<p>Many geotechnical engineering problems involve combining two or more independent physical processes as a coupled solution of seepage, volume change and shear strength. For any physical process being modeled, it is desirous to be able to compute any of the volume-mass soil properties. When the volume-mass soil properties are combined with the stress state of the soil, the result is a volume-mass constitutive relationship. Three volume-mass constitutive relationships (i.e., void ratio, water content and degree of saturation) are generally viewed as being the most fundamental; however, only two of the relations are independent. The unsaturated soil properties associated with seepage, volume change and shear strength problems are also related to the volume-mass soil properties. While the unsaturated soil properties are often estimated as simply being a function of the soil-water characteristic curve, it is more accurate to define the properties in a more rigorous manner in terms of the volume-mass soil properties. The advancement of computing capabilities means that it is quite easy to formulate constitutive relations for shear strength and permeability, for example, in terms of all volume-mass properties of the unsaturated soil.</p><p>The objectives of this dissertation include: i) the development of volume-mass constitutive models for unsaturated soils; ii) the further study and verification of the volume-mass constitutive behavior of unsaturated soils; and iii) the development of techniques for visualization of volume-mass constitutive surfaces for unsaturated soils. To achieve these objectives, the present research study was conducted from both theoretical and experimental bases.</p><p>The theoretical program commenced with a comprehensive literature review of the volume-mass constitutive relationships for unsaturated soils. A new, more rigorous volume-mass constitutive model was then proposed. Appropriate terminology was introduced for the development of the model, followed by an outline of the assumptions used and the mathematical derivation. The proposed model requires conventionally obtainable soil properties for its calibration. The model is capable of predicting both the void ratio and water content constitutive relationships for various unsaturated soils, taking into account elastic and plastic volume changes. Various stress paths can be simulated and hysteresis associated with the soil-water characteristic curve can be taken into account. </p><p>Two closed-form equations for the volume-mass constitutive relationships were derived. A computer software program was written based on the theory of the proposed volume-mass constitutive model. Techniques for the visualization of the volume-mass constitutive surfaces were then presented. An experimental program was conducted in the laboratory. The experimental program involved the verification of a new testing apparatus. Several soils were selected for testing purposes and appropriate testing procedures were established (i.e., soil specimens were initially slurry). The testing stress paths followed in the experimental program were different from most research programs conducted in the past and reported in the research literature. Conclusions regarding the compressibility, stress path dependency, and hysteretic nature of the soil-water characteristic curve of an unsaturated soil were presented.</p><p>A considerable number of test results (i.e., from both the experimental program and the research literature) were used in the verification of the new volume-mass constitutive model. This model has proven to be effective in predicting both collapse and expansion of a soil. The volume-mass constitutive model appears to predict behaviour in a satisfactory manner for a wide range of soils; however, the predictions appear to be superior for certain soils. In all cases the volume-mass predictions of the model appear to be satisfactory for geotechnical engineering practice.

