Fracture mechanics is applied to study the behavior of concrete containing expanded polystyrene (EPS) aggregate replacement. The EPS replaces a portion of the normal weight fine aggregate. Previous research has shown EPS aggregate replacement changes the failure mode in compression from a typical instantaneous failure, as in normal weight concrete (NWC), to a more gradual dissipation of load carrying capacity. This behavior is investigated through the use of fracture mechanics. The fracture energy, critical stress intensity factor and characteristic length of EPS concrete, NWC and fiber reinforced concrete (FRC) are experimentally determined. The two types of tests used to study these properties are the three point bending test recommended by the RILEM technical committee and a wedge splitting test developed recently. The conclusions derived from this research demonstrate that EPS aggregate replacement increases the size of the fracture process zone in front of the crack tip. This increase in size changes the failure mode of concrete allowing it to maintain load after reaching peak load and absorb more energy during the fracture process.

Orientador: Paulo César Lodi / Resumo: O poliestireno expandido (EPS), que entre vários materiais, também da origem a um gessintético, o geoexpandido, que é muito utilizado em obras geotécnicas, pois quando comparado a outros materiais, possui um menor peso específico o que diminui o peso próprio da estrutura, minimizando eventuais recalques. Além disso, a combinação de alta resistência e baixa compressibilidade o tornam uma boa escolha para obras geotécnicas. No entanto, o EPS é extremamente susceptível a solventes, hidrocarbonetos e raios ultravioletas. Nesse sentido, poucos trabalhos tem explorado os aspectos de degradação do material em aplicações geotécnicas. Assim, o presente trabalho avaliou a degradação do poliestireno expandido (EPS) por meio de ensaios laboratoriais. Para tanto, utilizaram-se amostras de EPS em cinco diferentes massas específicas, a saber: 10,0, 14,5, 18,0, 22,0 e 33,5 kg/m³. O processo de degradação das amostras foi avaliado por meio da exposição à intempérie por catorze, trinta e quarenta e cinco dias e exposição ao vapor de gasolina por sete, catorze e trinta dias. Para avaliação do processo degradativo foram realizados ensaios de absorção de água, compressão uniaxial e cisalhamento direto de interface (EPS/EPS). Os ensaios foram realizados após cada período de exposição e os resultados obtidos foram comparados aos valores de referência das amostras intactas. Os resultados mostram que os valores de absorção de água, para ambos os tipos de exposição, apresentam comportamento similar, d... (Resumo completo, clicar acesso eletrônico abaixo) / Abstract: Expanded polystyrene (EPS), which among many materials, also gives rise to a gessynthetic, geo-expanded, which is widely used in geotechnical works, because when compared to other materials, has a lower specific weight which decreases the structure's own weight. , minimizing any repression. In addition, the combination of high strength and low compressibility make it a good choice for geotechnical works. However, EPS is extremely susceptible to solvents, hydrocarbons and ultraviolet rays. In this sense, few studies have explored the degradation aspects of the material in geotechnical applications. Thus, the present work evaluates the degradation of expanded polystyrene (EPS) by results of laboratory tests. For this purpose, EPS samples were used in five different specific masses, namely: 10.0, 14.5, 18.0, 22.0 and 33.5 kg/m³. The degradation process of the samples was evaluated by exposure to the weather for fourteen, thirty and forty five days and exposure to gasoline vapor for seven, fourteen and thirty days. To evaluate the degradation process water absorption, uniaxial compression and (EPS/EPS) interface direct shear tests were performed. The tests were performed after each exposure period and the results obtained were compared to the reference values of the fresh samples. The main results show that the water absorption values, for both types of exposure, present similar behavior, so that the absorption is inversely proportional to the specific mass. Regarding uniaxial re... (Complete abstract click electronic access below) / Mestre

Espumas à base de amido possuem limitações para utilização como embalagens na indústria alimentícia, principalmente, devido à alta hidrofilicidade e fragilidade. Para melhorar essas propriedades, torna-se necessário o uso de plastificantes e outros aditivos, como proteínas e fibras lignocelulósicas, ou ainda um aditivo fonte desses recursos, como a torta de gergelim obtida como resíduo do processamento do gergelim. Sendo assim, o objetivo deste trabalho foi desenvolver e caracterizar espumas à base de amido de mandioca adicionadas de 0 – 40 % (m/m) de resíduo de gergelim, produzidas pelo processo de expansão térmica, a fim de avaliar a influência do aditivo nas propriedades físicas, morfológicas e mecânicas dos materiais obtidos para utilização como embalagens para alimentos. A adição do resíduo resultou em espumas com menores espessuras