This master thesis describes design of suitable surface treatment technology to get component resistant to corrosion of conventional atmosphere. Given component has a shape of pin and is made of construction steel. At the beginning, there is a theoretical study of galvanic zinc coating and galvanic surface treatment in general. Then there is analysis of damaged galvanic zinc surface and its impact of corrosive resistance of that layer with collaboration with company KOZÁK SVITAVY. Corrosive resistance of damaged zinc layer is then compared with corrosive resistance of quality zinc layer. At the end of this thesis is technical and economic evaluation.

The work is aimed at studying the thermal degradation of the protective zinc coating. Its large part deals with the structure of the various stages of transition and their arrangement, the main emphasis is on analysis of brittle intermetallic phases, which arise due to increased temperature. Conclusion of the work is trying to clear itself causes degradation of this protective layer.

Steel is an excellent material to build with, but consideration must be given to the fact that unprotected steel corrodes, rusts, therefore, as a rule, the steel must be protected in some way. This can be done by reducing the tendency of the steel to corrode by using stainless steel or by treating the steel with a protection method. The two most common methods of protection are corrosion protection paint and zinc coating. To determine the method, the corrosive category must first be evaluated and this is done in accordance to EN ISO 12944-2:1998. Stainless steel is available in many varieties but only some of them have properties that make them suitable for use as construction steels. There are many factors to be considered in the design of stainless steel to prevent corrosion from occurring. Design of stainless steel is slightly different from the design of plain carbon steel. In this thesis, only the differences are considered. There are many different systems of protective coating. These consist of at least two different layers of paint. Before the steel is painted, it must be pretreated to remove any impurities in the steel in order to get good adhesion. Galvanizing with a zinc coating can be done in a couple of ways, including hot-dip galvanizing and zinc spraying, where galvanizing is the most common method. When both galvanizing and painting is used it is called duplex systems. Which method that should be used depends on several factors such as economics, aesthetics and environmental impact. There is no simple solution, everything must be weighed and considered in each individual case. / Stål är ett utmärkt material att bygga med, men hänsyn måste tas till att oskyddat stål korroderar, rostar, därför ska stålet i regel rostskyddsbehandlas. Detta kan göras genom att minska stålets benägenhet för att korrodera genom att använda rostfritt stål eller genom att behandla stålet med någon skyddsmetod. De två vanligaste skyddsmetoderna är rostskyddsmålning och förzinkning. För att bestämma metod måste först korrosivitetsklassen bedömmas och det görs enligt SS-EN ISO 12944-2:1998. Rostfritt stål finns i många olika varianter och det är bara några av dessa som har egenskaper som gör att de kan användas till byggande. Det finns även många faktorer att tänka på för att förhindra att korrosion i rostfria konstruktioner uppstår. Dimensionering av rostfritt stål skiljer sig något från dimensionering av vanligt kolstål. I detta arbete tas endast skillnaderna upp. Det finns många olika färgsystem inom rostskyddsmålning. Dessa består av minst två stycken olika skikt med färg. Innan ett stål rostskyddsmålas måste det förbehandlas så att eventuella föroreningar på stålet försvinner och ger färgen bra vidhäftning. Förzinkning kan göras på ett par olika sätt, däribland varmförzinkning och sprutförzinkning där varmförzinkning är den vanligaste metoden. När både förzinkning och målning används fås så kallade duplexa system. Vilken metod som ska väljas för att skydda stålet mot korrosion beror på flera olika faktorer så som ekonomi, estetik och miljöpåverkan. Det finns ingen enkel lösningsmetod utan allt måste vägas samman och beaktas utefter varje enskilt fall.

Zn-Mo coatings are very promising environment friendly anticorrosive coatings as replacement materials for cadmium and chromium (VI) based conversion layers. Electrodeposition has become a favorable technique in fabricating coatings due to its low cost, ease of use, and overall experimental control of coating quality. Very little research so far has been done for the electrodeposition of Zn-Mo coatings under alkaline conditions. In this work, Zn and Zn-Mo coatings were electrochemically deposited on stainless steel from an aqueous alkaline citrate solution. An organic compound, vanillin, was added to the electrolyte as a leveling agent for improving interlayer adherence and corrosion resistance of Zn-Mo coatings. Ni-Mo alloys have been known to possess high tensile strength and excellent corrosion protection of steels, and MoTe2 layers have a potential for the application in anticorrosive coatings due to their hydrophobic properties. In this study, MoTe2-Ni-Mo coatings were deposited on stainless steel using both sputtering and electrodeposition methods. These coatings with high corrosion resistance and other desirable properties are in demand in the oil and gas industry since they can protect and thus extend the lifetime of the underlying materials when exposed to aggressive environments. The Zn-Mo and MoTe2-Ni-Mo coatings were evaluated for chemical composition and corrosion behavior using different types of instrumental and electrochemical techniques. The addition of vanillin to the electrolyte did not change the crystalline structure or composition of the Zn-Mo coating, however, the corrosion resistance of the coating was significantly improved by the leveling effect of vanillin during the electrodeposition. The corrosion resistance of the Ni-Mo coating was also enhanced by applying the hydrophobic MoTe2 monolayer on the top surface.

