<p>Extending the functional lifetime of acrylic poly(methyl methacrylate) (PMMA) bone cement may reduce the number of revision total joint replacement (TJR) surgeries performed each year. We developed a system utilizing an encapsulated water-reactive, FDA-approved tissue adhesive, 2-octyl cyanoacrylate (OCA), as a healing agent to repair microcracks within a bone cement matrix. The proposed research tested the following hypotheses: (1) reactive OCA can be successfully encapsulated and the resulting capsules thoroughly characterized; (2) the static mechanical properties of the PMMA composite can be improved or maintained through inclusion of an optimal wt% of OCA-containing capsules; (3) PMMA containing encapsulated OCA has a prolonged lifetime when compared with a capsule-free PMMA control as measured by the number of cycles to failure; and (4) the addition of capsules to the PMMA does not significantly alter the biocompatibility of the material. Based on the experiments reported herein, the primary conclusions of this dissertation are as follows: (1) functional OCA can be encapsulated within polyurethane spheres and successfully incorporated into PMMA bone cement; (2) lower wt% of capsules maintained the tensile, compressive, fracture toughness, and bending properties of the PMMA; (3) inclusion of 5 wt% of OCA-containing capsules in the matrix increased the number of cycles to failure when compared to unfilled specimens and those filled with OCA-free capsules; and (4) MG63 human osteosarcoma cell proliferation and viability were unchanged following exposure to OCA-containing PMMA when compared with a capsule-free control.</p> / Dissertation

Rising South African electricity prices and reduced sales following the 2008 economic recession have led cement manufacturers to seek ways to reduce production costs. Prior research has shown that reduced electricity costs are possible by shifting load from expensive Eskom peak pricing periods to lower cost times. Due to the complex considerations and variables in cement production, this is not typically implemented. Several simulation and optimisation models are available in literature to schedule plant operation in an electricity cost effective manner. However, these models have not been implemented in practice. The simulation models are reviewed and evaluated for the task of scheduling cement production on South African factories. A model is identified to be implemented, and the requirements for implementing this model on a cement factory are investigated. A computerised management system is designed to automatically incorporate the required information and data to implement the optimisation model on a practical level. An interface is also designed to allow factory personnel access to the optimised production plan. The system is implemented and evaluated through system level testing. Four case studies are presented within which the system is implemented on South African cement factories. The performance of the system is evaluated over a nine month period, within which a total cost saving of R8.6-million is reported. / Thesis (MIng (Computer and Electronic Engineering))--North-West University, Potchefstroom Campus, 2013.

Cement production is an energy intensive process. In South Africa the cost of energy increased since 2006, while cement sales have dropped dramatically. It has become important to focus on methods to optimise energy consumption to achieve cost savings in the cement industry. Various methods of reducing production cost by improving energy efficiency are available, but require extended installation periods and high initial capital expenditure. Other methods such as operational optimisation can reduce production cost, but offer limited savings. The aim of this study is to integrate the optimisation of multiple component operations to improve savings and reduce interruption during implementation. Although integrated optimisation models have been developed, no literature could be found on the application of these models in the cement industry. This thesis reports on the development and implementation of an energy management system at four South African cement plants. The total electricity costs were reduced without installing costly infrastructure upgrades. The results summarise the success of the improved production planning. A conclusion regarding the feasibility of this implementation is compiled by comparing the savings achieved by the implementation of the energy management system to other energy saving methods. Recommendations are also made for further study and the implementation of the energy management system in similar industries. / Thesis (MIng (Mechanical Engineering))--North-West University, Potchefstroom Campus, 2013.

