The development of a new catalyst system by The Dow Chemical Company has resulted in the production of isotactic polypropylene and propylene/ethylene copolymers with a unique defect and comonomer distribution. This work investigated the morphology and optical properties of cast and compression molded films made from the homopolymer and copolymers with up to 20 mol% ethylene comonomer. The defect distribution of the Dow Chemical copolymers resulted in materials with lower crystallinity than Ziegler-Natta or metallocene-made materials of similar ethylene content. These materials exhibited a gamma-phase crystal content ranging from 0-95%, depending on ethylene content, processing condition, and catalyst type. The gamma-phase crystal content of quiescently crystallized copolymer films was found to significantly influence their bulk optical properties, presumably through a change in the spherulite birefringence. The bulk haze, clarity, and transparency of a homopolymer film were degraded through annealing treatments, which decreased the fraction of gamma-phase crystallinity and increased the thickness of existing lamellae, resulting in an increased intensity of scattered light and a corresponding degradation in the optical properties of the film. The haze, clarity, transparency, and gloss of the copolymer films were found to improve at higher comonomer content and higher cooling rates. The variation in the length scale and degree of disorder in the bulk morphology of films processed under different conditions was shown to correlate with the optical quality of the films, with smaller scale morphologies scattering less light and resulting in films with better optical properties. It was also shown that no single metric can completely describe the optical quality of a polymer film; the relative importance of haze, transparency, and gloss, which depends on the intended application of the film, was discussed. The influence of surface scattering from the films was controlled through the compression molding of films using substrates of different surface roughness. The contribution of light scattered from the surface of the films was isolated and found to play a significant role in the degradation of optical quality. / Ph. D.

It has long been known that ship wakes are observable by synthetic aperture radar. However, incomplete physical understanding has prevented the development of simulation tools that can predict both the structure and persistence of wakes in the ocean environment. It is the focus of this work to develop an end-to-end multi-scale modeling-and-simulation methodology that captures the known physics between the source of disturbance and the sensor. This includes turbulent hydrodynamics, free-surface effects, environmental forcing through Langmuir-type circulations, generation of surface currents and redistribution of surface-active substances, surface-roughness modification, and simulation of the signature generated by reflection and scattering of electromagnetic waves from the ocean surface. The end-to-end methodology is based upon several customized computational fluid dynamics solvers and empirical models which are linked together. The unsteady Reynolds-averaged Navier-Stokes equations, including models for the Craik-Leibovich vortex force and near surface Reynolds-stress anisotropy, are solved at full-scale Reynolds and Froude numbers on domains that extend tens of kilometers behind the ship. A parametric study is undertaken to explore the effects of ship heading, ship propulsion, ocean-wave amplitude and wavelength, and the relative importance of Langmuir-type circulations vs. near-surface Reynolds-stress anisotropy on the generation of surface currents that are transverse to the wake centerline. Due to the vortex force, the structure of the persistent wake is shown to be a function of the relative angle between the ambient long-wavelength swell and the ship heading. Ships operating in head seas observe 1-3 streaks, while ships operating in following seas observe 2 symmetric streaks. Ships operating in calm seas generate similar wakes to those in following seas, but with reduced wake width and persistence. In addition to the structure of the persistent wake, the far wake is shown to be dominated by ship-induced turbulence and surface-current gradients generating a wide center wake. The redistribution of surface-active substances by surface currents is simulated using a scalar-transport model on the ocean surface. Simulation of surface-roughness modification is accomplished by solving a wave-action balance model which accounts for the relative change in the ambient wave-spectrum by the surface currents and the damping-effects of surface-active substances and turbulence. Simulated returns from synthetic aperture radar are generated with two methods implemented. The first method generates a perfect SAR image where the instrument and platform based errors are neglected, but the impact of a randomized ocean field on the radar cross section is considered. The second method simulates the full SAR process including signal detection and processing. Comparisons are made to full-scale field experiments with good agreement between the structure of the persistent wake and observed SAR imagery. / 1 / It has long been known that ship wakes are observable by synthetic aperture radar. However, incomplete physical understanding has prevented the development of simulation tools that can predict both the structure and persistence of wakes in the ocean environment, which is critical to understanding both the design and operation of maritime remote sensors as well as providing tactically relevant operational guidance and awareness of the maritime domain. It is the focus of this work to develop an end-to-end multi-scale modeling-and simulation methodology that captures the known physics between the source of disturbance and the sensor. This includes turbulent hydrodynamics, free-surface effects, environmental forcing, generation of surface currents and redistribution of surface-active substances, surface-roughness modification, and simulation of the signature from the ocean surface. The end-to-end methodology is based upon several customized computational fluid dynamics solvers and empirical models. The unsteady Reynolds-averaged Navier-Stokes equations, including models to account for environmental effects and near-surface turbulence, are solved at full-scale on domains that extend tens of kilometers behind the ship. A parametric study is undertaken to explore the effects of ship heading, ship propulsion, ocean-wave amplitude and wavelength, and the relative importance of environmental forcing vs. near-surface turbulence on the generation of surface currents that are transverse to the wake centerline. Due to the environmental forcing, the structure of the persistent wake is shown to be a function of the relative angle between the ambient long-wavelength swell and the ship heading. Ships operating in head seas observe 1-3 streaks, while ships operating in following seas observe 2 symmetric streaks. Ships operating in calm seas generate similar wakes to those in following seas, but with reduced wake width and persistence. In addition to the structure of the persistent wake, the far wake is shown to be dominated by ship-induced turbulence and surface-current gradients generating a wide center wake. The redistribution of surface films by surface currents is simulated using a scalar-transport model on the ocean surface. Simulation of surface-roughness modification is accomplished by solving a wave-action-balance model which accounts for the relative change in the ambient surface profile by the surface currents and the damping-effects of surface-active substances and turbulence. Simulated returns from synthetic aperture radar are generated with two methods implemented. The first method generates a perfect SAR image where the instrument and platform based errors are neglected, but the impact of a randomized ocean field on the radar cross section is considered. The second method simulates the full SAR process including signal detection and processing. Comparisons are made to full-scale field experiments with good agreement between the structure of the persistent wake and observed SAR imagery.

