Most of the moveable bridges use open grid steel decks, because these are factory assembled, light-weight, and easy to install. Open grid steel decks, however, are not as skid resistant as solid decks. Costly maintenance, high noise levels, poor riding comfort and susceptibility to vibrations are among the other disadvantages of these decks. The major objective of this research was to develop alternative deck systems which weigh no more than 25 lb/ft2, have solid riding surface, are no more than 4-5 in. thick and are able to withstand prescribed loading. Three deck systems were considered in this study: ultra-high performance concrete (UHPC) deck, aluminum deck and UHPC-fiber reinforced polymer (FRP) tube deck. UHPC deck was the first alternative system developed as a part of this project. Due to its ultra high strength, this type of concrete results in thinner sections, which helps satisfy the strict self-weight limit. A comprehensive experimental and analytical evaluation of the system was carried out to establish its suitability. Both single and multi-unit specimens with one or two spans were tested for static and dynamic loading. Finite element models were developed to predict the deck behavior. The study led to the conclusion that the UHPC bridge deck is a feasible alternative to open grid steel deck. Aluminum deck was the second alternative system studied in this project. A detailed experimental and analytical evaluation of the system was carried out. The experimental work included static and dynamic loading on the deck panels and connections. Analytical work included detailed finite element modeling. Based on the in-depth experimental and analytical evaluations, it was concluded that aluminum deck was a suitable alternative to open grid steel decks and is ready for implementation. UHPC-FRP tube deck was the third system developed in this research. Prestressed hollow core decks are commonly used, but the proposed type of steel-free deck is quite novel. Preliminary experimental evaluations of two simple-span specimens, one with uniform section and the other with tapered section were carried out. The system was shown to have good promise to replace the conventional open grid decks. Additional work, however, is needed before the system is recommended for field application.

Concrete technology has been in changeful evolution since the Roman Empire time. It is remarkable that the technological progress became of higher magnitude from the second part of the XX Century. Advances in the development of new cements, the appearance of the fibers as a reinforcement for structural applications, and specially the grand progress in the field of the water reducing admixtures enabled the emergence of several types of special concretes. One of the lasts is the Ultra High Performance Fiber Reinforced Concrete (UHPFRC), which incorporates advances of the Self-Compacting Concrete (SCC), Fiber-Reinforced Concrete (FRC) and Ultra High Strength Concrete (UHSC) technology. This exclusive material requires a detailed analysis of the components compatibility and a high control of the materials and processes. Mainly patented products have been used for the few structural elements carried out so far today, but the costs makes doubtful the development of many other potential applications. In accordance with the previously explained, a simplification of the UHPFRC components and processes is needed. This becomes the first main goal of this Ph.D. thesis, which emphasizes in the use of local available components and simpler mixing processes. Moreover, the singular properties of this material, between ordinary concrete and steel, allow not only the realization of slenderer structures, but also the viability of new concepts unthinkable with ordinary concrete. In this field is focused the second part of the Ph.D. thesis, which develops a bolted connection system between UHPFRC elements. This research summarizes, first of all, the subfamilies belonging to the HPC-UHPC materials. Afterwards, it is provided a detailed comparison between the dosage and properties of more than a hundred of mixtures proposed by several authors in the last ten years of technology. This becomes a useful tool to recognize correlations between dosages and properties and validate or no preconceived ideas about this material. Based on this state of art analysis was performed the later development of mixtures, on Chapter 4, which analized the effect of use of simpler components and processes on the UHPFRC. The main idea was use local components available in the Spanish market, identifying the combinations that provide the best rheological and mechanical properties. Steam curing use was avoided since a process simplification is intended. Diferent dosages were developed to be adapted to various levels of performance, and always trying to be as economical as possible. The concretes designed were selfcompacting and mainly combined two fiber types (hybrid), as the flexural performance was of greater relevance. The compressive strength obtained varied in the range between 100 and 170 MPa (cube L=100 mm), and the flexural strength between 15 and 45 MPa (prism 100 x 100 x 500 mm). Some of the components introduced are very rarely used in UHPFRC, as limestone coarse aggregate or FC3R, a white active residue from the petrol industry. As a result of the research, some simple and practical tips are provided for designers of UHPFRC dosage. At the end of this chapter, five dosages are characterized as examples of useful concretes for different requirement applications. In a second part, the idea of a bolted joint connection between UHPFRC elements was proposed. The connection system would be especially useful for struts and ties elements, as truss structures. The possible UHPFRC failure modes were introduced and two different types of tests were designed and performed to evaluate the joint capacity. The geometry of the UHPFRC elements was modified in order to correlate it with the failure mode and maximum load reached. Also a linear finite element analysis was performed to analyze the UHPFRC elements connection. This supported the results of the experimental tests to deduce formulations that predict the maximum load for each failure mode. Finally, a real size truss structure was assembled with bolted joints and tested to verify the good structural behavior of these connections. To conclude, some applications designed and developed at the Universitat Politècnica de València with the methods and knowledge acquired on UHPFRC are abstracted. In many of them the material was mixed and poured in a traditional precast concrete company, providing adequate rheological and mechanical results. This showed the viability of simpler UHPFRC technology enabling some of the first applications in Spain with this material. / Camacho Torregrosa, EE. (2013). Dosage optimization and bolted connections for UHPFRC ties [Tesis doctoral no publicada]. Universitat Politècnica de València. https://doi.org/10.4995/Thesis/10251/34790 / TESIS

