Hoy en día existen diversas estructuras en la que se ha dado la aplicación del concreto liviano estructural, por lo que empresas contratistas apuestan por agregados livianos para fabricar concreto liviano de alta resistencia y que cumpla con sus requisitos de diseño. Estos estudios comenzaron a principios de la década de 1980, con óptimos resultados en 1992. Como resultado de todos estos aportes, la información de diseño se ha convertido al alcance de muchos profesionales, y ha permitido que el concreto liviano sea utilizado en alta resistencia y alta durabilidad (Hoff 1992). Es por ello mismo, que nuestra investigación propone el uso de un concreto liviano estructural con perlita de poliestireno expandido en un sistema de albañilería confinada. Este estudio comprende la elaboración del diseño de un concreto liviano estructural; en primer lugar, se investigó un rango apropiado de perlita ya que según Thanon y Jihad (2016) señalan que para obtener óptimos resultados en resistencia a compresión la dosificación de perlita debe variar entre un intervalo de 13-23% ,y es por ello mismo que se escoge trabajar con un porcentaje de 16 % de perlita de poliestireno expandido, pero para términos de comprobación en las propiedades térmicas, también se diseñó con 26% y 36% de perlita; en segundo lugar, para proceder a realizar el diseño del concreto se diseña en base a los requisitos mínimos que establece ACI 318 y con referencias en ACI 211R, la cual interviene en ciertos parámetros para obtener las características de un concreto liviano estructural. / Today there are various structures in which there has been the application of lightweight structural concrete, so contractor companies are committed to lightweight aggregates to manufacture lightweight, high strength concrete that meets its design requirements. These studies conducted in the early 1980s, with optimal results in 1992. As a result of all these contributions, design information has become available to many professionals, and has allowed light concrete to be used for new applications and novelties where high strength and high durability are desirable (Hoff 1992). That is why our research proposes the use of a lightweight structural concrete with expanded polystyrene bead in a confined masonry system for single-family homes. This study includes the development of the design of a lightweight structural concrete; First, a range of bead was investigated since according to Thanon and Jihad (2016) it was pointed out that to obtain optimum results in compressive strength the dosage of perlite must vary between a range of 13-23%, and that is why same that it is chosen to work with a percentage of 16% expanded polystyrene perlite, but for terms of checking the thermal properties, it is also designed with 26% and 36% perlite; secondly, to proceed with the design of the concrete, it is designed based on the minimum requirements established by ACI 318 and with references in ACI 211R, the quality of intervention in specific parameters to obtain the characteristics of a lightweight structural concrete. / Tesis

Submitted by ROBSON ROSA DA SILVA (robsilva31@gmail.com) on 2016-07-04T18:50:31Z No. of bitstreams: 1 Silva_2016_New photonic structures_Self assembly of 1D Te structures_Multifunctional biopolymers and reused plastics.pdf: 40718449 bytes, checksum: 9c299b328a4a54c169de6647b0225f34 (MD5) / Approved for entry into archive by Ana Paula Grisoto (grisotoana@reitoria.unesp.br) on 2016-07-07T17:57:07Z (GMT) No. of bitstreams: 1 silva_rr_dr_araiq_par.pdf: 1063262 bytes, checksum: cc72dc79773da734cac767490756f56e (MD5) / Made available in DSpace on 2016-07-07T17:57:07Z (GMT). No. of bitstreams: 1 silva_rr_dr_araiq_par.pdf: 1063262 bytes, checksum: cc72dc79773da734cac767490756f56e (MD5) Previous issue date: 2016-05-23 / Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES) / Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP) / Nanoestruturas unidimensionais de telúrio (Te1D) na forma de whiskers, fios e hélices foram preparados com facilidade por uma síntese em etapa única na presença de solução aquosa de Pluronic® F68 à baixas temperaturas (< 100 °C) e pressão ambiente. A forma das nanoestruturas puderam ser controladas de acordo com a cinética da reação. Estruturas empacotadas de nanowhiskers e nanofios de Te foram obtidas via auto-organização em interface líquido-líquido e pela técnica de drop-cast em substrato de Si/SiO2. Estruturas híbridas 1D foram obtidas utilizando nanoestruturas Te1D como molde de sacrifício