No description available.

No description available.

Essential oils are natural products used to flavor food and beverages. With the increase in nutrition conscious consumers, manufacturers of food additives and food products are faced with the challenge of making healthy alternatives. In particular, food products going to market with label claims stating reductions in sugar and salt, organic certified, organic compliant, and all natural; moreover the ingredients used in flavors must meet these label claims as well. More often than not, the challenge in using ingredients that follow these requirements is the pricing, the sourcing and the variability among those sources. Variability is common in the ingredients coming from nature such as fruits and plants because the area of cultivation can vary by the soil at the sight of planting and/or the climate in the region. Pricing is also problematic in naturally grown ingredients because it is a matter of supply and demand. Stock could be depleted from natural disasters, disease carrying pest(s), pests that consume the crop, and/or other causes for scarce supply of crop(s). Essential oils are natural byproducts of fruit, peels, and leaves from plants that contribute to flavor formulae for a large variety of food products. Because the essential oils are a crop based commodity, every variety has inherent differences based on the growing conditions and their ripening stages [1]. Nevertheless, each type of oil has marker chemicals that make up the majority of its composition; these marker chemicals have the tendency to degrade over time based on their interaction with light, oxygen exposure, and temperature. For companies that manufacture flavorings, understanding the variability among sources of essential oils as well as the possible degradants of essential oils is valuable information to obtain because it is possible the variants and degradants will negatively impact the flavor profile. Flavor is without question the most important attribute of the food we consume and by default stability of said flavor(s) need to be understood [30]. The content in this dissertation involves the stability analysis of a common essential oil, Oil Mandarin Italian Select, from Citrus Reticulata Blanco. It has known off notes that form from unknown causes. Most common is the plastic note that has formed in carbonated products like soda. Studying this particular essential oil in various conditions is intended to shed light on what those degradants are and under which conditions they form to give mandarin oil an off-note when applied to high acid and carbonated beverage applications. Once the note is reproduced, a correlation between analytical data and sensory interpretation of the oil will be developed. Mandarin essential oil being in the Citrus genus is traditionally analyzed via gas chromatography (GC) because of the high quantities of volatile constituents that give an oil high aroma activity. The volatile fraction of mandarin oil to be studied includes stability of methyl-N-methylanthranilate (MNMA), a major component giving mandarin its distinct grapey character, as well as gamma terpinene, thymol, sinensal, alpha pinene, beta pinene, myrcene, para cymene, alpha terpineol, and beta caryophyllene. Each of these ten compounds contributes to the unique flavor profile of mandarin oils when compared to orange and tangerine essential oils [1]. It was the common knowledge that para cymene can be perceived as rancid in aroma and the many interconversions the terpenes make that cause para cymene formation in Citrus oils, which made monitoring the changes of this chemical in the three stability environments crucial. Attention is being paid to para-cymene, as a specific marker of degradation in Citrus. The data obtained from the applied stability studies were challenging to understand as the marker chemicals are volatile and sensitive to chemical change. In this work the chemical changes and trends were analyzed under various storage conditions. Significant statistical analyses were employed to help define criteria of usability. The analyses were required because of natural variants and apparent inconsistencies of the data. Dixon Q Test and the Z Test were applied to determine outliers. Additionally, the Bland Altman method was applied to compare storage conditions and to determine if this statistical approach could be used to define significant changes in the marker chemical stability. The Bland Altman plots suggest that each component met the statistical limits of agreement, meaning the samplings were not significantly changing, statistically speaking. A final approach to assess the analytical data of the mandarin oil for significant change was the mass balance of each marker chemical from week 0 to week 24. Instrumental fluctuations have an acceptable range of +/- 20% in the industry; hence, a significant change criterion for a chemical in the mass balance must be one that exceeded +/- 20%. Unlike classical statistic methods, the mass balance was indicative that significant change had occurred to the compounds in the three studies. Upon sensory analysis of the oil samples, display of plastic note, oxidation, and overall loss of characteristic mandarin notes, the mass balance was found to correlate best to the significant change detected by sensory evaluation of the oil samplings. Due to the inadequate number of validated methods on Citrus essential oil research and the absence of large groupings of terpenes validated in a unified methodology, reconciliation of mass balance is an underutilized method of assessment in the literature. As a final assessment of the GC method validated, a product containing the selected mandarin oil was analyzed to evaluate the ability of the method to separate the oil components within a significantly more complicated matrix than the initial samples. The method was successful though not all marker chemicals were detected due to their low formulation concentration being below the level of detection of the method. This should not be seen as a failure of the method. For the major components of the essential oil studied, the method was quantitatively successful, meeting industry requirements. / Chemistry