<p>Many geotechnical engineering problems involve combining two or more independent physical processes as a coupled solution of seepage, volume change and shear strength. For any physical process being modeled, it is desirous to be able to compute any of the volume-mass soil properties. When the volume-mass soil properties are combined with the stress state of the soil, the result is a volume-mass constitutive relationship. Three volume-mass constitutive relationships (i.e., void ratio, water content and degree of saturation) are generally viewed as being the most fundamental; however, only two of the relations are independent. The unsaturated soil properties associated with seepage, volume change and shear strength problems are also related to the volume-mass soil properties. While the unsaturated soil properties are often estimated as simply being a function of the soil-water characteristic curve, it is more accurate to define the properties in a more rigorous manner in terms of the volume-mass soil properties. The advancement of computing capabilities means that it is quite easy to formulate constitutive relations for shear strength and permeability, for example, in terms of all volume-mass properties of the unsaturated soil.</p><p>The objectives of this dissertation include: i) the development of volume-mass constitutive models for unsaturated soils; ii) the further study and verification of the volume-mass constitutive behavior of unsaturated soils; and iii) the development of techniques for visualization of volume-mass constitutive surfaces for unsaturated soils. To achieve these objectives, the present research study was conducted from both theoretical and experimental bases.</p><p>The theoretical program commenced with a comprehensive literature review of the volume-mass constitutive relationships for unsaturated soils. A new, more rigorous volume-mass constitutive model was then proposed. Appropriate terminology was introduced for the development of the model, followed by an outline of the assumptions used and the mathematical derivation. The proposed model requires conventionally obtainable soil properties for its calibration. The model is capable of predicting both the void ratio and water content constitutive relationships for various unsaturated soils, taking into account elastic and plastic volume changes. Various stress paths can be simulated and hysteresis associated with the soil-water characteristic curve can be taken into account. </p><p>Two closed-form equations for the volume-mass constitutive relationships were derived. A computer software program was written based on the theory of the proposed volume-mass constitutive model. Techniques for the visualization of the volume-mass constitutive surfaces were then presented. An experimental program was conducted in the laboratory. The experimental program involved the verification of a new testing apparatus. Several soils were selected for testing purposes and appropriate testing procedures were established (i.e., soil specimens were initially slurry). The testing stress paths followed in the experimental program were different from most research programs conducted in the past and reported in the research literature. Conclusions regarding the compressibility, stress path dependency, and hysteretic nature of the soil-water characteristic curve of an unsaturated soil were presented.</p><p>A considerable number of test results (i.e., from both the experimental program and the research literature) were used in the verification of the new volume-mass constitutive model. This model has proven to be effective in predicting both collapse and expansion of a soil. The volume-mass constitutive model appears to predict behaviour in a satisfactory manner for a wide range of soils; however, the predictions appear to be superior for certain soils. In all cases the volume-mass predictions of the model appear to be satisfactory for geotechnical engineering practice.

We consider a class of queueing systems that consist of server pools in parallel and multiple customer classes. Customer service times are assumed to be exponentially distributed. We study the asymptotic behavior of these queueing systems in a heavy traffic regime that is known as the Halfin and Whitt many-server asymptotic regime. Our main contribution is a general framework for establishing state space collapse results in the Halfin and Whitt many-server asymptotic regime for parallel server systems having multiple customer classes. In our work, state space collapse refers to a decrease in the dimension of the processes tracking the number of customers in each class waiting for service and the number of customers in each class being served by various server pools. We define and introduce a state space collapse function, which governs the exact details of the state space collapse. Our methodology is similar in spirit to that in Bramson (1998); however, Bramson studies an asymptotic regime in which the number of servers is fixed and Bramson does not require a state space collapse function. We illustrate the applications of our results in three different parallel server systems. The first system is a distributed parallel server system under the minimum-expected-delay faster-server-first (MED-FSF) or minimumexpected- delay load-balancing (MED-LB) policies. We prove that the MED-FSF policy minimizes the stationary distribution of total number of customers in the system. However, under the MED-FSF policy all the servers in our distributed system except those with the lowest service rate experience 100% utilization but under the MED-LB policy, on the other hand, the utilizations of all the server pools are equal. The second system we consider is known as the N-model. We show that when the service times only depend on the server pool providing service a static priority rule is asymptotically optimal. Finally, we study two results conjectured in the literature for V-systems. We show for all of these systems that the conditions on the hydrodynamic limits can easily be checked using the standard tools that have been developed in the literature to analyze fluid models.

This thesis attempts to provide a critical perspective on state failure together with its consequences, and how the reconstruction of state is carried out in the aftermath of failure. The thesis commences by discussing the emergence of &lsquo / modern&rsquo / nation-states, and proceeds by analyzing how current patterns of statehood respond to the classic nation-state denominations. Examining the concept of state failure, the thesis aims to verify whether established characteristics of statehood are applicable in view of contemporary dynamics of state weakness. The thesis then observes the difficulties for upholding inherent weaknesses in a state against the pressing nature of the contemporary dynamics of international relations / and, thus explores avenues for frameworks preventive to state failure, as well as postfailure resuscitation of states when these frameworks fail to take effect. Putting this analysis into perspective, the thesis discusses various aspects of international community&rsquo / s engagement for reconstruction of the state in Afghanistan, a country which represents an example for state failure and collapse par excellence, in the frame of a case study. Drawing from this case study, the thesis highlights the shortfalls and successes of state reconstruction in Afghanistan, in an attempt to provide useful hints for similar future engagements elsewhere.

