been determined and the relative reactivities of three different alkynes toward the 1,1-dimethylsilene has been determined. 1-Hydrido-1-methylsilene has been generated by gas phase thermal decomposition from three different precursors. Trapping studies with butadiene and trimethylsilane lead to products expected from dimethylsilylene. The most plausible explanation for these observations is that hydridomethylsilenes undergo a facile isomerization to divalent dimethylsilylene. Cycloaddition of 1,1-dimethylsilene to allene at 600°C in a flow vacuum pyrolysis system affords the first synthesis of 2-methylene-1,1-dimethylsilacyclobutane and smaller amounts of six other products. For static pyrolysis at 421°C, the 2-methylene-1,1-dimethyIsilacyclobutane isomerizes to 1,1-dimethylsilacyclopentenes. The kinetics of gas phase thermal decomposition of cyclopropyltrimethylsilane has been studied over the temperature range, 689.6-751.1 K at pressures near 14 torr. The Arrhenius parameters for formation of allyltrimethylsilane are k_1(sec^-1)=10^14.3 ± 0.1 exp(-56.5 ± 0.2 kcal mol^-1/RT) and those for the formation of E- and Z-1-propenyltrimethyIsilane are k_2(sec^-1)=10^14.9 ± 0.3 exp(-61.9 ± 0.8 kcal mol^-1/RT). The difference between activation energies has been interpreted in terms of anchimeric assistance or the β effect of the silicon atom. The syntheses of 3-trimethylsilyl-1-pyrazoline and 1-trimethyl-2-pyrazoline are described. The thermal decomposition of either pyrazoline affords four different products along with elimination of a nitrogen molecule. It was suggested that the relative rates of methylene-hydrogen migration to radical centers α and γ to silicon are approximately equal. The thermal isomerization of 3-trimethylsilyl-1-pyrazoline to 1-trimethylsilyl-2-pyrazoline has been investigated kinetically at 65°C by proton NMR spectroscopy and the reverse reaction has been detected by gas phase pyrolysis.

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To fully exploit the strengths of La2Zr2O7 pyroclores and promote them as a next-generation thermal barrier coating (TBC), the improvements of their thermally insulating property and fracture toughness are studied in this thesis. A strong phonon scattering source, rattlers, is found in Y3+-doped La2Zr2O7 pyrochlores. Rattlers dramatically flatten k (thermal conductivity)-T curves, or even make k approach the amorphous limit. The presence of rattlers is strongly dependent on (1) oversized atomic cages that are formed in pyrochlores; and (2) the occupation of smaller guest ions in those oversized cages. To maximize the rattling effect, In3+/Sc3+ ions that are much smaller than Y3+ are introduced to the La2Zr2O7 lattice. As envisaged, the smaller ions in the oversized lattice voids make k glass-like at a much lower doping content. Nevertheless, they are still not effective in reducing the high temperature plateau kmin. Instead, oxygen vacancies are very effective in reducing kmin, because they generate an electrostatic repulsion force among cations surrounding them, resulting in stronger lattice anharmonicity and weaker bonds. The plateau kmin is reduced dramatically by the filling of the B-sites in La2Zr2O7 with a 21% larger (and 50% heavier) Ce4+ guest ion rather than a 96% heavier (but similar-sized) Hf4+ ion, suggesting that a large absolute size of substitutional atoms is more effective in reducing kmin than a heavy absolute mass. This is because: (1) kmin is proportional to (E/M)0.5 (where E is the elastic modulus and M is the average atomic mass); (2) a larger size of guest ions tends to produce a weaker ionic bond and consequently, a lower E; and (3) the changing extent of E by introducing larger guest ions is much greater than that of M induced by adding heavier ones. Lastly, the fracture toughness (KIc) has been increased by dispersing the tetragonal 3 mol% Y2O3-stabilized zirconia (t-3YSZ) particulates in the La2Zr2O7 (LZ) matrix. The tendency of the dispersive t-3YSZ second phases transforming to monoclinic (m) phases strongly depends on the volume fraction introduced. For samples made from equilibrium route, they are toughened by phase transformations within the dispersive t-3YSZ second phases and a crack shielding effect arising from the residual compressive stress within the LZ matrix. An anticipated increase of KIc from ferroelastic toughening together with the residual compressive stress toughening highlights a potential to improve coating durability by depositing t’-3YSZ/LZ composite TBCs by the non-equilibrium route.