para anexar nanopartículas metálicas ou mesmo produzir nanoestruturas 1D metálicas. Por exemplo, nanoestruturas híbridas 1D foram preparadas decorando nanofios de Te com nanopartículas de Ag em solução aquosa de poli(vinilpirrolidona). Nanoestruturas 1D de Au com forma de nódulos foram preparados por deslocamento galvânico de íons Au3+ em uma mistura de nanohélices de Te, ácido ascórbico e solução aquosa de poli(vinilpirrolidona). Além disso, nanohélices de Te foram funcionalizadas com uma camada resina resorcinol-formaldeído em condições brandas de síntese. A resina de resorcinol-formaldeído é uma via intermédia para explorar a deposição de compostos opticamente ativos tais como nanopartículas de hidroxicarbonato de Tb3+ ou nanopartículas de Au. Para aplicações práticas é essencial que estas nanoestruturas possam ser suportadas em filmes rígidos ou flexíveis de alta qualidade óptica. Filmes de polímeros naturais puros e filmes híbridos de sol-gel epóxi foram avaliados como potenciais matrizes hospedeiras para luminóforos. A fabricação de híbridos é baseada na incorporação de 3-glicidoxipropiltrimetoxissilano na solução homogênea de polímero natural com posterior secagem sobre uma superfície plana. Particularmente, filmes flexíveis de fibroína da seda e acetato de celulose e os seus híbridos derivados exibiram excelentes propriedades ópticas para hospedar compostos opticamente ativos. Por exemplo, compostos de Eu3+ emissores na região do vermelho e corantes fluorescentes foram incorporados em matriz pura de polímero e híbridos epóxi e suas propriedades ópticas foram investigadas. Laser de corantes por feedback distribuído (DFB) foram fabricados dopando grades de difração de fibroína de seda com Rodamina 6G. Devido a sua capacidade de replicar superfícies padronizadas com resolução nanométrica, grades de fibroina da seda dopadas com corante foram depositadas contra a grade de difração de uma mídia de disco compacto comercial. Lasers modificados de DFB baseados em filmes de fibroina contendo nanopartículas espalhadoras de luz de SiO2 e Ag aleatoriamente distribuídas na grade de fibroina demonstraram aumento da intensidade do laser, além de estreitamento da largura do pico de emissão. Filmes híbridos flexíveis e transparentes (> 85%) de fibroina da seda e acetato de celulose modificados com função epóxi e contendo compostos fluorescentes na região do vermelho como complexos β-dicetonato de Eu3+ e nanopartículas de YVO4:Eu3+ em baixa proporção relativa mássica (<5%) foram preparados. De maneira geral, o resultado são filmes homogêneos com funções epoxi e/ou alcoxissilano não hidrolisados disponíveis para outras modificações químicas. Devido a matéria-prima limitada de polímeros naturais para uma alta demanda de fabricação de dispositivos ópticos, é igualmente importante desenvolver materiais com base na reutilização de polímeros sintéticos. Filmes finos de poliestireno foram concebidos por dissolução de poliestireno expandido (EPS) recuperado de resíduos em D-limoneno, um solvente verde proveniente de óleos cítricos. Filmes transparentes dopados com complexos β-dicetonato de Eu3+ demonstraram excelente transparência e aptos para uso em guias de luz. Estes resultados são motivadores para a) a engenharia de nanoestruturas 1D com propriedades ópticas sintonizáveis bem como, b) desenvolvimento de híbridos flexíveis e transparentes baseados em híbridos de polímeros naturais com alta funcionalidade química ou polímeros sintéticos reciclados como potenciais matrizes hospedeiras ópticas almejadas em aplicações fotônicas. / One-dimensional Te nanostructures (Te1D) in the shape of whiskers, wires and helices were prepared by a facile one-pot synthesis in the presence of aqueous Pluronic® F68 solution at low temperatures (< 100 ºC) and ambient pressure. The shape of Te1D nanostructures could be manuvered according with the reaction kinectics. We evaluate some techniques to assemble Te1D nanostructures on the pursuit for complex nanoarchitectures. Bundles of Te nanowhiskers and nanowires were achieved by self-assembly in liquid-liquid interface or by drop-cast technique in Si/SiO2 substrates. 