South African cement manufacturers are under financial pressure. Sales have declined due to the 2008 recession and electricity costs have tripled from 2005 to 2012. Electricity cost savings are therefore more important than ever. Unfortunately retrofitting highly energyefficient equipment is not ideal. These installations are costly and take a long time to implement. Alternative strategies that can produce quick results in reducing electricity costs are needed. One such alternative is a programme called Demand Market Participation (DMP). The DMP programme was implemented by Eskom, South Africa’s national electricity utility, to reduce electricity demand during supply shortages. This programme offers potential cost savings for clients with excess production capacity. Clients such as cement plants can switch off non-essential production equipment in Eskom’s peak demand periods for a financial incentive. To maximise the benefits for both the clients and Eskom, accurate electricity forecasting is needed, as are systems enabling a quick response to load reduction requests. In this study DMP opportunities on typical cement plants were identified. A DMP strategy to assist cement plants was developed to achieve maximum cost savings without influencing production, quality and safety. An existing energy management system (EnMS) was adapted to incorporate the new DMP participation strategy. The new EnMS and DMP strategy were implemented at a South African cement plant, resulting in savings of R220 000 per month. This translates into an annual cost-saving potential of R2-million for the plant, and an R13- million cost-saving potential for the total South African cement industry. / MIng (Mechanical Engineering), North-West University, Potchefstroom Campus, 2014

Rising South African electricity prices and reduced sales following the 2008 economic recession have led cement manufacturers to seek ways to reduce production costs. Prior research has shown that reduced electricity costs are possible by shifting load from expensive Eskom peak pricing periods to lower cost times. Due to the complex considerations and variables in cement production, this is not typically implemented. Several simulation and optimisation models are available in literature to schedule plant operation in an electricity cost effective manner. However, these models have not been implemented in practice. The simulation models are reviewed and evaluated for the task of scheduling cement production on South African factories. A model is identified to be implemented, and the requirements for implementing this model on a cement factory are investigated. A computerised management system is designed to automatically incorporate the required information and data to implement the optimisation model on a practical level. An interface is also designed to allow factory personnel access to the optimised production plan. The system is implemented and evaluated through system level testing. Four case studies are presented within which the system is implemented on South African cement factories. The performance of the system is evaluated over a nine month period, within which a total cost saving of R8.6-million is reported. / Thesis (MIng (Computer and Electronic Engineering))--North-West University, Potchefstroom Campus, 2013.

Cement production is an energy intensive process. In South Africa the cost of energy increased since 2006, while cement sales have dropped dramatically. It has become important to focus on methods to optimise energy consumption to achieve cost savings in the cement industry. Various methods of reducing production cost by improving energy efficiency are available, but require extended installation periods and high initial capital expenditure. Other methods such as operational optimisation can reduce production cost, but offer limited savings. The aim of this study is to integrate the optimisation of multiple component operations to improve savings and reduce interruption during implementation. Although integrated optimisation models have been developed, no literature could be found on the application of these models in the cement industry. This thesis reports on the development and implementation of an energy management system at four South African cement plants. The total electricity costs were reduced without installing costly infrastructure upgrades. The results summarise the success of the improved production planning. A conclusion regarding the feasibility of this implementation is compiled by comparing the savings achieved by the implementation of the energy management system to other energy saving methods. Recommendations are also made for further study and the implementation of the energy management system in similar industries. / Thesis (MIng (Mechanical Engineering))--North-West University, Potchefstroom Campus, 2013.

No description available.