e densidade aparente, bem como, maior capacidade de expansão dos materiais. Além disso, apresentaram melhores propriedades mecânicas e, em geral, menores capacidade de absorção de água e adsorção de água em baixas umidades relativas, em relação aos materiais compostos somente por amido. Embora as propriedades mecânicas das espumas sejam influenciadas pelas condições de umidade relativa de armazenamento, as espumas contendo 20 % de resíduo (20R) apresentaram uma combinação de propriedades no ensaio de tração (resistência à tração e módulo de elasticidade) que podem ser consideradas comparáveis às amostras de bandejas comercias de poliestireno expandido (EPS), nas três umidades relativas avaliadas (33, 53 e 90 %). Os resultados obtidos nos ensaios de flexão dessas espumas indicaram que as mesmas foram mais rígidas e menos flexíveis do que as amostras de EPS. A adição de 20 % de resíduo resultou em importantes melhorias nas propriedades físicas e mecânicas em comparação às espumas à base de amido de mandioca, além de apresentarem menos defeitos morfológicos do que os observados em espumas com maiores teores do resíduo (30 e 40 %). Foram realizados testes de aplicação das espumas 20R no acondicionamento de dois tipos de alimentos com diferentes teores de umidade: bolo (23 %) e brócolis (91 %), em comparação ao armazenamento em embalagens comerciais de EPS. A partir dos resultados obtidos para a variação de umidade, perda de massa e propriedades mecânicas na flexão das embalagens, foi observado que as espumas propostas não foram adequadas para o acondicionamento das amostras de brócolis, apresentando alta absorção de umidade e deformações após três dias de contato com o alimento. Por outro lado, as espumas 20R mostraram bom desempenho no acondicionamento das amostras de bolo, não apresentando mudanças significativas nas propriedades mecânicas no período de 3 a 9 dias de armazenamento. Dessa forma, o resíduo de gergelim em combinação com o amido de mandioca mostrou elevado potencial para o desenvolvimento de espumas que podem ser utilizadas como embalagens para alimentos com baixos teores de umidade, sendo necessários estudos mais detalhados, considerando principalmente aspectos de segurança para utilização de resíduos em produtos em contato direto com alimentos. / Starch based foams have limitations for use as food packaging, mainly due to high hydrophilicity and fragility. In order to improve these properties it is necessary the use of plasticizers and others additives, such as lignocellulosic fibers and proteins, or an additive source of these constituents like sesame cake, which it is obtained from sesame processing. In this way, the main objective of this work was to develop and characterize starch based foams added with 0 – 40 % (w/w) of sesame residue to evaluate the influence of this additive on physical, morphological and mechanical properties of materials for using as food packaging. The foams were produce by thermal expansion process. Residue addition resulted in foams with smaller thickness and density, as well as greater expansion capacity of the materials produced. In addition, foams incorporated with residue exhibited better mechanical properties and, in general, lower water capacity absorption and water adsorption at low relative humidities compared to foams made only with starch. Although mechanical properties of the foams are affected by storage humidity conditions, foams added with 20 % of residue (20R) showed tensile properties (tensile strength and tensile elasticity modulus) that can be considered comparable to expanded polystyrene (EPS) commercial trays for different relative humidities evaluated (33, 53 and 90 %). Flexural properties indicated that starch foams produced was tougher and less flexible than EPS commercial trays. Addition of 20 % of sesame residue on cassava starch-based foams resulted in relevant improvements compared to foams without residue. Besides that, fewer morphological defects were noted, as observed in foams with higher residue content (30 and 40 %). Thus, 20R formulation was selected to carrying out applicability tests of starch-based foams in packaging of two types of food with different moisture content: cake (23 %) and broccoli (91 %) compared to EPS commercial packaging. From the results obtained for moisture variation, loss of weight and flexural properties of the foams, it was found that the material proposed was not applicable to package broccoli samples. Due to high water absorption by the foams alterations on the shape were noted in the materials after 3 days in contact with this food. Nonetheless, foams based on cassava starch and 20 % of sesame residue exhibited a good performance during storage time of cake samples (9 days). It was not observed any effect on flexural mechanical properties for 3 to 9 days of storage. Thereby, sesame cake added to cassava starch showed high potential to developing foams that could be used as packaging for low moisture food. Additionally, more detailed studies are necessary, especially considering safety aspects mainly for using agricultural residues directly in contact with food products.