Land ice is losing mass to the worlds oceans at an accelerated rate. The worlds glaciers contain much less ice than the ice sheets but contribute equally to eustatic sea level rise and are expected to continue to do so over the coming centuries if global temperatures continue to rise. It is therefore important to characterize the mass balance of these glaciers and its relationship to climate trends and variability. In the Canadian High Arctic, analysis of long-term surface mass balance records shows a shift to more negative mass balances after 1987 and is coincident with a change in the mean location of the July circumpolar vortex, a mid-troposphere cyclonic feature known to have a strong influence on Arctic summer climate. Since 1987 the occurrence of July vortices centered in the Eastern Hemisphere have increased significantly. This change is associated with an increased frequency of tropospheric ridging over the Canadian High Arctic, higher surface air temperatures, and more negative glacier mass balance. However, regional scale mass balance modeling is needed to determine whether or not the long-term mass balance measurements in this region accurately reflect the mass balance of the entire Canadian High Arctic. The Canadian High Arctic is characterized by high relief and complex terrain that result in steep horizontal gradients in surface mass balance, which can only be resolved if models are run at high spatial resolutions. For such runs, models often require input fields such as air temperature that are derived by downscaling of output from climate models or reanalyses. Downscaling is often performed using a specified relationship between temperature and elevation (a lapse rate). Although a constant lapse rate is often assumed, this is not well justified by observations. To improve upon this assumption, near-surface temperature lapse rates during the summer ablation season were derived from surface measurements on 4 Arctic glaciers. Near-surface lapse rates vary systematically with free-air temperatures and are less steep than the free-air lapse rates that have often been used in mass balance modeling. Available observations were used to derive a new variable temperature downscaling method based on temperature dependent daily lapse rates. This method was implemented in a temperature index mass balance model, and results were compared with those derived from a constant linear lapse rate. Compared with other approaches, model estimates of surface mass balance fit observations much better when variable, temperature dependent lapse rates are used. To better account for glacier-climate feedbacks within mass balance models, more physically explicit representations of snow and ice processes must be used. Since absorption of shortwave radiation is often the single largest source of energy for melt, one of the most important parameters to model correctly is surface albedo. To move beyond the limitations of empirical snow and ice albedo parameterizations often used in surface mass balance models, a computationally simple, theoretically-based parameterization for snow and ice albedo was developed. Unlike previous parameterizations, it provides a single set of equations for the estimation of both snow and ice albedo. The parameterization also produces accurate results for a much wider range of snow, ice, and atmospheric conditions.

No description available.

The objective of this research is to develop a system capable of simulating snow depth and snow water equivalent in the Sherbrooke to Mount-Megantic area of Quebec's Eastern Townships using meteorological and digital terrain data as input.The working hypothesis is that meteorological data may drive a point energy and mass balance snow cover model.The model used was developed by the Hydrologic Research Lab (National Weather Service) which was calibrated for local conditions using field data collected during two winters at several sites on Mount-Megantic. Snow water equivalent and depth are used for calibration and validation of the model. Automated snow sensors were also used to obtain temperature calibration data.The snow surveys and correction of the air temperature for elevation improves the estimates of snow depth and water equivalent.The results suggest that data from the Sherbrooke meteorological stations can be used to estimate the snow cover over the area of Eastern Townships. Air temperature extrapolation across the field area is a challenge. However the simulated snow cover conforms generally well with data observed at several stations throughout the region.