Deterioration of reinforced concrete structures due to reinforcement corrosion is a serious problem that faces concrete infrastructure worldwide. Effect of the rebar corrosion in the shear span on the structural behaviour is not fully addressed in the published literature. This study examined the effects of corrosion of the longitudinal reinforcement in the shear span on the structural behaviour of RC beams and the effectiveness of three rehabilitation schemes on the structural performance of such beams. The experimental program consisted of testing fifteen medium-scale reinforced concrete beams (150mm wide x 350mm deep x 2400mm long) under static load. Test variables included: span to depth ratio, the degree of corrosion and the anchorage end condition and repair schemes. Two span to depth (a/d) ratios were considered: a/d=3.4 with one-point loading and a/d=2.4 with two-point loading. Two anchorage end-conditions were used: bonded or un-bonded reinforcement in the an-chorage zone. Four degrees of corrosion were chosen to simulate minor (2.5% to 5% mass loss), medium (7.5% mass loss), and severe (15% mass loss) degrees of corrosion. Corrosion was induced in the longitudinal reinforcement in the shear-span using accelerated corrosion techniques based on Faradays’ law. Three different repair scenarios were applied. The first scenario included removing the deteriorated concrete, cleaning the corroded steel and patching with a new self-compacting concrete. The second scenario included U-wrapping the beams cross-section using Glass fiber reinforced cement-based composite (GFRCM), and Carbon fiber reinforced cement-based composite (CFRCM) without removing the deteriorated concrete. The third scenario included patch repair and confinement by wrapping with GFRCM or CFRCM. Following corrosion and repair, all specimens were loaded statically to failure. Test results showed no major effect of shear-span corrosion on the flexural behaviour for the beams with end anchorage whereas a noticeable effect on the flexural behaviour was observed for beams with no end anchorage regions. The corrosion degree and the shear span to depth ratio affected the mode of failure for the specimens with no end anchorages. The type of repair significantly affected the overall behaviour of the corroded specimens. An analytical model was proposed and used to predict the load-deflection response of the tested specimens. The program calculated the mid-span deflection for a given load as an integration of the deflection of a series of elements, with the deflection being based on the elongation of the steel reinforcement in each element. A modified bond stress-slip model was incorporated into the calculations to account for the change in bond strength caused by the corrosion and/or confinement that are provided by repairs. The predicted results were in reasonable agreement with the experimental results.

Perlite is a volcanic glass which has high amount of silica and alumina. Those properties make it a candidate, if finely ground, for being used as a pozzolan. The studies on the pozzolanic properties of perlite are very limited, and none of them has dealt with the use of perlite in the blended cement production. The aim of this study is to investigate the pozzolanic properties of perlite, and if appropriate to investigate perlite&rsquo / s usability in blended cement production. For this purpose, perlites from two different sources &ndash / Izmir and Erzincan - are used as replacement of portland cement clinker with two different percentages: 20% and 30% by weight of total cement. Then for each different composition, materials are ground with some gypsum in order obtain grinding curves for the resultant cements. After obtaining the grinding curves, a total of 22 cements with two different finenesses are produced by intergrinding and separately grinding the materials for each composition. The obtained cements are used in paste and mortar production so that normal consistencies, setting times, autoclave expansions, and compressive strengths are determined.

Acrylic bone cements are one of the most important biomaterials used in orthopaedic surgery and dental applications to fill the cavities or provide mechanical interlock between prosthesis and the bone. Their biocompatibility can be increased by addition of different materials into the formulation, such as hydroxyapatite. Besides all the advantages, bone cements have several drawbacks including tissue necrosis, chemical necrosis, shrinkage of the cement and aseptic loosening. Therefore painstaking research and study are carried out on development of new formulations to improve mechanical and thermal properties as well as biocompatibilities. In this study, bone cements with different compositions were prepared and new formulations were examined to improve mechanical properties and to reduce maximum curing temperature. It was observed that addition of hydroxyapatite, while keeping polymer-to-monomer ratio constant at 2.0, decreased curing temperature and increased compressive strength about 11% (Group-C) when hydroxyapatite addition was 12%. Further addition of hydroxyapatite destroyed homogeneity of the cement dough and made it difficult to handle. The composition which contains 8% hydroxyapatite was chosen as the optimum composition in respect of mechanical properties with 102.62&deg / C curing temperature. In order to decrease the curing temperature ammonium nitrate this gives endothermic reactions with water, was added into the formulations. Addition of 0.5 g NH4NO3 decreased curing temperature from 94&deg / C to 79.3&deg / C while compressive strength kept in acceptable range with 95.99 MPa. Experiments demonstrated that the proposed formulation is acceptable for workability, homogeneity, mechanical strength and thermal properties. Further studies especially on curing temperature and biocompatibility should be achieved.