In 2007 the production of expanded polystyrene (EPS) in the world was over 4 million tonnes and is expected to grow at 6 percent per year. With the increased concern about environmental protection, alternative biodegradable materials from renewable resources are of interest. The present doctoral thesis work successfully demonstrates that starch-based foams with mechanical properties similar to EPS can be obtained by reinforcing the cell-walls in the foams with cellulose nanofibers (MFC). High cellulose nanofiber content nanocomposites with a highly plasticized (50/50) glycerol-amylopectin starch matrix are successfully prepared by solvent-casting due to the high compatibility between starch and MFC. At 70 wt% MFC, the nanocomposites show a remarkable combination of high tensile strength, modulus and strain to failure, and consequently very high work to fracture. The interesting combination of properties are due to good dispersion of nanofibers, the MFC network, nanofiber and matrix properties and favorable nanofiber-matrix interaction. The moisture sorption kinetics (30% RH) in glycerol plasticized and pure amylopectin film reinforced with cellulose nanofibers must be modeled using a moisture concentration-dependent diffusivity in most cases. The presence of cellulose nanofibers has a strong reducing effect on the moisture diffusivity. The decrease in zero-concentration diffusivity with increasing nanofiber content could be due to geometrical impedance, strong starch-MFC molecular interaction and constrained swelling due to the cellulose nanofiber network present. Novel biomimetic starch-based nanocomposite foams with MFC contents up to 40 wt% are successfully prepared by freeze-drying. The hierarchically structured nanocomposite foams show significant increase in mechanical properties in compression compared to neat starch foam. Still, better control of the cell structure could further improve the mechanical properties. The effect of cell wall composition, freeze-drying temperature and freezing temperature on the resulting cell structure are therefore investigated. The freeze-drying temperature is critical in order to avoid cell structure collapse. By changing the starch content, the cell size, anisotropy ratio and ratio between open and closed cells can be altered. A decrease in freezing temperature decreases the cell size and increases the anisotropy ratio. Finally, mechanical properties obtained in compression for a 30 wt% MFC foam prepared by freeze-drying demonstrates comparable properties (Young's modulus and yield strength) to expanded polystyrene at 50% RH and similar relative density. This is due to the reinforcing cellulose nanofiber network within the cell walls. / QC 20100913

Global concern about the environmental impacts of waste disposal and stringent implementation of environmental laws lead to numerous research on recycled materials. Increased awareness about the inherent engineering values of waste materials, lack of landfill sites and strong demand for construction materials have encouraged research on composite materials, which are either fully or partly made of recycled materials. This trend is particularly strong in transportation and geotechnical projects, where huge quantities of raw materials are normally consumed. Owing to the low mass-to-volume ratio, disposal of Expanded Polystyrene (EPS) is a major problem. In addition, EPS recycling methods are expensive, labour intensive and energy demanding. Hence, this thesis is focused on the development of a new soil composite made by mixing recycled EPS with expansive clays. Given the high cost of damage to various buildings, structures and pavements caused by the unpredictable ground movements associated with expansive soils, it has been considered prudent to try and develop a new method of soil modification using recycled EPS beads as a swell-shrink modifier and desiccation crack controller. The innovative application of recycled EPS as a soil modifier will minimise the quantity of waste EPS destined to the landfill considerably. An extensive experimental investigation has been carried out using laboratory reconstituted expansive soils - to represent varied plasticity indices - consisting of fine sand and sodium bentonite. Three soils notated as SB16, SB24 and SB32 representing 16%, 24% and 32% of bentonite contents respectively were tested with four EPS contents of 0.0%, 0.3%, 0.6% and 0.9%. The tests performed include compaction, free swell, swell pressure, shrinkage, desiccation, shear strength and hydraulic conductivity. All the tests have been performed at the respective maximum dry unit weight and optimum moisture content of the mixes. It has been observed that by mixing of recycled EPS beads with the reconstituted soil, a lightweight geomaterial is produced with improved engineering properties in terms of dry unit weight, swelling, shrinkage and desiccation. The EPS addition depends on the moulding moisture content of the soil. With increasing moisture content, additional EPS can be added. Also, there is a reduction in dry unit weight with the addition of EPS. Furthermore, the reduction of swell-shrink potential and desiccation cracking in soils, for example, is related to the partial replacement of soil particles as well as the elasticity of the EPS beads. There is a reduction in shear strength with the addition of EPS to soils. However, mixing of chemical stabilisers along with EPS can enhance the strength in addition to improved overall properties.

