Anthropogenic Climate Change is amongst the greatest challenges of human civilization. A key area that will play a large role in mitigating its effects are clean fossil fuel applications. Clean coal combustion is one such application with an urgent timeline. This can be achieved with an oxygen-fired pressurized fluidized bed combustor with downstream carbon capture and sequestration. In relation to pressurized fluidization processes, understanding the influence of pressure on bed hydrodynamics and in turn their effect on parameters including fuel residence time is essential. For the proposed combustor, the heat exchanger boiler tubes are submerged in the fluidized bed such that the effect of a horizontal tube bank on the fuel residence time is also of great importance. The main focus of present work was to evaluate the impact of gas velocity, pressure, presence of a tube bank and fuel feed rate on the average fuel residence time. Experiments were conducted under cold flow conditions in a pilot-scale pressurized fluidized bed with an inner diameter of 0.15 m. The fluidization material was relatively large glass beads (1.0 mm in diameter) while the fuel particles were simulated with smaller glass beads (40 to 138 μm in diameter), susceptible to entrainment. Operating pressures and superficial gas velocities tested were between 101.3 and 1200 kPa and 0.4 and 1.1 m/s respectively. To simulate coal combustors, experiments were then conducted in a continuous mode where the fuel particles were continuously fed to the fluidized bed of large particles over a desired period of time. Downstream, entrained particles were continuously captured to determine the entrainment rate and mass of fuel particles inside the fluidized bed at steady state, which yielded the average fuel residence time. The combination of elevated pressure with the tube bank present was found to enhance gas bubble break up and reduce the average gas bubble size. In turn, this increased the average fuel residence time of 83 μm particles by nearly 3 fold to a value of 77 s in comparison to 27 s at atmospheric pressure. The effect of gas velocity was not found to be statistically significant under the range tested. Similarly the effect of increased fuel feed rate by 50% neither had a statistically significant impact.

Parabolic trough systems are one of the most commercially and technically developed technologies for concentrated solar power. With the current research and development efforts, the cost of electricity from these systems is approaching the cost of electricity from medium-sized coal-fired power plants. Some of the cost-cutting options for parabolic trough systems include: (i) increasing the sizes of the concentrators to improve the system’s concentration ratio and to reduce the number of drives and controls and (ii) improving the system’s optical efficiency. However, the increase in the concentration ratios of these systems requires improved performance of receiver tubes to minimise the absorber tube circumferential temperature difference, receiver thermal loss and entropy generation rates in the receiver. As such, the prediction of the absorber tube’s circumferential temperature difference, receiver thermal performance and entropy generation rates in parabolic trough receivers therefore, becomes very important as concentration ratios increase. In this study, the thermal and thermodynamic performance of parabolic trough receivers at different Reynolds numbers, inlet temperatures and rim angles as concentration ratios increase are investigated. The potential for improved receiver thermal and thermodynamic performance with heat transfer enhancement using wall-detached twisted tape inserts, perforated plate inserts and perforated conical inserts is also evaluated. In this work, the heat transfer, fluid flow and thermodynamic performance of a parabolic trough receiver were analysed numerically by solving the governing equations using a general purpose computational fluid dynamics code. SolTrace, an optical modelling tool that uses Monte-Carlo ray tracing techniques was used to obtain the heat flux profiles on the receiver’s absorber tube. These heat flux profiles were then coupled to the CFD code by means of user-defined functions for the subsequent analysis of the thermal and thermodynamic performance of the receiver. With this approach, actual non-uniform heat flux profiles and actual non-uniform temperature distribution in the receiver different from constant heat flux profiles and constant temperature distribution often used in other studies were obtained. Both thermodynamic and multi-objective optimisation approaches were used to obtain optimal configurations of the proposed heat transfer enhancement techniques. For thermodynamic optimisation, the entropy generation minimisation method was used. Whereas, the