A preocupação com os recursos hídricos é mundial, devido principalmente ao seu grave estado atual. Esta tese aborda a atuação do estado brasileiro quanto à gestão de suas águas internas, compreendidas nessa gestão as principais normas jurídicas materiais existentes e verificação de sua aplicabilidade pelos tribunais nacionais, através das ações judiciais. O contributo deste trabalho é pesquisar onde reside o problema. Para isso, foi estudada a principal lei aplicável aos recursos hídricos, Lei 9.433/97, para conseqüente constatação da existência, no Brasil, de boas leis disciplinadoras da atuação do homem em relação aos recursos hídricos e cujas sanções não estão sendo devidamente aplicadas pelos tribunais tradicionais, através das ações judiciais existentes. Residindo o problema na forma como essas normas jurídicas são aplicadas, foram estudados quais são os meios judiciais atualmente existentes e suas eficiências. Assim, mostrou-se ser possível a utilização de outros métodos, como a criação de uma Justiça especializada em meio ambiente; a arbitragem tradicional após algumas alterações legislativas; e a efetiva participação de câmaras técnicas para solução de controvérsias, no seio dos comitês de bacia, junto ao Ministério Público a fim de que se consiga chegar a um termo de ajustamento de conduta mais eficaz; e apresentaram-se justificativas jurídicas destinadas a uma alteração do sistema atual. Este trabalho identificou os dispositivos legislativos que têm de ser alterados de maneira a dar legalidade aos novos métodos de solução das controvérsias propostas. / The concern with the water resources is a world-wide concern, mainly because of its serious current condition. This thesis approaches the performance of the brazilian state on the management of its internal waters. This management comprehends the main existing material rules of law as well as the verification of its application by national courts, through legal actions. The contribution of this work is to find out exactly where the problem is. For this, it was studied the main brazilian law applied to water resources, the law 9.433/1997. This legal tool demonstrated that Brazil has a good disciplinarian law about the performance of human beings in relation to water resources. It was also evidenced however, that the sanctions it brings are not being duly applied by the traditional courts, through the existing legal actions. Considering that the problem is on the way that these rules of law are applied, the currently existing judicial means and their efficiencies were analysed. Thus the use of other methods was shown to be possible, as the mediation, and legal justifications were presented for an alteration of the current system. This work identified the legislative devices that have to be modified with the means of conferring legality to the new proposed method of solution of controversies.

<p>U ovom radu vr&scaron;ena je izolacija sojeva<em>&nbsp; P. shigelloides</em>&nbsp; iz uzoraka povr&scaron;inskih voda<br />Panonske nizije i formirana je kolekcija kultura, nakon čega je obavljena karakterizacija<br />faktora virulencije i antibiotske rezistencije&nbsp; izolovanih sojeva. Pored toga vr&scaron;ena je<br />izolacija bakteriofaga specifičnih za vrstu <em>P. shigelloides</em> iz uzoraka povr&scaron;inskih i otpadnih voda kao i njihova karakterizacija. Karakterizacija je podrazumevala sledeće testove: ispitivanje efikasnosti lize, litičkog spektra, uticaja različitih ekolo&scaron;kih faktora,<br />određivanje proteinskog profila i karakterizaciju genoma. Pored toga, vr&scaron;ena je detekcija<br />izolovanih bakteriofaga kori&scaron;ćenjem protočnog citometra. Rezultati ovog rada su potvrdili<br />prisustvo bakterije <em>P. shigelloides</em>&nbsp; i njenih specifičnih bakteriofaga u povr&scaron;inskim&nbsp; vodama Panonske nizije. Budući da su bakteriofagi specifični za vrstu&nbsp;<em> P. shigelloides&nbsp;</em> po prvi put izolovani, rezultati ovog rada mogu predstavljajati prvi&nbsp; korak u ispitivanjima vezanim za regulaciju brojnosti ove bakterije putem primene bakteriofaga.