We study two classes of stochastic systems, the limited processor sharing system and the multi-server system. They share the common feature that multiple jobs/customers are being processed simultaneously, which makes the study of them intrinsically difficult. In the limited processor sharing system, a limited number of jobs can equally share a single server, and the excess ones wait in a first-in-first-out buffer. The model is mainly motivated by computer related applications, such as database servers and packet transmission over the Internet. This model is studied in the first part of the thesis. The multi-server queue is mainly motivated by call centers, where each customer is handled by an agent. The number of customers being served at any time is limited by number of agents employed. Customers who can not be served upon arrival wait in a first-in-first-out buffer. This model is studied in the second part of the thesis.

In several practical applications, hot-finished steel pipe that exhibits Lüders bands is bent to strains of 2-3%. Lüders banding is a material instability that leads to inhomogeneous plastic deformation in the range of 1-4%. This work investigates the influence of Lüders banding on the inelastic response and stability of tubes under rotation controlled pure bending. It starts with the results of an experimental study involving tubes of several diameter-to-thickness ratios in the range of 33.2 to 14.7 and Lüders strains of 1.8% to 2.7%. In all cases, the initial elastic regime terminates at a local moment maximum and the local nucleation of narrow angled Lüders bands of higher strain on the tension and compression sides of the tube. As the rotation continues, the bands multiply and spread axially causing the affected zone to bend to a higher curvature while the rest of the tube is still at the curvature corresponding to the initial moment maximum. With further rotation of the ends, the higher curvature zone(s) gradually spreads while the moment remains essentially unchanged. For relatively low D/t tubes and/or short Lüders strains, the whole tube eventually is deformed to the higher curvature entering the usual hardening regime. Subsequently it continues to deform uniformly until the usual limit moment instability is reached. For high D/t tubes and/or materials with longer Lüders strains, the propagation of the larger curvature is interrupted by collapse when a critical length is Lüders deformed leaving behind part of the structure essentially undeformed. The higher the D/t and/or the longer the Lüders strain is, the shorter the critical length. This class of problems is analyzed using 3D finite elements while the material is modeled as an elastic-plastic solid with an “up-down-up” response over the extent of the Lüders strain, followed by hardening. The analysis reproduces the main features of the mechanical behavior provided the unstable part of the response is suitably calibrated. The uniform curvature elastic regime terminates with the nucleation of localized banded deformation. The bands appear in pockets on the most deformed sites of the tube and propagate into the hitherto intact part of the structure while the moment remains essentially unchanged. The Lüders-deformed section has a higher curvature, ovalizes more than the rest of the tube, and develops wrinkles with a characteristic wavelength. For every tube D/t there exists a threshold of Lüders strain separating the two types of behavior. This bounding value of Lüders strain was studied parametrically. / text

This thesis presents a comprehensive study of the compressive response of hexagonal honeycomb panels from the initial elastic regime to a fully crushed state. Expanded aluminum alloy honeycomb panels with a cell size of 0.375 in (9.53 mm), a relative density of 0.026, and a height of 0.625 in (15.9 mm) are laterally compressed quasi statically between rigid platens under displacement control. The cells buckle elastically and collapse at a higher stress due to inelastic action. Deformation then first localizes at mid-height and the cells crush by progressive formation of folds; associated with each fold family is a stress undulation. The response densifies when the whole panel height is consumed by folds. The buckling, collapse, and crushing events are simulated numerically using finite element models involving periodic domains of a single or several characteristic cells. The models idealize the microstructure as hexagonal, with double walls in one direction. The nonlinear behavior is initiated by elastic buckling while inelastic collapse that leads to the localization observed in the experiments occurs at a significantly higher load. The collapse stress is found to be mildly sensitive to various problem imperfections. For the particular honeycomb studied, the collapse stress is 67% higher than the buckling stress. It was also shown that all aspects of the compressive behavior can be reproduced numerically using periodic domains with a fine mesh capable of capturing the complexity of the folds. The calculated buckling stress is reduced when considering periodic square domains as the compatibility of the buckles between neighboring cells tends to make the structure more compliant. The mode consisting of three half waves is observed in every simulation but its amplitude is seen to be accented at the center of the domains. The calculated crushing response is shown to better resemble measured ones when a 4x4 cell domain is used, which is smoother and reproduces decays in the amplitude of load peaks. However, the average crushing stress can be captured with engineering accuracy even from a single cell domain. / text

