Wärmespeicher tragen bei optimierter Integration in Wärme- und Kälteversorgungsanlagen zur Einsparung von installierter Erzeugerleistung, Brennstoffeinsatz und Betriebskosten bei. Leider treten in Wärmespeichern oft noch beachtliche Verluste auf und das Potenzial zur Kosten- und Energieeinsparung wird nicht vollständig ausgeschöpft. Dabei spielen nicht nur Wärmeverluste an die Umgebung, sondern vor allem auch innere Verluste im Speicher eine Rolle. Schwerpunkte der vorliegenden Arbeit sind die Beschreibung der einzelnen Verluste an Wasserwärmespeichern, die Ermittlung ihrer Ausmaße abhängig von der konstruktiven Gestaltung und der Betriebsweise des Speichers sowie die Auswirkungen der Verluste auf einen vorgelagerten Wärmeerzeuger und den Einsatz von Primärenergie. Die Ergebnisse basieren auf umfangreichen Speichermodellierungen mit dem CFD-Code Fluent sowie experimentellen Untersuchungen an drei Testspeichern. Der quantitative Vergleich der Verluste für ausgewählte Beispiele zeigt bestehende Defizite sowie die Potenziale für die Verbesserung der Konstruktion neuer Wasserwärmespeicher auf. / If hot water storage tanks are optimally integrated in heat or cold supply systems, they contribute to a reduction of required capacity, fuel and operation costs. Unfortunately, even today remarkable heat losses and internal losses occur in hot water storage tanks. The potential for cost and energy reductions is not completely utilized yet. Here, not only heat losses to the ambience, but also internal losses play a decisive role. Main focus of the presented work is the description of the single losses at hot water storage tanks and the determination of the correlation between the losses, the tank design and the mode of operation. Furthermore the effects of the losses in the tank on the efficiency of different types of heat generators and the input of primary energy into the system have been examined. The results are based on extended numerical modeling with the CFD-code Fluent as well as experimental test with three storage tanks. The quantitative comparison of the losses for selected examples shows the current shortcomings but even the potential for an optimized hot water storage tank design.

<p>With increasing concerns about the global warming effects of HFC refrigerants, low-GWP refrigerants and non-vapor compression heat pumps are investigated as potential mid- and long-term replacements for current vapor compression heat pump systems that rely on high-GWP refrigerants. To address the need for more environmentally friendly space cooling and heating, and water heating solutions. the U.S. Department of Energy (DOE) Office of Energy Efficiency & Renewable Energy (EERE) is supporting the development of smarter, more efficient, and affordable heat pumping systems operating with low- or near-zero GWP refrigerants through different programs including the Energy, Emissions, and Equity (E3) Initiative. In addition, the Emerging Technologies (ET) Program within the Building Technologies Office (BTO) emphasized the research and development efforts needed to support new technologies that could reduce energy usage in residential and commercial buildings by 50\% over the next decades. In the literature, limited studies were found that systematically investigated different combinations of conventional and emerging space conditioning and water heating technologies while accounting for real building loads, different climate zones, utility structures, and current state-of-the-art equipment. Existing literature primarily focused on thermodynamic performance evaluations at fixed boundary conditions. In addition, separate sensible latent cooling (SSLC) and other novel cooling and dehumidification systems (e.g., membrane-based systems) can significantly reduce the electricity usage for space conditioning. To compare the performance of conventional and emerging technologies several figures-of-merit such as the second law efficiency, are often used. However, limitations exist in previous studies to define the thermodynamic reversible limits and second law efficiency for cooling and dehumidification systems.</p><p>This study developed a comprehensive modeling framework to evaluate both current state-of-the-art vapor compression systems and emerging HVAC\&R technologies in real-world scenarios. The platform will be used to assess potential energy savings, scalability issues, and the effectiveness of combined technologies for different buildings, climate conditions, and utility structures.