Espumas à base de amido possuem limitações para utilização como embalagens na indústria alimentícia, principalmente, devido à alta hidrofilicidade e fragilidade. Para melhorar essas propriedades, torna-se necessário o uso de plastificantes e outros aditivos, como proteínas e fibras lignocelulósicas, ou ainda um aditivo fonte desses recursos, como a torta de gergelim obtida como resíduo do processamento do gergelim. Sendo assim, o objetivo deste trabalho foi desenvolver e caracterizar espumas à base de amido de mandioca adicionadas de 0 – 40 % (m/m) de resíduo de gergelim, produzidas pelo processo de expansão térmica, a fim de avaliar a influência do aditivo nas propriedades físicas, morfológicas e mecânicas dos materiais obtidos para utilização como embalagens para alimentos. A adição do resíduo resultou em espumas com menores espessuras e densidade aparente, bem como, maior capacidade de expansão dos materiais. Além disso, apresentaram melhores propriedades mecânicas e, em geral, menores capacidade de absorção de água e adsorção de água em baixas umidades relativas, em relação aos materiais compostos somente por amido. Embora as propriedades mecânicas das espumas sejam influenciadas pelas condições de umidade relativa de armazenamento, as espumas contendo 20 % de resíduo (20R) apresentaram uma combinação de propriedades no ensaio de tração (resistência à tração e módulo de elasticidade) que podem ser consideradas comparáveis às amostras de bandejas comercias de poliestireno expandido (EPS), nas três umidades relativas avaliadas (33, 53 e 90 %). Os resultados obtidos nos ensaios de flexão dessas espumas indicaram que as mesmas foram mais rígidas e menos flexíveis do que as amostras de EPS. A adição de 20 % de resíduo resultou em importantes melhorias nas propriedades físicas e mecânicas em comparação às espumas à base de amido de mandioca, além de apresentarem menos defeitos morfológicos do que os observados em espumas com maiores teores do resíduo (30 e 40 %). Foram realizados testes de aplicação das espumas 20R no acondicionamento de dois tipos de alimentos com diferentes teores de umidade: bolo (23 %) e brócolis (91 %), em comparação ao armazenamento em embalagens comerciais de EPS. A partir dos resultados obtidos para a variação de umidade, perda de massa e propriedades mecânicas na flexão das embalagens, foi observado que as espumas propostas não foram adequadas para o acondicionamento das amostras de brócolis, apresentando alta absorção de umidade e deformações após três dias de contato com o alimento. Por outro lado, as espumas 20R mostraram bom desempenho no acondicionamento das amostras de bolo, não apresentando mudanças significativas nas propriedades mecânicas no período de 3 a 9 dias de armazenamento. Dessa forma, o resíduo de gergelim em combinação com o amido de mandioca mostrou elevado potencial para o desenvolvimento de espumas que podem ser utilizadas como embalagens para alimentos com baixos teores de umidade, sendo necessários estudos mais detalhados, considerando principalmente aspectos de segurança para utilização de resíduos em produtos em contato direto com alimentos. / Starch based foams have limitations for use as food packaging, mainly due to high hydrophilicity and fragility. In order to improve these properties it is necessary the use of plasticizers and others additives, such as lignocellulosic fibers and proteins, or an additive source of these constituents like sesame cake, which it is obtained from sesame processing. In this way, the main objective of this work was to develop and characterize starch based foams added with 0 – 40 % (w/w) of sesame residue to evaluate the influence of this additive on physical, morphological and mechanical properties of materials for using as food packaging. The foams were produce by thermal expansion process. Residue addition resulted in foams with smaller thickness and density, as well as greater expansion capacity of the materials produced. In addition, foams incorporated