L’archipel des Açores dans l’océan Atlantique est édifiées sur un épais plateau océanique, à proximité de la jonction triple entre les plaques Nord-américaine (Na), Nubienne (Nu) et Eurasienne (Eu). La formation du plateau et l’origine du volcanisme ont été le plus souvent attribués à la présence d’une instabilité mantellique. Cependant, la répartition et la morphologie des édifices volcaniques semblent avoir été grandement influencés par la déformation régionale liée à la migration de la frontière de plaque (Eu/Nu). En effet, la frontière serait passée d’une faille transformante aujourd’hui inactive, la zone de fracture est des Açores (EAFZ), à un rift ultra lent actif appelé le Rift de Terceira (TR).Lors de ce travail, nous utilisons le volcanisme comme marqueur de la déformation régionale. Nous nous intéressons particulièrement aux îles de S. Miguel et Graciosa, qui sont localisées à l’intérieur du TR, et à Santa Maria, une île volcanique éteinte qui se situe entre la EAFZ et le TR. De par leur position, ces trois îles constituent donc des cibles particulièrement appropriées afin d’étudier l’architecture et l’évolution de la frontière de plaque Eu/Nu durant les dernier Millions d’années. A partir de nouvelles données géomorphologiques, stratigraphiques, géochronologiques et tectoniques, couplées aux données bathymétriques et géophysiques disponibles, nous reconstruisons les étapes successives de construction et de démantèlement de ces îles puis discutons de leur signification géodynamique. Ces données sont ensuite complétées par des expériences de mécanique des fluides afin d’investiguer les liens possibles entre un panache mantellique, la migration de la frontière de plaque sur plusieurs échelles d’espace et de temps.Les résultats montrent que les édifices localisés dans le TR se construisent via des pulses volcaniques courts (<100 kyr) et relativement synchrones, séparés par des épisodes d’effondrements catastrophiques. Nous proposons qu’une telle évolution reflète des épisodes brefs et intenses de déformation régionale le long de la frontière de plaque active. La distribution des marqueurs tectoniques ainsi que leurs orientations N110 et N150 dans la partie Est de S. Miguel, nous conduit à proposer que l’extension oblique du TR est principalement accommodée par les failles bordières majeures du rift. Nous identifions une nouvelle tendance tectonique orientée N50° qui pourrait représenter des failles transformantes accommodant les variations d’obliquité du TR. L’activité de île de Santa Maria est ici datée entre 5.7 et 2.8 Ma. S. Maria a été façonnée par plusieurs effondrements sectoriels catastrophiques, le plus probablement déclenchés par les mouvements tectoniques régionaux. Nous identifions également une nouvelle structure de type graben reliant les îles de S. Maria et S. Jorge plus loin au NW. La forme de ce graben est semblable au TR et est située entre l’ancienne et la nouvelle frontière Eu/Nu. Nous interprétons ce graben comme un ancien rift transitionnel et donc comme une ancienne frontière de plaque Eu/Nu. A partir de nos données géochronologiques, nous proposons que la partie Est de ce rift transitionnel aurait migré vers la partie Est du TR entre 2.8 et 1.7 Ma.La migration de la frontière Eu/Nu a été interprétées par Vogt and Jung (2004) comme résultant de sauts successifs vers le NE de l’axe du Rift afin de maintenir sa position au dessus d’un point chaud fixe. Nos expériences de mécanique des fluides suggèrent que l’archipel des Açores, comme celui des Canaries, du Cap Vert, de Madère ainsi que les volcans sous marins de Great Meteor sont la signature en surface d’un groupe d’instabilités mantellique prenant naissance et remontant à partir du sommet d’un dôme thermochimique situé dans le manteau inférieur. De plus, Ces panaches secondaires pourraient être suffisamment faibles pour adapter leurs mouvements aux équilibres de forces pré-existants, notamment la structure et la morphologie de la lithosphère. / The Azores archipelago in the Atlantic comprises nine volcanic islands which developed on a thick oceanic plateau close to the Triple Junction between the North American (Na), the Nubian (Nu), and the Eurasian (Eu) lithospheric plates. The formation of the plateau and the origin of the volcanism remain controversial, but have been generally attributed to a plume-like mantle instability. However, the distribution of the volcanic edifices east of the Mid-Atlantic Ridge (MAR) appears greatly influenced by regional deformation associated with the northward migration of the Eu/Nu plate boundary from an extinct old transform fault, the East Azores Fracture Zone (EAFZ), up to the presently active ultra-slow Terceira Rift (TR). In this thesis, we use the volcanism as a marker for regional deformation. We especially focus on S. Miguel and Graciosa, which are located within the TR, and on S. Maria, an old volcanically extinct island located between the EAFZ and the TR. These three islands thus constitute particularly suitable targets to track the architecture and the evolution of the Eu/Nu plate boundary during the last few Myr. From new