</p><p>To compare HVAC technologies, a new physics-based definition for the reversible limit and the second law efficiencies for cooling and dehumidification systems with air recirculation has been developed. The new framework is then extended to define a novel performance metric, the seasonal second law efficiency, to form a universal benchmark for assessing various cooling and dehumidification systems. Five cooling and dehumidification systems including magnetocaloric cooling, solid desiccant dehumidification, and membrane dehumidification are evaluated using this benchmark. Steady-state thermodynamic models are constructed for each system. Second law efficiency for each system under various outdoor temperatures and indoor sensible heat ratios (SHR) are calculated. The annual electricity usage of the five systems is used to justify the seasonal second law efficiency definition. The results show that compared to conventional vapor compression systems with mechanical dehumidification, the membrane-based AMX-R cycle can reduce annual electricity use by 12.2%-22.2% and increase the seasonal second law efficiency by 36%.</p><p>The advancements of nine not-in-kind (defined as non-vapor compression systems, solid-state, and chemical-based systems) technologies, i.e. magnetocaloric, thermoelectric, elastocaloric, electrocaloric, membrane-based, Vuilleumier, sorption, chemical looping, and desiccant, were reviewed in detail and compared with the state-of-the-art vapor compression systems. Suitable figures-of-merit were defined to compare the different technologies from a thermodynamic standpoint as well as technology readiness level. As a result of the thorough literature review, a roadmap was created to track the development of emerging HVAC&R technologies and future developments. More importantly, the roadmap enabled the identification of several case studies to evaluate potential energy savings both for space conditioning and water heating. Techno-economic studies for eight HVAC configurations for space heating, cooling, and water heating were conducted for a realistic building scenario under various climate conditions. Different combinations of advanced equipment such as heat pump water heater (HPWH), ground-source heat pumps (GSHP), cold-climate heat pumps (CCHP), and membrane-heat pumps were compared with traditional vapor compression heat pumps and gas furnaces. A building model was developed in EnergyPlus and validated with historical data from the DC Nanogrid House at the Purdue University campus. A total of eleven climate zones were considered, and both local weather conditions and utility pricing were implemented in the simulations. Moreover, future SEER2/HSPF2 equipment ratings and E3 Initiative targets were also included in the analyses.</p><p>The initial simulation results provided climate-based equipment selection guidelines and quantitative techno-economic assessments. For instance, CCHPs with two-stage compression in heating mode save 10%-20% in annual heating cost compared with single-stage VCHPs in Climate Zone 4A, 4C, 5A, 5B, 6A, and 6B. Membrane evaporative air-conditioners could provide cooling cost savings in places where is a significant cooling load, such as Zone 1A, 2A, 2B, 3A, 3C, 4A, 5A, and 6A. Gas furnaces should only be used in cold places where the electricity price per kWh to gas price ratio is higher than 3. GSHP has the lowest HVAC annual energy cost in six out of eleven climate zones in the U.S. Dual fuel heat pumps are not always the most economical option but yield better average cost savings among the eleven locations. HPWHs should be recommended in areas where the electricity price to gas price ratio is below 3. </p><p>The developed simulation framework will be instrumental to continue in-depth investigations of current and next-generation heat pump technologies. The ultimate goal of this research is to provide future guidelines on the selection of building-specific and climate-specific equipment solutions that will enable energy savings and future decarbonization strategies (e.g., geospatially-resolved simulations).</p>

Circular Economy (CE) aims at improving the resource efficiency of our society and decoupling economic growth from resource use. However, entropy and residues are still generated in CE, and resources such as energy, raw materials and water are used throughout the CE processes. The methodology developed in this thesis aims at evaluating and communicating the resource efficiency and environmental impacts of CE systems. Firstly, a digital twin of the system is created using process simulation to obtain detailed mass and energy balances. Then, a set of indicators is obtained for the evaluation of the material recoveries, residues and emissions generated, resource use and environmental impacts (LCA). Exergy indicators such as exergy dissipation and cost are also obtained from the simulation using a dedicated tool developed and implemented within this thesis. This methodology has been applied in three case studies within metallurgy and CE to evaluate, optimize and communicate their resource efficiency and environmental impacts. These case studies are the evaluation of the copper value chain, the comparison between different zinc production routes and the industrial symbiosis between the copper, zinc and cement value chains.