Properties of aggregates are affected by their morphological characteristics, including shape factors, angularity and texture. These morphological characteristics influence the aggregate's mutual interactions and strengths of bonds between the aggregates and the binder. The interactions between aggregates and bond strengths between the aggregate and the binder are vital to rheological properties, related to workability and friction resistance of mixtures. As a consequence, quantification of the aggregate's morphological characteristics is essential for better quality control and performance improvement of aggregates. With advancement of hardware and software, the computation capability has reached the stage to rapidly quantify morphological characteristics at multiple scales using digital imaging techniques. Various computational algorithms have been developed, including Hough transform, Fourier transform, and wavelet analysis, etc. Among the aforementioned computational algorithms, Fourier transform has been implemented in various areas by representing the original image/signal in the spatial domain as a summation of representing functions of varying magnitudes, frequencies and phases in the frequency domain. This dissertation is dedicated to developing the two-dimensional Fourier transform (FFT2) method using the Fourier Transform Interferometry (FTI) system that is capable to quantify aggregate morphological characteristics at different scales. In this dissertation, FFT2 method is adopted to quantify angularity and texture of aggregates based on surface coordinates acquired from digital images in the FTI system. This is followed by a comprehensive review on prevalent aggregate imaging techniques for the quantification of aggregate morphological characteristics, including the second generation of Aggregate Image Measurement System (AIMS II), University of Illinois Aggregate Image Analyzer (UIAIA), the FTI system, etc. Recommendations are made on the usage of aggregate imaging system in the measurements of morphological parameters that are interested. After that, the influence of parent rock, crushing, and abrasion/polishing on aggregate morphological characteristics are evaluated. Atomic-scale roughness is calculated for crystal structures of five representative minerals in four types of minerals (i.e., α-quartz for quartzite/granite/gravel/aplite, dolomite for dolomite, calcite for limestone, haematite and magnetite for iron ore); roughness ranking at atomic-scale is further compared with surface texture ranking at macroscale based on measurement results using the FTI system and AIMS II. Morphological characteristics of aggregates before and after crushing test and micro-deval test are measured to quantitatively evaluate the influences of the crushing process and the abrasion/polishing process on morphological characteristics of aggregates, respectively. / Ph. D.