geomorphological, stratigraphic, geochronologic, structural/tectonic data, and existing bathymetric and geophysical data, we reconstruct the successive stages of growth and destruction of the islands, and discuss their geodynamic meaning. These data are then complemented by fluid dynamic modelling using laboratory experiments to examine the possible links between mantle instability, plate boundary migration and the development of the volcanism on various spatial and temporal scales.The new results on the islands show that the edifices located within the TR grew through short (<100 kyr) and partly synchronous volcanic pulses, separated by catastrophic sector collapses. We propose that such evolution reflects brief and intense episodes of regional deformation along the still active Eu/Nu plate boundary. The distribution of tectonic markers and the recognition of N110 and N150 tectonic structures in eastern S. Miguel leads us to propose that oblique extension in the TR is mainly accommodated by the master faults of the rift, and that the TR is presently not the locus of appreciable sea-floor spreading. Furthermore, we identify a new N050 trend, which may represent transform faults accommodating the variation in obliquity of the TR. The activity of S. Maria is here dated between 5.7 and 2.8 Ma. Like the recent islands, S. Maria experienced catastrophic flank collapses, most probably triggered by regional tectonics. We identify a new graben structure linking Santa Maria to the island of S. Jorge further NW. The shape of this graben is similar to the TR and it is located between the EAFZ and the current plate boundary. We interpret this graben as a former transient rift, and therefore an old Eu/Nu plate boundary. From the new data, we propose that the eastern part of the transient rift migrated to the eastern part of the TR between 2.8 Ma and 1.7 Ma.The overall migration of the Eu/Nu plate boundary to the north and the creation of the Azores plateau has been interpreted by Vogt and Jung (2004) as resulting from successive NE jumps of the rift axis to maintain its position over a fixed ‘hotspot’. Our fluid mechanics experiments suggest that the Azores, as Canary, Cape Verde, Madeira Islands and Great Meteor seamounts might be the surface signature of a cluster of mantle instabilities rising from the top of a large thermochemical dome located in the lower mantle. However, such secondary plumes present a strong time-dependence 5-40 Myr time scale. Moreover, they could be sufficiently weak to adapt their motions to the pre-existing force balances and morphology of the lithosphere. We therefore present a scenario of the Azores area evolution combining a triple junction and decompression melting buoyant material (i.e. such in volatiles and/or temperature) under a thickening lithosphere.

Les groupes ethniques minoritaires sont parmi les secteurs de la société qui sont menacés en permanence par des risques plus élevés de catastrophes. Le fondement d'un tel constat est les impacts négatifs disproportionnés de catastrophes passées. Il est de ce fait nécessaire d'intégrer tous les groupes ethniques en particuliers les minorités dans la réduction des risques de catastrophe (RRC). Pourtant, la communauté scientifique a peu étudié le rôle de l’ethnicité dans la vulnérabilité et la capacité des populations exposées à divers aléas. Ainsi les praticiens sur le terrain et les organisations non-gouvernementales (ONG), ne possèdent pas de méthodes et d’outils appropriés pour intégrer les minorités ethniques dans la RRC. En plus, des exemples de méthodologies et de politiques visant à rendre cet objectif opérationnel et institutionnalisés sont également limités. Cette étude vise à répondre à ces lacunes, en prenant l’exemple des communautés multiethniques autour de Mont Kanlaon situé sur l'île de Negros aux Philippines. La zone d'étude se caractérise par une grande diversité ethnique composé d'au moins trois grands groupes ethniques (Ilonggos, Cebuanos et Bukidnons). Les résultats de cette étude suggèrent que cette mosaïque constitue une dimension importante de la RRC puisque chaque groupe ethnique possède ses propres formes de vulnérabilité et de capacité face aux aléas volcaniques et d’autres origines. Ces minorités ethniques sont parmi les secteurs les plus vulnérables de la société philippine en raison de leur statut marginalisés. En outre, les résultats de cette étude suggèrent que chaque groupe ethnique possède des capacités issues en grande partie de ressources locales qui sont utiles aux fins de la RRC. / The ethnic minority groups are among the sectors of the society who are permanently threatened by higher risk of disasters. The basis of such claim is the disproportionate negative impacts of both major and minor disasters. There is thus a pressing need to integrate ethnic minority groups in disaster risk reduction (DRR). However, within the scientific community, there are limited studies in the current literature of disaster that investigated the role of ethnicity in shaping the vulnerability and capacity of the ethnic groups. The authorities, non-government organizations (NGOs), and researchers have limited defined methods and tools to make such as objective operational in the field. Finally, plans, actions and policies to make such objective institutionalized are also limited. This study aimed to fulfill those gaps. The study has adapted an integrated DRR framework and a methodology that follows the ideals and principles of Community-Based Disaster Risk Reduction (CBDRR). The present study focuses on the multiethnic communities surrounding Mt. Kanlaon located in the island of Negros, Philippines. The study area is characterized by a great ethnic diversity composed of at least three major ethnic groups (Ilonggos, Cebuanos, and Bukidnons). The results of the study suggest that this ethnic mosaic constituted a major dimension of DRR because each ethnic group portrays different vulnerabilities and capacities in the face of volcanic hazards and other natural hazards. These ethnic minorities are among the most vulnerable sectors of the Philippine society due to their marginalized and minority status. In addition, the results of this study also suggest that each ethnic group possesses capacities derived from local resources that are useful for the purpose of DRR.

FundaÃÃo Cearense de Apoio ao Desenvolvimento Cientifico e TecnolÃgico / A RegiÃo Metropolitana de Fortaleza, no Estado do Cearà à composta por uma diversificada paisagem geomorfolÃgica, estruturada e modificada ao longo de milhÃes de anos durante a era geolÃgica. Entre as diversas morfologias, as formas originadas a partir do Ãltimo evento vulcÃnico ocorrido no Nordeste brasileiro hà 30 milhÃes merecem total apreÃo devido sua singularidade morfogenÃtica. Tais relevos tiveram suas gÃneses ligadas a partir da aÃÃo de um hot spot que ocorreu nesta Ãrea e juntos recebem o nome de FormaÃÃo Messejana. Esta formaÃÃo compÃe-se de uma dezena de pequenos relevos que se dispÃe em setores da margem continental ao longo da regiÃo metropolitana de Fortaleza. Dentre estes estÃo os relevos vulcÃnicos do Caruru, do Ancuri e PÃo-de-aÃÃcar. Esta pesquisa tem como objetivo: estabelecer a origem, estruturaÃÃo, caracterizaÃÃo morfolÃgica e ambiental destes relevos, assim como, definir as etapas da evoluÃÃo geomorfolÃgica da paisagem local. Para compreender tais objetivos buscamos se aprofundar na bibliografia sobre o assunto, interpretaÃÃo de material cartogrÃfico de diversas escalas, dados fÃsicos-ambientais com apoio de ferramentas de geoprocessamento e visitas a ÃrgÃos pÃblicos e a campo. Como resultados podemos concluir que os trÃs relevos da FormaÃÃo Messejana analisados neste trabalho apresentam-se em formas de Necks arredondados (Caruru e PÃo-de-AÃÃcar) e elipsoidal (Ancuri) e sÃo compostos por rochas alcalinas. Tais relevos se caracterizam por apresentarem extensÃes e altitudes bem diferentes, vertentes Ãngremes, solos poucos desenvolvidos e vegetaÃÃo de pequeno porte. Por fim, o Caruru, apresenta-se parcialmente destruÃdo devido à extraÃÃo das rochas para a construÃÃo civil, enquanto que no Ancuri esta atividade cessou hà aproximadamente sete anos. / The Metropolitan Area of Fortaleza, capital of the Cearà State, North-east Brazil, is composed by a diversified geomorphologic landscape, which has been structured and modified during geological times. Among this diversity, there are forms originated by the last volcanic event occurred in the Brazilian northeast, 30 millions ago, which create a very singular local morphology. Such prominences were probably originated by the action of a âhot spotâ. The magma extrusion resulting of this action created a geological domain named  Formation Messejana Â. This formation is composed by a set of ten volcanic reliefs, as small prominences disposed in many sectors of the city of Fortaleza coastal area and adjacencies. Among these prominences are the Caruru, Ancuri and PÃo de AÃucar hills. The present research has as objective to establish the origin, the processes of morphological structuration, the morphological characterization and the environmental situation of these volcanic prominences, as well as define the phases of morphological evolution of the local landscape. For this purpose, the following stages have been developed: bibliographical research about the matter, interpretation of cartographical data, with the use of diverse scales and thematic maps and cartographical geoprocessing techniques, and field work. As results, we are able to conclude that the three prominences of the Formation Messejana analyzed in this work present form of dome-like necks (Caruru and PÃo de AÃucar) and ellipsoidal form (Ancuri), being composed by alkaline rocks. Such prominences are characterized for presenting different extensions and altitudes, steep slopes, poorly developed soils and sparse vegetation cover. In the present moment, the Caruru hill is a place of mining activity, being partially destroyed due to the extraction of the rocks for the civil construction. This situation creates environmental problems, which may be extended to other volcanic hills, fact that put in danger of eradication these singular elements of the Cearà geomorphic landscape.