Ultra-high performance concrete (UHPC) was evaluated as a potential material for future bridge deck designs. Material characterization tests took place to identify potential challenges in mixing, placing, and curing UHPC. Biaxial testing was performed to evaluate behavior of UHPC in combined tension and compression stress states. A UHPC bridge deck was designed to perform similarly to a conventional concrete bridge deck, and a single unit bridge deck section was tested to evaluate the design methods used for untreated UHPC. Material tests identified challenges with placing UHPC. A specified compressive strength was determined for structural design using untreated UHPC, which was identified as a cost-effective alternative to steam treated UHPC. UHPC was tested in biaxial tension-compression stress states. A biaxial test method was developed for UHPC to directly apply tension and compression. The influence of both curing method and fiber orientation were evaluated. The failure envelope developed for untreated UHPC with random fiber orientation was suggested as a conservative estimate for future analysis of UHPC. Digital image correlation was also evaluated as a means to estimate surface strains of UHPC, and recommendations are provided to improve consistency in future tests using DIC methods. A preliminary bridge deck design was completed for untreated UHPC and using established material models. Prestressing steel was used as primary reinforcement in the transverse direction. Preliminary testing was used to evaluate three different placement scenarios, and results showed that fiber settling was a potential placement problem resulting in reduced tensile strength. The UHPC bridge deck was redesigned to incorporate preliminary test results, and two single unit bridge deck sections were tested to evaluate the incorporated design methods for both upside down and right-side up placement techniques. Test results showed that the applied design methods would be conservative for either placement method. / Ph. D.

<p>Paper-based flexible devices represent a new frontier in electronics technology. The research has focused on the fabrication of the lightweight, and flexible paper-based lithium ion batteries. A lithium ion battery relies on the interplay of multiple components. These components themselves, as well as the processes used to create them, need to be adjusted and modified in order to achieve a fully flexible lithium ion battery. These components include the electrode current collector, active material, and electrolyte. By modifying these components to be fully flexible and resistant to damages caused by deformation, a fully flexible battery can be achieved.</p> <p> </p> <p>Herein, the paper-based platform utilized is key to provide flexibility for the battery components. The goal of this work not only focused on the creation of a paper-based flexible battery to be used as an integrable energy storage system for flexible devices, but also on developing methodologies and processes that can advance the emerging area of paper-based electronics, where different functional units must be fabricated within a single paper substrate. The key to make effective paper-based batteries, is to achieve a highly conductive paper structure as the base. In this work, conductive nanomaterials including carbon nanotubes (CNT) and graphene were used to fabricate conductive paper, where wood microfibers were coated with layers of these nanomaterials via layer-by-layer nanoassembly. These fibers were then combined into paper sheets. The resulting paper offers a conductive and porous base for electronic devices that utilized only small quantities of CNT or reduced graphene oxide (rGO) to provide length resistances of 468 Ω/cm and 74.6 Ω/cm, respectively for each fabricated conductive paper. </p> <p> </p> <p>Flexible lithium ion batteries were then made by using CNT paper-based electrodes and a solid polymer gel electrolyte. The electrodes were made by deposition of lithium active materials over the conductive paper and where shown to be flexible, durable, and light weight. With respect to the electrolyte, a new type of gel electrolyte based on PVDF-HFP was fabricated to overcome problems related to the use of liquid electrolytes in flexible batteries. This gel, which provides a high electrolyte uptake (450% by weight), was made by infusing both liquid and ceramic electrolytes inside a polymer gel structure and demonstrated conductivity up to 10^-4 S/cm. The paper-based battery developed with these new materials has a comparable capacity to commercial batteries and represents a flexible and light weight alternative. The use of ultra-high capacity lithium compounds as cathode materials, such as vanadium pentoxide (with theoretical capacities of 440 mAh/g) in conjunction with rGO-paper as a stand-alone electrode (with a reversible capacity 546 mAh/g) were also explored and results will be discussed. </p> <p> </p> <p>This research has led to the development of a novel method of making a fully flexible lithium ion batteries, using paper-based current collectors, leak proof polymer gel electrolytes and ultra-high capacity lithium ion active materials. Thus, flexible high conductive paper-based current collectors, polymer-gel electrolytes, vanadium based ultra-high capacity cathode electrodes, and graphene-based stand-alone paper-based anodes have been developed and tested.</p> <p> </p>