1D hybrid structures have been conceived by using Te1D nanostructures as sacrificial template to attach metallic nanoparticles or even produce metallic 1D nanostructures. For example, 1D hybrid nanostructures were easily prepared by decorating Te nanowires with Ag nanoparticles in aqueous solution of poly(vinylpyrrolidone). Au 1D nanostructures with nodular-like shape were prepared by galvanic displacement of Au3+ ions in a mixture of Te nanohelices, ascorbic acid and an aqueous solution of poly(vinylpyrrolidone). Furthermore, Te1D nanohelices were functionalized with a layer of resorcinol-formaldehyde resin at mild synthesis conditions. The RF resin allowed us to fashion an intermediate pathway to explore the deposition of optically active compounds like Tb3+ hydroxylcarbonate or Au nanoparticles. Seeking practical applications, these nanostructures should be hosted over rigid or flexible films possessing excellent optical properties. Pure natural polymers and epoxy sol-gel hybrids films were evaluated as potential host for luminophors. The fabrication of epoxy hybrids is based on the incorporation of 3-glycidoxypropyltrimethoxysiloxane on the homogenous solution of natural polymer with subsequent casting over flat surface. Particularly, flexible silk fibroin and cellulose acetate films and their derivative hybrids displayed excellent optical properties to host optically active compounds. For instance, red emitting Eu3+ compounds and fluorescent dyes were hosted on pure natural polymer and hybrid films and the optical features of the luminescent films were investigated thoroughly. Distributed feedback dye-lasers were fabricated by doping silk fibroin diffraction gratings with Rhodamine 6G. Owing its ability to mimic patterned surfaces at nanoscale resolution, dye-doped SF gratings were fabricated using replica-casting patterning against a commercial blank digital versatile disc as template. A modified DFB Laser based on SF films with Ag or SiO2 light scattering particles randomly distributed on the grating unveiled an enhancement of laser intensity withal narrowing of emission peak linewidth. Flexible and highly transparent SF- and CA-epoxy hybrids (> 85%) containing red fluorescent Eu3+ b-diketonate complex and YVO4:Eu3+ nanoparticles at low relative content (< 5 wt%) were tailored. In general, the outcome is homogeneous films with epoxy and/or unhydrolized alkoxysilane functions available for further chemical modification. Owing the limited feedstock of natural polymers for high demanding production of optical devices, it is equally important develop materials based on the reuse of synthetic polymers. Thin films of polystyrene were conceived by dissolving waste-recovered expanded-polystyrene (EPS) in D-limonene, a green solvent from citrus oil. Transparent EPS films doped with Eu3+ b-diketonate complex displayed excellent transparency and light waveguiding, These assertions provide a framework that motivates the research on a) engineering of 1D hybrids nanostructures with tunable optical properties and b) flexible natural polymer/epoxy hybrid with enhanced functionality or plastic recycled as potential optical hosts sought in photonic applications. / FAPESP: 2013/12367-6

El problema más frecuente en los muros de albañilería se presenta en su deterioro debido a la exposición prolongada a la humedad que se manifiesta mediante daños drásticos en las unidades de albañilería sin recubrimiento, los cuales pueden ser pulverización, descamación y agrietamiento. En la actualidad, en la ciudad de Cusco, el sistema estructural de albañilería es el más empleado con un 96.67% de edificaciones usándolo. Estos se exponen a la humedad cuando la temperatura fluctúa entre congelamiento y descongelamiento, generado durante la temporada de lluvias y heladas manifestadas en la ciudad. Esta investigación se realizó mediante un proceso de cuatro fases. Primero, se realizaron los diseños de las mezclas de mortero de junta y revestimiento con proporciones de 5%, 7%, 10% y 30%, 40% y 50% de sustitución de agregado fino por perlas de poliestireno expandido, respectivamente. Segundo, se determinó la durabilidad de los morteros por medio de la resistencia a compresión de las muestras sometidas a heladicidad. En la tercera fase, luego de determinar los morteros con porcentajes adecuados, con la finalidad de validar las características de la propuesta, se elaboraron pilas de ladrillos para someterlos a ensayos de heladicidad y analizar el comportamiento en conjunto de los elementos de un muro de albañilería. Por último, se propuso un proceso constructivo para lograr rendimientos similares a los ya existentes en obra y se realizó un análisis de costo – beneficio, el cual compara la aplicación del mortero modificado y convencional en un muro de albañilería. Los resultados indican una disminución en la resistencia a compresión de 14.76 kg/cm2 en los prismas