<p>Traditionally, textiles were dried outdoors with the wind and the sun enhancing the drying process. Tumble dryers offer a fast and convenient way of drying textiles independent of weather conditions. Tumble dryers, however, consume large amounts of electrical energy. Over 4 million tumble dryers are sold each year in Europe and a considerable amount of energy is used for drying of clothes. Increasing energy costs and the awareness about environmental problems related to a large energy use has increased the demand for dryers with better energy efficiency. The aim with this thesis is to show how to improve the energy efficiency of domestic tumble dryers.</p><p>Two types of tumble dryers are available on the market today: the open cycle dryer and the closed cycle dryer. In the open cycle dryer room air is heated and led into the drying drum. The exhaust air leaves the dryer and is often evacuated outside the building. In the closed cycle dryer an internal airflow is recirculated inside the dryer. When the hot air has passed through the drying drum it is led through a heat exchanger where the water vapour is condensed before the air is heated again and led to the drum. The heat exchanger is cooled with room air.</p><p>Drying at low temperature has been shown to reduce the specific energy use for an open cycle tumble dryer. In Paper I a correlation between the specific energy use, the drying time and the heat supply was established for a specific load by using the exhaust air temperature. It was shown that the total drying time and specific energy use could be predicted from data during the first hour of the process. This result indicated a possibility to create a control system that makes it possible for the user to choose between low energy use or short drying time.</p><p>The focus of Paper II is to reduce the energy use for a closed cycle tumble dryer. Energy and mass balances were established in order to determine feasible improvements. Energy and mass flows in the dryer indicated that reducing leakage from the internal system of the dryer gave the largest reduction of specific energy use. Insulation of the back cover of the dryer and opening the internal system during the falling drying rate period also gave positive results on the energy use. In total a feasible reduction of the energy use of approximately 17% was calculated.</p>

