The fluid flow channels of modern heat exchangers are often equipped with different flow disturbance elements which enhance the convective heat transfer coefficient in each channel. These structural or surface roughness elements induce enhanced flow mixing and convective heat transfer at low Reynolds numbers (500 < Re < 2200) by fluid mixing near the channel walls and increasing the surface area. These elements, however, are accompanied by higher pressure drops in comparison to hollow smooth channels (without inserts). The Run-Around Membrane Energy Exchanger (RAMEE) system is an air-to-air energy recovery system comprised of two remote liquid-to-air membrane energy exchangers (LAMEEs) coupled by a pumped liquid desiccant loop. LAMEEs use semi-permeable membranes that are permeable to water vapor, but impermeable to liquid water. The membranes separate the liquid desiccant from the air flow channels, while still allowing both heat and water vapor transfer. The air channels are equipped with turbulence enhancing inserts which serve dual purposes: (a) to support the adjacent flexible membranes, and (b) to enhance the convective heat and mass transfer. This research experimentally investigates the increase in the air pressure drop and average convective heat transfer coefficient after an air-side insert is installed in a Small-scale wind tunnel for exchanger insert testing (WEIT) facility that is designed to simulate the air channels of a LAMEE and to measure all the properties required to determine the flow friction factor and Nusselt number. Experiments are conducted in the test section under steady state conditions at Reynolds numbers between 900 and 2200 for a channel with and without inserts. The 500-mm-long test section has a rectangular cross section (5 mm wide and 152.4 mm high) and is designed to maintain a specified constant heat flux on each side wall. The flow is laminar and hydrodynamically fully developed at the entrance of the test section and, within the test section, thermal development occurs. Nine different insert panels are tested. Each insert is comprised of several plastic rib spacers, each aligned parallel to the stream-wise direction, and several cross-bars aligned normal to the flow direction. The plastic rib spacers are placed either 30 mm, 20 mm or 10 mm apart, and the distance between the cylindrical bars is either 30 mm, 45 mm, 60 mm or 90 mm. The measured convective heat transfer coefficient and the friction factor have uncertainties that are less than ±7% and ±11%, respectively. It is found that the Nusselt number and friction factor are dependent on the insert geometry and the Reynolds number. An empirical correlation is developed for the inserts to predict Nusselt number and friction factor within an air channel of a LAMEE. The correlations are able to determine the Nusselt number and the friction factor within ±9% and ±20% of the experimental data. Results show the flow insert bar spacing is the most important factor in determining the convective heat transfer improvement. As an application of the experimental data in this thesis, the experimental and the numerical results from a LAMEE which has an insert in each airflow channel are presented. The results show that the insert within the air channel of the LAMEE is able to improve the total effectiveness of the LAMEE by 4% to 15% depending on the insert geometry and air flow Reynolds number and operating inlet conditions for the exchanger.

Marriage prevention and enhancement programs are vital to the future of society due to their expanded ability to reach many couples that might not otherwise seek help in building the tools necessary for a successful relationship. Because marital distress has been related to many negative long-term health and emotional consequences, preventing these damaging outcomes is a rising priority for psychologists and the health care field. In this study, 55 couples started a secondary marital enhancement and prevention program called SUCCES. The SUCCES program merges multiple interventions from distinct empirically supported couples treatments within a conceptually pluralistic framework. Cognitive behavioral skills development as well as insight and emotion-focused couples therapy techniques are interwoven with each other in the program. Thirty-two couples completed the 9-week intervention and the six-month follow-up assessment period. Although there was no control group, repeated-measures MANOVAs yielded positive results when assessing increases in interpersonal functioning. Couples who participated in the program reported higher levels of satisfaction in broad and specific areas of their relationship upon completion. In addition, couples reported fewer relationship problem areas and an increased quality of life. Almost all increases remained significant at six-month follow-up. These positive initial findings suggest the potential efficacy of the SUCCES program and the importance of future controlled outcome studies to validate its clinical utility.

Femtosecond time scale allows us to follow and control atomic and molecular motion. The atomic vibrations happen in the range of femtosecond scale. Thus, femtosecond technology effectively measures the atomic vibration. However, to determine electron motion, one needs to reach sub-femtosecond time scale that is in attosecond time scale. High Harmonic Generation (HHG) is a non-linear process that converts infrared light to shortest wavelength, such as in the XUV regime. HHG allows to explore electronic motion and to control electron dynamics. HHG easily reaches to XUV region and is enabling attosecond pulse generation. In this thesis we focused to generate attosecond pulses by using noble gases and their mixtures. We used only argon gas, only hydrogen molecule and their mixture with neon gas. We wanted to improve the conversion efficiency (10^-6) of the fundamental light into high harmonics. We use Ne and H2 gas mixture to look enhancement of the HHs.