Pendant une éruption volcanique sur des sommets englacés, des coulées de débris syn-eruptifs,dénommées lahars, peuvent être générées par la fonte partiale de glaciers. Ce phénomène estbien connu sur le volcan Cotopaxi, Equateur. La présente étude concerne trois vallées et un cônede déjection sur le flanc sud-ouest de ce volcan. Une première analyse a été conduite par relevésde formes géomorphologiques dans ces vallées qui témoignent des processus d’érosion et desédimentation lors du passage de lahars dans le passé, notamment ceux du dernier événementéruptif datant de 1877 AD. Bien que les types des formes géomorphologiques déterminées sontles mêmes, leur distribution spatiale varie d’une vallée à l’autre en fonction d’une interaction deparamètres morphologiques locaux. Les conditions environnementales individuelles déterminentégalement le volume de l’écoulement, paramètre crucial dans la délimitation de zones de risques delahars dans les plaines adjacentes. Pour cela, une deuxième étude a été menée à grande échelle surle cône de déjection à l’exutoire de la vallée la plus au Sud des trois. Une analyse intégrale de la morphologiede surface et des affleurements naturels a été complétée par des données stratigraphiquesde subsurface obtenues via un sondage avec un Géoradar. Reconstituer l’architecture sédimentairede ce cône permet de visualiser la distribution spatiale de formes érosives et de dépôts. L’étude àrévélé que différentes parties du cône sont actives à des moments distincts et les épaisseurs dedépôts de lahars sont variables en fonction du type d’écoulement et de son volume. Ceci permetde relier les dynamiques géomorphologiques des plaines alluviales aux zones d’initiation de laharssur les flancs du volcan. Enfin, cette étude a débouché sur la mise en place d’une nouvelle fonctiondans le logiciel de modélisation de lahars LAHARZ prenant en compte l’incorporation progressive desédiment dans un contexte érosif dans les vallées, ce qui permet une meilleure délimitation de zonesde risque de lahars sur le cône. / During a volcanic eruption at ice capped volcanoes, syn-eruptive volcanic debris flows, lahars, canbe triggered through the partial melting of the glaciers. This phenomenon is well known to have happenedat Cotopaxi volcano, Ecuador, where the present study has been realized. The latter concernsthree drainages on the southwestern flank of the volcano and one alluvial fan. A first analysis hasbeen conducted assessing geomorphologic features in the drainages testifying from erosional anddepositional processes during past lahars, in particular of those generated during the last eruptiveevent dating back to 1877 AD. Although the types of determined geomorphologic features are thesame, their spatial distribution varies among the three valleys as a function of an interplay of localmorphologic parameters. The individual environmental conditions determine also the flow volumeof such lahars, a critical parameter when to delineating hazard zones in the adjacent lowlands. Thesecond analysis has therefore be performed at large scale on the alluvial fan forming at the mouthof the southernmost of the three drainages. An integral study of the surface morphology and naturalexposures was enriched with subsurface stratigraphic information obtained through a ground penetratingradar survey. The sediment architecture of the fan provides valuable insights on the distributionof erosional features and deposits. Different fan parts appear to be active at different times andlahar deposit thicknesses are highly variable as a function of flow type and volume. This allows torelate floodplain dynamics to the initiation zone of lahars on the upper flanks of the volcano. At last,this research led to integrate a new bulking function acknowledging for erosional processes in thevalleys into the lahar-modeling software LAHARZ allowing to better delineate lahar hazard zones onthe fan.