<p>During the past few years a vast amount of research has been done to increase the understanding of the complex ecosystem of the Baltic Sea. Modelling and simulations are important tools to increase knowledge of the system. A suitable model must be simple to use and the parameters and variables needed in the model must be easy to access.</p><p>In this paper a dynamical mass-balance model, CoastMab, which is validated for smaller coastal areas, has been used to predict concentrations and transports of phosphorus in three large coastal areas - the Gulf of Finland, the Gulf of Gdansk and the Gulf of Riga. CoastMab uses ordinary differential equations to regulate inflow, outflow and internal flows. To reflect seasonal variations in temperature and different types of flows the model has a temporal resolution of a month. The main purposes of this paper have been to evaluate CoastMab, predict the concentrations and the transports of phosphorus in each coastal area and to analyse how much and why the results differ from empirical data.</p><p>The performed simulations show the importance of a correct calculation of the wave base. This is due to its influence on the division between surface and deep water as well as the division of areas of accumulation and areas of erosion and transport. The retention times of surface and deep water calculated by the model also is of great importance because of their direct influence on the flow of water between the study area and the sea outside the area. This together with the concentration of phosphorus determines the flow of phosphorus in and out of the study area.</p><p>The dynamical mass-balance model is considered to work well in the three studied areas even though the areas are outside the model domain in several respects. Even if the predictions of the phosphorus concentration in the gulf of Riga was less accurate than in the other study areas, the prediction was inside the interval of standard deviation that has been calculated from empirical data. The major flow of phosphorus in the model was in the cross section between the Baltic proper and the modelled coastal area.</p><p>Since the model is easy to use and requires only a small number of obligatory input variables it would be appealing to continue development of the model to handle coastal areas of the same size and larger than the study areas in this paper.</p> / <p>Under senare år har mycket forskning utförts för att öka förståelsen av det komplexa ekosystem Östersjön utgör. Viktiga redskap för att öka förståelsen för systemet är modellering och simulering. För att en modell ska vara lämplig att använda är det viktigt att den inte är för komplicerad och att de parametrar och variabler som används i modellen är lättillgängliga.</p><p>I detta arbete har en dynamisk massbalansmodell, CoastMab, som är validerad för mindre kustområden använts för att modellera fosforkoncentrationer och fosforflöden i tre större kustområden - Finska viken, Gdanskbukten och Rigabukten. CoastMab reglerar genom ordinära differentialekvationer inflöden, utflöden och interna flöden. För att kunna hantera säsongsvariationer i temperatur och olika typer av flöden har modellen en temporär upplösning på en månad. Syftet med arbetet har främst varit att se hur väl CoastMab predikterar fosforkoncentrationen och fosforflöden inom respektive område, samt att analysera hur mycket och varför prediktionerna skiljer sig från empiriska data.</p><p>De simuleringar som utfördes visade att djupet på den teoretiska vågbasen, som modellen beräknar, är av stor betydelse eftersom den i sin tur bestämmer fördelningen yt- och djupvatten samt fördelningen av ackumulationsbottnar och erosions- och transportbottnar. De utbytestider för yt- och djupvatten som modellen beräknar är också av största vikt eftersom de har en direkt inverkan på vattenflödet mellan studerat område och havet utanför, vilket i sin tur tillsammans med fosforkoncentrationen bestämmer fosforflöden in och ut ur det studerade området.</p><p>Den dynamiska massbalansmodellen kan anses fungera väl för samtliga tre studerade områden, trots att de ligger utanför modellens domän i flera avseenden. Även om prediktionen av fosforkoncentrationen i Rigabukten blev sämre än för de två övriga områdena, låg prediktionen inom det intervall för standardavvikelsen som beräknats utifrån empiriska data. De största fosforflödena i modellen förekom för samtliga områden i gränssnittet mellan egentliga Östersjön och det modellerade kustområdet.</p><p>Enkelheten i att använda modellen och det låga antalet obligatoriska drivvariabler gör att den är väl värd att utveckla för att hantera områden av samma eller större storlek än de nu studerade områdena.</p>

<p>Naturvårdsverket rankar övergödningen som det allvarligaste hotet mot Östersjön. Strategin för att bekämpa övergödningen i Östersjön har varit att reducera antropogena utsläpp av fosfor och kväve från punktkällor och diffusa källor. Många forskare anser att primärproduktionen i egentliga Östersjön huvudsakligen är begränsad av kväve varför Sverige har infört ett ambitiöst och kostsamt program för avancerad kväverening på reningsverk. Andra experter hävdar istället att reducerade kväveutsläpp är meningslösa eller rent av skadliga.</p><p>I ljuset av dessa fundamentalt olika åsikter och de helt motsatta strategier de innebär syftar denna studie till att försöka klargöra vilka åtgärder som borde vidtas för att minska övergödningen genom att undersöka området Himmerfjärden som ofta används som ett exempel på lyckad kväverening. Området har också studerats intensivt sedan 1970-talet.</p><p>Detta arbete har använt en processbaserad dynamisk massbalansmodell för salt för att beräkna vattenutbytestider i Himmerfjärden. Flöden av vatten och näringsämnen till och från fjärden har beräknats och det har visats att bidraget av kväve och fosfor till Himmerfjärden från reningsverket är mycket marginellt jämfört med bidraget från Östersjön.</p><p>Denna studie har också genom att granska litteratur och mätdata från Himmerfjärden visat att det finns goda skäl att ifrågasätta hypotesen om att primärproduktionen i Himmerfjärden skulle vara långsiktigt begränsad av kväve. Resultaten av denna studie kommer att användas i framtida massbalansmodelleringar av fosfor, kväve och cyanobakterier i Himmerfjärden.</p> / <p>The Swedish Environmental Protection Agency has ranked eutrophication as the most severe threat to the Baltic Sea. The strategy to combat the eutrophication in the Baltic has been to reduce antrophogenous emissions of phosphorus and nitrogen from point and diffuse sources. Many scientists argue that the primary production in the Baltic proper is primarily limited by nitrogen which is why Sweden and other countries have implemented an ambitious and expensive program of advanced nitrogen removal in sewage treatment plants. Other experts argue that reduced nitrogen load to the Baltic Sea is either pointless or even harmful.</p><p>In the light of these fundamentally different views and the very opposite management strategies they imply, this study aims to more bring clarity to which measures should be taken to reduce eutrophiction by investigating the area of Himmerfjärden. Himmerfjärden is often used as an example of successful removal of nitrogen and the area has been intensively monitored since the 1970’s.</p><p>This work used a process-based dynamic mass balance model for salt to calculate water retention times in Himmerfjärden. Water and nutrient flows to and from the bay have been calculated. It was shown that the contribution of nutrients to Himmerfjärden from the treatment plant is small compared to the contribution from the Baltic Sea.</p><p>This study showed by reviewing literature on Himmerfjärden that there are good reasons to question the hypothesis of Himmerfjärden being nitrogen limited in the long-run. The findings of this study will be used in future mass balance modelling of phosphorus, nitrogen and cyanobacteria in Himmerfjärden.</p>

