Techn. Hochsch., Diss.--Aachen, 2008.

Techn. Universiẗat, Diss., 2004--Kaiserslautern.

The wear process in three-body contact causes problems of abrasion such as volume loss and changes of geometry of the triboelements. The wear problem leads to increased failure and high costs for repairing or replacing equipment. To understand the nature of the wear behaviour and to predict the wear rate in advance, experimental investigation and numerical simulation of the wear process are required. In this work, the wear process is analysed and the influencing parameters governing the wear behaviour are investigated experimentally to develop a new wear model. Main influential factors are considered such as kinematics of abrasive particles, contact stiffness of the particle layer, friction characteristics, and wear factors. The experiments to study kinematics of particle layers are performed on a new observation tester. To define the contact stiffness of abrasive particles, experiments are conducted by the uniaxial spindle compression tester. Moreover, a tribometer test rig with applied load up to 200 N and velocity up to 1000 mm/s is used to investigate the friction characteristics and the wear behaviour of three-body tribosystem. Analyses of influential factors on the wear behaviour in dependency of predefined process parameter are carried out. Additionally, based on the results of the experimental investigations, approximation equations representing the relation of the influential factors and the process parameters are determined. A three-body wear model is build up to represent the wear behaviour by physical wear laws. Furthermore, these approximation equations and the relevant parameters obtained by experimental investigations are included in the Fleischer’s wear equation to simulate the wear process. With the coupled model the wear process of the sample can be simulated twodimensional over the sliding distance. It is possible to predict the wear depth and the wear intensity, which can be used to estimate the wear rate. Additionally, from the results of the wear simulation the worn surface and the local contact pressure in the contact region are determined which provide a deeper insight into the wear process. With this simulation the understanding of the wear behaviour can be improved which is important to solve wear problems.

The production of fuel and chemicals is expected to be based on renewable energies in the next few years. However, combustion causes CO2 emission. Its reduction is one of the main focuses to regulate greenhouse effect, as expected by the Kyoto protocol. One combustion technology which could reduce CO2 emissions is chemical-looping combustion coupled to a CO2 capture device. This technique involves the use of a bed-material, with a size between 100 and 500 µm, composed of an oxide supported by a porous ceramic. This oxide acts as an oxygen carrier and circulates from a reducing atmosphere reactor, where oxygen reacts with CO to produce CO2, to an oxidising reactor, where combustion occurs. In order to improve the reactivity of this carrier, a fluidized bed reactor is used and involves gas velocity. Attrition resistant granulates are therefore needed because of the high impacts occurring in the reactors. Moreover, large pore network is expected to improve the reactivity of the carrier because of the higher accessibility of the gas. Granulates studied for oxygen carrier supports are frequently based on γ-alumina, which is highly mesoporous. In order to understand the importance of microstructure, three different routes were studied with samples composed of macropores, mesopores and a sample composed of both type of pores. Pore size could be successfully tailored with addition of diatomite, composed of pores in the micrometer range. This thesis aims to describe the tailoring of microstructure with addition of diatomite and at understanding its influence on attrition resistance. To be able to verify the performance of the developed supports, impregnation of copper oxide and looping experiments were performed.

The wear process in three-body contact causes problems of abrasion such as volume loss and changes of geometry of the triboelements. The wear problem leads to increased failure and high costs for repairing or replacing equipment. To understand the nature of the wear behaviour and to predict the wear rate in advance, experimental investigation and numerical simulation of the wear process are required. In this work, the wear process is analysed and the influencing parameters governing the wear behaviour are investigated experimentally to develop a new wear model. Main influential factors are considered such as kinematics of abrasive particles, contact stiffness of the particle layer, friction characteristics, and wear factors. The experiments to study kinematics of particle layers are performed on a new observation tester. To define the contact stiffness of abrasive particles, experiments are conducted by the uniaxial spindle compression tester. Moreover, a tribometer test rig with applied load up to 200 N and velocity up to 1000 mm/s is used to investigate the friction characteristics and the wear behaviour of three-body tribosystem. Analyses of influential factors on the wear behaviour in dependency of predefined process parameter are carried out. Additionally, based on the results of the experimental investigations, approximation equations representing the relation of the influential factors and the process parameters are determined. A three-body wear model is build up to represent the wear behaviour by physical wear laws. Furthermore, these approximation equations and the relevant parameters obtained by experimental investigations are included in the Fleischer’s wear equation to simulate the wear process. With the coupled model the wear process of the sample can be simulated twodimensional over the sliding distance. It is possible to predict the wear depth and the wear intensity, which can be used to estimate the wear rate. Additionally, from the results of the wear simulation the worn surface and the local contact pressure in the contact region are determined which provide a deeper insight into the wear process. With this simulation the understanding of the wear behaviour can be improved which is important to solve wear problems.

The production of fuel and chemicals is expected to be based on renewable energies in the next few years. However, combustion causes CO2 emission. Its reduction is one of the main focuses to regulate greenhouse effect, as expected by the Kyoto protocol. One combustion technology which could reduce CO2 emissions is chemical-looping combustion coupled to a CO2 capture device. This technique involves the use of a bed-material, with a size between 100 and 500 µm, composed of an oxide supported by a porous ceramic. This oxide acts as an oxygen carrier and circulates from a reducing atmosphere reactor, where oxygen reacts with CO to produce CO2, to an oxidising reactor, where combustion occurs. In order to improve the reactivity of this carrier, a fluidized bed reactor is used and involves gas velocity. Attrition resistant granulates are therefore needed because of the high impacts occurring in the reactors. Moreover, large pore network is expected to improve the reactivity of the carrier because of the higher accessibility of the gas. Granulates studied for oxygen carrier supports are frequently based on γ-alumina, which is highly mesoporous. In order to understand the importance of microstructure, three different routes were studied with samples composed of macropores, mesopores and a sample composed of both type of pores. Pore size could be successfully tailored with addition of diatomite, composed of pores in the micrometer range. This thesis aims to describe the tailoring of microstructure with addition of diatomite and at understanding its influence on attrition resistance. To be able to verify the performance of the developed supports, impregnation of copper oxide and looping experiments were performed.