with residue exhibited better mechanical properties and, in general, lower water capacity absorption and water adsorption at low relative humidities compared to foams made only with starch. Although mechanical properties of the foams are affected by storage humidity conditions, foams added with 20 % of residue (20R) showed tensile properties (tensile strength and tensile elasticity modulus) that can be considered comparable to expanded polystyrene (EPS) commercial trays for different relative humidities evaluated (33, 53 and 90 %). Flexural properties indicated that starch foams produced was tougher and less flexible than EPS commercial trays. Addition of 20 % of sesame residue on cassava starch-based foams resulted in relevant improvements compared to foams without residue. Besides that, fewer morphological defects were noted, as observed in foams with higher residue content (30 and 40 %). Thus, 20R formulation was selected to carrying out applicability tests of starch-based foams in packaging of two types of food with different moisture content: cake (23 %) and broccoli (91 %) compared to EPS commercial packaging. From the results obtained for moisture variation, loss of weight and flexural properties of the foams, it was found that the material proposed was not applicable to package broccoli samples. Due to high water absorption by the foams alterations on the shape were noted in the materials after 3 days in contact with this food. Nonetheless, foams based on cassava starch and 20 % of sesame residue exhibited a good performance during storage time of cake samples (9 days). It was not observed any effect on flexural mechanical properties for 3 to 9 days of storage. Thereby, sesame cake added to cassava starch showed high potential to developing foams that could be used as packaging for low moisture food. Additionally, more detailed studies are necessary, especially considering safety aspects mainly for using agricultural residues directly in contact with food products.

Espumas à base de amido possuem limitações para utilização como embalagens na indústria alimentícia, principalmente, devido à alta hidrofilicidade e fragilidade. Para melhorar essas propriedades, torna-se necessário o uso de plastificantes e outros aditivos, como proteínas e fibras lignocelulósicas, ou ainda um aditivo fonte desses recursos, como a torta de gergelim obtida como resíduo do processamento do gergelim. Sendo assim, o objetivo deste trabalho foi desenvolver e caracterizar espumas à base de amido de mandioca adicionadas de 0 – 40 % (m/m) de resíduo de gergelim, produzidas pelo processo de expansão térmica, a fim de avaliar a influência do aditivo nas propriedades físicas, morfológicas e mecânicas dos materiais obtidos para utilização como embalagens para alimentos. A adição do resíduo resultou em espumas com menores espessuras e densidade aparente, bem como, maior capacidade de expansão dos materiais. Além disso, apresentaram melhores propriedades mecânicas e, em geral, menores capacidade de absorção de água e adsorção de água em baixas umidades relativas, em relação aos materiais compostos somente por amido. Embora as propriedades mecânicas das espumas sejam influenciadas pelas condições de umidade relativa de armazenamento, as espumas contendo 20 % de resíduo (20R) apresentaram uma combinação de propriedades no ensaio de tração (resistência à tração e módulo de elasticidade) que podem ser consideradas comparáveis às amostras de bandejas comercias de poliestireno expandido (EPS), nas três umidades relativas avaliadas (33, 53 e 90 %). Os resultados obtidos nos ensaios de flexão dessas espumas indicaram que as mesmas foram mais rígidas e menos flexíveis do que as amostras de EPS. A adição de 20 % de resíduo resultou em importantes melhorias nas propriedades físicas e mecânicas em comparação às espumas à base de amido de mandioca, além de apresentarem menos defeitos morfológicos do que os observados em espumas com maiores teores do resíduo (30 e 40 %). Foram