The processes involved in the enhancement of the fluorescence profile of dipicolinic acid (DPA) were measured and analysed, with particular emphasis on their potential application to the rapid identification of suspicious powders. The research was conducted in contribution to the anthrax detector currently under development at this department. Using the enhancement of fluorescence as a method of determining whether a sample contains spores shows great potential because DPA is not found in most powders that do not contain spores. Thus, its detection is a good indication of the presence of spores. The research presented in this thesis primarily focuses on the optimisation of measurement and enhancement techniques. Both DPA and milk powder (containing spores) were used as anthrax simulants. We found that 210 nm light was the optimal wavelength for the enhancement of DPA; however, as most light sources have a higher intensity at longer wavelengths, the use of 270 nm light may be more effective. At low concentrations, there is a linear relationship between detected fluorescence intensity and the quantity of DPA present. A linear response was also found to the enhancement-light exposure time.

Impression management (IM) handlar om enmedveten eller omedveten process att styra intrycken av sig själv som ges tillomgivningen i syfte att imponera och söka erkännande. Tidigare forskning har istor utsträckning berört anställningsrekommendation utifrån intervjuer och demest framgångsrika resultaten har visat sig vara självförbättrande IM taktik.Studiens syfte vara att undersöka hur självförbättrande IM taktik i personligtbrev, två kvalitéer av meriter, påverkar ett beslut omanställningsrekommendation, samt undersöka hur en uppsättning personliga egenskaperrelaterar till självförbättrande IM taktik. Deltagarna var studenter, 57kvinnor och 32 män. Studien var experimentell 2 x 2 x 2 mellangruppsdesign. Deviktigaste fynden var att, högre kvalité av meriter innebar högre skattning avanställningsrekommendation samt att högre skattning av egenskaper vidsjälvförbättrande IM taktik skattats. Meriters kvalité visades viktig,egenskaper visade samband med IM dock satte IM trovärdighet på spel.Könsskillnader påträffades även och vidare forskning förslås göras mellankönen.

Transmission Control Protocol (TCP) is the dominant transport protocol in the Internet and supports many of the most popular Internet applications, such as the World Wide Web (WWW), file transfer and e-mail. TCP congestion control algorithms dynamically learn the network bandwidth and delay characteristics of a network and adapt its performance to changes in traffic so as to avoid network collapse. TCP is designed to perform well in traditional wireline networks with the assumptions that packet losses are mainly due to network congestion and random bit error rate (BER) is negligible. However, networks with wireless links suffer from significant packet losses due to random bit errors and handoffs. Hence TCP performs poorly in networks with wireless links because it treats any packet loss in the network to be a result of network congestion and slows down its transmission rate, or even cause the TCP sender to experience unnecessary timeouts, further reducing its performance. The development of advance wireless networks, such as WiFi, UMTS and WiMAX, make it necessary to find ways to improve TCP's efficiency and resource utilization, as well as improve the user's experience and reduce latency times. In order to find effective solutions to this effect, packet losses across wireless links should be distinguished from congestion related packet losses. In this thesis, we concentrate on two main strategies for enabling the TCP congestion control mechanism to determine the cause for a packet loss. One is a proxy-based mechanism that monitors the radio network interface and sends radio network feedback (RNF) to the TCP sender with the status of the wireless link. The other one is an end-to-end mechanism, in which the packet error pattern is used as the system metric to fine-tune the congestion control mechanism. It also presents an analytical model of TCP with enhanced recovery mechanism for wireless environments. In a proxy-based mechanism, TCP sender is explicitly informed of any effects caused by wireless links. However, the implementation technique is network dependent. We have proposed and developed three proxy-based schemes; the radio network feedback (RNF) scheme over an 802.11 WLAN network, the radio network controller (RNC) feedback over a UMTS network and a wireless enhancement proxy (WENP) over both the 802.11 WLAN and UMTS networks. The RNF scheme is introduced at the 802.11 WLAN base station that monitors the TCP packet flows over the wireless links, detects wireless packet losses and provides feedback to the TCP sender using one of the TCP header reserved control bits, called RNF flag. TCP Reno is modified to utilize the radio network feedback to distinguish the losses due to wireless effects form the congestion and fine-tuned to perform wireless enhanced fast retransmit and fast recovery mechanisms. The RNF scheme is implemented using the OPNET tool, and the simulation results show that the TCP performance is significantly improved. The RNC feedback mechanism, similar to the RNF scheme, is developed and implemented in a UMTS network. The GPRS Tunneling Protocol (GTP) layer of the UMTS Radio Network Control (RNC) protocol stack was modified to detect and notify the TCP sender of the wireless packet losses, which is the main difference between the RNF and RNC mechanisms. The simulation results shows that the RNC feedback mechanism significantly improves the TCP performance compared to that of standard TCP over UMTS. The wireless enhancement proxy (WENP) is developed to minimize spurious TCP timeouts over wireless networks and implemented in both 802.11 WLAN and UMTS networks. WENP extends the proposed RNF and RNC feedback mechanisms to detect both wireless packet losses and large delays across the wireless link, and to notify the TCP sender of these events with the aid of two reserved bits in the TCP header. TCP Reno is further modified to utilize the WENP feedback to distinguish both wireless packet losses from congestion losses and spurious timeouts from normal timeouts. It is also fine-tuned to perform both the wireless enhanced fast retransmit and fast recovery mechanism and the timeout mechanism. The simulation results demonstrate that the proposed scheme markedly improves the TCP performance compared to that of standard WLAN and UMTS implementations. An end-to-end early packet loss recovery (EPLR) mechanism that modifies the TCP Reno fast retransmit algorithm to detect packet losses early and to speed up the packet recovery process to reduce the number of TCP timeouts over networks with heavy packet losses, such as wireless networks is also presented. TCP Reno with EPLR scheme is implemented in a UMTS network and its performance is compared with that of TCP Reno and New Reno. Simulation results shows that Reno with EPLR improves the TCP performance and application response time significantly compared to that of both Reno and New Reno by reducing the TCP timeouts, which is the main cause of degradation of the TCP performance in a wireless environment. Finally, we develop an analytical TCP throughput model with enhanced TCP Reno fast retransmit algorithm to avoid timeouts. The model captures the TCP fast retransmit mechanism and expresses the steady state congestion window and throughput as a function of network utilization factor, round trip time (RTT) and loss rate. Another new feature added to the model is dynamic adjustment of the congestion window size depending on the packet drop rates. This speeds up the packet recovery process and reduces the number of TCP timeouts over networks with heavy packet losses. The proposed model is implemented over a UMTS network and its performance is compared with that of TCP Reno. Simulation results show that the proposed model reduces the TCP timeouts and improves the TCP performance compared to that of TCP Reno. It is also found that the model provides a very good match to the steady-state congestion window behavior.