multi-objective optimisation approach was implemented in ANSYS DesignXplorer to obtain Pareto solutions for maximum heat transfer and minimum fluid friction for each of the heat transfer enhancement techniques. Results showed that rim angles lower than 60o gave high absorber tube circumferential temperature differences, higher receiver thermal loss and higher entropy generation rates, especially for flow rates lower than 43 m3/h. The entropy generation rates reduced as the inlet temperature increased, increased as the rim angles reduced and as concentration ratios increased. Existence of an optimal Reynolds number at which entropy generation is a minimum for any given inlet temperature, rim angle and concentration ratio is demonstrated. In addition, for the heat transfer enhancement techniques considered, correlations for the Nusselt number and fluid friction were obtained and presented. With heat transfer enhancement, the thermal efficiency of the receiver increased in the range 5% – 10%, 3% – 8% and 1.2% – 8% with twisted tape inserts, perforated conical inserts and perforated plate inserts respectively. Results also show that with heat transfer enhancement, the absorber tube’s circumferential temperature differences reduce in the range 4% – 68%, 3.4 – 56% and up to 67% with twisted tape inserts, perforated conical inserts and perforated plate inserts respectively. Furthermore, the entropy generation rates were reduced by up to 59%, 45% and 53% with twisted tape inserts, perforated conical inserts and perforated plate inserts respectively. Moreover, using multi-objective optimisation, Pareto optimal solutions were obtained and presented for each heat transfer enhancement technique. In summary, results from this study demonstrate that for a parabolic trough system, rim angles, concentration ratios, flow rates and inlet temperatures have a strong influence on the thermal and thermodynamic performance of the parabolic trough receiver. The potential for improved receiver thermal and thermodynamic performance with heat transfer enhancement has also been demonstrated. Overall, this study provides useful knowledge for improved design and efficient operation of parabolic trough systems. / Thesis (PhD)--University of Pretoria, 2015. / tm2015 / Mechanical and Aeronautical Engineering / PhD / Unrestricted

Orientador: Carlos Teofilo Salinas Sedano / Dissertação (mestrado) - Universidade Estadual de Campinas, Faculdade de Engenharia Mecânica / Made available in DSpace on 2018-08-27T04:21:17Z (GMT). No. of bitstreams: 1 Armengol_JanMateu_M.pdf: 6999606 bytes, checksum: e35806586b55eb3f8f1b370625009ba8 (MD5) Previous issue date: 2015 / Resumo: Neste trabalho é apresentado um modelo para a formação de gelo poroso entre placas planas paralelas baseado em um novo tratamento bidimensional da taxa de crescimento. O modelo considera as equações de transporte de quantidade de movimento, energia e massa. Para a resolução do modelo, as equações são discretizadas usando o método de volumes finitos em um domínio bidimensional composto por ar e gelo poroso. A interface móvel ar-gelo é tratada utilizando a formulação de malha fixa. O domínio computacional inclui a região frontal das placas planas com a finalidade de estudar o crescimento do gelo poroso nessa região. O código numérico é verificado por partes de acordo com artigos de referência na literatura e o modelo é validado com dados experimentais. Os dados experimentais, reportando temperatura e crescimento de forma locais, coincidem com os resultados numéricos com um erro relativo inferior a 10 \% para o caso intermediário de taxa de umidade / Abstract: In this study, a frost formation model is presented based on a new two-dimensional approach for the growth rate. For modeling the frost formation over parallel cold plates, the basic transport equations of mass, energy and momentum have been discretized using the finite volume method in a two-dimensional domain in which air and frost are considered. A volume tracking method employing a fixed grid formulation is used to deal with the air-frost moving boundary. An extended domain in the inlet boundary has been considered in order to study the frost formation in the leading edge of the plate. The numerical code is gradually verified using benchmarking references. The numerical results have been validated against experimental data in which frost growth and temperature as a function of time are reported as local values. The model predictions of the frost thickness as a function of time agree with the experimental data within 10 \% of deviation for the case of intermediate humidity ratio / Mestrado / Termica e Fluidos / Mestre em Engenharia Mecânica