L’objectif général de cette thèse est d’étudier la prise de décision des individus en situation de catastrophe naturelle, en l’occurrence d’origine volcanique, et d’aboutir à des applications possibles, notamment à une amélioration de la prise de décision des populations exposées. Nous nous sommes intéressés à l’incertitude, dimension essentielle des situations de catastrophe naturelle, qui présente un impact important sur les émotions et la prise de décision des individus. D’une part, l’incertitude situationnelle est déterminante quant aux émotions prospectives comme la peur, et, d’autre part, l’incertitude des conséquences influence l’utilisation des heuristiques émotionnelles (émotions comme éléments pertinents à la décision) dans la prise de décision (système 1). Ce travail de thèse a été traité selon trois axes complémentaires. Dans le premier axe, intitulé Incertitude situationnelle, effet de cadrage et prise de décision, nous avons montré que la simple exposition à l’incertitude situationnelle impliquerait une absence d’effet de cadrage, qui, selon les travaux précédents, pourrait provenir d’une augmentation du traitement systématique (système 2), liée au processus de régulation fronto-amygdalienne. Dans le second axe, Incertitude des conséquences, information à la population et prise de décision, nous avons mis en évidence le fait qu’une réduction de l’incertitude des conséquences dans l’information donnée à la population permettait, dans certains cas précis, d’aboutir à de meilleures prises de décision. L’effet obtenu n’a néanmoins été identifié que dans les situations impliquant de fortes émotions anticipatoires (domicile, dilemmes moraux), situations fréquentes au cours des catastrophes naturelles. Enfin, dans le troisième axe, Création d’une base de stimuli pour l’étude du comportement humain face aux risques naturels, nous avons présenté la construction et la validation d’une base d’images liées aux catastrophes naturelles et au volcanisme, nommée « Natural Disasters Picture System » (NDPS). / The overall aim of this thesis is to examine the decision-making of individuals at risk of natural disaster, specifically related to volcanism, and to achieve potential applications, notably to improve the decision-making of individuals at risk. We focused on the uncertainty, an essential aspect of natural disaster events, which greatly impacts individuals’ emotions and decision-making. On the one hand, the situational uncertainty is an essential component for prospective emotions such as fear, and on the other hand, the uncertainty of consequences determines the use of affect heuristics (emotions used as relevant aspects of the decision) in decision-making (system 1). This doctoral thesis followed three complementary axes. In the first axis, namely Situational Uncertainty, Framing Effect and Decision-Making, we exhibited that the mere exposure to situational uncertainty could negate the framing effect, which could be explained, based on previous works, by an increase of systematic processing (system 2), stemming from the processes of the fronto-amygdala regulation. In the second axis, Uncertainty of Consequences, Information to Population and Decision-Making, we have evidenced that a reduction of the uncertainty of consequences applied to the information to population could improve, under certain circumstances, the individuals’ decisions. This effect was only identified in situations of highly charged anticipatory emotions (home environment, moral dilemmas), which are frequently encountered situations during natural disasters. Lastly, in the third axis, Creation of a Stimuli Dataset for the Study of the Human Behavior Facing Natural Hazard, we detailed the conception and validation of an image dataset dedicated to natural disasters and volcanism, named “Natural Disasters Picture System” (NDPS).

Tephra deposits are one of the possible outcomes of explosive volcanic eruptions and are the result of vertical settling of volcanic particles that have been expelled from the volcanic vent into the atmosphere, following magma fragmentation within the volcanic conduit. Tephra fallout represents the main volcanic hazard to populated areas and critical facilities. Therefore, it is crucial to better understand processes that lead to tephra transport, sedimentation and hazards. In this study, and based on detailed mapping and sampling of the tephra deposit of the 2450 BP Plinian eruption of Pululagua volcano (Ecuador), I investigate tephra deposits through a variety of approaches, including empirical and analytical modeling of tephra thickness and grain size data to infer important eruption source parameters (e.g. column height, total mass ejected, total grain size distribution of the deposit). I also use a statistical approach (smoothed bootstrap with replacement method) to assess the uncertainty in the eruptive parameters. The 2450 BP Pululagua volcanic plume dynamics were also explored through detailed grain size analysis and 1D modeling of tephra accumulation. Finally, I investigate the influence of particle shape on tephra accumulation on the ground through a quantitative and comprehensive study of the shape of volcanic ash. As the global need for energy is expected to grow in the future, many future natural hazard studies will likely involve the assessment of volcanic hazards at critical facilities, including nuclear power plants. I address the potential hazards from tephra fallout, pyroclastic flows and lahars for the Bataan Nuclear Power Plant (Philippines) posed by three nearby volcanoes capable of impacting the site during an explosive eruption. I stress the need for good constraints (stratigraphic analysis and events dating) on past eruptive events to better quantify the probability of future events at potentially active volcanoes, the need for probabilistic approaches in such volcanic hazard assessments to address a broad range of potential eruption scenarios, and the importance of considering coupled volcanic processes (e.g. tephra fallout leading to lahars) in volcanic hazard assessments.