</p> / <p>We analyzed surface waters collected in Panonian plane, for the presence of bacterium&nbsp; <em>P. shigelloides</em>. The bacterial strains were preserved and characterized for virulence factors and antibiotic resistance. In addition, isolation of&nbsp; <em>P. shigelloides</em>&nbsp; specific bacteriophages was performed. Characterization of isolated phages included the following tests: examination of lytic efficacy, lytic spectrum, the influence of various ecological factors, the determination of the protein profile and the characterization of the genome. In addition, isolated bacteriophages were detected using a flow cytometer. The results of this paper demonstrate that the surface waters of Panonian plane contain bacterium&nbsp; <em>P. shigelloides&nbsp;</em> and its specific bacteriophages. Since&nbsp; <em>P. shigelloides</em>&nbsp; &ndash;&nbsp; specific bacteriophages are for the&nbsp;first time isolated, the results of this paper can represent the first step in the studies related to the regulation of the number of this bacterium by the application of bacteriophages.</p>

The design of rubble mound breakwaters usually focuses on the main armor layer. A review of the existing literature reveals that different equations are used to design rock armors in non-breaking wave conditions. However, most rubble mound breakwaters are constructed in the depth-induced breaking zone where they are attacked by waves breaking in the foreshore; in these conditions, existing design equations are not valid. Therefore, in this PhD thesis, the hydraulic stability of double-layer rock armors is analyzed through a series of small-scale tests conducted with a bottom slope m=1/50. Based on test results, a new potential relationship is given to design rock armors in depth-limited breaking wave conditions with armor slope cot¿=1.5, stability numbers within the range 0.98¿Hm0/(¿Dn50)¿2.5, and relative water depth at the toe 3.75¿hs/(¿Dn50)¿7.50. When concrete units are used for the armor layer, mound breakwaters are usually protected by a toe berm. This toe berm is placed on the seafloor or underlayer, providing support for the concrete armor units which are placed later on the structure slope. Toe berm design is commonly related to the armor design; in non-breaking wave conditions, the mass of toe berm rocks is one order of magnitude lower than the units of the layer. In breaking wave conditions, however, the highest waves start breaking on the bottom and impact directly on the toe berm. This is the common case of rocky sea bottoms with m=1/10 or higher slopes and thus, a correct design of the toe berm is crucial to guarantee the armor stability. The present PhD thesis examines the hydraulic stability of rock toe berms placed on a m=1/10 bottom slope and in very shallow waters (0.5<hs/Dn50<5.01). Small-scale tests were conducted with double-layer cube armored breakwaters and rock toe berms with different widths (Bt) and thicknesses (tt). Firstly, a new equation is proposed to design emerged and submerged standard rock toe berms (Bt=3Dn50 and tt=2 Dn50) using three parameters: (1) deep water wave height, Hs0, (2) deep water wave length, L0p, and (3) water depth at the toe, hs. Secondly, the influence of toe berm width (Bt) on toe berm stability is analyzed introducing two new concepts to characterize wide toe berms (Bt>3Dn50): (1) the nominal toe berm or the most shoreward toe berm area which effectively supports the armor layer, and (2) the sacrificial toe berm or the most seaward toe berm area which serves to protect the nominal toe berm. Considering the nominal toe berm damage, a new method is developed to reduce the rock toe berm size (Dn50) by increasing the toe berm width (Bt) if the required rock size is not available at the quarries. Finally, cube armor damage is examined, and the influence of the placement technique on armor stability is also characterized from physical tests conducted with cubes randomly- and uniformly- placed on the armor in two layers. / El manto principal de los diques en talud suele estar formado por escollera natural o elementos prefabricados de hormigón; su función es resistir la acción del oleaje. Una revisión del estado del arte pone de manifiesto que son numerosas las fórmulas existentes para el diseño de mantos derivadas de ensayos físicos