With a birth prevalence of 1 in 1000, neural tube defects (NTD)s contribute considerably to morbidity and healthcare costs. Known genetic and environmental (non-inherited) risk factors for NTDs account for a small portion of risk, suggesting unidentified risk factors. In animal studies, maternal alcohol and pesticide exposures, independently, led to excess neural cell death, resulting in too few cells for neural tube closure. Human studies report no association between alcohol exposure and NTDs, but small to moderate positive associations for pesticide exposure. Such human etiologic studies of NTDs require a large base population, but frequently include only live births. Exclusion of cases by pregnancy outcomes may create ascertainment and response bias, complicating interpretation of findings. Using data from the National Birth Defects Prevention Study (NBDPS) and the Iowa Registry for Congenital and Inherited Disorders (IRCID), the independent effects of maternal periconceptional (1 month prior through 2 months postconception) alcohol and occupational pesticide exposure on the development of NTDs were examined, and differences in Iowa NTD cases were characterized by pregnancy outcome. Maternal reports of alcohol exposure were obtained for 1223 NTD case infants and 6807 control infants. Adjusted odds ratios, estimated using multivariate logistic regression, were near unity for NTDs by any maternal alcohol exposure, binge episode(s), and type(s) of alcohol consumed. Occupational pesticide exposure was assigned by industrial hygienists for mothers of 502 case and 2950 control infants. Adjusted odds ratios for any exposure and cumulative exposure to any pesticide, insecticides only, and insecticides + herbicides + fungicides were near unity for NTDs. Insecticide + herbicide exposure was positively associated with spina bifida. Among the 279 Iowa NTD case infants ascertained by the IRCID, 167 live births and 112 were other pregnancy outcomes (fetal deaths and elective terminations), which increased in proportion over time. Selected infant and maternal characteristics of live births and other pregnancy outcomes were similar. NBDPS eligibility varied significantly by pregnancy outcome, but participation rates did not. NTD case mothers were similar to Iowa NBDPS control mothers. Efforts were made to improve upon prior etiologic studies of these exposures and NTDs, including increased sample size and improved exposure specificity. Some exposure strata (e.g., herbicides only) and outcome strata (e.g., other rare subtypes) were limited by small numbers. All results may have been affected by response and ascertainment bias. Future studies should aim to use similarly detailed exposure classification methods, increase sample size in less prevalent NTD subtypes, and improve ascertainment of fetal deaths.

Titanium dioxide and aluminum oxide are conventional materials used in heterogeneous catalysis as catalyst support. The widely used crystalline phase of both supports is the metastable phase (anatase and γ-Al$_2$O$_3$) in which they possess a higher specific surface area compared to the thermodynamically stable phase (rutile and α-Al$_2$O$_3$). However, these phases have better thermal and mechanical stability than anatase and γ-Al$_2$O$_3$. A novel method to induce phase transformation and structural modification of crystalline materials is by applying shock waves. This study aims to experimentally investigate the effects of shock wave treatment on titania and alumina. A pressure-driven shock tube was used in this work to generate the shock waves. Two sets of experiments were carried out for TiO$_2$ and one for Al$_2$O$_3$. Titania samples were prepared in the form of pellets for the first set. Titania and alumina samples were maintained as powder for the second set of experiments. For titania, twenty shocks were applied at nominal temperature and pressure of ~ 1772 K and 23.3 bar in the first set of experiments, while thirty shocks of ~ 1572 K and 66 bar were applied in the second set of experiments. For alumina, twenty shock loadings were applied at the same conditions used for the second set of titania. Characterization techniques, such as XRD, Raman spectroscopy, TEM, SEM, XPS, and N$_2$ physisorption were employed on treated samples in order to understand the effects of shock wave treatment. Partial phase transformation was observed in shock treated TiO2 from Raman spectra and TEM images. Crystallite size reduction was observed in the first set of experiments, while increase in defects was observed by the enhanced Ti$^{+3}$ in XPS spectra in both sets of experiments. Partial phase transformation was also observed in shock treated Al$_2$O$_3$, when mixed with CNF (carbon nanofibers), from XRD patterns and confirmed with XPS. For alumina, TEM and SEM images showed the smallest particles in contact with carbon fibers, while the biggest particles exhibited agglomeration. Physisorption experiments showed a decrease of 40% in surface area and pore collapse.