Noise-immune cavity-enhanced optical heterodyne molecular spectroscopy, NICE-OHMS, is a laser-based spectroscopic detection technique that comprises the concepts of frequency modulation (FM, for reduction of 1/f-noise by detecting the signal at a high frequency) and cavity enhancement (CE, for a prolongation of the optical path length) in a unique way. Properly designed, this gives the technique an intrinsic immunity against the frequency-to-noise conversion that limits many other types of CE techniques. All this gives it an exceptionally high sensitivity for detection of molecular species. Although originally developed for frequency standard purposes in the late 1990s, soon thereafter development of the technique towards molecular spectroscopy and trace gas detection was initiated. This thesis focuses on the further development of Doppler- broadened NICE-OHMS towards an ultra-sensitive detection technique. A number of concepts have been addressed. A few of these are: i) The detection sensitivity of fiber-laser-based NICE- OHMS has been improved to the 10−12 cm−1 range, which for detection of C2H2 corresponds to a few ppt (parts-per-trillion, 1:1012) in gas phase, by improving the locking of the laser to a cavity mode by use of an acousto-optic modulator. ii) It is shown that the system can be realized with a more compact footprint by implementation of a fiber-optic circulator. iii) A systematic and thorough investigation of the experimental conditions that provide maximum signals, referred to as the optimum conditions, e.g. modulation and demodulation conditions and cavity length, has been performed. As a part of this, an expression for the NICE-OHMS line shape beyond the conventional triplet formalism has been proposed and verified. iv) To widen the applicability of NICE-OHMS for detection of pressure broadened signals, also a setup based upon a distributed-feedback (DFB) laser has been realized. v) In this regime, the Voigt profile cannot model signals with the accuracy that is needed for a proper assessment of analyte concentrations. Therefore, the thesis demonstrates the first implementations of line profiles encompassing Dicke narrowing and speed-dependent effects to NICE-OHMS. While such profiles are well-known for absorption, there were no expressions available for their dispersion counterparts. Such expressions have been derived and validated by accompanying experiments. vi) The applicability of the technique for elemental detection, then referred to as NICE-AAS, has been prophesied. / Brusimmun kavitetsförstärkt optisk-heterodyndetekterad molekylärspektroskopi (NICE-OHMS) är en laser-baserad spektroskopisk teknik som förenar frekvensmodulation (för reducring av 1/f-brus genom detektion vid en hög frekvens) och kavitetsförstärkning (KF, för en förlängning av den optiska väglangden) på ett unikt sätt. Korrekt realiserad uppvisar tekniken en inneboende immunitet mot omvandling av frekvensbrus till intensitetsbrus som många andra KF-tekniker är begränsade av. Allt detta ger tekniken en exceptionellt hög känslighet för molekyldetektion. Ursprungligen utvecklad för frekvensstandardändamål i slutet av 1990, har den sedan dess utvecklats för molekylspektroskopi och spårgasdetektering. Denna avhandling fokuserar på vidareutvecklingen av NICE-OHMS mot en tillämpbar, ultrakänslig detektionsteknik. Ett antal koncept har adresserats. Några av dessa är: i) Detektionskänsligheten hos fiberlaserbaserad NICE-OHMS har förbättrats till 10-12 cm-1 området, vilket för detektion av C2H2 i gasfas motsvarar några få ppt (parts per biljon, 1:1012), genom att förbättra låsningen av lasern till en kavitetsmod med hjälp av en akustooptisk modulator. ii) Det har demonstrerats att NICE-OHMS kan realiseras mer kompakt med hjälp av en fiber-kopplad optisk cirkulator. iii) En systematisk och grundlig utredning av de experimentella förhållanden som ger maximala signaler, betecknade de optimala förhållanden, t.ex. modulering och demodulering och kavitetslängden, har utförts. Som ett led i detta har ett uttryck för NICE-OHMS linjeform bortom den konventionella triplett formalismen föreslagits och verifierats. iv) För att bredda tillämpbarheten av NICE-OHMS för detektering av tryckbreddade signaler har även en instrumentering baserad på en distribuerad-återkopplad (eng. distributed feedback, DFB) laser realiserats. v) I detta område kan inte Voigt profilen modellera signalen med den noggrannhet som krävs för en korrekt bedömning av analytkoncentrationer. Därför visar avhandlingen de första implementeringarna i NICE-OHMS av linjeprofiler som inkluderar Dicke avsmalning (eng. Dicke narrowing) och hastighetsberoende effekter (eng. speed-dependent effects). Emedan sådana profiler är välkända för absorption, fanns det inga uttryck för deras dispersiva motparter. Sådana uttryck har därför härletts och validerats av medföljande experiment. vi) Tillämpbarheten av tekniken för detektion av atomer, NICE-AAS, har diskuterats och förutspåtts. / <p>Ytterligare forskningsfinansiär: Kempestiftelserna</p>