a escala reducida con oleaje sin rotura por fondo. Sin embargo, la mayoría de diques en talud se construyen en la zona de rompientes con oleaje limitado por fondo, donde las ecuaciones de diseño habituales no son del todo válidas. En esta tesis doctoral se analiza la estabilidad hidráulica de mantos bicapa de escollera, a partir de ensayos a escala reducida con pendiente de fondo m=1/50. En base a los resultados obtenidos de los ensayos físicos, se propone una nueva relación potencial para el diseño de mantos de escollera en condiciones de oleaje limitado por fondo, válida para taludes con cot¿=1.5, números de estabilidad 0.98¿Hm0/(¿Dn50)¿2.5, y profundidades relativas a pie de dique de 3.75¿hs/(¿Dn50)¿7.50. Cuando el manto principal está formado por elementos de hormigón, es habitual construir una berma de pie que proporciona apoyo a los elementos del manto y, en su caso, colabora en la protección de la zona inferior del dique contra la socavación. Dicha berma suele construirse con escollera natural y su peso está condicionado al de los elementos del manto en el caso de no haber rotura por fondo. El peso de los elementos de la berma de pie suele ser un orden de magnitud inferior al peso de las unidades del manto; sin embargo, si la pendiente de fondo es fuerte (p.e. m=1/10) y las aguas someras esta regla no se cumple ya que algunas olas rompen sobre el fondo impactando directamente sobre la berma de pie. En estos casos, el peso de la escollera de la berma puede sobrepasar el de las unidades del manto y su correcto diseño es crucial para garantizar la estabilidad del dique. Además de estudiar la estabilidad del manto principal de diques de escollera, la presente tesis doctoral analiza también la estabilidad hidráulica de bermas de pie de escollera ubicadas en fondos con pendiente m=1/10 y aguas someras (0.5<hs/Dn50<5.01), en base a ensayos físicos a escala reducida realizados con mantos bicapa de cubos y bermas de escollera con diferentes dimensiones. En primer lugar, se propone una nueva ecuación para el diseño de bermas escollera estándar (Bt=3Dn50 y tt=2 Dn50), tanto emergidas como sumergidas, a partir de tres parámetros: (1) altura de ola en aguas profundas, Hs0, (2) longitud de onda en aguas profundas, L0p, (3) profundidad a pie de dique, hs. Posteriormente, se analiza la influencia del ancho de la berma (Bt) en su estabilidad hidráulica, introduciendo dos nuevos conceptos para caracterizar bermas de pie anchas (Bt>3Dn50): (1) berma nominal o zona de la berma de pie sobre la que realmente apoya el manto principal, y (2) berma de sacrificio o zona de la berma de pie que protege a la berma nominal. A partir del daño de la berma de pie nominal, se propone un nuevo método para reducir el tamaño de piedra (Dn50) incrementando el ancho de la berma (Bt) cuando no se disponga del tamaño requerido en cantera. Finalmente, se examina el daño del manto de cubos y se analiza la influencia del método de colocación sobre el mismo, a partir de ensayos realizados con mantos bicapa de cubos con colocación aleatoria y uniforme. / El mantell principal dels dics en talús sol estar format per roca o elements prefabricats de formigó, la seva funció és resistir l'acció de l'onatge. Una revisió de l'estat de l'art manifesta que són nombroses les equacions de disseny existents per a condicions d'onatge no trencat. No obstant això, la majoria de dics en talús es construeixen a la zona de rompents amb onatge limitat per fons, on les equacions de disseny existents no són del tot vàlides. En aquesta tesi doctoral s'analitza l'estabilitat hidràulica de mantells bicapa de roca, a partir d'assajos a escala reduïda realitzats amb pendent de fons m = 1/50. En base als resultats obtinguts dels assajos, es proposa una relació potencial per al disseny de mantells de roca en condicions d'onatge limitat per fons vàlida per a talussos amb cot¿ = 1.5, nombres d'estabilitat 0.98¿Hm0/(¿Dn50) ¿2.5, i profunditats relatives a peu de dic de 3.75¿hs/(¿Dn50)¿7.50. Quan mantell principal està format per elements de formigó , és habitual construir una berma de peu que proporciona suport als elements del mantell i, si escau, col¿labora en la protecció de la zona inferior del dic contra la