realizados testes de aplicação das espumas 20R no acondicionamento de dois tipos de alimentos com diferentes teores de umidade: bolo (23 %) e brócolis (91 %), em comparação ao armazenamento em embalagens comerciais de EPS. A partir dos resultados obtidos para a variação de umidade, perda de massa e propriedades mecânicas na flexão das embalagens, foi observado que as espumas propostas não foram adequadas para o acondicionamento das amostras de brócolis, apresentando alta absorção de umidade e deformações após três dias de contato com o alimento. Por outro lado, as espumas 20R mostraram bom desempenho no acondicionamento das amostras de bolo, não apresentando mudanças significativas nas propriedades mecânicas no período de 3 a 9 dias de armazenamento. Dessa forma, o resíduo de gergelim em combinação com o amido de mandioca mostrou elevado potencial para o desenvolvimento de espumas que podem ser utilizadas como embalagens para alimentos com baixos teores de umidade, sendo necessários estudos mais detalhados, considerando principalmente aspectos de segurança para utilização de resíduos em produtos em contato direto com alimentos. / Starch based foams have limitations for use as food packaging, mainly due to high hydrophilicity and fragility. In order to improve these properties it is necessary the use of plasticizers and others additives, such as lignocellulosic fibers and proteins, or an additive source of these constituents like sesame cake, which it is obtained from sesame processing. In this way, the main objective of this work was to develop and characterize starch based foams added with 0 – 40 % (w/w) of sesame residue to evaluate the influence of this additive on physical, morphological and mechanical properties of materials for using as food packaging. The foams were produce by thermal expansion process. Residue addition resulted in foams with smaller thickness and density, as well as greater expansion capacity of the materials produced. In addition, foams incorporated with residue exhibited better mechanical properties and, in general, lower water capacity absorption and water adsorption at low relative humidities compared to foams made only with starch. Although mechanical properties of the foams are affected by storage humidity conditions, foams added with 20 % of residue (20R) showed tensile properties (tensile strength and tensile elasticity modulus) that can be considered comparable to expanded polystyrene (EPS) commercial trays for different relative humidities evaluated (33, 53 and 90 %). Flexural properties indicated that starch foams produced was tougher and less flexible than EPS commercial trays. Addition of 20 % of sesame residue on cassava starch-based foams resulted in relevant improvements compared to foams without residue. Besides that, fewer morphological defects were noted, as observed in foams with higher residue content (30 and 40 %). Thus, 20R formulation was selected to carrying out applicability tests of starch-based foams in packaging of two types of food with different moisture content: cake (23 %) and broccoli (91 %) compared to EPS commercial packaging. From the results obtained for moisture variation, loss of weight and flexural properties of the foams, it was found that the material proposed was not applicable to package broccoli samples. Due to high water absorption by the foams alterations on the shape were noted in the materials after 3 days in contact with this food. Nonetheless, foams based on cassava starch and 20 % of sesame residue exhibited a good performance during storage time of cake samples (9 days). It was not observed any effect on flexural mechanical properties for 3 to 9 days of storage. Thereby, sesame cake added to cassava starch showed high potential to developing foams that could be used as packaging for low moisture food. Additionally, more detailed studies are necessary, especially considering safety aspects mainly for using agricultural residues directly in contact with food products.