In this thesis, exergy based SI engine model optimisation (EBSIEMO) is studied and evaluated. A four-stroke bi-fuel spark ignition (SI) engine is modelled for optimisation of engine performance based upon exergy analysis. An artificial neural network (ANN) is used as an emulator to speed up the optimisation processes. Constrained particle swarm optimisation (CPSO) is employed to identify parameters such as equivalence ratio and ignition time for optimising of the engine performance, based upon maximising ¿total availability¿. In the optimisation process, the engine exhaust gases standard emission were applied including brake specific CO (BSCO) and brake specific NOx (BSNOx) as the constraints. The engine model is developed in a two-zone model, while considering the chemical synthesis of fuel, including 10 chemical species. A computer code is developed in MATLAB software to solve the equations for the prediction of temperature and pressure of the mixture in each stage (compression stroke, combustion process and expansion stroke). In addition, Intake and exhaust processes are calculated using an approximation method. This model has the ability to simulate turbulent combustion and compared to computational fluid dynamic (CFD) models it is computationally faster and efficient. The selective outputs are cylinder temperature and pressure, heat transfer, brake work, brake thermal and volumetric efficiency, brake torque, brake power (BP), brake specific fuel consumption (BSFC), brake mean effective pressure (BMEP), concentration of CO2, brake specific CO (BSCO) and brake specific NOx (BSNOx). In this model, the effect of engine speed, equivalence ratio and ignition time on performance parameters using gasoline and CNG fuels are analysed. In addition, the model is validated by experimental data using the results obtained from bi-fuel engine tests. Therefore, this engine model was capable to predict, analyse and useful for optimisation of the engine performance parameters. The exergy based four-stroke bi-fuel (CNG and gasoline) spark ignition (SI) engine model (EBSIEM) here is used for analysis of bi-fuel SI engines. Since, the first law of thermodynamic (the FLT), alone is not able to afford an appropriate comprehension into engine operations. Therefore, this thesis concentrates on the SI engine operation investigation using the developed engine model by the second law of thermodynamic (the SLT) or exergy analysis outlook (exergy based SI engine model (EBSIEM)) In this thesis, an efficient approach is presented for the prediction of total availability, brake specific CO (BSCO), brake specific NOx (BSNOx) and brake torque for bi-fuel engine (CNG and gasoline) using an artificial neural network (ANN) model based on exergy based SI engine (EBSIEM) (ANN-EBSIEM) as an emulator to speed up the optimisation processes. In the other words, the use of a well trained an ANN is ordinarily much faster than mathematical models or conventional simulation programs for prediction. The constrained particle swarm optimisation (CPSO)-EBSIEM (EBSIEMO) was capable of optimising the model parameters for the engine performance. The optimisation results based upon availability analysis (the SLT) due to analysing availability terms, specifically availability destruction (that measured engine irreversibilties) are more regarded with higher priority compared to the FLT analysis. In this thesis, exergy based SI engine model optimisation (EBSIEMO) is studied and evaluated. A four-stroke bi-fuel spark ignition (SI) engine is modelled for optimisation of engine performance based upon exergy analysis. An artificial neural network (ANN) is used as an emulator to speed up the optimisation processes. Constrained particle swarm optimisation (CPSO) is employed to identify parameters such as equivalence ratio and ignition time for optimising of the engine performance, based upon maximising ¿total availability¿. In the optimisation process, the engine exhaust gases standard emission were applied including brake specific CO (BSCO) and brake specific NOx (BSNOx) as the constraints. The engine model is developed in a two-zone model, while considering the chemical synthesis of fuel, including 10 chemical species. A computer code is developed in MATLAB software to solve the equations for the prediction of temperature and pressure of the mixture in each stage (compression stroke, combustion process and expansion stroke). In addition, Intake and exhaust processes are calculated using an approximation method. This model has the ability to simulate turbulent combustion and compared to computational fluid dynamic (CFD) models it is computationally faster and efficient. The selective outputs are cylinder temperature and pressure, heat transfer, brake work, brake thermal and volumetric efficiency, brake torque, brake power (BP), brake specific fuel consumption (BSFC), brake mean effective pressure (BMEP), concentration of CO2, brake specific CO (BSCO) and brake specific NOx (BSNOx). In this model, the effect of engine speed, equivalence ratio and ignition time on performance parameters using gasoline and CNG fuels are analysed. In addition, the model is validated by experimental data using the results obtained from bi-fuel engine tests. Therefore, this engine model was capable to predict, analyse and useful for optimisation of the engine performance parameters. The exergy based four-stroke bi-fuel (CNG and gasoline) spark ignition (SI) engine model (EBSIEM) here is used for analysis of bi-fuel SI engines. Since, the first law of thermodynamic (the FLT), alone is not able to afford an appropriate comprehension into engine operations. Therefore, this thesis concentrates on the SI engine operation investigation using the developed engine model by the second law of thermodynamic (the SLT) or exergy analysis outlook (exergy based SI engine model (EBSIEM)) In this thesis, an efficient approach is presented for the prediction of total availability, brake specific CO (BSCO), brake specific NOx (BSNOx) and brake torque for bi-fuel engine (CNG and gasoline) using an artificial neural network (ANN) model based on exergy based SI engine (EBSIEM) (ANN-EBSIEM) as an emulator to speed up the optimisation processes. In the other words, the use of a well trained an ANN is ordinarily much faster than mathematical models or conventional simulation programs for prediction. The constrained particle swarm optimisation (CPSO)-EBSIEM (EBSIEMO) was capable of optimising the model parameters for the engine performance. The optimisation results based upon availability analysis (the SLT) due to analysing availability terms, specifically availability destruction (that measured engine irreversibilties) are more regarded with higher priority compared to the FLT analysis.