Junction flows originate from the interaction between a fluid moving over a wall with an obstacle mounted on the same surface. Understanding the physics of such flows is of great interest to engineers responsible for the design of systems consisting of wall-body junctions. From aerodynamics to turbomachinery and electronics to bridge hydraulics, a number of phenomena (drag, heat transfer, scouring) are driven by the behavior of the most prominent feature of junction flows: the horseshoe vortex system (HVS). Focusing on turbulent flows, the complex dynamics of the HVS is established through its unsteadiness and non-uniformity. The fundamentals of this dynamically-rich phenomenon have been described within the body of a rapidly-expanding literature. Nevertheless, important aspects remain inadequately understood and call for further scrutiny. This study emphasized three of them, by investigating the effects of: model scale, wall roughness, and bed geometry. High-resolution experiments were carried out using Particle Image Velocimetry (PIV). Statistical analyses, vortex identification schemes, and Proper Orthogonal decomposition were employed to extract additional information from the large PIV datasets. The time-averaged topology of junction flows developing over a smooth and impermeable wall was independent of the flow Reynolds number, Re (parameter that expresses the effects of scale). On the contrary, time-resolved analysis revealed a trend of increasing vorticity, momentum, and eruptions of near-wall fluid with Re. New insights on the modal dynamics of the HVS were also documented in a modified flow mechanism. Wall roughness (modeled with a permeable layer of crushed stones) diffused turbulence and vorticity throughout the domain. This effect manifested with high levels of intermittency and spatial irregularity for the HVS. Energetic flow structures were also identified away from the typical footprint of the HVS. Finally, a novel implementation of PIV allowed for unique velocity measurements over an erodible bed. It was demonstrated that, during the initial stages of scouring, the downflow at the face of the obstacle becomes the dominant flow characteristic in the absence of the HVS. Notwithstanding modeling limitations, the physical insight contributed here could be used to enhance the design of systems with similar flow and geometrical characteristics. / Ph. D.

<p dir="ltr">Experiments were performed in the Boeing/AFOSR Mach-6 Quiet Tunnel to study the effect of flight-derived discrete roughness elements repeated in an axisymmetric pattern near the nose of a sharp 7° cone. The aim of the roughness array was to simulate natural vehicle roughness and attempt to introduce a deterministic roughness pattern with the ability to cancel out the instabilities caused by the natural roughness. The cone was pitched at a 6° of attack to determine the three-dimensional flow field effects of the roughness elements. Tests were also ran at 0° of attack for comparison. Quiet flow testing included the designed-for freestream unit Reynolds number of 10.8x10⁶, and Reynolds numbers above and below. In noisy flow, comparable Reynolds numbers were also tested at to isolate the effects of noise in a conventional flow wind tunnel.</p><p dir="ltr">Infrared thermography and surface pressure sensors were used to document the behavior of the boundary layer. It was found that the roughness pattern was in general unsuccessful in controlling the added boundary layer instabilities as intended at 6° of attack, but it did create different instability amplitudes and heating patterns. Additionally, it was determined to reduce Mack's second-mode instability amplitudes at 0° of attack.</p><p dir="ltr">Additionally, work was done to document and characterize the roughness patterns found on samples of hypersonic glide vehicles PRIME (SV-5D or X-23) and ASSET (ASV-3). These samples were taken in the form of molded impressions of the surface which were able to be analyzed with an optical profilometer and considered for future experimental distributed roughness studies.</p>

When a polymer film is deposited onto a roughened substrate, the film masks over the underlying substrate roughness. Then when attempting to measure the roughness of the polymer film surface using a stylus-type profile meter, the pressure between the tip of the stylus and the film is sufficient to plastically deform the polymer surface. The result is a possible erroneous measurement of the surface roughness of the polymer film. This thesis reports on attempts to quantify the actual roughness of the polymer film from the measurement obtained by the profile meter. Extensive surface profile data were collected and analyzed to determine the characteristics of the surface of the substrate and of the coating on the substrate. The tracks made by the stylus in the film were then observed in a scanning electron microscope, from which the depth of the stylus tracks were measured. The effects of the film thickness, stylus traversing speed, and substrate roughness on the stylus penetration depth, the variation in the depth, and the measured film roughness are assessed and discussed. It was found that using the fastest stylus traversing speed minimizes the variation of the stylus penetration depth and thus results in the most accurate measurement of the film surface. To predict this stylus indentation depth, a plane strain plastic deformation model is developed using slip-line field theory. It is found that the slip-line model gives good estimates of the stylus indentation depth when the film thickness is large. / Master of Science

The instability of flows around hump and dip imperfections is investigated. The mean flow is calculated using interacting boundary layers, thereby accounting for viscous/inviscid interaction and separation bubbles. Then, the two-dimensional linear instability of this flow is analyzed, and the amplification factors are computed. Results are obtained for several height/width ratios and locations. The theoretical results have been used to correlate the experimental results of Greening and Walker. The observed transition locations are found to correspond to amplification factors varying between 7.4 and 10, consistent with previous results for flat plates. The method accounts for Tollmien-Schlichting waves, the shear layer instability, and their interaction. Separation is found to increase significantly the amplification factor. / Master of Science

The aircraft industry has long been concerned with the increase of drag on airplanes due to fouling of the wings by insects. The present research studied the effects of surface energy and surface roughness on the phenomenon of insect sticking. Aluminum plates of different roughnesses were coated with thin films of polymers with varying surface energies. The coated plates were attached to a custom jig and mounted on top of an automobile for insect collection. Contact angle measurements, x-ray photoelectron spectroscopy and specular reflectance infrared spectroscopy were used to characterize the surfaces before and after the insect impact experiments. Scanning electron microscopy showed the topography of insect residues on the exposed plates. Moments were calculated in order to find a correlation between the parameters studied and the amount of bugs collected on the plates. An effect of surface energy on the sticking of insect residues was demonstrated. / M.S.