Hydrophobic interactions guide important molecular self-assembly processes such as protein folding. On the macroscale, hydrophobic interactions consist of the aggregation of "oil-like" objects in water by minimizing the interfacial energy. However, the hydration mechanism of small hydrophobic molecules on the nanoscale (~1 nm) differs fundamentally from its macroscopic counterpart. Theoretical studies over the last two decades have pointed to an intricate dependence of molecular hydration mechanisms on the length scale. The microscopic-to-macroscopic cross-over length scale is critically important to hydrophobic interactions in polymers, proteins and other macromolecules. Accurate experimental determination of hydration mechanisms and their interaction strengths are needed to understand protein folding. This thesis reports the development of experimental and analytical techniques that allow for direct measurements of hydrophobic interactions in a single molecule. Using single molecule force spectroscopy, the mechanical unfolding of a single hydrophobic homopolymer was identified and modeled. Two experiments examined how hydrophobicity at the molecular scale differ from the macroscopic scale. The first experiment identifies macroscopic interfacial tension as a critical parameter governing the molecular hydrophobic hydration strength. This experiment shows that the solvent conditions affect the microscopic and macroscopic hydrophobic strengths in similar ways, consistent with theoretical predictions. The second experiment probes the hydrophobic size effect by studying how the size of a non-polar side-chain affects the thermal signatures of hydration. Our experimental results reveal a cross-over length scale of approximately 1 nm that bridges the transition from entropically driven microscopic hydration mechanism to enthalpically driven macroscopic hydration mechanism. These results indicate that hydrophobic interactions at the molecular scale differ from macroscopic scale, pointing to potential ways to improve our understanding and predictions of molecular interactions. The system established in this thesis forms the foundation for further investigation of polymer hydrophobicity.

[Truncated abstract] As a consequence of the increase in terrorist incidents, many comprehensive researches, both experimental and numerical modelling of structure and blast interaction, have been conducted to examine the behaviour of civilian structures under dynamic explosion and its impact. Nevertheless most of the works in literature are limited to response of simple structures such as masonry walls, reinforced concrete beams, columns and slabs. Although these studies can provide researchers and structural engineers a good fundamental knowledge regarding blast load effect, it is more likely for blast load to act upon entire structures in actual explosion events. The interaction between blast load and structures, as well as the interaction among structural members may well affect the structural response and damage. Therefore it is necessary to analyse more realistic reinforced concrete structures in order to gain an extensive knowledge on the possible structural response under blast load effect. Among all the civilian structures, bridges are considered to be the most vulnerable to terrorist threat and hence detailed investigation in the dynamic response of these structures is essential. This thesis focuses on the study of the response of a modern cable-stayed bridge under blast loadings. ... Firstly, analysis is conducted to examine the failure of four main components namely pier, tower, concrete back span and steel composite main span under close proximity dynamic impact of a 1000 kg TNT equivalent blast load. Secondly, based on such results, the remainder of the bridge structure is then tested by utilizing the loading condition specified in the US Department of Defence (DoD) guideline with the aim to investigate the possibility of bridge collapse after the damage of these components. It is found that failure of the vertical load bearing elements (i.e. pier and tower) will lead to catastrophic collapse of the bridge. Assuming that terrorist threat cannot be avoided, hence protective measures must be implemented into the bridge structure to reduce the damage induced by explosive blast impact and to prevent bridge from collapse. As such, a safe standoff distance is determined for both the pier and tower under the blast impact of 10000 kg TNT equivalent. This information would allow the bridge designer to identify the critical location for placing blast barriers for protection purpose. For the case of bridge deck explosion, carbon fibre reinforced polymer (CFRP) is employed to examine in respect of its effectiveness in strengthening the concrete structure against blast load. In this research, appropriate contact is employed for the numerical model to account for the epoxy resin layer between the CFRP and concrete. In addition, to ensure that the CFRP can perform to its full capacity, anchors are also considered in the numerical study to minimize the chance of debonding due to the weakening of the epoxy. The results reveal that although severe damage can still be seen for locations in close proximity to the explosive charge, the use of CFRP did reduce the dynamic response of the bridge deck as compared to the unprotected case scenario. Further investigation is also carried out to examine the change in damaged zone and global response through variation in CFRP thickness.