<p> Design and optimization of aircraft thermal management systems (TMS) is typically conducted by considering a single system architecture at steady-state conditions, using per?formance metrics such as bleed air flow rate, fuel burn flow rate, or total system mass. However, when trying to increase the overall performance of a legacy system or analyzing new system architectures, it can be difficult to identify how individual component or sub?system changes will propagate throughout the overall TMS. In this thesis, new knowledge and tools are presented that will advance the use of exergy-based design techniques for next generation aircraft thermal management systems (TMS). This is motivated by the fact that exergy destruction is a quantity that can be calculated for any subsystem or component, regardless of energy domain or function. The relationship between exergy destruction min?imization (EDM) and conventional design metrics is investigated and quantified. This is performed through the use of a steady-state analysis and by leveraging a high fidelity model of a complex TMS. It is shown that exergy destruction is not only sensitive to individual component parameters in a manner consistent with conventional performance metrics, but that due to its generalizability, it also captures how changes in one subsystem propagate throughout the overall TMS. Specifically, through a design case study, it is shown that minimizing system-wide exergy destruction rate (without an engine model) yields a similar engine fuel burn rate as when fuel burn is minimized directly, but also results in a signif?icantly lower system mass. Building on these results, a transient design and analysis tool for TMS is developed using a graph theoretic approach. The tool is used on a case study of an air cycle machine (ACM) and on an architecture enumeration case study for a notional TMS. The transient exergy-based analysis is shown to provide insight into how efficiently energy is used at a component level, and captures the differences in thermal performance between architectures. </p>

[pt] Esta tese tem como objetivo encorajar o desenvolvimento da tecnologia híbrida de lixo-energia e sua aplicação em países com acesso a reservas de gás natural, tal como o Brasil. O método consiste em avaliá-la por meio de uma análise integrada de indicadores de desempenho energético, exergético, econômico e ambiental. A tecnologia inclui dois ciclos integrados: um ciclo superior e um inferior que interagem por meio de uma caldeira de recuperação. O lixo urbano não reciclável, in natura, alimenta o ciclo inferior na caldeira de lixo enquanto o gás natural alimenta o ciclo superior na turbina a gás. O objetivo da modelagem destes sistemas consiste em propor um layout de máxima eficiência aliado a um custo acessível de produção de eletricidade/tratamento do lixo, o que é atingido com um design otimizado. O desempenho termodinâmico mais eficiente é proporcional ao percentual de gás natural, isto é, quanto maior a quantidade de lixo em relação ao gás, menos eficiente é a planta, uma vez que o lixo tem menor poder calorífico. Portanto, o desafio é buscar uma maior eficiência com maior percentual de lixo, aliando também o aspecto custo. De uma forma geral, dois cenários coexistem no mundo atual, o dos países desenvolvidos e o dos países em desenvolvimento. Os primeiros possuem inúmeras aplicações de usinas não híbridas, poucas reservas próprias de gás natural e enfrentam redução na produção de lixo, causando a sub-utilização dos sistemas. Esta tese traz uma análise completa de potenciais alternativas para re-potenciamento de plantas sub-utilizadas, demonstrando o quão pior é o seu desempenho em comparação com o ciclo otimizado. Nos países em desenvolvimento ocorre o inverso: há crescente geração de resíduos, reservas pouco exploradas de gás natural e nenhuma usina lixo-energia. Portanto, existe um grande potencial para implantação de usinas híbridas, as quais, conforme a tese demonstra, são uma alternativa muito mais razoável do que implantar usinas convencionais não híbridas. / [en] This thesis aims to foster the development of hybrid waste-energy technology and its application in countries with access to natural gas reserves, such as Brazil. The method consists of evaluating it through an integrated analysis of energy, exergy, economic and environmental indicators. The investigated system consists of a topping and a bottoming cycle integrated through a heat recovery boiler. Raw non-recyclable urban waste feeds the waste boiler while natural gas feeds a gas turbine. The goal is to propose a cycle with high efficiency able to generate electricity/treat waste within affordable costs, which is achieved with an optimized design. The cycle s performance is proportional to the share of natural gas thermal input, that is, the greater the amount of waste the lower the efficiency (waste has lower calorific value). Therefore, the challenge is to seek greater efficiency with higher percentage of waste, including also the cost aspect. In general, there are two scenarios in the world: developed and developing countries. The former has several non-hybrid plants, few natural gas reserves and face reduced waste production, causing underutilization of the existing systems. This thesis provides a complete analysis of potential alternatives for re-potentiation of underutilized plants, demonstrating how worse their performance is compared to the optimized cycle. On the other hand, developing countries present increasing waste generation, under exploited reserves of natural gas and zero waste-to-energy plants. Therefore, there is a great potential for building hybrid waste-to-energy systems, which this work demonstrates are a much more reasonable alternative than nonhybrid conventional waste-to-energy plants.