The interaction of magma with continental crust at convergent margins is fundamental to understanding if and how continents grow. Isotopic and elemental data constrain the progressive stages of development of the magmatic underpinnings of the long-lived Aucanquilcha Volcanic Cluster (AVC), situated atop the thick continental crust of the central Andes in northern Chile. Whole rock data are used in conjunction with mineral compositions to infer processes that gave rise to eleven million years of intermediate, dominantly dacite, arc volcanism. A pulse of volcanic activity at the AVC between ~5 and 2 Ma is bracketed by more sluggish rates. We document chemical changes in the lavas that accompany this eruptive evolution. Trace element data suggest that crystal fractionation and magma mixing were the dominant mechanisms generating the diversity observed in the AVC whole rock data. Fractionation was dominant during early and waning stages of magmatism, and magma mixing was an important process during the high flux period. Peak thermal maturity of the AVC underpinnings coincided with the high magma flux and likely promoted open system processes during this time. Mineral compositions from zircon, amphibole, pyroxene, and Fe-Ti oxides confirm the importance of material recycling in the production of evolved AVC rocks. Various geothermometers were employed to calculate the pre-eruptive conditions of AVC magma using mineral compositions. Pressure estimates from amphibole and two-pyroxene barometry indicate crystallization depths of 1 ��� 5 kb and 4 ��� 6 kb, respectively. Temperature estimates from zircon, Fe-Ti oxides, amphiboles, and pyroxenes indicate temperatures ranging from ~700��C to 1100��C. Zircon temperatures are always the lowest (700��C - 950��C), and pyroxene temperatures are always the highest (1000��C - 1100��C), with Fe-Ti oxide and amphiboles temperatures falling in between. U-Pb ages from zircons and thermometry from individual samples evidence the thermal maturation and consolidation of the underpinnings below the AVC, presumably culminating in a large, crystal-rich mush zone where magmas were trapped and processed. It is in these middle to upper crustal zones where magmatic diversity is attenuated and giant, relatively homogeneous batholiths are formed. Isotopes of AVC lavas are similar to values observed from other central Andes volcanic centers. Lead isotopes are consistent with the AVC's location within a Pb isotope transition zone between the Antofalla and Arequipa basement terranes. Oxygen and Sr isotopic ratios are high and Nd isotopic ratios low with respect to a depleted mantle. Through time, ������Sr/������Sr values of AVC lavas progressively increase from lows of ~0.70507 to ~0.70579 (upper values of 0.70526 to 0.70680), and ��Nd values decrease from highs of -1.0 to -4.6 (lows of -1.6 to -7.3). Similarly, O isotopes (�������O) show a slight increase in base level through time from lows of 6.5��� to 7.0��� (highs of 6.75��� ��� 7.5���). Dy/Yb and Sm/Yb ratios also increased systematically from highs of 2.11 to 3.45, and 2.76 to 6.67, respectively. Despite the temporal isotopic variation, there is little isotopic variation with indices of fractionation, suggesting this signal is the consequence of deep magmatic processing, here attributed to an expanding zone of melting, assimilation, storage, and homogenization (MASH) of mantle-derived magma in the deep crust. Upward expansion brought the MASH zone into contact with rocks that were increasingly evolved with respect to Sr and Nd isotopes, explaining the isotopic shifts. Downward expansion of the MASH zone enhanced garnet stability during basalt fractionation, explaining the increased Dy/Yb and Sm/Yb ratios. Mass balance calculations involving Sr, Nd, and O isotope modeling are consistent with a crustal component making up 10 - 30% of AVC lavas, implying that although the history of central Andean magmatism is replete with large scale crustal recycling, the current phase is largely a crust formation event. / Graduation date: 2012

While Andosols have a proven capacity to buffer acid inputs, their long-term chemical response to elevated acid deposition remains poorly known. In this respect, the high anion retention capacity of Andosols constitutes a key parameter. Yet, the mechanisms involved in anion retention, especially sulphate, are still a matter of scientific debate. In this study, we report on the impacts of volcanogenic S and acid depositions on (i) the sulphate distribution and (ii) the processes involved in the neutralisation of the acid inputs, in two distinct soil series located downwind from Masaya volcano (Nicaragua), one of the world's largest natural source of SO2. The first series corresponds to weathered Eutric Andosols rich in allophanic constituents and the second series to weakly developed Vitric Andosols rich in volcanic glass. Long-term acid gas emission by Masaya volcano has led to important