Presented here are the results from the steady state flow boiling of R245FA in a laboratory scale horizontal stainless-steel test tube with an inner diameter of 8.5 mm and a length of 900 mm at a saturation temperature of 35 °C and 40 °C. Experiments were conducted at mass fluxes ranging between 200 and 300 kg/m²s at inlet vapour qualities from 0.2 to 0.7 under uniform, and non-uniform imposed heat flux cases that are expected to exist in horizontal parabolic trough solar collectors. Nine (9) different heat flux distributions were investigated. Local and average heat transfer coefficients (HTC’s) were determined based on wall temperature measurements taken along the length and around the circumference of the test section. Through the choice of the fluid being linked to the possible usage of DSG technology in organic Rankine cycles, the qualitative trends and observed performance variations can be used to predict the same for a working fluid such as water. It was found that the non-uniformity of the heat flux greatly alters the HTC’s of the fluid undergoing boiling but has no effect on the pressure drop characteristics of the fluid undergoing boiling. Heating only on the sides of the tube yielded HTC’s that were 46 % lower than achieved under uniform heating. Heating only from the top proved to be more effective in heat transmission to the fluid than heating only from the bottom (as is the case on PTC solar fields), by only a slight margin, and both these cases yielded HTC’s that were 30 % lower than the uniform heating case. Applying a bell curve heat flux distribution over the tube walls yielded overall HTC’s that differed from the uniform case by a maximum of 5 %, even as the peak heat flux position changes around the circumference of the tube. A further study may be done to quantify the degree to which the non-uniformity of the heat flux influences the local HTC’s, and to develop correlations that may aid in predicting these cases. An integration with flow pattern mapping may also be done to solidify the understanding of the phenomenon governing these observations. / Dissertation (MEng)--University of Pretoria, 2021. / Department for International Development (DFID) through Royal Society-DFID Africa Capacity Building Initiative. / The UK Engineering and Physical Sciences Research Council (EPSRC) [grant numbers EP/T03338X/I and EP/P004709/1]. / Russian Government "Megagrant" project 075-15-2019-1888. / Mechanical and Aeronautical Engineering / MEng / Unrestricted

The diploma thesis deals with the design of hybrid microphone preamplifier with stepless choice of amplification technology between active part using tube or semiconductor elements. Before the design, the basic physical relations of electroacoustics were described. Problems of connection of audio devices, their voltage and noise conditions. At last technical properties of microphones and tubes were described. In the practical part, the overall structure of the hybrid preamplifier is designed and the goals of the thesis are set. This is followed by a detailed design of the preamplifiers. From input circuits through individual amplifier stages of the semiconductor and tube sections to the output of the device. Much of the circuit was tested by software simulations. Based on the results obtained in the design of the signal part of the preamplifier, the power circuits were designed. Finaly the preamplifier functionality was verified by measurement on the Audio Analyzer.