Dans ce travail, la production in-situ d'hydrogène (pur) à partir de vapo-reformage d’éthanol (ESR) dans un réacteur catalytique à membrane (MR) a été étudiée. Un mélange d'éthanol pur et distillé a été utilisé comme combustible. Le réacteur est constitué d’un catalyseur Pd-Rh/CeO2 et d’une membrane Pd-Ag: l’ensemble est désigné par « reformeur ». Les expériences sur ce reformeur ont été effectuées dans diverses conditions de fonctionnement: température, pression, débit de combustible et rapport molaire de l'eau-éthanol (rapportSC). La performance du réacteur catalytique à membrane (CMR) a été étudiée en termes de facteur de production d'hydrogène théorique, d’efficacité de production de l’hydrogène et de la part d’hydrogène récupérée. L’évaluation thermodynamique du reformeur a été présentée. L'analyse exergétique a été réalisée sur la base des résultats expérimentaux visant non seulement à comprendre la performance thermodynamique du reformeur, mais aussi d'introduire l'application de l'analyse exergétique dans les études CMRs. L'analyse exergétique a fourni des informations importantes sur l'effet des conditions d'exploitation et les pertes thermodynamiques, et a donné lieu à la compréhension des meilleures conditions de fonctionnement. Outre les évaluations expérimentales et thermodynamiques du reformeur, la simulation de la dynamique de la production d'hydrogène (perméation) a été effectuée comme la dernière étape pour étudier l'applicabilité d'un tel système dans le cadre d'une utilisation finale réelle, qui peut être l’alimentation d’une pile à combustible. La simulation présentée dans ce travail est semblable aux ajustements de débit d'hydrogène nécessaires pour régler la charge électrique d'une pile à combustible répondant à des besoins variables. / In this work, in-situ production of fuel cell grade hydrogen (pure hydrogen) via catalytic ethanol steam reforming (ESR) in a membrane reactor (MR) was investigated. A mixture of pure ethanol and distilled was used as the fuel. ESR experiments were carried out over a Pd-Rh/CeO2 catalyst in a Pd-Ag membrane reactor – named as the fuel reformer – at variety of operating conditions regarding the operating temperature, pressure, fuel flow rate, and the molar ratio of water-ethanol (S/C ratio). The performance of the catalytic membrane reactor (CMR) was studied in terms of pure hydrogen production, hydrogen yield, andhydrogen recovery.Thermodynamic evaluation of the CMR was presented as a supplement to the comprehensive investigation of the overall performance of the mentioned pure hydrogen generating system. Exergy analysis was performed based on the experimental results aiming not only to understand the thermodynamic performance of the fuel reformer, but also to introduce the application of the exergy analysis in CMRs studies. Exergy analysis provided important information on the effect of operating conditions and thermodynamic losses, resulting in understanding of the best operating conditions.In addition to the experimental and thermodynamic evaluation of the reforming system, the simulation of the dynamics of hydrogen production (permeation) was performed as the last step to study the applicability of such a system in connection with a real end user, which can be a fuel cell. The simulation presented in this work is similar to the hydrogen flow rate adjustments needed to set the electrical load of a fuel cell, if fed on line by the studied pure hydrogen generating system.

