Solar ultraviolet (UV) radiation ionizes the neutral components in the atmosphere, which is partly responsible for the formation of the ionosphere, and contributes to heating of the atmosphere. Solar flares change the solar spectrum at times by several orders of magnitude. These changes modify the Earth's upper atmosphere, causing problems to communication systems and space operations, such as increased satellite drag. Unfortunately, solar UV measurements are limited since they can only be observed with space-based sensors. In order to work around this limitation, the solar radio emissions at a wavelength of 10.7 cm have been used as a proxy for the solar UV radiation. These measurements, known as the F10.7 index, are a snapshot of the solar activity at the time they are taken and do not capture the changes that occur throughout the day, such as flares. In order to capture this daily variation, we used 1-second cadence solar radio data and compared it to solar UV measurements taken once per orbit by the TIMED satellite. We found significant correlations between some radio frequencies and different UV wavelengths during quiet times. These correlations changed in terms of radio frequency and UV wavelength during solar flares.

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Seasonal sea ice is an important component of the global climate system. Sea ice influences exchange rates of heat, moisture, and gas between the ocean and atmosphere. Sea ice also plays critical roles in high latitude ecosystems and marine carbon cycling. Records of sea-ice extent and duration in the Arctic Ocean and its marginal seas through geologic time are valuable resources for better understanding the intricate relationships between sea ice and climate. IP25, a compound biosynthesized exclusively by diatoms associated with sea ice, has been used to construct qualitative records of sea ice from sediment cores in some areas of the Arctic. However, IP25 has not previously been applied to sediments from the Bering and Chukchi Seas. This area exhibits a wide range of interannual seasonal ice duration, which makes the region a promising natural laboratory for developing a quantitative core-top calibration between sea ice and the IP25 biomarker. A sample suite of surface sediments from the Bering and Chukchi Seas representing a range of latitudes (60-72o N) and durations of sea ice per year (0.5-11 months/year) are analyzed for this study. Gas chromatography/mass spectrometry analysis of sediment solvent extracts reveals the presence of IP25 in all samples and higher IP25 concentrations in the Chukchi Sea compared to in the Bering Sea. IP25 concentrations are compared with data for several sea surface conditions: mean annual sea-ice duration, sea surface temperature and salinity, and insolation data. An exponential relationship between TOC-normalized IP25 concentration and average annual duration of sea ice is identified. Negative exponential relationships are identified between IP25 and the other sea surface conditions: average annual and August sea surface temperature and average annual and August sea surface salinity. Exponential relationships are also identified between TOC-normalized IP25 concentrations and insolation, and insolation coupled with sea-ice concentration. IP25 in surface sediments is a viable quantitative proxy for sea-ice duration in the Bering and Chukchi Seas. However, sea surface conditions, such as temperature, salinity, sea-ice duration/concentration, and insolation are not independent variables. Therefore it is difficult to determine which of these environmental factors has/have the most influence on IP25 production. Further research and statistical analysis may serve to refine these relationships.

Detta arbete är en fallstudie som undersöker konflikten i Ukraina. Syftet med denna studie är att studera kriget i Ukraina utifrån begreppet proxy war och Sveriges utrikespolitik gentemot Ukrainakriget. Metoden är av kvalitativ karaktär till följd av en vetenskaplig litteraturinsamling och semi-strukturerade intervjuer som empiriskt material. Intervjupersonerna är universitetslektorer på svenska universitet. Arbetet är avgränsat till det upptrappade kriget år 2022, med en viss djupdykning i krigets början, vilket är år 2014. Studiebidraget med detta arbete är en djupare förståelse kring olika krigsaspekter.Det finns huvudsakliga slutsatser som resultat av undersökningen. Den ena är att Ukrainakriget inte är en isolerad konflikt mellan Ukraina och Ryssland. Det finns olika inslag av ombudskrig i konflikten med externa aktörer som försöker nå ett önskat strategiskt utfall med krigsutvecklingen. Externa aktörer deltar som icke-krigförande genom att stödja Ukraina utan att själva direkt ingå i direkta krigshandlingar. Den andra huvudsakliga slutsatsen är att svensk utrikespolitik nått en historisk brytpunkt. Det svenska stödet till Ukraina och de utrikespolitiska åtgärderna är utmärkande. Till följd av kriget har Sverige antagit en positiv inställning till NATO-anslutning och lagt sina säkerhetspolitiska kort på ett lyckat ukrainskt försvar. Sverige bidrar med ett omfattande stöd till Ukraina, sanktionerar ryska aktörer och är i linje med den västerländska enheten. Därmed har Sverige överlämnat alliansfriheten.