<p>Threats from man-made radionuclides include waste issues, increasing number of power plants, underground bomb testing, nuclear weapons, and “dirty bombs”. Until recently the ionizing radiation protection system focused on protecting humans with an implied protection of biota. However, goals of sustainable development and precautionary principles for human activity are leading to an inclusion of plant and animal populations in the protection system.</p><p>From this perspective, the present thesis examines wetlands that function as sinks for the radionuclide 137Cs, and describes calculated and measured radiation doses to residing biota. Also, multi-level effects from exposure to low-dose rate ionizing radiation were studied. Accumulation of 137Cs after the Chernobyl accident fallout was studied in a riparian wetland with a mean activity concentration of 1 200 kBq m-2 in Sweden (paper I). A mass balance budget of 137Cs showed that the sedimentation of new material was balanced by the decay process of 137Cs in parts of the wetland (paper I).</p><p>Frogs were identified as organisms of concern in this wetland. Internal radiation doses, based on whole body measurements of frogs, were estimated to be lower than external doses based on soil samples (paper II). Current dose models for biota resulted in a wide range of doses depending on different levels of conservatism in the models. Therefore, in situ measurements with frog-phantoms were found to provide valuable dose information (paper III). Measured doses using frog-phantoms were lower than calculated doses using several dose models. Although a dose conversion factor by FASSET was found to be useful for comparison with measurements in the field. A higher dose was measured to the phantom surface in comparison to inner parts, i.e. the sensitive skin of frogs receives the highest dose. Estimated and measured radiation doses to frogs were below suggested dose rate limits.</p><p>Low-dose rate 137Cs exposure of eggs and tadpoles from three amphibian species, Scaphiopus holbrookii, Bufo terrestris, and Rana catesbeiana, showed no increased levels of strand breaks in red blood cells, and no effects on development, survival or growth up to metamorphosis (paper IV). The ecological factor larval density had a stronger effect on metamorphic traits than low-dose rate radiation. Higher levels of strand breaks were detected after an acute dose in R. catesbeiana than after a chronic dose supporting a dose rate limit for protection of amphibians rather than a dose limit (paper IV).</p><p>Based on current knowledge, frogs in the contaminated wetland are probably not exposed to radiation doses from 137Cs that are harmful for the population. However, variations in sensitivity between populations and species, and adaptive responses have been shown for amphibians exposed to other stressors. This supports further research on effects of chronic low-dose rates of ionizing radiation on amphibians.</p>