É conveniente que as políticas ambientais municipais contem não apenas com os instrumentos previstos na legislação federal, mas também com instrumentos urbanístico-ambientais a serem inseridos na legislação de parcelamento, uso e ocupação do solo. Assim, objetivou-se neste trabalho desenvolver um tal instrumento. Para tanto, estabeleceu-se: a) requisitos do instrumento: simplicidade, flexibilidade e embasamento teórico; b) objetivos ambientais considerados: promoção da qualidade ecossistêmica, melhoria do microclima e promoção do controle de drenagem na fonte; c) desenvolvimento de métricas: para os dois primeiros objetivos ambientais, demonstrou-se teoricamente ser satisfatório como indicador único uma simplificação do conceito de ecoexergia devido a Jørgensen e, para o último objetivo ambiental, o pico da vazão de saída do lote; d) estabelecimento de padrões: para os dois primeiros objetivos, definição de valores mínimos da ecoexergia simplificada para lotes em diferentes locais e com diferentes usos e taxas de ocupação, enquanto para o último objetivo, impacto zero. Coincidentemente, enquanto esse instrumento era desenvolvido a Prefeitura do Município de São Paulo (Brasil) procedia a uma revisão da lei de parcelamento, uso e ocupação do solo, tendo sido aceito que o instrumento teórico acima servisse como base para o desenvolvimento de um novo instrumento denominado Quota Ambiental (QA). A transformação do instrumento teórico acima na Quota Ambiental, que terminou por ser inserida no projeto de lei encaminhado à Câmara Municipal e depois aprovado por ela, foi objeto de um estudo sui generis, visto que o autor participou ativamente do desenvolvimento da QA como servidor público. Tal demandaria um método a meio caminho entre o estudo de caso e a observação participante, tendo-se optado por um método análogo ao fenomenológico. Para o desenvolvimento da QA foi formado um pequeno grupo de trabalho do qual o autor participou. O instrumento teórico recebeu diversas modificações não só para conformação a diretrizes e decisões políticas, como para amadurecimento de conceitos e cálculos, mostrando-se viável como base para o desenvolvimento da QA. Diversos grupos de interesse influenciaram o desenvolvimento da QA em diferentes fases e em diferentes níveis, chegando a ocorrer de eles se manifestarem diretamente junto ao grupo de trabalho. A Superior Administração prestigiou o processo, mas mostrou-se às vezes dividida em relação ao conflito entre aspectos ambientais e sociais. O grupo teve sucesso em potencializar os ganhos decorrentes da complementaridade de expertises decorrentes da heterogeneidade em termos de formação e experiência dos membros do grupo. Ele procurou harmonizar as diferentes pressões, muitas vezes até se antecipando a elas. Para tanto, o grupo de trabalho desenvolveu uma dinâmica para chegar a consensos internos e para prever, internalizar e posicionar-se frente a pressões, frequentemente conflitantes. As pressões mais severas provieram da própria burocracia municipal. Em todos esses processos a simplicidade, como requisito, foi perdendo-se. A Quota Ambiental mostrou-se um instrumento inovador, aparentando dar satisfação aos reclamos de diversos grupos de interesse e, principalmente, representando uma cunha ambiental inserida na legislação de parcelamento, uso e ocupação do solo. / It is appropriate that municipal environmental policies incorporate not only the instruments provided for in federal legislation, but also the urban-environmental instruments to be inserted in the urban legislation. Thus, it was aimed in this work to develop such an instrument. To do so, it was established the following: a) requirements of the instrument: simplicity, flexibility and theoretical background; b) environmental objectives considered: promotion of ecosystem quality, improvement of microclimate and promotion of drainage control at source; c) development of metrics: a simplification of the concept of eco-exergy due to Jørgensen has been theoretically proven to be satisfactory as a single indicator of the first two environmental objectives; for the last environmental objective, the lot peak output flow; d) establishment of legal standards: for the first two objectives, definition of minimum values of simplified eco-exergy for lots in different locations and with different uses and occupation rates, whereas for the last objective, zero impact. Coincidentally, while this instrument was being developed, the City of São Paulo (Brazil) proceeded to a review of the zoning law, thus being accepted that the above theoretical instrument should serve as the basis for the development of a new instrument called Environmental Quota (Quota Ambiental, QA, in Portuguese). The transformation of the above theoretical instrument into the QA, which ended up being inserted in the bill forwarded to the City Council and later approved by it, was the subject of a sui generis study, as the author participated actively in the development of QA as a public servant. This would require a method halfway between the case study and the participant observation. A method analogous to the phenomenological one was chosen. A small working group in which the author participated was formed for the development of QA. The theoretical instrument received several modifications not only to conform to political guidelines and decisions, but to maturation of concepts and calculations as well, proving feasible as a basis for the development of QA. Several special interest groups influenced the development of QA in different phases and at different levels; it even occurred to interest groups to directly sue the working group. The High Administration supported the process, but it became sometimes divided in relation to the conflict between environmental and social aspects. The group succeeded in enhancing the gains derived from the complementarity of skills resulting from the heterogeneity in terms of training and experience of the working group members. It sought to harmonize the different pressures, often even foreseeing them. To this end, the working group has developed a dynamic to reach internal consensus and to anticipate, internalize and position itself in the face of frequently conflicting pressures. The most severe pressures came from the municipal bureaucracy itself. In all these processes simplicity, as a requirement, was lost. The Environmental Quota proved to be an innovative instrument, appearing to satisfy the demands of various interest groups and, mainly, representing an environmental wedge inserted in the zoning law.