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BitTorrent is a peer-to-peer protocol useful for distributing large files over the Internet. Many organizations use BitTorrent to distribute their software in order to reduce client download time and reduce the load on their servers. While there is a lot of legitimate content available via BitTorrent, some organizations ban BitTorrent usage due to concerns over copyright infringement and the amount of bandwidth that peers can consume. A BitTorrent proxy will allow organizations to control those risks and allow its members to use the BitTorrent protocol for approved uses. It will allow the organization to control the files that are downloaded and the total bandwidth that can be used, and it will eliminate redundant downloads by acting as a cache.

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Calcified skeletons are produced within complex assemblages of proteins and polysaccharides whose roles in mineralization are not well understood. Researchers have long postulated that living organisms utilize the macromolecules of organic matrices to actively guide the formation of crystal structures. The timing and placement of the subsequent minerals that form are most easily controlled during nucleation; however, a physical and chemical picture of how organic functional group chemistry influences the initial stages of nucleation is not yet established. These processes are further complicated by the realization that carbonate biominerals can form by an amorphous to crystalline transformation process, which has prompted the question of how chemical signatures are recorded during mineralization. Investigations of mineralization processes such as the kinetics of nucleation and the transformation of amorphous calcium carbonate (ACC) to crystalline products are critical to building a better understanding of biomineral formation. Only from that fundamental basis can one begin to decipher changes in climate and seawater chemistry over geologic time and by recent anthropogenic effects. This dissertation presents the findings from experimental studies of the thermodynamics and kinetics of multiple mineral formation processes, including nucleation and transformation from an amorphous phase. The kinetics of calcite nucleation onto a suite of high-purity polysaccharide (PS) substrates were quantified under controlled conditions. Nucleation rates were measured as a function of 1) supersaturation extending above and below ACC solubility and 2) ionic strength extending to seawater salinity. These conditions decipher the chemical interactions between the PS substrate, calcite crystal, and solution. These investigations show the energy barrier to calcite formation is regulated by competing interfacial energies between the substrate, crystal, and liquid. The energy barriers to nucleation are PS-specific by a systematic relationship to PS charge density and substrate structure that is rooted in minimization of the competing substrate-crystal and substrate-liquid interfacial energies. The data also suggest ionic strength regulates nucleation barriers through substrate-liquid and crystal-liquid interfacial energetics. In a second experimental study, stable isotope labeling was used to directly probe the transformation pathway. Four processes were considered: dissolution-reprecipitation, solid-state, or combinations of these end member processes. Isotope measurements of calcite crystals that transform from ACC have signatures that are best explained by dissolution-reprecipitation. The extent of isotopic mixing correlates with the amount of ACC transferred and the time to transformation, suggesting the calcite crystals are recording the changing local solution environment during the transformation. These investigations into different mineralization mechanisms build a framework for how functional group chemistries of organic molecules regulate mineralization and the resulting isotopic and elemental signatures in the calcite. This may provide useful insights to interpreting chemical signatures of carbonate biominerals in fossil record and understanding ocean chemistry changes throughout geologic time. / Ph. D.