changes in the chemistry of the Andosols downwind. Sustained acid inputs have decreased the pH and exchangeable base cations contents in both Vitric and Eutric soils. These soils also show substantial S enrichment (up to 5470 mg S kg-1). However, these changes do not affect the soil acid neutralising capacity of the solid phase (ANCs) in a significant way. Despite the larger ANCs of the Vitric comparatively to the Eutric Andosols, soil pH was less in the Vitric than in the Eutric Andosols. This is related to the naturally and kinetically different mechanisms involved in the regulation of the volcanogenic acid fluxes: mineral weathering (slow kinetics) is the dominant process in Vitric Andosols, whereas cation exchange and sulphate sorption (rapid kinetics) significantly contribute to regulate proton consumption in Eutric Andosols. Formation of basic aluminium sulphate (BAS) [(K,Na)nAlx(OH)y(SO4)z] minerals in soils exposed to volcanogenic S-rich acid inputs was inferred from the results of selective extraction experiments (NH4F, KH2PO4 and oxalate). Precipitation of BAS probably constitutes the most effective inorganic SO42- retention mechanism (9-51% of total S), SO42- adsorption onto soil constituents (1-36% of total S) and occlusion into short-range ordered minerals (0-22% of total S), probably governed by ferrihydrite, constituted additional effective inorganic SO42- retention processes. Using transmission electron microscopy coupled with energy-dispersive analysis, we provide the first direct evidence of BAS minerals in soils. BAS minerals can form in these Andosols, because of the large inputs of H+ and SO2 and the availability of readily weatherable volcanic glass, which acts as an effective source of Al. Surface precipitation, i.e. two-dimensional chemisorption followed by three-dimensional nucleation and precipitation, rather than direct precipitation from solution, is likely the formation pathway of BAS particles in these soils. / Malgré une capacité importante à neutraliser les apports acides, le fonctionnement à long terme des Andosols est aussi susceptible d'être affecté par les dépôts acides. A cet égard, la capacité de rétention anionique élevée des Andosols constitue un paramètre clef. Or, les mécanismes de rétention des anions, en particulier du sulfate, demeurent un sujet controversé.Nous étudions ici les effets de dépôts acides et soufrés d'origine volcanique sur (i) la distribution du sulfate et (ii) les processus impliqués dans la neutralisation des apports acides, dans deux séries d'Andosol contrastées exposées aux émissions du volcan Masaya (Nicaragua), une des principales sources naturelles de SO2 atmosphérique. La première série comprend des Andosols Vitriques possèdant une réserve importante de minéraux altérables de nature vitreuse et la seconde est constituée d'Andosols Eutriques, plus évolués, possèdant des teneurs élevées en minéraux secondaires à organisation cristalline à courte distance. Les émissions prolongées de gaz acides provenant du volcan Masaya modifient fortement la chimie des sols exposés à ces apports. Ainsi, le pH et les teneurs en cations échangeables des Andosols Vitriques et Eutriques diminuent alors que la concentration totale en S augmente (jusqu'à 5470 mg S kg-1) en réponse aux apports d'acides. Par contre, la capacité de la phase solide de ces sols à neutraliser l'acidité (ANCs) n'est pas significativement affectée. Malgré une ANCs plus élevée dans les Andosols Vitriques comparativement aux Andosols Eutriques, le pH de ces sols est plus faible parce que les mécanismes impliqués dans la régulation des flux de protons sont différents: ceux-ci s'opèrent principalement par des réactions lentes d'altération minérale dans les Andosols Vitriques et par des réactions rapides impliquant l'échange ionique et la sorption d'anions sulfates dans les Andosols Eutriques. Sur base d'extractions sélectives (NH4F, KH2PO4 et oxalate), l'immobilisation sous forme de minéraux hydroxy-alumino-sulfatés [(K,Na)nAlx(OH)y(SO4)z] apparaît comme le mécanisme de rétention du SO42- inorganique le plus important (9-51% du S total), l'adsorption du SO42- à la surface de constituants du sol (1-36% du S total) et le piégeage du SO42- (0-22% du S total), vraisemblablement au sein d'oxydes de fer mal cristallisés, constituent également des processus efficaces de rétention du sulfate inorganique. Nous mettons en évidence par observation directe, pour la première fois, la présence de minéraux hydroxy-alumino-sulfatés dans des sols par microscopie électronique à transmission couplée à une sonde analytique EDS. La formation de ces minéraux est elle-même favorisée par l'apport considérable de sulfate d'origine volcanique et l'hydrolyse intense des verres qui libère l'aluminium en solution. La précipitation à la surface des phases adsorbantes plutôt que la précipitation directe en solution semble être le mécanisme de formation des minéraux hydroxy-alumino-sulfatés dans ces sols.