Ziel der durchgeführten Arbeiten war, verschiedene Oxide mit elektrochemischen Methoden in eine Zinkschicht einzubauen. Um den Mechanismus der Dispersionsabscheidung aufzuklären wurden die Feststoffpartikeln durch Zetapotentialmessungen, Partikelgrößenanalyse und die Bestimmung der spezifischen Oberfläche charakterisiert. Außerdem wurde die Abhängigkeit der Partikel-Einbaurate in den abgeschiedenen Zinkschichten von der Art des Bades, der Partikelkonzentration im Bad, der Rührgeschwindigkeit, dem pH-Wert, der Mahlung der Partikeln, der Art des elektrischen Stromes und der Elektrodenanordnung untersucht. Der Anteil an Oxiden in den Zinkschichten wurde mit verschiedenen Meßmethoden analysiert. Die optimierten Dispersionsschichten sind durch verschiedene Methoden charakterisiert worden.

Design of flat pallet for automatic parking garage. Parking and description of automatic parking systems. Welding and weldability of materials. Electric arc welding and welding by melting electrode in protective gas by MIG/MAG method, welding instruments. Design of parking palette calculation and calculation this palette by MKP method. Process of drawing documentation for parking palette. Design of welding process and WPS. Description of annealing and zinc coating. Economic-technical analysis of palette for automatic parking system production.

The topic of this thesis is the interaction between gas jet flow and a liquid film dragged by a solid substrate. This method, known as jet-wiping, is used in several industrial processes. Hot-dip galvanization of steel strips is an important application, where jet wiping is used to control the thickness of the liquid zinc that is applied on a continuous steel substrate. Unsteady phenomena in the process lead to the creation of waves on the liquid film, which is known as undulation. This unwanted phenomenon deteriorates the quality of the final product.<p>The aim of the current study is to identify the causes of the undulation and propose possible solutions to tackle the problem. This is achieved through studying the hydrodynamic interaction between the gas jet flow and the liquid film. Experiments on a laboratory test facility and numerical simulations with 3 different Computational Fluid Dynamics (CFD) codes are employed for that purpose. / Doctorat en Sciences de l'ingénieur / info:eu-repo/semantics/nonPublished

The doctor thesis deals about the influence of zinc coating morphology on limit conditions formability of a thin sheet metal. In the introduction of the thesis is discusesed about current problems searching the most suitable morphology of the steel sheet metals, a method of appliing to the zinc sheet metal. The hot dip zinc coating is discussed in next chapter, the topical knowledges about the influence of the individual factors have some effect to coat calibre and quality. In literary researchs are discussed the concrete technological tests of zinc coating to harder sheet metal forming, the theory of the bend and the basic theory of pressing sheet metal. In following chapter is devoted interpretation selected technological tests, according to that is described behaviour, characteristics, influence of zinc coating formability of basic material and his morphology.

Ziel der durchgeführten Arbeiten war, verschiedene Oxide mit elektrochemischen Methoden in eine Zinkschicht einzubauen. Um den Mechanismus der Dispersionsabscheidung aufzuklären wurden die Feststoffpartikeln durch Zetapotentialmessungen, Partikelgrößenanalyse und die Bestimmung der spezifischen Oberfläche charakterisiert. Außerdem wurde die Abhängigkeit der Partikel-Einbaurate in den abgeschiedenen Zinkschichten von der Art des Bades, der Partikelkonzentration im Bad, der Rührgeschwindigkeit, dem pH-Wert, der Mahlung der Partikeln, der Art des elektrischen Stromes und der Elektrodenanordnung untersucht. Der Anteil an Oxiden in den Zinkschichten wurde mit verschiedenen Meßmethoden analysiert. Die optimierten Dispersionsschichten sind durch verschiedene Methoden charakterisiert worden.