Este trabalho trata da questão da redução de consumo de combustível fóssil em instalações de máquinas de navios. É um tema de grande interesse no momento, devido ao alto custo operacional e à emissão de poluentes decorrentes do processo da combustão desses derivados de petróleo. Apresenta-se, inicialmente o cenário atual e tendências futuras das instalações propulsoras convencionais que usam óleo pesado ou Diesel. Em seguida, são examinadas alternativas propostas para redução de consumo de combustíveis fósseis nos navios, que são enquadradas em três categorias. A primeira delas envolve possíveis melhorias de projeto para redução da demanda de energia. As outras categorias se referem ao emprego de fontes alternativas de energia, que introduzem uma força propulsora adicional, reduzindo o empuxo requerido do hélice, ou uma potência suplementar no eixo propulsor. Em ambos os casos há também uma redução de demanda de potência requerida do motor Diesel. Na seqüência, são apresentados e discutidos fundamentos termodinâmicos, com ênfase nas análises energética e exergética, como ferramentas para avaliação das máquinas dos navios. A análise exergética, diferentemente do enfoque apenas energético, é a ferramenta mais apropriada para tratar as questões ligadas ao meio ambiente, pois a própria definição de exergia está relacionada com o ambiente de referência. Finalmente, utilizando dados de um navio porta contêineres da frota nacional, é exercitado um exemplo de aplicação com as análises termodinâmicas do motor de propulsão; são também avaliadas e simuladas as diversas alternativas de melhorias e novas fontes de energia, que visam a redução de consumo de combustível fóssil. / This work addresses the issue of reduction of fossil fuel use on ship machinery. Presently it is an interesting topic due to high operational cost and the pollution emissions generated by the combustion process. Initially, it is introduced the present scenario and future trends regarding conventional ship machinery that use heavy or diesel fuel oil. In the sequence, the proposed alternatives for reducing the use of fossil fuel on ships are presented and examined. These alternatives are classified into three categories. The first category comprises possible improvements to the design of ships for reduction of total energy demand. The other categories refer to the use of alternative energy sources, that produce and additional force on the ship reducing the required propeller thrust; or a supplementary power added to the propulsion shaft. For both cases there is also a reduction in the power required from the Diesel engine. Afterwards, the pertaining thermodynamics theory is revised and discussed with focus on the energy and exergy analysis as aid tools for evaluation of ship machinery. The energetic analysis, different from the sole energetic focus, is the most applicable tool to be employed for environmental issues as the self definition of exergy relates to an environment reference. Finally, using data from a typical container ship belonging to the national fleet, an application example using the thermodynamic analysis is performed to the propulsion main engine; as well as it is also simulated several alternative conditions for improvements and new energy sources, aiming to the reduction of fossil fuel consumption.