Made available in DSpace on 2014-06-11T19:23:32Z (GMT). No. of bitstreams: 0 Previous issue date: 2011-02-08Bitstream added on 2014-06-13T20:30:20Z : No. of bitstreams: 1 fraga_js_me_arafcl.pdf: 570399 bytes, checksum: c4d98662c4b2a66e86a84c364b2ae848 (MD5) / Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES) / O presente trabalho tem como objetivo analisar a experiência do Japão após os colapsos das bolhas especulativas dos ativos na década de 1990. Aceitando que o pior já passou, ou seja, que a crise financeira japonesa foi finalmente resolvida, uma coisa é certa; não antes de uma “década perdida” caracterizada por um longo período, de baixo crescimento, aumento das taxas de desemprego, deflação nos preços dos ativos, falências bancárias e persistência dos no-performing loans. Nesse contexto, as principais respostas obtidas por este trabalho foram: a crença que a recuperação econômica viria com o passar do tempo e a falta de entendimento sobre o tamanho do problema que a morosidade de atuação levaria ao sistema, explica em certo ponto a tolerância inicial do governo japonês frente à crise econômica. A política fiscal expansionista foi eficaz, mas, não utilizada de forma consistente, a natureza “stop-start” dos estímulos realizados, e em particular as prematuras reversões fiscais diminuíram a sua eficácia, outros fatores prováveis para a baixa eficácia durante os anos 90 foram: os estímulos fiscais podem ter sido prejudicados pela queda dos multiplicadores fiscais; os efetivos investimentos públicos foram menores que os anunciados e ao invés de se dar ênfase a obras públicas, priorizou-se cortes em impostos. De outra forma, um caminho fundamental de maximizar os estímulos fiscais é através da restauração do crédito do setor bancário, caso a recapitalização e as restaurações do setor fossem realizas em uma fase inicial, os efeitos dos estímulos poderiam ser de curta duração, se o sistema financeiro estivesse em boa saúde. No Japão, as injeções nos bancos “em grande escala” ocorreram apenas em 1999. Por outro lado, a política monetária, com base em uma versão alternativa da armadilha da liquidez levou o BOJ a tomar algumas medidas... / This dissertation intend to analyze the experience of Japan after the collapse of speculative bubbles in assets in the 1990s. Accepting that the worst is over, that is to say, that the Japanese financial crisis was finally resolved, one thing is certain; not before a “lost decade” characterized by a long period of low growth, increasing rates of unemployment, deflation in asset prices, bank failures and persistence of no-performing loans. In this context, the main responses received for this work were: the belief that economic recovery would come with the passage of time and lack of understanding about the size of the problem that the slowness of action would lead to the system; this explains in some degree the initial tolerance of the Japanese government by the economic crisis. The expansionary fiscal was effective, but not consistently used, the nature of “stop-start” of the stimuli made, and in particular the early tax reversals decreased its effectiveness, other likely factors for the low efficiency during the year 1990 were: the fiscal stimuli may have been harmed by falling tax multipliers; the effective public investments were lower than those advertised instead of giving emphasis to public works, the priority was tax cuts. On the other hand, a fundamental way to maximize the tax incentives is through the restoration of credit from the banking sector, if the recapitalization and the restorations of the sector were held in an early stage, the effects of stimuli could be short term, if the financial system was in good health. In Japan, the injections in banks “large scale” occurred only in 1999. Moreover, monetary policy, based on an alternative version of the liquidity trap led the BOJ to take some innovative measures since 2001. Centered on a strategy to ensure liquidity and extend the warranties on direct purchases of assets, quantitative easing was implanted... (Complete abstract click electronic access below)