Research has shown that desirable responding can be detrimental to social relationships, achievement and health. This study used an experimental design to (a) induce an increase in desirable responding through threat to self-image and then (b) compare the effectiveness of self-compassionate and self-affirming writing in attenuating that increase. Control groups included no threat exposure, threat exposure alone and threat exposure plus neutral writing. Desirable responding was measured along two dimensions: self-enhancement and exaggerated virtue. Results show the threat did not result in the predicted increase in desirable responding so the effectiveness of the two strategies with regards to attenuating increases in desirable responding could not be examined and compared. However, results do reveal a difference in the mechanism of these two strategies. Engaging in self-compassionate writing resulted in a significant decrease in exaggerated virtue whereas being self-affirmed resulted in a significant increase, suggesting a possible benefit of a self-compassion strategy.

Poor employee performance is one of employer’s most common challenges. The study aims to explore the effectiveness of a Performance Enhancement Programme (PEP) used within an electricity supply company and identifying the contributing factors for managers and supervisors not utilizing the programme. The research method consists of two parts, a literary review and an empirical study. The empirical study was done by means of a survey conducted on a sample of 210 Eskom supervisors and managers of the North Western Region of Eskom. The measuring instrument consisted of a structured questionnaire, developed by the researcher. The results revealed that supervisors and managers are using PEP and that they see it as a good tool to manage poor performance. Respondents indicated very clearly that they need training to be able to address poor performance. The findings concerning the effectiveness of the PEP were inconclusive. The small sample size was a limitation to the study. The questionnaire proved to be lacking in determining the effectiveness of the Performance Enhancement Programme. The sample only included supervisors and managers in the North Western Region of Eskom. Further research needs to be conducted with a larger sample including employees on all levels. / Thesis (MBA)--North-West University, Potchefstroom Campus, 2012.

Poor employee performance is one of employer’s most common challenges. The study aims to explore the effectiveness of a Performance Enhancement Programme (PEP) used within an electricity supply company and identifying the contributing factors for managers and supervisors not utilizing the programme. The research method consists of two parts, a literary review and an empirical study. The empirical study was done by means of a survey conducted on a sample of 210 Eskom supervisors and managers of the North Western Region of Eskom. The measuring instrument consisted of a structured questionnaire, developed by the researcher. The results revealed that supervisors and managers are using PEP and that they see it as a good tool to manage poor performance. Respondents indicated very clearly that they need training to be able to address poor performance. The findings concerning the effectiveness of the PEP were inconclusive. The small sample size was a limitation to the study. The questionnaire proved to be lacking in determining the effectiveness of the Performance Enhancement Programme. The sample only included supervisors and managers in the North Western Region of Eskom. Further research needs to be conducted with a larger sample including employees on all levels. / Thesis (MBA)--North-West University, Potchefstroom Campus, 2012.