La caractérisation de la variabilité naturelle du climat est importante pour comprendre la réponse de celui-ci aux forçages naturels et pour identifier les influences anthropiques. L'objectif de cette thèse est de reconstituer les changements climatiques dans le sud-ouest de la France, une région qui se caractérise par des périodes de sécheresse récurrentes, où les reconstitutions millénaires basées sur des « proxies » à haute résolution font défaut.La reconstruction est basée sur plusieurs proxies dans deux archives continentales : les spéléothèmes et les cernes d'arbre. Leur combinaison permet de tirer avantage de leurs points forts tout en compensant leurs faiblesses. Il y a deux objectifs principaux : d’une part de mieux comprendre les influences climatiques et non climatiques qui s’exercent sur chaque proxy ; et, d'autre part, de reconstituer les périodes de sécheresse dans le passé.La composition isotopique en oxygène (δ18O) des inclusions fluides des spéléothèmes et de la cellulose des cernes d’arbre est contrôlée dans une large mesure par le δ18O des précipitations, qui peut servir de traceur de la circulation atmosphérique. Pour interpréter ces proxies en termes de climat, il est nécessaire de comprendre comment le signal climatique est enregistré dans le proxy, et quels processus modifient ce signal lors de la formation de l'archive.Les mesures de δ18O dans les précipitations, l'eau d’infiltration, et les inclusions fluides dans des échantillons de spéléothèmes modernes de la Grotte de Villars démontrent que la composition isotopique de l'eau d’infiltration dans la grotte correspond à une moyenne pluriannuelle des précipitations, et que les inclusions fluides des spéléothèmes préservent la composition isotopique de cette eau d’infiltration. Sur la base de cette calibration, il est possible de reconstituer les variations de la composition isotopique de l'eau d’infiltration à partir de celles des inclusions fluides d’une stalagmite vieille de plus de 2000 ans, datée par comptage de lamines, et par des mesures U-Th et 14C. Des changements dans l'environnement de la grotte, par exemple du couvert végétal, sont indiqués par d'autres proxies de la même stalagmite (les isotopes stables dans la calcite et les concentrations d'éléments traces), mais ces changements n'ont pas d'incidence significative sur le δ18O des inclusions fluides.La composition isotopique de la cellulose des cernes d'arbre de Quercus spp. dans la zone d'étude est fortement influencée par les conditions climatiques estivales. Cependant, des influences non-climatiques sur la composition isotopique de la cellulose sont identifiées ; elles sont liées à l'âge de l'arbre et à l'hydrologie du site, et doivent être prises en compte dans l'échantillonnage et dans les procédures analytiques. Grace à l’inter-datation de carottes d’arbres vivants et de poutre de bâtiments historiques des environs d'Angoulême, une chronologie de δ18O dans la cellulose à résolution annuelle a été établie. Des corrélations significatives avec les données météorologiques permettent une calibration des données isotopiques et une reconstruction des périodes de sécheresse depuis 1360 AD.Enfin, cette thèse explore une nouvelle approche intégrant les enregistrements isotopiques de l'oxygène dans les inclusions fluides des spéléothèmes et dans la cellulose des cernes d’arbre de sites proches pour reconstruire la variabilité à la fois haute et basse fréquence des sécheresses dans le passé. / The characterization of natural climate variability is important in order to understand the climate response to natural forcings and to identify anthropogenic influences. The aim of this thesis is to reconstruct climate changes in the southwest of France, a region which is characterised by recurrent drought periods, where high resolution proxy records of the last millennia were lacking.The reconstruction is based on multiple proxies from two continental archives: speleothems and tree rings. Their combination can make use of the strengths of each archive while compensating their weaknesses. There are two principal objectives: first, to gain a better understanding of the climatic and non-climatic influences on each proxy; and second, to reconstruct drought periods in the past.The oxygen isotopic composition (δ18O) of speleothem fluid inclusions and tree ring cellulose is controlled to a large extent by the δ18O of precipitation, which can serve as a tracer of the atmospheric circulation. In order to interpret these proxies in terms of climate, it is necessary to understand how the climate signal becomes recorded in the proxy, and which processes modify the original signal during the formation of the archive.Measurements of δ18O in precipitation, cave drip water, and fluid inclusions in modern speleothem samples from Villars Cave demonstrated that the isotopic composition of cave drip water corresponds to the pluri-annual average precipitation. The speleothem fluid inclusions, in turn, preserve the isotopic composition of the drip water. Based on this calibration, it is possible to reconstruct drip water isotope variability using fluid inclusions in a more than 2000 year old stalagmite, which has been dated by laminae counting, as well as U-Th and 14C measurements. Changes in the cave environment, e.g. the vegetation cover, are indicated by other proxies from the same stalagmite (stable isotopes in calcite and trace element concentrations), but these changes do not seem to impact the fluid inclusion δ18O significantly.The isotopic composition of tree ring cellulose from Quercus spp. in the study area is strongly influenced by climate conditions during the summer. However, non-climatic influences on the isotopic composition of cellulose are identified. They are linked to the age of the trees and to site hydrology, and must be accounted for in the sampling and analytical procedures. Crossdated cores from living trees and timber wood in historic buildings near Angoulême are used to build an annually resolved chronology of cellulose δ18O. Significant correlations with meteorological data enable a calibration and a reconstruction of drought periods since 1360 AD.Lastly, this thesis explores a novel approach of integrating oxygen isotope records from speleothem fluid inclusions and tree ring cellulose from closely located sites to reconstruct both high- and low-frequency variability of droughts in the past.