convencionales y un aumento de 1.88 kg/cm2 en prismas con mortero modificado. Lo cual indica que los prismas modificados, en ladrillo y mortero, incrementan su resistencia en un 4%. / The most frequent problem in masonry walls is in their deterioration, due to the prolonged exposure to moisture, that is manifested by drastic damage in the uncoated masonry units, which can be pulverized, flaking and cracking. Currently, in the city of Cusco, masonry constructions represent 96.67% of the total of constructions, and the presence of moisture in the walls occurs when there is variation of temperatures between the freezing and thawing cycles, generated by the rainy and freezing season that manifests in the city. This research was conducted through a four-step process. First, we made the designs of the joint and coating mortar mixtures with ratios of 5%, 7%, 10% and 30%, 40% and 50% substitution of fine aggregate with expanded polystyrene beads, respectively. Second, the durability of the mortars was determined by the compressive strength of the samples subjected to frost. In the third stage, after determining the mortars with appropriate percentages, to validate the characteristics of the proposal, Bricks piles were developed for ice-freezing testing and for analyzing the behavior of the elements of a masonry wall. Finally, a constructive process was proposed to achieve yields like those already existing on site and a cost - benefit analysis was carried out, which compares the application of modified and conventional mortar on a masonry wall. The results indicate a decrease in compressive strength of 14.76 kg/cm2 in conventional prisms and an increase of 1.88 kg/cm2 in prisms with modified mortar. This indicates that the modified prisms, in brick and mortar, increase their resistance by 4%. / Tesis

The master´s thesis analyzes influence of direct and reflected solar radiation to heat strain and degradation of thermal insulation in the flat roof construction. In many building was a problem in a significant degradation of thermal insulation made from expanded polystyrene in the vicinity of glass surfaces. To determine the causes of this problem, it was necessary to study and test the properties of building materials and the physical nature of the effect of solar radiation on the building structure. In the introductory section lists the cases of buildings with degradation of thermal insulation and existing knowledge on this issue. The theoretical part describes the technical properties of thermal insulating materials used in the flat roof construction, nature and division of solar radiation, optical laws of light reflection and physical theory to explain the technical thermal behavior of building materials and structures. The last part describes a practical model and analyzing measured data in thermal stress in the flat roof construction. The practical part also determines the importance of different influences configuration structures using to dynamic simulations. At the end of the practical part they are validated theoretical knowledge obtained by analyzing data from a practical model.

The diploma thesis processes project documentation in the stage of construction for modernization of an apartment house near the center on the street Vlhká 22 in Brno. The building is divided into four residential floors and nonresidential basement and attic. On the first floor there are two residential units and the other four residential units. The foundation structures are made of solid bricks. The vertical load-bearing and non-load-bearing structures are also made of solid bricks. Exceptionally drywall partitions. In the basement, the ceiling structures are made of brick barrel vaults, above the above-ground floors there are wooden beamed ceilings. The roof structure of the building is made of purlin system with standing stool and covering of ceramic roof tiles. Three additional housing units will be built in the attic. In the basement, the masonry will be undercut by a chain saw, partly by pressure grouting and partly by a new layer with a waterproofing layer. All wood-beamed ceilings will be replaced with prefabricated ceiling beams with aerated concrete inserts without overhead slab. The garden part of the building will be insulated with mineral wool. The roof structure will be constructed from the street side as a shed roof and in the garden part a flat roof with a gradient layer of expanded polystyrene thermal insulation and a waterproofing layer of thermoplastic poleolefin.