É conveniente que as políticas ambientais municipais contem não apenas com os instrumentos previstos na legislação federal, mas também com instrumentos urbanístico-ambientais a serem inseridos na legislação de parcelamento, uso e ocupação do solo. Assim, objetivou-se neste trabalho desenvolver um tal instrumento. Para tanto, estabeleceu-se: a) requisitos do instrumento: simplicidade, flexibilidade e embasamento teórico; b) objetivos ambientais considerados: promoção da qualidade ecossistêmica, melhoria do microclima e promoção do controle de drenagem na fonte; c) desenvolvimento de métricas: para os dois primeiros objetivos ambientais, demonstrou-se teoricamente ser satisfatório como indicador único uma simplificação do conceito de ecoexergia devido a Jørgensen e, para o último objetivo ambiental, o pico da vazão de saída do lote; d) estabelecimento de padrões: para os dois primeiros objetivos, definição de valores mínimos da ecoexergia simplificada para lotes em diferentes locais e com diferentes usos e taxas de ocupação, enquanto para o último objetivo, impacto zero. Coincidentemente, enquanto esse instrumento era desenvolvido a Prefeitura do Município de São Paulo (Brasil) procedia a uma revisão da lei de parcelamento, uso e ocupação do solo, tendo sido aceito que o instrumento teórico acima servisse como base para o desenvolvimento de um novo instrumento denominado Quota Ambiental (QA). A transformação do instrumento teórico acima na Quota Ambiental, que terminou por ser inserida no projeto de lei encaminhado à Câmara Municipal e depois aprovado por ela, foi objeto de um estudo sui generis, visto que o autor participou ativamente do desenvolvimento da QA como servidor público. Tal demandaria um método a meio caminho entre o estudo de caso e a observação participante, tendo-se optado por um método análogo ao fenomenológico. Para o desenvolvimento da QA foi formado um pequeno grupo de trabalho do qual o autor participou. O instrumento teórico recebeu diversas modificações não só para conformação a diretrizes e decisões políticas, como para amadurecimento de conceitos e cálculos, mostrando-se viável como base para o desenvolvimento da QA. Diversos grupos de interesse influenciaram o desenvolvimento da QA em diferentes fases e em diferentes níveis, chegando a ocorrer de eles se manifestarem diretamente junto ao grupo de trabalho. A Superior Administração prestigiou o processo, mas mostrou-se às vezes dividida em relação ao conflito entre aspectos ambientais e sociais. O grupo teve sucesso em potencializar os ganhos decorrentes da complementaridade de expertises decorrentes da heterogeneidade em termos de formação e experiência dos membros do grupo. Ele procurou harmonizar as diferentes pressões, muitas vezes até se antecipando a elas. Para tanto, o grupo de trabalho desenvolveu uma dinâmica para chegar a consensos internos e para prever, internalizar e posicionar-se frente a pressões, frequentemente conflitantes. As pressões mais severas provieram da própria burocracia municipal. Em todos esses processos a simplicidade, como requisito, foi perdendo-se. A Quota Ambiental mostrou-se um instrumento inovador, aparentando dar satisfação aos reclamos de diversos grupos de interesse e, principalmente, representando uma cunha ambiental inserida na legislação de parcelamento, uso e ocupação do solo. / It is appropriate that municipal environmental policies incorporate not only the instruments provided for in federal legislation, but also the urban-environmental instruments to be inserted in the urban legislation. Thus, it was aimed in this work to develop such an instrument. To do so, it was established the following: a) requirements of the instrument: simplicity, flexibility and theoretical background; b) environmental objectives considered: promotion of ecosystem quality, improvement of microclimate and promotion of drainage control at source; c) development of metrics: a simplification of the concept of eco-exergy due to Jørgensen has been theoretically proven to be satisfactory as a single indicator of the first two environmental objectives; for the last environmental objective, the lot peak output flow; d) establishment of legal standards: for the first two objectives, definition of minimum values of simplified eco-exergy for lots in different locations and with different uses and occupation rates, whereas for the last objective, zero impact. Coincidentally, while this instrument was being developed, the City of São Paulo (Brazil) proceeded to a review of the zoning law, thus being accepted that the above theoretical instrument should serve as the basis for the development of a new instrument called Environmental Quota (Quota Ambiental, QA, in Portuguese). The transformation of the above theoretical instrument into the QA, which ended up being inserted in the bill forwarded to the City Council and later approved by it, was the subject of a sui generis study, as the author participated actively in the development of QA as a public servant. This would require a method halfway between the case study and the participant observation. A method analogous to the phenomenological one was chosen. A small working group in which the author participated was formed for the development of QA. The theoretical instrument received several modifications not only to conform to political guidelines and decisions, but to maturation of concepts and calculations as well, proving feasible as a basis for the development of QA. Several special interest groups influenced the development of QA in different phases and at different levels; it even occurred to interest groups to directly sue the working group. The High Administration supported the process, but it became sometimes divided in relation to the conflict between environmental and social aspects. The group succeeded in enhancing the gains derived from the complementarity of skills resulting from the heterogeneity in terms of training and experience of the working group members. It sought to harmonize the different pressures, often even foreseeing them. To this end, the working group has developed a dynamic to reach internal consensus and to anticipate, internalize and position itself in the face of frequently conflicting pressures. The most severe pressures came from the municipal bureaucracy itself. In all these processes simplicity, as a requirement, was lost. The Environmental Quota proved to be an innovative instrument, appearing to satisfy the demands of various interest groups and, mainly, representing an environmental wedge inserted in the zoning law.