O poliestireno expandido (EPS), conhecido popularmente no Brasil como Isopor®, foi introduzido recentemente no país como material de baixa massa específica para construções de aterros, principalmente sobre solos moles, e encontro de pontes. Contudo, ainda não há experiência consolidada deste material em ensaios do ponto de vista da engenharia geotécnica entre nós. Este trabalho apresenta os resultados da primeira pesquisa com ensaios mecânicos e hidráulicos de laboratório específicos da caracterização do EPS para o uso geotécnico. Os ensaios mecânicos compreenderam compressão uniaxial simples e cíclica, compressão triaxial, cisalhamento direto e de interface (junta) e fluência em compressão. Os ensaios hidráulicos incluíram absorção de água por imersão e permeabilidade. Um ensaio de perda de massa por ataque de roedores foi realizado de forma simples, e ensaios químicos foram feitos para estudar o polímero. As amostras ensaiadas foram escolhidas de modo a se abranger ao máximo àquelas utilizadas em obras. Tentou-se, também, antecipar a utilização de amostras não convencionais, com massas específicas elevadas e de materiais reciclados. Os resultados mostram que o EPS possui uma grande resistência a solicitações de compressão simples, cíclica e triaxial, de cisalhamento, elevado valor de ângulo de atrito da junta e absorção de água, permeabilidade variável com a massa específica e baixo coeficiente de Poisson. Estas propriedades chave, aliado ao baixo peso específico oferecem a este material um grande potencial de aplicação como geossintético na engenharia geotécnica. / Expanded polystyrene (EPS), in Brazil, commonly know as Isopor®, has been recently introduced in this country as lightweight material for construction of embankments on soft soils, and bridge abutments. Despite this fact, there is no consolidated experience, in Brazil, in testing this product from a geotechnical point of view. This paper presents the first research data, obtained in Brazil, on mechanical and hydraulic laboratory tests, aiming the characterization of EPS samples specifically for geotechnical use. The mechanical tests comprised simple and cyclic unconfined compression, triaxial compression, joint and direct shear and creep in compression. The hydraulic tests included water absorption by immersion and water permeability. A simple loss weight test by mice attack was also conducted. And chemical tests were done to study the polymer. The results show that EPS has a great resistance to simple, cyclic and triaxial compression and joint shear solicitation, high friction angle and water absorption, varied permeability with the density and low Poisson coefficient. These key properties with its very low density give this material large potential application for geosynthetic use in geotechnical engineering.

Αντικείμενο της Διατριβής αποτελεί η διερεύνηση των δυνατοτήτων του Γεωαφρού Διογκωμένης Πολυστερίνης (ΓΔΠ) για τη χρησιμοποίησή του ως σεισμικό μονωτικό παρέμβλημα σε συμβατικούς τοίχους εδαφικής αντιστήριξης (τύπου βαρύτητας ή προβόλου) καθώς και σε ακρόβαθρα γεφυρών. Η παρούσα έρευνα βασίζεται στην αριθμητική ανάλυση της συμπεριφοράς συμβατικών τοίχων αντιστήριξης κάτω από τη δράση οριζόντιας σεισμικής διέγερσης βάσης. Οι αναλύσεις διεξάγονται τόσο για μη-μονωμένους τοίχους όσο και για τοίχους σεισμικά μονωμένους με παρέμβλημα ΓΔΠ. Το παρέμβλημα έχει τη μορφή κατακόρυφου φύλλου μικρού σχετικά πάχους που τοποθετείται σε επαφή με την πίσω όψη του τοίχου παρεμβαλλόμενο μεταξύ τοίχου και επιχώματος. Οι αναλύσεις διεξάγονται χρησιμοποιώντας τη μέθοδο πεπερασμένων στοιχείων (κώδικας PLAXIS v.8) με την παραδοχή ιξωδοελαστικής συμπεριφοράς εδαφικού επιχώματος και κατακόρυφου ελαστικού τοίχου δεδομένης ευκαμψίας και στροφικής αντίστασης της βάσης. Ως δυναμική διέγερση βάσης χρησιμοποιούνται αρμονικές χρονοϊστορίες επιτάχυνσης μεταβαλλόμενου εύρους και συχνότητας. Κατ’ αρχήν αξιολογείται η αξιοπιστία της χρησιμοποιούμενης μεθόδου ανάλυσης και τα αποτελέσματα των αναλύσεων συγκρίνονται με ανάλογα δημοσιευμένα αποτελέσματα και διαπιστώνεται πολύ καλή συμφωνία όσον αφορά την τιμή της σεισμικής ώθησης και το ύψος εφαρμογής της από τη βάση του τοίχου. Για την περίπτωση των σεισμικά μονωμένων (με παρέμβλημα ΓΔΠ) τοίχων οι