The presented work deals with the creation of computational model of total hip endoprosthesis and the subsequent stress-strain analysis. The models of geometry of the pelvis and femur were created on base of CT data. In this model were fitted components od endoprosthesis, i.e. femoral stem and acetabular cup (metal and polyethylene pad) and also cement. On this system was subsequently modelled the rals loads conditions. Just the real loading of the prosthesis leads to the wear. It has a great influence on the quality of bone tissue, what is deteriorated. The deteriorated tissue was simulated under the acetabular component. The behaviour of the whole system is assessed on base of stress-strain analysis. This problems is very topical these days.

<p> Fouling is one of the main problems in the food processing industry. The formation of fouling generates complications that could significantly impact the cost of production due to a reduction in heat transfer capacity or sanitation problems. Fouling formation inside enclosed systems can also lead to the growth of biofilms, causing food safety hazards. The fouling layers are firmly attached to the food contact surface of the equipment in ultra-high temperature (UHT) systems where a food product gets sterilized. Clean in place (CIP) is the most common process for cleaning and removal of fouling as it reduces cleaning time, chemicals, and water consumption compared to a regular cleaning out of place process. While cleaning and solids removal, microbubbles (MB) have shown improvement by enhancing the interaction of the components in the cleaning process with the source of contamination. Therefore, a novel pilot-scale microbubble-based CIP (MBCIP) technology was used for cleaning of fouled surfaces and compared to the traditional CIP process in terms of efficiency and reduction in water usage. The fouling layers attached to the food contact surface of the equipment in UHT was the main area examined. The research evaluated the fouling created at 110ºC in sections of stainless-steel pipes heated in a convection oven and at 121 ºC during regular processing in a UHT with coil heat exchangers system. Reconstituted Non-fat Dry Milk Powder (NFDM) was used as the primary source of protein to evaluate the cleaning efficiency. CIP factors were combined with temperatures at 21.11 ºC, 43.33 ºC, and 76.66 ºC, together with water, alkali, and acid, respectively. The optimal conditions for MBCIP were established and applied to a pilot-scale UHT system representative of a commercial-scale UHT system. The sequence of the CIP was water, alkali, water, acid, and water. The results showed that the acid solution at 76.66 ºC with microbubbles had a significantly higher protein removal compared to the rest of the evaluated conditions, removing 72% of the initial protein content compared to alkali and water which were 10 and <2.55%, respectively during 60 minute of CIP. During the full CIP with the combination of water, alkali, and acid, the effect of alkali was significantly higher than in the rest of the steps performed individually. With the addition of MB overall, CIP removed a considerable amount of protein (>21.5%) in a UHT system compared to the traditional CIP method within the 60 minutes period. CIP chemicals were the main factor contributing to the protein removal, and the gas content was the second most crucial factor in determining the removal. The addition of MB will have a meaningful impact when interacting with cleaning chemicals for industrial CIP. MB also occupies a very small amount of space inside the pipelines representing <0.05% of the volume fraction of the fluid inside the pipes, nevertheless, it can potentially reduce water consumption and provides a sustainable cleaning method for the food industry </p>

When compared to traditional concrete, steel fibre reinforced concrete (SFRC) shows several enhancements in performance, including improved tensile resistance, toughness and ductility. One potential application for SFRC is in columns where the provision of steel fibres can improve performance under axial and lateral loads. The use of SFRC can also allow for partial replacement of transverse reinforcement required by modern seismic codes. To improve workability, self-consolidating concrete (SCC) can be combined with steel fibres, leading to highly workable SFRC suitable for structural applications. Recent advances in material science have also led to the development of ultra-high performance fibre reinforced concretes (UHPFRC), a material which exhibits very high compressive strength, enhanced post-cracking resistance and high damage tolerance. In heavily loaded ground-story columns, the use of UHPFRC can allow for reduced column sections. This thesis presents the results from a comprehensive research program conducted to study the axial behaviour of columns constructed with highly workable SFRC and UHPFRC. As part of the experimental program, twenty-three full-scale columns were tested under pure axial compressive loading. In the case of the SFRC columns, columns having rectangular section and constructed with SCC and steel fibres were tested, with variables including fibre content and spacing of transverse reinforcement. The results confirm that use of fibres results in improved column behaviour due to enhancements in core confinement and cover behaviour. Furthermore, the results demonstrate that the provision of steel fibres in columns can allow for partial replacement of transverse reinforcement required by modern codes. The analytical investigation indicates that confinement models proposed by other researchers for traditional RC and SFRC can predict the response of columns constructed with SCC and highly workable SFRC. In the case of the UHPFRC columns, variables included configuration and spacing of transverse reinforcement. The results demonstrate that the use of appropriate detailing in UHPFRC columns can result in suitable ductility. Furthermore, the results demonstrate the improved damage tolerance of UHPFRC when compared to traditional high-strength concrete. The analytical investigation demonstrates the need for development of confinement models specific for UHPFRC.