Performance testing methods of boilers in transient operating conditions (start, stop and combustion power modulation sequences) need the combustion rate quantified to allow for the emissions to be quantified. One way of quantifying the combustion rate of a boiler during transient operating conditions is by measuring the flue gas flow rate. The flow conditions in chimneys of single family house boilers pose a challenge however, mainly because of the low flow velocity. The main objectives of the work were to characterize the flow conditions in residential chimneys, to evaluate the use of the Pitot-static method and the averaging Pitot method, and to develop and test a calibration method for averaging Pitot probes for low 𝑅𝑅𝑅𝑅.A literature survey and a theoretical study were performed to characterize the flow conditions in in single family house boiler chimneys. The flow velocities under normal boiler operating conditions are often below the requirements for the assumptions of non-viscous fluid justifying the use of the quadratic Bernoulli equation. A non-linear calibration coefficient is required to correct for these viscous effects in order to avoid significant measurement errors. The flow type in the studied conditions changes from laminar, across the transition regime, to fully turbulent flow, resulting in significant changes of the velocity profile during transient boiler operation. Due to geometrical settings occurring in practice measurements are often done in the hydrodynamic entrance region, where the velocity profiles are neither fully developed nor symmetrical. The predicted changes in velocity profiles are also confirmed experimentally in two chimneys.Several requirements set in ISO 10780 and ISO 3966 for Pitot-static probes are either met questionably or not met at all, meaning that the methods cannot be used as such. The main issues are the low flow velocity, viscous effects, and velocity profiles that change significantly during normal boiler operation. The Pitot-static probe can be calibrated for low 𝑅𝑅𝑅𝑅, but is not reliable because of the changing velocity profiles.The pressure averaging probe is a simple remedy to overcome the problems with asymmetric and changing velocity profiles, but still keeping low the irrecoverable pressure drop caused by the probe. However, commercial averaging probes are not calibrated for the characterized chimney conditions and the information available on the performance of averaging probes at low 𝑅𝑅𝑅𝑅 is scarce. A literature survey and a theoretical study were done to develop a method for calibrating pressure averaging probes for low 𝑅𝑅𝑒 flue gas flows in residential chimneys.The experimental part consists of constructing a calibration rig, testing the performance of differential pressure transducers, and testing a prototype pressure averaging probe. The results show good correlation over a wide operation range, but the low 𝑅𝑅𝑅𝑅 characteristics of the probe could not be identified due to instability in the chosen pressure transducer, and temperature correlation for one of the probes while not for the other. The differential pressures produced are close to the performance limitations of readily available transducers and it should be possible to improve the method by focusing on finding or building a suitable pressure transducer. The performance of the averaging method can be improved further by optimizing the geometry of the probe. Another way of reducing the uncertainty would be to increase the probe size relative to the conduit diameter to produce a higher differential pressure, at the expense of increasing the irrecoverable pressure drop.

Future thrusts for gasoline engine development can be broadly summarized into two categories: (i) efficiency improvements in conventional spark ignition engines, and (ii) development of advance compression ignition (ACI) concepts. Efficiency improvements in conventional spark ignition engines requires downsizing (and turbocharging) which may be achieved by using high octane gasolines, whereas, low octane gasolines fuels are anticipated for ACI concepts. The current work provides the essential combustion kinetic data, targeting both thrusts, that is needed to develop high fidelity gasoline surrogate mechanisms and surrogate complexity guidelines. Ignition delay times of a wide range of certified gasolines and surrogates are reported here. These measurements were performed in shock tubes and rapid compression machines over a wide range of experimental conditions (650 – 1250 K, 10 – 40 bar) relevant to internal combustion engines. Using the measured the data and chemical kinetic analyses, the surrogate complexity requirements for these gasolines in homogeneous environments are specified. For the discussions presented here, gasolines are classified into three categories: (i) Low octane gasolines including Saudi Aramco’s light naphtha fuel (anti-knock index, AKI = (RON + MON)/2 = 64; Sensitivity (S) = RON – MON = 1), certified FACE (Fuels for Advanced Combustion Engines) gasoline I and J (AKI ~ 70, S = 0.7 and 3 respectively), and their Primary Reference Fuels (PRF, mixtures of n-heptane and iso-octane) and multi-component surrogates. (ii) Mid octane gasolines including FACE A and C (AKI ~ 84, S ~ 0 and 1 respectively) and their PRF surrogates. Laser absorption measurements of intermediate and product species formed during gasoline/surrogate oxidation are also reported. (iii) A wide range of n-heptane/iso-octane/toluene (TPRF) blends to adequately represent the octane and sensitivity requirements of high octane gasolines including FACE gasoline F and G (AKI ~ 91, S = 5.6 and 11 respectively) and certified Haltermann (AKI ~ 87, S = 7.6) and Coryton (AKI ~ 92, S = 10.9) gasolines. To assess conditions where shock tubes may not be ideal devices for ignition delay measurements, this work also presents a detailed discussion on shock tube pre-ignition affected ignition data and the ignition regimes in homogeneous environments. The shock tube studies on pre-ignition and associated bulk ignition advance may help engines research community understand and control super-knock events.

