Carbide-derived carbon Monoliths (CDC-Ms) containing a multimodal arrangement with high volumes of micro- meso- and macropores are prepared by direct nanocasting of silica monoliths with polycarbosilane precursors. CDC-Ms show well-defined pore structures along with specific surface areas of more than 2600 m2 g−1 and overall pore volumes as high as 3.14 cm3 g−1. They exhibit advanced gas filtration properties compared to purely microporous materials due to enhanced storage capacities and kinetics as demonstrated by thermal response measurements based on InfraSORP technology.
| Identifer | oai:union.ndltd.org:DRESDEN/oai:qucosa.de:bsz:14-qucosa-151398 |
| Date | 01 September 2014 |
| Creators | Nickel, Winfried, Oschatz, Martin, von der Lehr, Martin, Leistner, Matthias, Hao, Guang-Ping, Adelhelm, Philipp, Müller, Philipp, Smarsly, Bernd M., Kaskel, Stefan |
| Contributors | Royal Society of Chemistry, |
| Publisher | Saechsische Landesbibliothek- Staats- und Universitaetsbibliothek Dresden |
| Source Sets | Hochschulschriftenserver (HSSS) der SLUB Dresden |
| Language | English |
| Detected Language | English |
| Type | doc-type:article |
| Format | application/pdf |
| Source | Journal of materials chemistry A, 2014,2, 12703-12707, ISSN: 2050-7496 |
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