A modern conceptualization of psychotic disorders is as neurodevelopmental disorders, with different stages characterized by discrete clusters of symptoms. This conceptualization includes a stage of pre-psychotic prodrome, a target of contemporary research as an attempt to intervene before the development of psychosis. However, these at-risk individuals rarely present to the mental health services before transitioning into psychosis, even more so for male patients. In this study, a method of inductive thematic analysis has been employed to inquire into the pathways to care for young men at Ultra-High Risk (UHR) for psychosis to gain knowledge of- and generate hypotheses about pathways to care for this group. Data was collected using semi-structured interviews (n = 9) over video conference or telephone. Three core-themes were developed as “Willingness to Disclose Distress”, “The Gatekeeping Confidant”, and “The Boiler”, with “Openness” as a core organizing category permeating the core-themes. Together, the themes represent findings on both the importance of relations in help-seeking, as well as how the young men commonly employ non-disclosure, and how this lack of openness delays pathways to care, often resulting in adversities for the participants. Findings provide implications for further inquiry into how to increase the likelihood of young men to disclose distress, as well as providing additional rationale for the development of Mental Health Literacy in the public to make peers as well as participants more able to recognize symptoms of the pre-psychotic prodrome, when, where and how to seek help.

The effect of ultra-high temperature (UHT) on production of polycyclic aromatic hydrocarbons (PAHs) on the surface of beef steaks was determined. Beef steaks were treated with five treatments, raw, UHT, UHT/grill marks, UHT/grill marks/microwave, and charcoal grilled. Four PAHs, benzo[a]pyrene, benz[a]anthracene, benzo[b]fluoranthene, and benzo[k]fluoranthene, were quantified. High performance liquid chromatography (HPLC) and gas chromatography (GC) were used to purify and analyze the PAH extracts, respectively. Levels of PAH found on charcoal-grilled steaks were higher than those observed in the literature. A balanced incomplete block design was used to analyze the data. There were no significant differences among the treatments in the production of the benzofluoranthenes. There were significant increases in production of benzo[a]pyrene and benz[a]anthracene when grill marks were applied to the UHT steak. Microwaving significantly decreased the levels of benzo[a]pyrene and benz[a]anthracene. The production of these PAHs on UHT/grill mark/microwave steak did not differ significantly from the charcoal-grilled steak in the levels of PAH quantified.

Yogurts were made from intermediate-high temperature (100, 110, 120, and 130°C for 4 or 16 s), ultra-high temperature (140°C for 4 or 16 s), and vat heat (82°C for 20 min) treatments of skim milk fortified to 5% protein by either ultrafiltration or the addition of nonfat dry milk (NOM). Whey protein denaturation in heated milks increased with temperature and holding time from indirect plate heating and was highest in vat-heated milks. Whey protein denaturation and yogurt water-holding capacity increased with protein levels in the fortified milks compared to skim milk. Penetrometer gel strength and stirred viscosity in 21 day-old yogurt made from heated ultrafiltered skim milk exceeded those of yogurts made from NOM-fortified skim milk, even though the NOM yogurts contained more solids (13.0 vs 11.4%). Maximum gel strength and viscosity, and least syneresis of yogurts from ultrafiltered and NOM fortified yogurts occurred following intermediate-high temperature treatments of 1 00°C for 16 s, 110°C for 4 or 16 s, and 120°C for 4 s. There was significantly lower whey protein denaturation at these intermediate-high temperatures compared to UHT or vat heating. Gel strength and viscosity were lower and syneresis greater in yogurts from ultrafiltered or NOM-fortified skim milk following UHT treatment compared to yogurts made with intermediate-high temperature treatments or vat heating. The water-holding capacity of yogurts from fortified milks treated at intermediate-high temperatures was comparable to that of yogurts from vatheated milks. Fortification by ultrafiltration, to lower total solids (and without use of stabilizers) resulted in yogurt with higher gel strength and viscosity, and reduced syneresis compared to yogurt from NOM fortification. Yogurt prepared by intermediate-high temperature treatment had comparable or better gel strength and viscosity, and reduced syneresis compared to yogurt prepared by traditional vat heating.