soscavació. Aquesta berma sol construir amb roca i el seu pes està condicionat al dels elements del mantell en el cas de no haver trencament per fons. El pes dels elements de la berma de peu sol ser un ordre de magnitud inferior al pes de les unitats del mantell; però, si el pendent de fons és fort ( p.e. m = 1 /10) i les aigües someres aquesta regla no es compleix ja que algunes onades trenquen sobre el fons impactant directament sobre la berma de peu. En aquests casos, el pes de la roca de la berma pot sobrepassar el de les unitats del mantell, i el seu correcte disseny és crucial per garantir l'estabilitat del dic. A més d'estudiar l'estabilitat del mantell principal de dics de roca, la present tesi doctoral analitza també l'estabilitat hidràulica de bermes de roca ubicades en fons amb pendents m = 1/10 i aigües someres (0.5<hs/Dn50<5.01), utilitzant assajos a escala reduïda realitzats amb mantells de doble capa de cubs i bermes de roca amb diferents dimensions. En primer lloc, es proposa una nova equació per al disseny de bermes de roca estàndard (Bt = 3 Dn50 i tt = 2 Dn50), tant emergides com submergides, a partir de tres paràmetres: (1) alçada d'ona significant en aigües profundes, Hs0, (2) longitud d'ona en aigües profundes, L0p, i (3) profunditat a peu de dic, hs. Posteriorment, s'analitza la influència de l'amplada de la berma (Bt) en la seua estabilitat hidràulica, introduint dos nous conceptes per caracteritzar bermes de peu amples (Bt > 3 Dn50): (1) berma nominal o zona de la berma de peu sobre la qual recolza el mantell principal, i (2) berma de sacrifici o zona de la berma de peu que protegeix la berma nominal. A partir del dany de la berma de peu nominal, es proposa un nou mètode per reduir el tamany de roca (Dn50) incrementant l'amplada de la berma (Bt) quan no es disposi de la mida requerit en pedrera. Finalment, s'examina el dany del mantell de cubs i s'analitza la influència del mètode de col¿locació sobre el mateix , a partir d'assajos realitzats amb mantells bicapa de cubs amb col¿locació aleatòria i uniforme. / Herrera Gamboa, MP. (2017). Mound Breakwater Design in Depth-Limited Breaking Wave Conditions [Tesis doctoral no publicada]. Universitat Politècnica de València. https://doi.org/10.4995/Thesis/10251/82553 / TESIS

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Water scarcity for agriculture is one of the most important challenges to improve food security worldwide. In this thesis we study the potential to develop a low-cost controller for a small scale brackish desalination plant that consists of proven water treatment technologies, reverse osmosis, cation exchange, and nanofiltration to treat groundwater into two final products: drinking water and irrigation water. The plant is powered by a combination of wind and solar power systems. The low-cost controller uses Arduino Mega, and Arduino DUE, which consist of ATmega2560 and Atmel SAM3X8E ARM Cortex-M3 CPU microcontrollers. These are widely used systems characterized for good performance and low cost. However, Arduino also requires drivers and interfaces to allow the control and monitoring of sensors and actuators. The thesis explains the process, as well as the hardware and software implemented.

Synthetic musk compounds were first prepared artificially in the late 19th century. They have been used to perfume cosmetics, detergents and personal care products. The attention of many researchers has been focused on it recently, due to its high penetration into the nature which is a logical consequence of its great use. The main goal of this thesis is to determine the effect of the ultrafiltration on the concentration reduction of substances mentioned above in the industrial waste waters produced by the cosmetic company. Analytes from the sample were extracted using solid phase microextraction (SPME) and on gas chromatography analysis with mass spectroscopy (GC / MS) has been performed. The whole method was optimized and evaluated. Determination of the average efficiency of the ultrafiltration was made based on data obtained before and after ultrafiltration. Such efficiency determines the suitability of use of this method for removal of synthetic musk compounds from waste waters.