In the boreal forests of the Northern Hemisphere, time series of tree-ring width (TRW) and maximum density in the latewood (MXD) are highly correlated to local instrumental summer-temperature data and are thus widely used as proxies in high-resolution climate reconstructions. Hence, much of our present knowledge about climatic variability in the last millennium is based on tree-rings. However, many tree-ring records have a lack of data in the most recent decades, which severely hampers our ability to place the recent temperature increase in a longer-timescale perspective of natural variability. The main objective of this thesis is to update and extend the Torneträsk TRW and MXD records in northern Sweden. Local instrumental climate-data is used to calibrate the new tree-ring records. The results show that TRW is mainly forced by temperature in the early growing season (June/July) while MXD has a wider response window (June – August) and has a higher correlation to temperature. Two reconstructions of summer temperature are made for (i) the last 7,400 years based on TRW, and (ii) the last 1,500 years based on a combination of TRW and MXD. The reconstructions show natural variability on timescales from years to several centuries. The 20th century does not stand out as a notably warm period in the long timescale perspective. A medieval period from AD 900 – 1100 is markedly warmer than the 20th century. The environmental impact from a large explosive volcanic eruption in 1628/1627 BC is analysed in the tree rings of 14C-dated bog pines in south-central Sweden and in absolutely-dated subfossil pines from Torneträsk. The results show evidence of an impact in the southern site at approximately this time but no detectable impact in the North. Subfossil trees of Fitzroya cupressoides in southern Chile were 14C-dated to approx. 50,000 years BP and amalgamated into a 1,229-year TRW chronology. This tree-ring record is the oldest in the world. The variability in this Last-glacial chronology is similar to the variability in present-day living trees of the same species. These results suggest that the growth–forcing mechanisms 50,000 years ago were similar to those at present.

Selenium (Se) is an element with important health implications that is emitted in significant amounts from volcanoes. Attracted by the fertility of volcanic soils, around 10% of the world population lives within 100 km of an active volcano. Nevertheless, the behaviour of Se in volcanic environments is poorly understood. Therefore, the main aim of this thesis is to investigate the role of soils in the Se cycling in volcanic environments. Prior to the geochemical studies, precise and accurate methods for the determination of Se contents, speciation and isotopic signatures were developed. Afterwards, a combination of field studies and lab controlled experiments were performed with soils from two contrasting European volcanic settings: Mount Etna in Sicily (Italy) and Mount Teide in Tenerife (Spain). The results showed a strong link between Se behaviour and soil development, indicating that Se mobility in volcanic soils is controlled by sorption processes and soil mineralogy. / El selenio (Se) tiene afectas sobre la salud y es emitido por los volcanes. Atraída por la fertilidad de los suelos volcánicos, un 10% de la población mundial vive <100 km de volcanes activos. Sin embargo, el comportamiento geoquímico del Se en ambientes volcánicos es aún poco conocido. El objetivo de esta tesis es contribuir a la comprensión del papel del suelos en el ciclo del Se en medios volcánicos. En una primera etapa se desarrollaron métodos analíticos para determinar el contenido, la especiacíon y las relaciónes isotópicas del Se. Los estudios geoquímicos se realizaron con suelos de dos lugares con características muy distintas: el Monte Etna (Italia) y el volcán Teide (Tenerife). Los estudios de terreno y de laboratorio revelaron una gran interrelación entre el comportamiento del Se y el desarrollo de suelos, y que la movilidad de Se está controlado por los procesos de adsorción y la mineralogía en suelos volcánicos.