Retaining walls (RW) are among the most common geotechnical structures. They have been widely used in railways, bridges (e.g. bridges abutment), buildings, hydraulic and harbor engineering. Once built, the RW can be exposed to dynamic loads, such as those produced by earthquakes, machines, vehicles and explosions. They must remain operational in aftermath of the natural or human-induced dynamic events. Hence, the understanding of the geotechnical response of RW to these dynamic loads is critical for the safe design of several civil engineering structures such as railways, highways, bridges, and buildings. Although fairly reliable methods have been developed for assessing and predicting the response of RW to dynamic loads induced by earthquakes, there is very little information to guide engineers in the design of RW that are exposed to surface explosions (surface blast loadings). These methods for assessing RW response to earthquake loads cannot directly be applied to the design of RW subjected to surface blast loads. Indeed, blast loads are short duration dynamic loads and their durations are very much shorter than those of earthquakes. The predominant frequencies of a blast wave are usually 2-3 orders of magnitudes higher than those of earthquake wave, and the same can be said for blast wave acceleration as compared to the peak acceleration that results from an earthquake. Thus, RW response under blast loading could be significantly different from that under a loading with much longer duration such as an earthquake. There is a need to increase our understanding of the response of RW to surface explosion loadings since there is a significant increase of terrorist threat on important buildings and some lifeline infrastructures. Transportation structures (bridges, highway, and railway) are unquestionably being regarded as potential targets for terrorist attacks. The purpose of this PhD research is to investigate the geotechnical response of reinforced concrete retaining wall (RCRW) with sand as a backfill material to surface blast loads. The soil-RW model was subjected to a simulated blast load using a shock tube. The influence of the backfill relative density, backfill saturation, blast load intensity, and live load surcharge on the behaviour of RCRW with sand backfill was studied. The dimensions of the stem and heel of the retaining wall in this study were 650 mm (height) x 500 mm (width) x 60 mm (thickness) and 400 mm (width) x 500 mm (length) x 60 mm (thickness), respectively. Soil-RW model was placed inside a wooden box. The overall height of the box was 1565 mm. The retained backfill extended behind the wall for 1300 mm. Based on the results, it is found that the maximum dynamic earth pressures were recorded at a time greater than the positive phase duration regardless of the backfill condition. The total earth pressure distribution along the height of the wall showed that the magnitude of total earth pressure for loose and medium backfill at the mid-height of the wall slightly exceeded the dense backfill. In addition, the lateral earth pressures increased with the increase in the blast load intensities. On the other hand, under the same load conditions, an increase in the wall movement was noticed in loose backfill, and a translation response mode was evident in this condition. The mobilized passive resistance of the RW backfill induced by blast load was used to determine the force-displacement relationship. Finally, the susceptibility of the RW with saturated dense sand to liquefaction was examined, and it was ascertained that liquefaction was not triggered when the RW was subjected to a blast load of 50 kPa. The results and findings of this PhD research will provide valuable information that can be used to evaluate the vulnerability of transportation structures to surface blast events as well as to develop guidance for their design.