This Master’s thesis deals with the determination of selected micro and macro elements in bottled water purchased in retail chains Czech Republic. There are described macro elements and micro elements that occur in the waters, bottled waters legislation and the most frequent used instrumental methods for elemental analysis. In this work for the analysis of bottled water were used methods optical emission spectrometry with inductively coupled plasma (ICP-OES) and ion chromatography (IC). Elemental composition of bottled water after analysis corresponded to the composition indicated on the labels, there were recorded only minor deviations from the reported concentrations. All bottled water meets the conditions of the legislation of the Czech Republic. The measured data were statistically processed in the XL Stat program and by multivariate data analysis was examined whether it is possible to individual bottled water from each other based on the analyzes differentiate, which can help in verifying the authenticity of bottled water and in the detection of adulteration of bottled water for profit.

The PhD thesis deals with determination of sulfonamides and tetracyclines in waste waters. Sulphonamides and tetracyclines are widely used in human and veterinary medicine. They are biologically active compounds and block biological processes in waste water treatment plants. These substances can influence microorganisms in the environment. Sulphonamides and tetracyclines induce resistance in low concentrations. These substances penetrate into the environment from industrial production, use in households, hospitals, veterinary clinics and fish farms. Tetracyclines and sulphonamides were determined in waste water from waste water treatment plants in Brno. Optimalization of extraction of these compounds was performed by solid phase extraction. Sulphonamides and tetracyclines were determined by liquid chromatography coupled with diode array detector or coupled with mass spectrometry. Optimalized method was used for determination tetracyclines and sulphonamides in waste water from waste water treatment plants in Brno in years 2007 – 2010.

Monitoring of Chemical Parameters of Mining Waters from Hyperspectral Image Data Abstract The thesis deals with utilization of hyperspectral image data for mining water quality monitoring. Sokolov lignite basin, facing many environmental problems caused by brown coal mining activities is the area of interest. Airborne hyperspectral image data acquired by the HyMap sensor in 2009 and 2010 and ground truth data - chemical and physical parameters of water samples are the main data sources for the thesis. Practical part aims at estimating of the amount of the dissolved iron and suspended sediments in selected water bodies. Two approaches were used to achieve this goal - the empirically derived relationship between the ground measurements and reflectance of the water bodies, and spectral unmixing method. Comparison of the two mentioned approaches and evaluation of validity to use the proposed methods for the data acquired by the same sensor one year later is also a part of this thesis.

Radiohydrochemical exploration took place in east part of the "smrčinský" pluton between "Skalná-Plesná-Bad Brambach in years 2016-2018. The main aim of the exploration was location and thorough research of possible occurrence of waters with radioactive concretation higher than 1500 Bq/l. That is a value for radioactive mineral waters given by the "lázeňským" law number 164/2001 Sb. Most important area is Plesná-south where was discovered several springs with values exceeding 5000 Bq/l. Eminent spring is called "Břetislav-Radonka" and lies one kilometre southwest from the train station Plesná-Šneky with an activity of about 12.5 kBq / l 222 Rn and a flow rate of about 2.5 l / min. It is the most active surface discharge of radon mineral water in the Czech Republic Another significant source area is north of Skalna - north. These springs were discovered almost 60 years ago, Dr. Marie Zukriegelová. The main source of this area was named after its discoverer - the "Marie Z" spring with an activity of 5800 Bq / l 222 Rn.Further the research focused on historical radioactive conduit which were used to supply village Skalné with water. The conduit was separated on two "branches" and the younger one was built ten years after the first one. In both pipes were found radioactive waters and the most important...