εξεταζόμενες παράμετροι περιλαμβάνουν το σχήμα του παρεμβλήματος, την πυκνότητα και το ποσοστιαίο (σε σχέση με το ύψος του τοίχου) πάχος του ΓΔΠ, tr, την ευκαμψία του τοίχου, την καθ’ ύψος μεταβολή του μέτρου ελαστικότητας του ΓΔΠ και τη συχνότητα διέγερσης της βάσης. Η αποτελεσματικότητα της σεισμικής μόνωσης περιγράφεται ποσοτικά με τον συντελεστή Ar που ορίζεται ως το επί τοις εκατό ποσοστό της μείωσης (λόγω μόνωσης) της σεισμικής ώθησης σε σχέση με την τιμή που προκύπτει χωρίς μόνωση. Σχετικά με το σχήμα του παρεμβλήματος (κατά την έννοια του ύψους του τοίχου) διεξήχθησαν αναλύσεις για ορθογωνικό σχήμα και τρία τριγωνικά σχήματα και τα αποτελέσματα υποδεικνύουν ότι η βέλτιστη αποτελεσματικότητα επιτυγχάνεται με χρήση ορθογωνικού σχήματος. Επίσης διαπιστώθηκε ότι είναι δυνατή η επίτευξη τιμών της αποτελεσματικότητας σεισμικής μόνωσης Ar>50% για τιμές πάχους παρεμβλήματος tr 15%. Τα αποτελέσματα υποδεικνύουν επίσης ότι, επειδή η προκύπτουσα σχέση Ar - tr είναι μη γραμμική, απαιτούνται σχετικά μεγάλα πάχη παρεμβλήματος για τη μείωση της σεισμικής ώθησης σε ποσοστό μεγαλύτερο του 50%. Τέλος, για τον αντισεισμικό σχεδιασμό τοίχων αντιστήριξης προτείνεται δοκιμαστικά η εφαρμογή διαδικασίας που βασίζεται στον ΕΑΚ 2000, χρησιμοποιώντας όμως διπλάσια τιμή για το συντελεστή συμπεριφοράς, qw, εφόσον επιδιώκεται η επίτευξη αποτελεσματικότητας Ar=50%. / The objective of the Thesis is the investigation of the possibility to use the Expanded Polystyrene Geofoam (EPS Geofoam) for the seismic isolation of earth retaining walls. The research is based on the results of numerical analyses (using the finite element method) for determining the response of vertical walls supporting horizontal backfill and subjected to horizontal harmonic base excitation. The seismic isolation is realized by placing a column of EPS geofoam (compressible inclusion) between the back-face of the wall and the backfill. The response is calculated by using elastic analysis (with viscous damping for the backfill material). The efficiency of seismic isolation is quantitavely described by the Isolation Efficiency, Ar, defined as the ratio (in percent) of the reduction of earthquake thrust (due to isolation) to the earthquake thrust without isolation. The parameters investigated are the shape of the inclusion, the density and the (percent) thickness, tr, of the EPS geofoam, the wall flexibility, the variation of EPS geofoam modulus of elasticity with depth as well as the amplitude and frequency of excitation. The results of the analyses indicate that the optimum shape of the inclusion is the orthogonal (i.e. constant thickness with depth) whereas the effect of the inhomogeneity of the EPS geofoam along the depth of the wall is negligible, as long as the analysis is conducted using a constant mean value for the Modulus of Elasticity of EPS. The results also indicate that an Isolation Efficiency of about 50% may be achieved by using an inclusion thickness of about 15% of the wall height. Due to the nonlinearity of the relation Ar – tr, further increase of the inclusion thickness has a minor effect on the isolation efficiency of the inclusion. Based on the results of all analyses a tentative procedure is proposed for the earthquake resistant design of earth retaining walls. According to the procedure, the wall is designed following the methodology of the Hellenic Seismic Code (2000) and using qw values twice as those indicated by the Code. The required thickness of the EPS inclusion, tr, is then selected from a diagram relating the tr value to the flexibility of the wall and the density of the inclusion.

The composite material of different density, where porous cement paste serves as matrix and crushed waste expanded polystyrene packages serve as inclusions, was developed. The compositions of formative mixtures and technological parameters of production for this composite material were selected and its properties were investigated. / Sukurta skirtingo tankio kompozitinė medžiaga, kurioje matrica yra poringoji cemento tešla, o intarpai - trupintos polistireninio putplasčio pakavimo taros atliekos. Parinktos minėtos kompozitinės medžiagos formavimo mišinių sudėtys, gamybos technologiniai parametrai ir ištirtos jos bandinių savybės.