This study focuses on measuring and normalizing the roughness noise of multiple roughness types across numerous layouts and flow speeds. Using the Virginia Tech Anechoic Wall Jet Facility, far field noise was recording for the flow of a turbulent wall jet boundary layer over cubes, hemispheres, and gravel, with element heights in the range of 14.3 - 55.2% of the boundary layer thickness. The sound radiated from the various layouts showed that the elements acted as independent sources when separated by three element diameters center-to-center or more. When the elements were placed shoulder to shoulder, interaction between the elements and shielding of the higher velocity flow lowered the noise per element produced. The far field roughness noise was then normalized using the theory of Glegg et al. (2007), which assumes a dipole efficiency factor. Comparisons were made between the theoretical drag spectrum model proposed by Glegg et al. (1987) and a modified version of this model made using the empirical data gathered. Overall, the theory of Glegg et al. (2007) succeeds greatly in collapsing the data into its non-dimensional drag spectra, but the original model spectrum did not fit well. The modified spectrum showed much greater fit with the data at all layouts and speeds. The collapse of the data using the theory of Glegg et al. (2007) confirms that roughness noise is dipole in nature. / Master of Science

<p dir="ltr">Prediction of boundary-layer transition is a critical element of hypersonic vehicle design</p><p dir="ltr">due to the impact transition has on boundary-layer separation, heat transfer, and aerodynamic</p><p dir="ltr">control. Transition is affected by many factors including surface roughness. The</p><p dir="ltr">roughness on a hypersonic vehicle can cause a boundary-layer to become turbulent. However,</p><p dir="ltr">there is a limited understanding of the impacts that roughness can have, and the conditions</p><p dir="ltr">under which it is important.</p><p dir="ltr">The rocket-sled track at Holloman Air Force Base was selected as a ground-test facility</p><p dir="ltr">for transition measurements. The present work is about understanding the mechanism of</p><p dir="ltr">transition on blunt ogives or blunt cones with moderate nose radii, as it appears that nosetip</p><p dir="ltr">roughness affects boundary-layer transition on the afterbody for moderate nose radii. A</p><p dir="ltr">single test-track shot is to be executed for a blunt ogive to determine if the test track can</p><p dir="ltr">make useful measurements of boundary-layer transition.</p><p dir="ltr">Initially, the present research used a boundary-layer solver to estimate target roughnesses</p><p dir="ltr">that would be applied to the nose tip. Preliminary analysis was conducted on test cases for</p><p dir="ltr">sharp cones and blunt cones. However, due to time constraints, the target roughnesses were</p><p dir="ltr">then estimated with a higher fidelity code by Brad Wheaton of JHU APL. Two separate</p><p dir="ltr">roughness targets were established for the upper and lower sides of the hemispherical nosetip.</p><p dir="ltr">The focus of this work then shifted to measurements of the roughness that was applied</p><p dir="ltr">by others to the hemisphere nose tip for a blunt ogive. Utilizing the Zygo ZeGage 3D optical</p><p dir="ltr">profiler, roughness scans were collected both directly under the profiler head and indirectly</p><p dir="ltr">using rubber molds. Profilometer measurements were also recorded. Twelve iterations were</p><p dir="ltr">completed to allow the polisher to develop appropriate procedures for applying the roughness,</p><p dir="ltr">given the material and curvature. The first five iterations involved roughness applied to</p><p dir="ltr">cylindrical-shaped test areas. After achieving the target roughnesses on these test areas,</p><p dir="ltr">the hemispherical ends of test specimens were then polished and measured until both the</p><p dir="ltr">rough and smooth halves met the roughness target. During this time, the three roughness measurement</p><p dir="ltr">techniques were refined until good agreement was reached between them. When the roughness-application and </p><p dir="ltr">roughness-measurement techniques were sufficiently mature,</p><p dir="ltr">the actual blunt-ogive nose tip was then polished until the roughness target was achieved.</p>